CN104304253A - Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use - Google Patents
Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use Download PDFInfo
- Publication number
- CN104304253A CN104304253A CN201410468659.XA CN201410468659A CN104304253A CN 104304253 A CN104304253 A CN 104304253A CN 201410468659 A CN201410468659 A CN 201410468659A CN 104304253 A CN104304253 A CN 104304253A
- Authority
- CN
- China
- Prior art keywords
- chlorfenapyr
- zen
- composition pesticide
- seed
- active component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use. The pesticide composition contains active components of chlorfenapyr and picoxystrobin and a weight ratio of chlorfenapyr to picoxystrobin is in a range of 1: 80 to 80: 1. The pesticide composition can be processed to form a suspending agent, emulsion in water, wettable powder, microemulsion, water dispersible granules and a seed treatment agent. The pesticide composition containing chlorfenapyr and picoxystrobin can be used for preventing and controlling plant diseases and insect pests of a plurality of crops such as cotton, vegetables, beet, soybean, grape, fruit trees and crop seeds.
Description
Technical field
The invention belongs to technical field of pesticide and have a kind of containing chlorfenapyr of synergistic effect and the composition pesticide, preparation and uses thereof of ZEN 90160, its active component is chlorfenapyr and ZEN 90160.
Background technology
ZEN 90160, english common name: Picoxystrobin, molecular formula: C
18h
16f
3nO
4, chemical name: (E)-3-methoxy-2-[2-[6-(trifluoromethyl)-2-pyridine oxygen methyl] phenyl] methyl acrylate.ZEN 90160 belongs to mitochondrial respiratory inhibitor, and its mechanism of action suppresses mitochondrial breathing by electro transfer between cytochrome b and C1.Bacterial strain 14-demethylation enzyme inhibitor, benzamides, dicarboxylic dihydrazides amine and benzimidazole being produced to resistance is effective.ZEN 90160, once be absorbed by blade, will move, flow with current in transportation system in xylem; It also flows and flows in xylem again after absorption enters blade from gas phase in the gas phase of blade surface.Be mainly used in preventing and treating foliage disease as leaf blight, leaf rust, glume blight, brown spot, powdery mildew etc., compared with existing strobilurin series bactericidal agent, have stronger result for the treatment of to leaf blight, net blotch and moire disease.
Chlorfenapyr, english common name: Chlorfenapyr, molecular formula: C
15h
11brClF
3n
2o, chemical name: 4-bromo-2-(4-chlorphenyl)-1-(ethoxyl methyl)-5-(trifluoromethyl) pyrroles-3-nitrile, this medicine is mainly with the insecticide of stomach toxicity and action of contace poison and miticide.In plant, show good conductivity, but interior absorption is poor.Chlorfenapyr is a kind of preinsecticide, itself to insect without toxic action.Insect's food-taking or contact chlorfenapyr after in insect bodies, chlorfenapyr changes concrete insecticidal active compound under the effect of mixed-functional oxidase, and its target is the mitochondria in insect bodies cell.Cell is synthesized and stops vital functions because lacking energy, after laxative, pest activity dies down, and occur spot, color changes, movable stopping, and stupor is weak and limp, finally causes death.Be mainly used in the control of the serious insect of the Lepidoptera on vegetables, tea tree, fruit tree, Semiptera, mite and resistance, excellent control efficiency is had to brill moth, sucking and chewing type insect and mite class, especially antagonism diamond-back moth and beet armyworm etc. have special efficacy, comprising the insect and the evil mite that carbamate, organic phosphor and chrysanthemum ester insecticide are produced to resistance.
Because the Long-Time Service of single-activity component at crop pest control easily develops immunity to drugs, cause drug effect to reduce, be unfavorable for the Long-Time Service of this medicine, drug cost increases simultaneously, and the mixture of different pesticide species, be the common methods of preventing and treating agriculture resistance disease pest and weed.Being screened by formulation of pesticide, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the drug-fast generation of disease pest and weed, extend the service life of medicament, is the important means that agricultural synthesis is administered.Inventor is found by test; by chlorfenapyrs different for the mechanism of action and ZEN 90160 composite; it is unexpected that discovery said composition have synergistic effect significantly; the control efficiency for the treatment of, protection can be improved significantly; decrease usage amount and the spraying times of agricultural chemicals simultaneously; effectively slow down the generation of resistance, reach the double effect controlled of effect of holding concurrently.
At present, chlorfenapyr and ZEN 90160 composite and be applied in and have no report both at home and abroad.
Summary of the invention
The object of the present invention is to provide a kind of mixture reasonable, the composition pesticide, preparation and uses thereof of the containing chlorfenapyr that control efficiency is good and ZEN 90160, sterilization and disinsection simultaneously can be reached, reduce environmental pollution, reduce the object of labour cost.The present invention is achieved through the following technical solutions:
Containing a composition pesticide of planting chlorfenapyr and ZEN 90160, comprise active component, the active component of described composition pesticide is the binary built of chlorfenapyr and ZEN 90160, and wherein the weight ratio of active component chlorfenapyr and ZEN 90160 is 1:80 ~ 80:1.
The weight ratio of described chlorfenapyr and ZEN 90160 is preferably 1:70 ~ 70:1.
Described composition adds auxiliary agent and is made into one in suspending agent, aqueous emulsion, wetting powder, microemulsion, water dispersible granules and the seed treatment agriculturally allowed.
The weight percentage of described active component is 0.1% ~ 90% of described composite preparation gross weight.
The weight percentage of described active component is preferably 1% ~ 70% of described composite preparation gross weight.
Auxiliary agent in pesticide combination preparation of the present invention includes but not limited to one or more the mixture in emulsifier, wetting agent, dispersant, thickener, co-emulsifier, disintegrant, solvent, film forming agent, defoamer, antifreezing agent, filler.
Described dispersant be selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalenesulfonateformaldehyde formaldehyde amine condensation product sodium salt, alkylphenol polyoxyethylene, polyoxyethylene carboxylate, ester APEO one or more.
Described wetting agent is selected from: lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, AEO series, spaonin powder, sldium lauryl sulfate, tea are withered, one or more in silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, glucose, aluminium chloride.
Described antifreezing agent is selected from: one or more in ethylene glycol, propane diols, glycerine, polyethylene glycol.
Described defoamer adopts C
8 ~ 10aliphatic alcohols, C
10 ~ 20one or more in saturated fat acids and acid amides, organic silicone oil, silicone compound.
Described emulsifier be selected from alkyl benzene sulfonate calcium salt, styrene polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, ethylene oxide-propylene oxide block copolymer, triethanolamine salt, phenethyl phenol polyethenoxy ether, agriculture breast 400#, 506#, 600#, 700#, NP-10 phosphate, OP-10 phosphate, castor oil polyoxyethylene ether, sorbester p17, Tween 80,602# one or more, emulsifier is purchased from Jiangsu Hai'an Petrochemical Plant.
Described co-emulsifier is one or more in butanols, isobutanol, dodecanol, tetradecanol, octadecanol.
Described solvent be selected from toluene, dimethylbenzene, methyl alcohol, ethanol, acetone, ether, cyclohexanone, vegetable oil, dimethyl formamide, acetonitrile, polyethylene glycol, ethyl acetate, pyrrolidones, solvent N-chain alkyl pyrrolidones one or more.
Described film forming agent is selected from: one or more in polyvinyl alcohol, polyvinyl acetate, carboxymethyl cellulose, gum Arabic, gelatin, xanthans, starch.
Described binding agent/or thickener are selected from: one or more in xanthans, aluminium-magnesium silicate, sodium alginate, bentonite, polyvinylpyrrolidone, polyvinyl alcohol, PAA, sodium propionate.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Containing a composition pesticide purposes for kind of chlorfenapyr and ZEN 90160, described composition pesticide is for preventing and treating the damage by disease and insect of cotton, vegetables, beet, soybean, grape, fruit tree and crop seed.
Containing a composition pesticide purposes for kind of chlorfenapyr and ZEN 90160, it is characterized in that: described composition pesticide as seed treatment, by the method treatment of plant propagation material of seed soaking, seed dressing or seed pelleting.
Composition pesticide of the present invention has sterilization and disinsection characteristic concurrently, especially to Oomycete, Ascomycetes, deuteromycetes class germ and to boring moth, to suck and chewing type insect and mite class have excellent control efficiency, may be used for various crop as cotton, vegetables, beet, soybean, grape, fruit tree etc.
The composition pesticide of a kind of containing chlorfenapyr of the present invention and ZEN 90160, can be used for seed treatment, by seed soaking, seed dressing or the method treatment of plant propagation material of seed pelleting.
Beneficial effect of the present invention is:
(1) composition pesticide of the present invention has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.
(2) utilize reactive compound ZEN 90160 of the present invention to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.
(3) present composition is compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.
(4) in the present composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment
Below by specific embodiment, the invention will be further described, but the present invention not limited by following examples, and adding of each component is measured by weight.
Embodiment 1
50% chlorfenapyr ZEN 90160 suspending agent
A kind of composition pesticide suspending agent containing planting chlorfenapyr and ZEN 90160 of the present embodiment, the percentage by weight formula of its component is: 20% chlorfenapyr, 30% ZEN 90160,10% polycarboxylate, 5% sldium lauryl sulfate, 0.5% silicone compound, 1% PAA, 2% glycerine, 31.5% water, take water as medium, active component and auxiliary agent are added in sand mill and grind, then emulsification in high-shear emulsifying still is added, obtained suspending agent.The suspending agent the key technical indexes of the present embodiment is shown in Table 1, and from table 1, the obtained suspending agent indices of embodiment 1 all meets Pesticidal products specification requirement, and properties of product are stablized, suspension is good, fineness is high, heat storage stability and low-temperature stability strong.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 2
24% chlorfenapyr ZEN 90160 aqueous emulsion
A kind of composition pesticide aqueous emulsion containing planting chlorfenapyr and ZEN 90160 of the present embodiment, the percentage by weight formula of its component is: 10% chlorfenapyr, 14% ZEN 90160,5% ethyl acetate, 5% vegetable oil, 3% agriculture breast 400#, 6% ethylene oxide-propylene oxide block copolymer, 2% polyethylene glycol, 2% sodium propionate, 0.5% silicone oil, 52.5% water, active component and auxiliary agent are dissolved into homogeneous oil phase, add water under high-speed stirred, namely form the aqueous emulsion of favorable dispersibility.The aqueous emulsion the key technical indexes of the present embodiment is shown in Table 2, and the aqueous emulsion the key technical indexes of the present embodiment is shown in Table 2.From table 2, the aqueous emulsion indices that embodiment 2 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and heat storage stability is good, low-temperature stability is good.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 3
30% chlorfenapyr ZEN 90160 wetting powder
A kind of composition pesticide wetting powder containing planting chlorfenapyr and ZEN 90160 of the present embodiment, the percentage by weight formula of its component is: 25% chlorfenapyr, 5% ZEN 90160,9% naphthalene sulfonic acid-formaldehyde condensation product sodium salt, 5% tea are withered, 56% kaolin, namely obtain wetting powder through ultra-fine pulverizer disintegrating.The wetting powder the key technical indexes of the present embodiment is shown in Table 3, from table 3, the wetting powder indices that embodiment 3 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and good dispersion, suspensibility are high, fineness is excellent, water content is low, MEBO ribbon gauze is short.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 4
25% chlorfenapyr ZEN 90160 microemulsion
A kind of composition pesticide microemulsion containing planting chlorfenapyr and ZEN 90160 of the present embodiment, the percentage by weight formula of its component is: 8% chlorfenapyr, 17% ZEN 90160,5% acetone, 4% acetonitrile, 1.5% ethylene glycol, 2% polyvinyl alcohol, 5% agriculture breast 600#, 4%AEO series, 0.5% silicone compound, 53% water, obtained microemulsion.The microemulsion the key technical indexes of the present embodiment is shown in Table 4, and the microemulsion the key technical indexes of the present embodiment is shown in Table 4.From table 4, the microemulsion indices that embodiment 4 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and heat storage stability is good, low-temperature stability is good.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 5
62% chlorfenapyr ZEN 90160 water dispersible granules
A kind of composition pesticide water dispersible granules containing planting chlorfenapyr and ZEN 90160 of the present embodiment; the percentage by weight formula of its component is: 60% chlorfenapyr, 2% ZEN 90160,8% polycarboxylate, 7% wetting and penetrating agent F, 3% ammonium sulfate, 20% diatomite; the adjuvant such as active component, filler is mixed; pulverize through micro jet; then add the granulation on comminutor of appropriate water again, in drying box, drying obtains water dispersible granules.The water dispersible granules the key technical indexes of the present embodiment is shown in Table 5, from table 5, the water dispersible granules indices that embodiment 5 obtains all meets Pesticidal products specification requirement, and properties of product are stablized, and good dispersion, suspensibility are high, fineness is excellent, water content is low, MEBO ribbon gauze is short.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 6
30% chlorfenapyr ZEN 90160 suspension seed-coating agent
A kind of composition pesticide suspension seed-coating agent containing planting chlorfenapyr and ZEN 90160 of the present embodiment, the percentage by weight formula of its component is: 20% chlorfenapyr, 10% ZEN 90160,15% agriculture breast 600#, 2% neopelex, 0.5% polyvinyl acetate, 3.0% n-octyl alcohol, 3.0% glycerine, 0.5% Rosa Damascana, 46% water, active component, emulsifier, dispersant are put into sand mill and ground 2h, again by other auxiliary agents such as film forming agent, stabilizing agent grinding 1h, filter and obtain suspension seed-coating agent.The suspension seed-coating agent the key technical indexes of the present embodiment is shown in Table 6, and from table 6 result, the suspension seed-coating agent indices that embodiment 6 obtains all meets the requirement of suspension seed-coating agent, and properties of product are stablized, less by low temperature effect, and expulsion rate is low.
The composition pesticide of the present embodiment has sterilization and disinsection characteristic concurrently, expands application target and effect, and has special interior absorption, has well treatment and protective effect to crop.Utilize the present embodiment reactive compound ZEN 90160 to have interior absorption, not only protect seed itself during process seed but also the plant that obtains after protecting rudiment avoids the invasion and attack of disease, when can save sowing or the short period interior to crop dispenser immediately.The present embodiment composition, compared with independent reactive compound, has synergistic function, decreases the use of agricultural chemicals, reduces the use cost of peasant, decreases the pollution to environment simultaneously.In the present embodiment composition there is not cross resistance problem in each active component, and can reaching of said composition delays the drug-fast generation of pathogen and development, contributes to the application effect extending this medicament, reduces pesticide resistance and produce probability.
Embodiment 7
Application method: field trial
Experimental subjects: cucumber downy mildew, phytophthora root rot of soybean, water melon frost mildew.
Present composition bactericidal range is better than one-component bactericidal effect, and the synergy of composition is obvious especially, and can delay the pesticide resistance of pathogen to ZEN 90160.Field experiment shows, improves more than 20% to the preventive and therapeutic effect of disease.
Application 1: the effect of ZEN 90160 and chlorfenapyr composition field control cucumber downy mildew, is shown in Table 7.
Application 2: the effect of ZEN 90160 and chlorfenapyr composition field control phytophthora root rot of soybean, is shown in Table 8.
Application 3: the effect of ZEN 90160 and chlorfenapyr composition field control water melon frost mildew, is shown in Table 9.
15% ZEN 90160 wetting powder, 15% chlorfenapyr wetting powder, 15% ZEN 90160 (5%)+chlorfenapyr (10%) wetting powder and 15% ZEN 90160 (10%)+chlorfenapyr (5%) wetting powder that above-mentioned application is processed for active component with ZEN 90160 and chlorfenapyr, two single doses are compared with two composite preparations, composition is under the working concentration of dilution 4000 times, the diseases such as field control cucumber downy mildew, phytophthora root rot of soybean, water melon frost mildew, effectively can delay the pesticide resistance of pathogen to ZEN 90160.
Application 4: ZEN 90160 chlorfenapyr seed treatment processed soybeans seed-test
12% ZEN 90160 chlorfenapyr seed treatment processed soybeans seed-test.
ZEN 90160 5%, chlorfenapyr 7%, polycarboxylate 3%, lignosulfonates 4%, neopelex 4%, xanthans 3%, polyvinyl acetate 5%, alkyl benzene sulfonate calcium salt 3%, deionized water add to 100%, the obtained 12% ZEN 90160 chlorfenapyr seed treatment of mixing.This proportioning presses the seed dressing of 25g/100kg seed, in closed container, seed dressing is mixed 15 minutes with seed jolting, then by planting seed to experimental field, and in one day laggard row man-made irrigation.After planting 28 days calculate preventive effect is 100%, does not observe and infects.Contrast medicament 22.5% ZEN 90160 suspending agent and 24% chlorfenapyr are used according to same method, within after planting 28 days, calculate preventive effect and are respectively 86.3% and 18.4%.
Above-described embodiment only illustrates inventive concept of the present invention for explaining, but not the restriction to rights protection of the present invention, all changes utilizing this design the present invention to be carried out to unsubstantiality, all should fall into protection scope of the present invention.
Table 1
Table 2
Table 3
Table 4
Table 5
Table 6
Table 7
* in table, data are added up through duncan's new multiple range method, are that extreme difference is not remarkable containing same letter person
Table 8
* in table, data are added up through duncan's new multiple range method, are that extreme difference is not remarkable containing same letter person
Table 9
* in table, data are added up through duncan's new multiple range method, are that extreme difference is not remarkable containing same letter person
Claims (7)
1. one kind contains the composition pesticide of kind of chlorfenapyr and ZEN 90160, it is characterized in that: comprise active component, the active component of described composition pesticide is the binary built of chlorfenapyr and ZEN 90160, wherein the weight ratio of active component chlorfenapyr and ZEN 90160 is 1:80 ~ 80:1.
2. a kind of composition pesticide containing planting chlorfenapyr and ZEN 90160 according to claim 1, is characterized in that: the weight ratio of described chlorfenapyr and ZEN 90160 is 1:70 ~ 70:1.
3. a kind of composition pesticide preparation containing kind of chlorfenapyr and ZEN 90160 according to claim 1, is characterized in that: described composition adds auxiliary agent and is made into one in suspending agent, aqueous emulsion, wetting powder, microemulsion, water dispersible granules and the seed treatment agriculturally allowed.
4. a kind of composition pesticide preparation containing planting chlorfenapyr and ZEN 90160 according to claim 3, is characterized in that: the weight percentage of described active component is 0.1% ~ 90% of described composite preparation gross weight.
5. a kind of composition pesticide preparation containing planting chlorfenapyr and ZEN 90160 according to claim 4, is characterized in that: the weight percentage of described active component is 1% ~ 70% of described composite preparation gross weight.
6. containing a composition pesticide purposes for kind of chlorfenapyr and ZEN 90160, it is characterized in that: described composition pesticide is for preventing and treating the damage by disease and insect of cotton, vegetables, beet, soybean, grape, fruit tree and crop seed.
7., containing a composition pesticide purposes for kind of chlorfenapyr and ZEN 90160, it is characterized in that: described composition pesticide as seed treatment, by the method treatment of plant propagation material of seed soaking, seed dressing or seed pelleting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410468659.XA CN104304253A (en) | 2014-09-15 | 2014-09-15 | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410468659.XA CN104304253A (en) | 2014-09-15 | 2014-09-15 | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104304253A true CN104304253A (en) | 2015-01-28 |
Family
ID=52359691
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410468659.XA Pending CN104304253A (en) | 2014-09-15 | 2014-09-15 | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104304253A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107212027A (en) * | 2017-05-10 | 2017-09-29 | 南宁为辰科技有限公司 | A kind of pesticide synergistic composition of leaf essential oil containing camphor tree and chlorfenapyr |
| CN116210702A (en) * | 2023-03-14 | 2023-06-06 | 青岛恒宁生物科技有限公司 | Pesticide composition containing chlorfenapyr and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002003310A (en) * | 2000-06-19 | 2002-01-09 | Nippon Soda Co Ltd | Insecticidal/miticidal composition |
| WO2011039105A2 (en) * | 2009-09-29 | 2011-04-07 | Basf Se | Pesticidal mixtures |
| WO2014079813A1 (en) * | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
-
2014
- 2014-09-15 CN CN201410468659.XA patent/CN104304253A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002003310A (en) * | 2000-06-19 | 2002-01-09 | Nippon Soda Co Ltd | Insecticidal/miticidal composition |
| WO2011039105A2 (en) * | 2009-09-29 | 2011-04-07 | Basf Se | Pesticidal mixtures |
| WO2014079813A1 (en) * | 2012-11-23 | 2014-05-30 | Basf Se | Pesticidal mixtures |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107212027A (en) * | 2017-05-10 | 2017-09-29 | 南宁为辰科技有限公司 | A kind of pesticide synergistic composition of leaf essential oil containing camphor tree and chlorfenapyr |
| CN116210702A (en) * | 2023-03-14 | 2023-06-06 | 青岛恒宁生物科技有限公司 | Pesticide composition containing chlorfenapyr and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100586282C (en) | Insecticidal composition containing chlorantraniliprole and monosultap | |
| CN101703054B (en) | Insecticidal composition of Cyantraniliprole and methylamino abamectin benzoate | |
| CN107668063A (en) | Pesticidal combination containing Biphenthrin and Rynaxypyr | |
| CN102630696A (en) | Insecticidal composite containing Cyantraniliprole and anabasine compounds | |
| CN102302035B (en) | Pesticide composition containing methoxyfenozide | |
| CN102388892B (en) | Pesticide composition containing chlorantraniliprole and thiocyclam | |
| CN102599169A (en) | Tolfenpyrad-containing insecticidal composition | |
| CN102228056B (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN102232385A (en) | Insecticidal composition containing clothianidin and abamectin | |
| CN104304253A (en) | Pesticide composition containing chlorfenapyr and picoxystrobin and its preparation and use | |
| CN102696625A (en) | Sterilization composition containing difenoconazole and picoxystrobin and application of sterilization composition | |
| CN102342284A (en) | Sterilization disease-resistant composition and suspension seed coating agent thereof | |
| CN102228055A (en) | Pesticide composite containing fenazaquin | |
| CN102217633A (en) | Pesticide composition containing sulfoxaflor | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN104814031B (en) | A kind of Pesticidal combination containing butene-fipronil and clothianidin | |
| CN102805089A (en) | Insect and mite killing composition containing Cyflumetofen and emamectin benzoate | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN102228053B (en) | Pesticide composition containing novaluron and pyrethroid compound | |
| CN104351238A (en) | Pesticide composition containing picoxystrobin and pyrethroids, preparation and application thereof | |
| CN104255735A (en) | Pyridalyl and tetra-chlorantraniliprole compounded insecticidal composition | |
| CN102228048A (en) | Pesticide composition containing benzimidazole bactericide | |
| CN102428948A (en) | Pesticidal composition containing clothianidin and acetamiprid | |
| CN108391666A (en) | A kind of Pesticidal combination containing ethyl pleocidin and paichongding | |
| CN109392928A (en) | A kind of Pesticidal combination containing emamectin benzoate Yu second azoles mite nitrile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150128 |