CN102183382B - Water passive sampler of pollutants - Google Patents

Water passive sampler of pollutants Download PDF

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Publication number
CN102183382B
CN102183382B CN 201110040648 CN201110040648A CN102183382B CN 102183382 B CN102183382 B CN 102183382B CN 201110040648 CN201110040648 CN 201110040648 CN 201110040648 A CN201110040648 A CN 201110040648A CN 102183382 B CN102183382 B CN 102183382B
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China
Prior art keywords
box body
lid
adsorption film
sieve plate
passive sampler
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Expired - Fee Related
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CN 201110040648
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Chinese (zh)
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CN102183382A (en
Inventor
徐世平
曾永平
鲍恋君
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Guangzhou Institute of Geochemistry of CAS
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Guangzhou Institute of Geochemistry of CAS
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Priority to CN 201110040648 priority Critical patent/CN102183382B/en
Publication of CN102183382A publication Critical patent/CN102183382A/en
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Publication of CN102183382B publication Critical patent/CN102183382B/en
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  • Separation Using Semi-Permeable Membranes (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)

Abstract

The invention discloses a water passive sampler of pollutants, which comprises a box body and an adsorption film arranged in the box body, wherein the box body comprises a box body frame and a box cover forming a closed box body together with the box body frame; a filter screen and a filter film are arranged in the box cover in sequence, and the upper side and the lower side of the filter film are respectively provided with a sieve plate. In the invention, the adsorption film is arranged in the box body, particulate matters can be filtered by the box cover provided with the filter screen and the filter film, and thus, active organisms are prevented from entering into the box body to adhere to the adsorption film; and the sieve plates arranged at the upper side and the lower side of the filter film can protect the filter film from being damaged under the impact of water stream. The sampler can effectively prevent the water environment in the box body from being polluted by outside particulate matters and microorganisms. The sampler can be applied to the field of water sampling of pollutants.

Description

A kind of pollutant water body Passive sampler
Technical field
The present invention relates to a kind of pollutant water body sampler, particularly relate to a kind of pollutant water body Passive sampler.
Background technology
That persistence organic pollutant refers to is residual in the environment midium or long term, migration and the high toxicity hydrophobic organic accumulated in biosome, persistence organic pollutant in the environment is mainly composed and is stored in the sediment organic phase, and the natural waters such as rivers,lakes and seas preserve the carrier except conduct, the important gravitation of persistence organic pollutant migration is the important content of Research of Environmental Sciences and environmental monitoring so measure the concentration of persistence organic pollutant in the water body especially.
The water body environment organic contaminant method of sampling is divided into initiatively sampling and passive sampling two classes, passiveness sampling method comes enriched sample with the spe medium of high partition factor, need not additionaling power in the sampling process, be suitable for monitoring in the open air to be used, the passiveness sampling method of existing water pollutant mainly contains original position solid phase micro-extraction technique, Immunohistochemistry and low density polyethylene films abstraction technique.
The original position solid phase micro-extraction technique is take coating of high molecular polymer as adsorbent; use multi-hole copper tube and glass fibre membrane protection spe membrane and filtration of particulate matters, solid phase micro-extraction technique has the volume of water sample demand little, detects the low advantage of limiting the quantity of; but the extraction probe price is very expensive, and is very easily damaged.
Immunohistochemistry is that lipoid is sealed in the semi-permeable diaphragm, be enriched to the mode of biosome by water through biological membrane with similar organic compound, organic pollutants is extracted, measure after the counter-infiltration, but the lipoid that this kind detection method is used is expensive, thereby permeability biological and the particle meeting of adhesion reduction polyethylene film reduces sampling rate.
Later stage research finds that polyethylene film can adsorb object equally, so Immunohistochemistry develops into the low density polyethylene films abstraction technique, but can stick particle and microorganism in the water body in the exposed low density polyethylene films abstraction technique lowered in field environment, affect measurement result.
Summary of the invention
For addressing the above problem, the invention provides a kind of pollutant water body Passive sampler that can effectively avoid particle and microorganism in the water body.
The technical solution adopted for the present invention to solve the technical problems is:
A kind of pollutant water body Passive sampler, comprise box body and be arranged at the interior adsorption film of described box body, box body comprises that the box body framework reaches the lid that forms airtight box body with the box body framework, is provided with successively screen pack and filtering membrane in the lid, and the up and down both sides of filtering membrane are equipped with sieve plate.
Be further used as the improvement of technical solution of the present invention, sieve plate is provided with the O-ring seal that can be embedded in the lid outward.
Be further used as the improvement of technical solution of the present invention, the both ends open of box body framework is equipped with lid, and lid is provided with some spring carrier arms, is provided with fastening spring between the corresponding spring carrier arm in box body framework two ends.
Be further used as the improvement of technical solution of the present invention, be provided with the support that supports adsorption film in the box body, support comprises the support base plate and is fixed in the pillar of the support base plate both sides some equidistant arrangements vertical with the support base plate that adsorption film is arranged in an intercolumniation wound in parallel.
Be further used as the improvement of technical solution of the present invention, screen pack and lid all adopt copper product, and filtering membrane is glass fiber filter, and sieve plate is the stainless steel sieve plate.
Beneficial effect of the present invention: this invention is arranged at the adsorption film of absorbability in the box body; carry out the filtration of particle by the lid that is provided with screen pack and filtering membrane; prevent that simultaneously microorganism from entering box body and attaching on the adsorption film; sieve plate is set in the up and down both sides of filtering membrane can protects the filtering membrane can be damaged under water impact, this sampling thief can effectively avoid water environment in the box body by extraneous particle and microbial contamination.
Description of drawings
The invention will be further described below in conjunction with accompanying drawing:
Fig. 1 is integrally closed structural representation of the present invention;
Fig. 2 is lid inner filtration device synoptic diagram of the present invention;
Fig. 3 is adsorption film support synoptic diagram of the present invention.
Embodiment
With reference to Fig. 1, Fig. 2, a kind of pollutant water body Passive sampler, comprise box body and be arranged at the interior adsorption film 1 of described box body, box body comprises that box body framework 3 reaches the lid 4 that forms airtight box body with box body framework 3, be provided with successively screen pack 7 and filtering membrane 8 in the lid 4, the up and down both sides of filtering membrane 8 are equipped with sieve plate 10.
This invention is arranged at adsorption film 1 in the box body; carry out the filtration of particle by the lid 4 that is provided with screen pack 7 and filtering membrane 8; prevent that simultaneously active bio from entering box body and attaching on the adsorption film 1; sieve plate 10 is set in the up and down both sides of filtering membrane 8 can protects the filtering membrane 8 can be damaged under water impact, this sampling thief can effectively avoid water environment in the box body by extraneous particle and microbial contamination.
As the preferred embodiment of the present invention, the sieve plate 10 outer O-ring seals 9 that can be embedded in the lid 4 that are provided with.O-ring seal 9 can further seal box body framework 3 and lid 4, prevents that particle and microorganism from entering in the box body.
As the preferred embodiment of the present invention, the both ends open of box body framework 3 is equipped with lid 4, and lid 4 is provided with some spring carrier arms 5, and 5 corresponding of spring carrier arms of box body framework 3 two ends are provided with fastening spring 6.
The lid 4 of box body framework 3 both sides is interior all need to arrange filtration unit; box body is set to the combination of box body framework 3 with the lid 4 at box body framework 3 two ends of both ends open; can be beneficial to the exchange of the interior water body of box and extraneous water body; spring 6 tightly is hung on the spring carrier arm 5 that is arranged on the two ends lid 4; a plurality of springs 6 are beneficial to better protection box body, make its driving fit more firm.
As shown in Figure 3, as the preferred embodiment of the present invention, be provided with the support 2 that supports adsorption film 1 in the box body, support 2 comprises support base plate 21 and is fixed in the pillar 22 of the vertical some equidistant arrangements of support base plate 21 both sides and support base plate 21 that adsorption film 1 is in 22 wound in parallel arrangements of pillar.
Pillar 22 on the support 2 is perpendicular with support base plate 21, thereby the adsorption film 1 that is wound on the pillar 22 can be vertical with lid 4, support base plate 21 can make things convenient for freely passing through of water body, current filter by the filtration unit that is provided with in the two ends lid 3, arrive adsorption film 1 and carry out the pollutant sampling, adsorption film 1 is wound on the pillar 22, can effectively increase the absorption area of sampling thief, and the laying of adsorption film 1 is parallel to water (flow) direction, is conducive to flowing freely of current.
As the preferred embodiment of the present invention, screen pack 7 and lid 4 all adopt copper product, and filtering membrane 8 is glass fiber filter, and sieve plate 10 is the stainless steel sieve plate.
Filtering membrane 8 adopts glass fiber filters, and the aperture of glass fiber filter is about 0.7 micron, can effectively stop in the water body particle diameter at the particle more than 1 micron.Screen pack 7 and lid 4 all adopt copper product, and after copper screen pack 7 and lid 4 placed water body, copper produced copper ion through the peroxidating meeting, and copper ion can suppress the growth of Measures of Algae in Water Body biology, is convenient to better prevent that algae bio from adhering at sampling thief.
Certainly, the invention is not limited to above-mentioned embodiment, those of ordinary skill in the art also can make equivalent variations or replacement under the prerequisite of spirit of the present invention, the modification that these are equal to or replacement all are included in the application's claim limited range.

Claims (4)

1. pollutant water body Passive sampler, comprise box body and be arranged at the interior adsorption film (1) of described box body, it is characterized in that: be provided with the support (2) that supports described adsorption film (1) in the described box body, described support (2) comprises support base plate (21) and is fixed in the pillar (22) of the inboard two ends of support base plate (21) the some equidistant arrangements vertical with support base plate (21), described box body comprises that box body framework (3) reaches the lid (4) that forms airtight box body with box body framework (3), be provided with successively screen pack (7) and filtering membrane (8) in the described lid (4), the up and down both sides of described filtering membrane (8) are equipped with sieve plate (10), and described adsorption film (1) wound in parallel between pillar (22) is arranged.
2. pollutant water body Passive sampler according to claim 1 is characterized in that: the outer O-ring seal (9) that can be embedded in the lid (4) that is provided with of described sieve plate (10).
3. pollutant water body Passive sampler according to claim 1 and 2, it is characterized in that: the both ends open of described box body framework (3) is equipped with lid (4), described lid (4) is provided with some spring carrier arms (5), is provided with fastening spring (6) between the corresponding spring carrier arm (5) in described box body framework (3) two ends.
4. pollutant water body Passive sampler according to claim 1, it is characterized in that: described screen pack (7) and lid (4) all adopt copper product, described filtering membrane (8) is glass fiber filter, and described sieve plate (10) is the stainless steel sieve plate.
CN 201110040648 2011-02-19 2011-02-19 Water passive sampler of pollutants Expired - Fee Related CN102183382B (en)

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Application Number Priority Date Filing Date Title
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CN102183382B true CN102183382B (en) 2013-01-09

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CN102680284B (en) * 2012-05-29 2014-09-10 大连交通大学 Passive sampling device for persistent organic pollutants (POPs) in air
CN104198221B (en) * 2012-10-31 2017-02-15 中国科学院南京地理与湖泊研究所 Aquatic plant grease-cellulose acetate composite semipermeable membrane type bionic passive sampling device
US9518896B2 (en) * 2012-12-14 2016-12-13 Guangzhou Institute Of Geochemistry, Chinese Academy Of Sciences Gradually-ascending spiraled passive sampler for measuring sediment-water diffusion flux of organic pollutants
CN103048162B (en) * 2012-12-14 2015-05-06 中国科学院广州地球化学研究所 Gradually-rising spiral passive sampler for organic pollutants on water-sediment interface
CN103558059B (en) * 2013-11-04 2016-06-08 南开大学 A kind of chitosan gel rubber Passive sampler during for Heavy Metal Pollution in Water Environment of China thing controlled
CN104729878A (en) * 2013-12-24 2015-06-24 南开大学 Novel passive water body sampling technique based on supported ionic liquid
CN104977185A (en) * 2015-07-03 2015-10-14 农业部亚热带果品蔬菜质量监督检验测试中心 Farmland irrigation water sampling method
CN105043821B (en) * 2015-07-31 2017-10-13 大连理工大学 A kind of cyclodextrin is the balance Passive sampler of adsorbent
CN105158018B (en) * 2015-08-11 2017-12-26 中国科学院生态环境研究中心 A kind of pellicle continuous sampling device for the sampling of water body passive type
CN105417617B (en) * 2015-12-21 2018-05-29 浙江大学 A kind of passive adsorption sampling apparatus for Organic Pollutants In Water
CN105699566B (en) * 2016-01-05 2018-03-13 南京大学 A kind of sampling determination method of macrolide antibiotics in measure water body
CN106442012B (en) * 2016-11-23 2019-09-24 华中农业大学 A kind of Portable manual nutsch filter for collecting water body particulate organic matter
CN106908279B (en) * 2017-04-11 2019-05-07 陇南市凯信安全检测有限公司 A kind of environmental monitoring water sampler
CN108507830B (en) * 2018-07-16 2024-03-26 未名环境分子诊断(常熟)有限公司 Passive sampler and sampling method for collecting nonpolar organic pollutants in sewer
CN108801675B (en) * 2018-08-07 2024-05-28 中国科学院南京地理与湖泊研究所 Device and method for collecting sediment surface subsided aquatic plant propagule library
CN109777730A (en) * 2019-02-20 2019-05-21 合肥职业技术学院 A kind of culture sampler and application method for lake water bacterium
CN110702855B (en) * 2019-10-16 2022-06-07 暨南大学 Water environment in-situ biological exposure-passive sampling combined device and method
CN110927023A (en) * 2019-11-18 2020-03-27 暨南大学 Device and method for measuring equilibrium distribution coefficient of strong hydrophobic organic matter

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