CN102197808A - Cycloxaprid water dispersible granule and preparation method thereof - Google Patents
Cycloxaprid water dispersible granule and preparation method thereof Download PDFInfo
- Publication number
- CN102197808A CN102197808A CN2011100810471A CN201110081047A CN102197808A CN 102197808 A CN102197808 A CN 102197808A CN 2011100810471 A CN2011100810471 A CN 2011100810471A CN 201110081047 A CN201110081047 A CN 201110081047A CN 102197808 A CN102197808 A CN 102197808A
- Authority
- CN
- China
- Prior art keywords
- water dispersible
- dispersible granules
- epoxy worm
- worm pyridine
- mixing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of insecticide, and discloses a cycloxaprid water dispersible granule, and a preparation method thereof. The water dispersible granule comprises an effective component of cycloxaprid. The preparation method comprises: adding a moistening agent, a dispersing agent, an adsorbent, a disintegrating agent, a binder, a stabilizing agent and a carrier to the cycloxaprid; uniformly mixing the mixture; carrying out air jet pulverization to prepare a wettable powder; carrying out kneading, pelletizing, drying and screening to obtain products. The cycloxaprid water dispersible granule provided by the present invention is one of agricultural formulations of the cycloxaprid, and has advantages of quick disintegrating, good dispersibility, high suspending rate, good stability, easy storing, convenient using and no requirement of solvent. In addition, with the present invention, active ingredients are protected such that the active ingredients can play a role.
Description
Technical field
The present invention relates to a kind of epoxy worm pyridine formulation and preparation method thereof, particularly epoxy worm pyridine water dispersible granules and preparation method thereof.
Background technology
The pyridine of epoxy worm is a kind of high activity, the hypotoxic agricultural insecticide of East China University of Science's research invention.The pyridine of epoxy worm is efficient to homoptera pest, lepidoptera pest also had the anti-effect of holding concurrently, particularly great insect brown planthopper of paddy rice and exotic invasive insect Bemisia tabaci are had good control efficiency, can be used for the control of insects such as cabbage aphid, diamond-back moth, rice leaf roller in addition.Synthetic and the purposes of epoxy worm pyridine has at present been applied for Chinese invention patent and International PCT patent, and relevant epoxy worm pyridine formulation yet there are no relevant report.
Summary of the invention
So one of technical problem to be solved by this invention is providing a kind of epoxy worm pyridine water dispersible granules at the deficiencies in the prior art; this epoxy worm pyridine water dispersible granules is a kind of of the agricultural formulation of epoxy worm pyridine; has fast, the good dispersion of disintegration; suspensibility height, good stability, be beneficial to storage, easy to use, do not need solvent, protection active ingredient characteristics such as play a role.
Two of technical problem to be solved by this invention is to provide the preparation method of above-mentioned epoxy worm pyridine water dispersible granules.
Epoxy worm pyridine water dispersible granules as first aspect present invention is characterized in that, comprises the pyridine of active ingredient epoxy worm, and formulation is a water dispersible granules.
Described epoxy worm pyridine water dispersible granules also comprises auxiliary agent and carrier.
Described auxiliary agent is one or both and the two or more mixing in wetting agent, dispersant, adsorbent, disintegrant, binding agent, the stabilizing agent.
In a preferred embodiment of the invention, raw material total amount in epoxy worm pyridine water dispersible granules is 100%, the weight proportion of each raw material is: epoxy worm pyridine 2～90%, wetting agent 1～10%, dispersant 2～15%, adsorbent 1～5%, disintegrant 0～10%, binding agent 1～10%, stabilizing agent 1～10%, all the other are carrier.
In above-mentioned specific embodiment, described wetting agent is a kind of or both combinations in anionic surfactant, the nonionic surface active agent.
Described anionic surfactant is one or both and the two or more mixing of drawing back in powder, lauryl sodium sulfate, NNO, lignosulfonates, the calcium dodecyl benzene sulfonate.
Described nonionic surface active agent is one or both and the two or more combination in alkyl polyoxyethylene ether OP series, 602 series, 1601 series, the By series.
Described dispersant is anionic surfactant, nonionic surface active agent, water-soluble high-molecular substance, inorganic dispersant, sulfite paper slurries and does one or both and two or more mixing in the solid natural products.
Described anionic surfactant is one or both and the two or more mixing in Sulfonates, polycarboxylic acid salt, the phosphoric acid salt.
Described nonionic surface active agent is polyoxyethylene polyoxyethyl propyl ether block copolymers or alkylphenol-polyethenoxy base phosphate.
Described water-soluble high-molecular substance is one or both and the two or more mixing in polyvinyl alcohol, polyethylene glycol, the polyvinylpyrrolidone.
Described inorganic dispersant is a condensed phosphate.
Described Sulfonates is one or both and the two or more mixing in the alkylaryl sulfonates of naphthalene sulfonate, alkyl formaldehyde condensation products sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base sulfonate, lignin and derivative sulfonate thereof, polymerization.
Described polycarboxylic acid salt is a Sodium Polyacrylate.
Described phosphoric acid salt is one or both the combination in fatty alcohol ethylene oxide adduct phosphate, the alkylphenol-polyethenoxy base ether phosphate salt.
Described adsorbent is one or both and the two or more mixing in diatomite, attapulgite, calcium carbonate, white carbon, thenardite, the avicel cellulose etc.
Described disintegrant is one or both and the two or more mixing in urea, ammonium sulfate, calcium chloride, sodium chloride, magnesium chloride and the aluminium chloride.
Described binding agent is one or both and the two or more mixing in soluble starch, dextrin, gum Arabic and the polyvinyl acetate.
Described stabilizing agent is sodium hydroxide, sodium carbonate, sodium bicarbonate, one or both in benzoic acid, the citric acid and two or more mixing.
Described carrier is one or both and the two or more mixing in diatomite, white carbon, bentonite, kaolin, precipitated calcium carbonate and the attapulgite.
Epoxy worm pyridine water dispersible granules preparation method as second aspect present invention; be with the pyridine of epoxy worm, wetting agent, dispersant, adsorbent, disintegrant, binding agent, stabilizing agent and carrier in proportion behind the mixing; comminution by gas stream; make wetting powder,, add in the kneader simultaneously and mediate wetting powder and quantitative water; make plastic material; send this material to Squeezinggranulator at last, carry out granulation, obtain the water dispersible granules product by dry, screening.
Stable under the storage requirement of epoxy worm pyridine water dispersible granules of the present invention " 2.3 " acceleration storage test method prescribed limit in standard GB/T 19136-2003, controlling object comprises insects such as rice fulgorid, leafhopper.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer and more definite, below in conjunction with example the present invention is done to describe in further detail, describe only limiting to better explain the present invention herein, and be not used in qualification the present invention.Embodiment provides the prescription of part epoxy worm pyridine water dispersible granules for the technical staff, and the technical staff can prepare with reference to these prescriptions.
Embodiment 1
By weight percentage epoxy worm pyridine 50%, lauryl sodium sulfate 3%, sodium lignin sulfonate 6%, white carbon 5%, urea 3%, soluble starch 1%, sodium carbonate 3%, diatomite are complemented to 100%; mixed airflow is pulverized; after adding the water kneading; add again and carry out granulation in the comminutor, then drying, sieve epoxy worm pyridine water dispersible granules.
Embodiment 2
By weight percentage epoxy worm pyridine 70%, lauryl sodium sulfate 4%, calcium lignosulfonate 7%, white carbon 5%, urea 3%, soluble starch 1%, sodium bicarbonate 5%, kaolin are complemented to 100%; mixed airflow is pulverized; after adding the water kneading; add again and carry out granulation in the comminutor, then drying, sieve epoxy worm pyridine water dispersible granules.
Embodiment 3
Epoxy worm pyridine field efficacy is measured:
With the 50% epoxy worm pyridine WG of embodiment 1 with 22.5g a.i./hm
2, 30.0g a.i./hm
2, 37.5ga.i./hm
2Prevent and treat the rice fulgorid in the paddy field, the investigation dispenser after 1 day, 5 days, 15 days, 30 days control efficiency to rice fulgorid.Investigation result compares with the contrast medicament, and 50% epoxy worm pyridine WG has preventive effect preferably to the paddy rice brown planthopper, has long characteristics of lasting period, and to rice safety, the results are shown in Table 1.
Table 1 50% epoxy worm pyridine WG control paddy rice brown planthopper field control effectiveness test result
With 3000,5000,20000 times of controls of the 70% epoxy worm pyridine WG of embodiment 2 dilution grape leafhoppers, after the investigation dispenser 1 day, 3 days, 7 days, 14 days control efficiency.Experiment shows that 70% epoxy worm pyridine WG has higher preventive effect to the grape leafhopper nymph, and in time the preventive effect of each chemicals treatment of prolongation all improves behind the medicine, illustrate that this medicament has lasting effect preferably, and this medicament the results are shown in Table 2 to grape growth safety.
Table 2 70% epoxy worm pyridine WG field efficacy
Claims (21)
1. epoxy worm pyridine water dispersible granules is characterized in that, comprises the pyridine of active ingredient epoxy worm, and formulation is a water dispersible granules.
2. epoxy worm pyridine water dispersible granules as claimed in claim 1 is characterized in that, also comprises auxiliary agent and carrier.
3. epoxy worm pyridine water dispersible granules as claimed in claim 2 is characterized in that, described auxiliary agent is one or both and the two or more mixing in wetting agent, dispersant, adsorbent, disintegrant, binding agent, the stabilizing agent.
4. epoxy worm pyridine water dispersible granules as claimed in claim 3, it is characterized in that, raw material total amount in epoxy worm pyridine water dispersible granules is 100%, the weight proportion of each raw material is: epoxy worm pyridine 2～90%, wetting agent 1～10%, dispersant 2～15%, adsorbent 1～5%, disintegrant 0～10%, binding agent 1～10%, stabilizing agent 1～10%, all the other are carrier.
5. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that, described wetting agent is a kind of or both combinations in anionic surfactant, the nonionic surface active agent.
6. epoxy worm pyridine water dispersible granules as claimed in claim 5, it is characterized in that described anionic surfactant is one or both and the two or more mixing of drawing back in powder, lauryl sodium sulfate, NNO, lignosulfonates, the calcium dodecyl benzene sulfonate.
7. epoxy worm pyridine water dispersible granules as claimed in claim 5 is characterized in that, described nonionic surface active agent is one or both and the two or more combination in alkyl polyoxyethylene ether OP series, 602 series, 1601 series, the By series.
8. epoxy worm pyridine water dispersible granules as claimed in claim 4, it is characterized in that described dispersant is anionic surfactant, nonionic surface active agent, water-soluble high-molecular substance, inorganic dispersant, sulfite paper slurries and does one or both and two or more mixing in the solid natural products.
9. epoxy worm pyridine water dispersible granules as claimed in claim 8 is characterized in that, described anionic surfactant is one or both and the two or more mixing in Sulfonates, polycarboxylic acid salt, the phosphoric acid salt.
10. epoxy worm pyridine water dispersible granules as claimed in claim 8 is characterized in that, described nonionic surface active agent is polyoxyethylene polyoxyethyl propyl ether block copolymers or alkylphenol-polyethenoxy base phosphate.
11. epoxy worm pyridine water dispersible granules as claimed in claim 8 is characterized in that, described water-soluble high-molecular substance is one or both and the two or more mixing in polyvinyl alcohol, polyethylene glycol, the polyvinylpyrrolidone.
12. epoxy worm pyridine water dispersible granules as claimed in claim 8 is characterized in that described inorganic dispersant is a condensed phosphate.
13. epoxy worm pyridine water dispersible granules as claimed in claim 9, it is characterized in that described Sulfonates is one or both and the two or more mixing in the alkylaryl sulfonates of naphthalene sulfonate, alkyl formaldehyde condensation products sulfonate, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base sulfonate, lignin and derivative sulfonate thereof, polymerization.
14. epoxy worm pyridine water dispersible granules as claimed in claim 9 is characterized in that described polycarboxylic acid salt is a Sodium Polyacrylate.
15. epoxy worm pyridine water dispersible granules as claimed in claim 9 is characterized in that, described phosphoric acid salt is one or both the combination in fatty alcohol ethylene oxide adduct phosphate, the alkylphenol-polyethenoxy base ether phosphate salt.
16. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that, described adsorbent is one or both and the two or more mixing in diatomite, attapulgite, calcium carbonate, white carbon, thenardite, the avicel cellulose etc.
17. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that, described disintegrant is one or both and the two or more mixing in urea, ammonium sulfate, calcium chloride, sodium chloride, magnesium chloride and the aluminium chloride.
18. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that, described binding agent is one or both and the two or more mixing in soluble starch, dextrin, gum Arabic and the polyvinyl acetate.
19. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that described stabilizing agent is sodium hydroxide, sodium carbonate, sodium bicarbonate, one or both in benzoic acid, the citric acid and two or more mixing.
20. epoxy worm pyridine water dispersible granules as claimed in claim 4 is characterized in that, described carrier is one or both and the two or more mixing in diatomite, white carbon, bentonite, kaolin, precipitated calcium carbonate and the attapulgite.
21. method for preparing the described epoxy worm of claim 2 pyridine water dispersible granules; be with the pyridine of epoxy worm, wetting agent, dispersant, adsorbent, disintegrant, binding agent, stabilizing agent and carrier in proportion behind the mixing; comminution by gas stream; make wetting powder,, add in the kneader simultaneously and mediate wetting powder and quantitative water; make plastic material; send this material to Squeezinggranulator at last, carry out granulation, obtain the water dispersible granules product by dry, screening.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110081047 CN102197808B (en) | 2011-03-31 | 2011-03-31 | Cycloxaprid water dispersible granule and preparation method thereof |
| PCT/CN2012/076299 WO2012130190A1 (en) | 2011-03-31 | 2012-05-30 | Water dispersible cycloxaprid granules and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110081047 CN102197808B (en) | 2011-03-31 | 2011-03-31 | Cycloxaprid water dispersible granule and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102197808A true CN102197808A (en) | 2011-09-28 |
| CN102197808B CN102197808B (en) | 2013-10-30 |
Family
ID=44658998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110081047 Active CN102197808B (en) | 2011-03-31 | 2011-03-31 | Cycloxaprid water dispersible granule and preparation method thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN102197808B (en) |
| WO (1) | WO2012130190A1 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102405918A (en) * | 2011-12-25 | 2012-04-11 | 上海生农生化制品有限公司 | Cycloxaprid water dispersible tablets and preparation method thereof |
| WO2012130190A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Water dispersible cycloxaprid granules and preparation method thereof |
| WO2012130189A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Wettable powder of cycloxaprid and preparation method thereof |
| WO2012130191A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Suspension concentrate of cycloxaprid and preparation method thereof |
| CN102960347A (en) * | 2012-12-14 | 2013-03-13 | 江苏七洲绿色化工股份有限公司 | Bactericidal composition containing prothioconazole and trifloxystrobin |
| CN104082318A (en) * | 2014-07-18 | 2014-10-08 | 江苏省绿盾植保农药实验有限公司 | Composite insecticide containing ethylicin and cycloxaprid and application of composite insecticide |
| CN106472538A (en) * | 2016-10-12 | 2017-03-08 | 佛山迅拓奥科技有限公司 | A kind of cycloxaprid and carbamide compound synergic insecticide |
| CN108323522A (en) * | 2018-04-11 | 2018-07-27 | 佛山市普尔玛农化有限公司 | A kind of novel Pesticidal combination |
| CN114426553A (en) * | 2020-10-16 | 2022-05-03 | 华东理工大学 | Eutectic crystal and solvate of cycloxaprid and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268290A (en) * | 2000-04-25 | 2000-10-04 | 江苏省农药研究所 | Granulating method of pesticide water-dispersing granules preparation |
| CN1741740A (en) * | 2003-01-23 | 2006-03-01 | 日本曹达株式会社 | Water dispersible granules for agricultural and horticultural use |
| CN1957696A (en) * | 2006-10-20 | 2007-05-09 | 新沂市中港农用化工有限公司 | Water dispersion granules of pesticide, and preparation method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101747320B (en) * | 2008-12-19 | 2013-10-16 | 华东理工大学 | Dialdehyde-built nitrogen or oxygen-containing heterocyclic compound with insect-killing activity and preparation method |
| CN102093389B (en) * | 2009-12-09 | 2014-11-19 | 华东理工大学 | Duplex and oxygen bridge heterlcyclic ring anabasine compound and preparation method thereof |
| CN102197808B (en) * | 2011-03-31 | 2013-10-30 | 上海生农生化制品有限公司 | Cycloxaprid water dispersible granule and preparation method thereof |
-
2011
- 2011-03-31 CN CN 201110081047 patent/CN102197808B/en active Active
-
2012
- 2012-05-30 WO PCT/CN2012/076299 patent/WO2012130190A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1268290A (en) * | 2000-04-25 | 2000-10-04 | 江苏省农药研究所 | Granulating method of pesticide water-dispersing granules preparation |
| CN1741740A (en) * | 2003-01-23 | 2006-03-01 | 日本曹达株式会社 | Water dispersible granules for agricultural and horticultural use |
| CN1957696A (en) * | 2006-10-20 | 2007-05-09 | 新沂市中港农用化工有限公司 | Water dispersion granules of pesticide, and preparation method |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012130190A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Water dispersible cycloxaprid granules and preparation method thereof |
| WO2012130189A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Wettable powder of cycloxaprid and preparation method thereof |
| WO2012130191A1 (en) * | 2011-03-31 | 2012-10-04 | 上海生农生化制品有限公司 | Suspension concentrate of cycloxaprid and preparation method thereof |
| CN102405918A (en) * | 2011-12-25 | 2012-04-11 | 上海生农生化制品有限公司 | Cycloxaprid water dispersible tablets and preparation method thereof |
| CN102960347A (en) * | 2012-12-14 | 2013-03-13 | 江苏七洲绿色化工股份有限公司 | Bactericidal composition containing prothioconazole and trifloxystrobin |
| CN104082318A (en) * | 2014-07-18 | 2014-10-08 | 江苏省绿盾植保农药实验有限公司 | Composite insecticide containing ethylicin and cycloxaprid and application of composite insecticide |
| CN106472538A (en) * | 2016-10-12 | 2017-03-08 | 佛山迅拓奥科技有限公司 | A kind of cycloxaprid and carbamide compound synergic insecticide |
| CN108323522A (en) * | 2018-04-11 | 2018-07-27 | 佛山市普尔玛农化有限公司 | A kind of novel Pesticidal combination |
| CN114426553A (en) * | 2020-10-16 | 2022-05-03 | 华东理工大学 | Eutectic crystal and solvate of cycloxaprid and preparation method thereof |
| CN114426553B (en) * | 2020-10-16 | 2023-08-01 | 华东理工大学 | Eutectic and solvate of cycloxaprid and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012130190A1 (en) | 2012-10-04 |
| CN102197808B (en) | 2013-10-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102197808B (en) | Cycloxaprid water dispersible granule and preparation method thereof | |
| CN102197807A (en) | Cycloxaprid wettable powder and preparation method thereof | |
| CN101999346B (en) | Emulsifiable granule containing etofenprox composition and preparation method thereof | |
| CN102228043A (en) | Bactericide water dispersible granules compounded from difenoconazole and pyraclostrobin and preparation method thereof | |
| CN101176448B (en) | Bismerthiazol water dispersible granula bactericide and preparation method thereof | |
| CN101518242B (en) | Emamectin benzoate-hexaflumuron water dispersible granule and preparation method thereof | |
| CN102369922A (en) | Pyrazosulfuron water dispersible granule and preparation method thereof | |
| CN100588322C (en) | Tebuconazole water dispersible granule and preparation method thereof | |
| CN101642105B (en) | Uniconazole water dispersible granules and preparation method thereof | |
| CN101971829B (en) | Chlorantraniliprole and azadirachtin complex water dispersible granule and preparation method thereof | |
| CN102217638A (en) | Pesticide composition for preventing and treating plant virus diseases | |
| CN102228025A (en) | Pesticide composition containing cytosinpeptidemycin and lentinan | |
| CN101204153A (en) | Triflumizole water dispersant and preparation method thereof | |
| CN101971830B (en) | Chlorantraniliprole and rotenone complex insecticidal water dispersible granule and preparation method thereof | |
| CN102047877A (en) | Cyhalofop-butyl water-dispersible granule and preparation method thereof | |
| CN102754649A (en) | Sterilizing composition containing phenylate bi (imidazole) and epoxiconazole | |
| CN102228036A (en) | Pesticide composition containing strobilurin fungicide | |
| CN101485324A (en) | Agricultural insecticide containing flufenoxuron | |
| CN102669138A (en) | Water dispersible granule formulated by azoxystrobin and cymoxanil and preparation method thereof | |
| CN101167462A (en) | Diniconazole water dispersible granule and preparation method thereof | |
| CN104304253A (en) | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use | |
| CN101167464B (en) | Clofentezine water dispersible granule and preparation method thereof | |
| CN104522034A (en) | Compound granule for direct broadcasting and application | |
| CN102258048A (en) | Imidacloprid water dispersible granules | |
| CN103843798A (en) | Pesticide composition containing aureonucleomycin and strobilurin fungicide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Songjiang District Jing Dong Zhen Dong Zhou road 201619 Shanghai City No. 51 Patentee after: Shanghai biochemical products Limited by Share Ltd Patentee after: East China University of Science and Technology Address before: Songjiang District Jing Dong Zhen Dong Zhou road 201619 Shanghai City No. 51 Patentee before: Shengnong Biological-Chemical Products Co., Ltd., Shanghai Patentee before: East China University of Science and Technology |