CN102181898A - On-line pretreatment device for copper-coated stainless steel wires - Google Patents

On-line pretreatment device for copper-coated stainless steel wires Download PDF

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Publication number
CN102181898A
CN102181898A CN 201110099360 CN201110099360A CN102181898A CN 102181898 A CN102181898 A CN 102181898A CN 201110099360 CN201110099360 CN 201110099360 CN 201110099360 A CN201110099360 A CN 201110099360A CN 102181898 A CN102181898 A CN 102181898A
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China
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stainless steel
liquid level
steel wire
copper
washing bath
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CN 201110099360
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CN102181898B (en
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周海军
陈炎
徐钦华
顾文祥
吴镇国
冯超
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Fasten Group Co Ltd
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Fasten Group Co Ltd
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  • Electroplating Methods And Accessories (AREA)

Abstract

The invention relates to a pretreatment device, in particular to an on-line pretreatment device for coating copper on the surfaces of stainless steel wires, and belongs to the technical field of electroplating. The pretreatment device comprises a pickling tank(1), a rinsing tank(2) and a sealed container(3), wherein the top of the rinsing tank(2) is enclosed and provided with an air inlet(5), the upper part of the rinsing tank(2) is provided with a plurality of spray headers(7), the lower part of the rinsing tank(2) is divided into a plurality of zones, the liquid level of the first zone is the lowest, and the liquid level of the last zone is the highest; the number of spray headers(7) are equal to that of ladder zones; the upper part of the first zone is provided with an overflow opening(9), while the bottom is provided with a water outlet(10); the upper part of the last zone is provided with a water inlet(8); the sealed container(3) is connected with an outlet of the rinsing tank(2); and the sealed container(3) is provided with an air outlet(6) formed above the electroplating liquid level. By the pretreatment device of the invention, a thick and stable copper-coated layer can be obtained, the bonding force between the coating and the basal body is effectively improved, and the water consumption of the rinsing tank is low.

Description

The online pretreating device of Copper Coated Stainless Steel Wire
Technical field
The present invention relates to a kind of pretreating device, especially relate to a kind of online pretreating device, belong to the electroplating technology field at the Stainless Steel Wire copper coating.
Background technology
Along with expanding economy, industry power cord such as robot calculator, medical facilities, car electrics constantly develop to lightweight and filament direction, present power cord is made by fine copper usually, but because the shortage of China's copper resource and rising steadily of copper price, caused the power cord production cost too high, manufacturers press for the new metallic substance of searching and substitute original fine copper product.In recent years, occurred a kind of Copper Coated Stainless Steel Wire that can be used for substituting original fine copper product on the market, the cost of saving copper industry resource, reduction product has been played a good role.
During the Stainless Steel Wire electro-coppering, requiring must have good bonding force between copper layer and the Stainless Steel Wire matrix, therefore must guarantee that Stainless Steel Wire has fresh matrix through pre-treatment when plating tank enters the mouth.The main process of traditional online pretreating device is: Stainless Steel Wire is online pass the electrolytic pickling groove after, after washing, directly enter the alkaline electro plating bath and carry out electro-coppering.
Mainly there is following shortcoming in this pretreating device:
1, the washing bath water content consumption is big and the washing effect is undesirable, and the Stainless Steel Wire surface still is attached with residual acid, and is bigger to the influence of the basic plating solution pH value in the plating tank, coating instability and thinner thickness.
2, Stainless Steel Wire obtains fresh matrix after electrolytic pickling, and dry up again can be oxidized in the process through washing pressurized air, causes the bonding force of last copper plate and stainless steel base poor, comes off easily when being subjected to extraneous stress.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency, provide a kind of Copper Coated Stainless Steel Wire online pretreating device, can obtain the thicker copper plate of thickness, and effectively improve the stability of coating and the bonding force of coating and matrix, the water content consumption of washing bath is also less simultaneously.
The object of the present invention is achieved like this: the online pretreating device of a kind of Copper Coated Stainless Steel Wire, described device is arranged at before the plating tank, it comprises pickling tank and washing bath, be characterized in: described device also comprises sealed vessel, described sealed vessel one end is connected with the outlet of washing bath Stainless Steel Wire, the other end stretches into plating tank and electroplates the liquid level below, also be provided with the air outlet on the sealed vessel, the air outlet is positioned at described plating liquid level top, described washing bath top seal, and its top also is provided with inlet mouth.
Described washing bath top is provided with several mouth sprays, the bottom is separated into several staircase areas from A-P, wherein first area liquid level is minimum, last area liquid level is the highest, each zone is provided with a mouth spray, and described several mouth sprays lay respectively at the top of described several staircase areas, and described first regional top is provided with overflow port, the bottom is provided with water outlet, and described last regional top is provided with water-in.
Compared with prior art, the invention has the beneficial effects as follows:
The online pretreating device of a kind of Copper Coated Stainless Steel Wire of the present invention, it comprises pickling tank, washing bath and sealed vessel, wherein be full of reducing gas in washing bath and the sealed vessel, prevented that effectively Stainless Steel Wire matrix fresh after the pickling is oxidized before entering electroplating solution, improved the bonding force of coating and matrix, and washing bath is divided into several staircase areas, divide some roads to clean, the rinse water in back road can overflow to preceding road and carry out recycle, the water yield that washing bath consumes is less and the washing effect is better, the residual acid of Stainless Steel Wire surface attachment seldom, pH value to electroplating solution does not have influence substantially, helps obtaining the thicker and stable coating of thickness.
Description of drawings
Fig. 1 is the structural representation of the online pretreating device of Copper Coated Stainless Steel Wire of the present invention.
Wherein:
Pickling tank 1, washing bath 2, sealed vessel 3, plating tank 4, inlet mouth 5, air outlet 6, mouth spray 7, water-in 8, overflow port 9, water outlet 10, guide wheel 11, cathode bar 12, dividing plate 13.
Embodiment
Referring to Fig. 1, the present invention relates to the online pretreating device of a kind of Copper Coated Stainless Steel Wire, described device is arranged at before the plating tank 4, it comprises pickling tank 1, washing bath 2 and sealed vessel 3, washing bath 2 top seals, and its top is provided with the inlet mouth 5 that is used for injecting reducing gas in washing bath, washing bath 2 tops are provided with several mouth sprays 7, the bottom is separated into several staircase areas from A-P by dividing plate 13, wherein first area liquid level is minimum, last area liquid level is the highest, described mouth spray 7 quantity equate with described staircase areas quantity, described several mouth sprays 7 lay respectively at the top of some staircase areas, described first regional top is provided with overflow port 9, the bottom is provided with water outlet 10, described last regional top is provided with water-in 8, described sealed vessel 3 one ends are connected with the outlet of washing bath 2 Stainless Steel Wires, the other end stretches into plating tank 4 and electroplates the liquid level below, sealed vessel 3 is provided with the air outlet 6 of reducing gas, and air outlet 6 is positioned at described plating liquid level top.
Principle of work:
Stainless Steel Wire obtains fresh matrix after electrolytic pickling, enter then in the sealing washing bath 2 that is full of reducing gas, after some roads washing of some staircase areas, enter again in the sealed vessel 3 that is full of reducing gas outside the washing bath 2, enter via guide wheel 11 and cathode bar 12 Stainless Steel Wires at last and begin copper facing in the electroplating solution, because all be full of reducing gas in washing bath 2 and the encloses container 3, can prevent effectively that Stainless Steel Wire matrix fresh after the pickling is oxidized, improved the bonding force of coating and matrix, each staircase areas all disposes a lift pump and is used for the water in the zone is extracted into mouth spray 7 cleaning Stainless Steel Wires, residual acid in the staircase areas reduces gradually from A-P, can enter front region after the rinse water overflow in the back region and carry out recycle, through the surperficial basic noresidue acid of washing back, some roads Stainless Steel Wire from A-P, the washing effect is better and water content consumption is less.

Claims (2)

1. online pretreating device of Copper Coated Stainless Steel Wire, described device is arranged at plating tank (4) before, it comprises pickling tank (1) and washing bath (2), it is characterized in that: described device also comprises sealed vessel (3), described sealed vessel (3) one ends are connected with the outlet of washing bath (2) Stainless Steel Wire, the other end stretches into plating tank (4) and electroplates the liquid level below, also be provided with air outlet (6) on the sealed vessel (3), air outlet (6) is positioned at described plating liquid level top, described washing bath (2) top seal, and its top also is provided with inlet mouth (5).
2. the online pretreating device of a kind of Copper Coated Stainless Steel Wire according to claim 1, it is characterized in that: described washing bath (2) top is provided with several mouth sprays (7), the bottom is separated into several staircase areas from A-P, wherein first area liquid level is minimum, last area liquid level is the highest, mouth spray (7) quantity equates with staircase areas quantity, described several mouth sprays (7) lay respectively at the top of described several staircase areas, described first regional top is provided with overflow port (9), the bottom is provided with water outlet (10), and described last regional top is provided with water-in (8).
CN 201110099360 2011-04-20 2011-04-20 On-line pretreatment device for copper-coated stainless steel wires Active CN102181898B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 201110099360 CN102181898B (en) 2011-04-20 2011-04-20 On-line pretreatment device for copper-coated stainless steel wires

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Application Number Priority Date Filing Date Title
CN 201110099360 CN102181898B (en) 2011-04-20 2011-04-20 On-line pretreatment device for copper-coated stainless steel wires

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CN102181898B CN102181898B (en) 2012-07-25

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105986307A (en) * 2016-03-11 2016-10-05 合肥汇通控股股份有限公司 Water saving type electroplating three-level washing tank
CN108672706A (en) * 2018-05-11 2018-10-19 娄底市格林新材料科技有限公司 A kind of preparation process of stainless steel fibre micro mist
CN108914147A (en) * 2018-07-12 2018-11-30 西南铝业(集团)有限责任公司 Coiled material coating lye spray degreasing processing unit
CN109897988A (en) * 2019-03-08 2019-06-18 嘉善雄真金属钮扣厂(普通合伙) A kind of metal button and its production technology using composite material

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01111896A (en) * 1987-10-27 1989-04-28 Nippon Steel Corp Surface treatment of stainless steel sheet

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01111896A (en) * 1987-10-27 1989-04-28 Nippon Steel Corp Surface treatment of stainless steel sheet

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105986307A (en) * 2016-03-11 2016-10-05 合肥汇通控股股份有限公司 Water saving type electroplating three-level washing tank
CN108672706A (en) * 2018-05-11 2018-10-19 娄底市格林新材料科技有限公司 A kind of preparation process of stainless steel fibre micro mist
CN108672706B (en) * 2018-05-11 2021-11-26 娄底市格林新材料科技有限公司 Preparation process of stainless steel fiber micro powder
CN108914147A (en) * 2018-07-12 2018-11-30 西南铝业(集团)有限责任公司 Coiled material coating lye spray degreasing processing unit
CN109897988A (en) * 2019-03-08 2019-06-18 嘉善雄真金属钮扣厂(普通合伙) A kind of metal button and its production technology using composite material

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