CN102179150A - Tail gas purification device for detecting sulfur hexafluoride decomposition products and method thereof - Google Patents
Tail gas purification device for detecting sulfur hexafluoride decomposition products and method thereof Download PDFInfo
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- CN102179150A CN102179150A CN2011100777399A CN201110077739A CN102179150A CN 102179150 A CN102179150 A CN 102179150A CN 2011100777399 A CN2011100777399 A CN 2011100777399A CN 201110077739 A CN201110077739 A CN 201110077739A CN 102179150 A CN102179150 A CN 102179150A
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- sodium hydroxide
- hydroxide solution
- sulfur hexafluoride
- catabolite
- absorption bottle
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/30—Capture or disposal of greenhouse gases of perfluorocarbons [PFC], hydrofluorocarbons [HFC] or sulfur hexafluoride [SF6]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
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- Treating Waste Gases (AREA)
Abstract
The invention refers to tail gas purification device for detecting sulfur hexafluoride decomposition products and a method thereof; the device comprises an absorption bottle, a closing plug arranged on the bottle opening, and an intake tube and an exhaust tube arranged inside the absorption bottle; sodium hydroxide solution with a concentration of 0.1 mol/L is filled in the absorption bottle; the tail end of the intake tube is extended in the solution; the tail end of the exhaust tube is positioned inside a space between the solution liquid level and the closing plug; and the method comprises the following steps of: preparing 0.1 mol/L sodium hydroxide solution; filling the detected tail gas in the sodium hydroxide solution to react, wherein decomposition products are absorbed by the sodium hydroxide solution, and non-toxic sulfur hexafluoride gas generated by the reaction is discharged out through the exhaust tube; and neutralizing the used sodium hydroxide solution by using 0.1 mol/L sulfuric acid solution to be neutral and then discharging. The device and the method are simple to operate and reliable to use, thereby solving the problem that the sulfur hexafluoride decomposition product gases on the spot are harmful for human body and improving the work efficiency.
Description
Technical field
The present invention relates to a kind of exhaust gas cleaner and method that the sulfur hexafluoride catabolite detects that be used for, belong to the electrical equipment field.
Technical background
Pure sulfur hexafluoride gas is a kind of nontoxic and gas with good insulation performance, by generally as the insulating gas of electrical equipment, though pure SF
6Gas is nontoxic, but SF
6Gas can contain a certain amount of catabolite move a period of time in breaker after, and these catabolites all have toxicity.SF in the electrical equipment
6The source of the poisonous decomposed substance of gas is as follows: the SF in the one, electrical equipment
6Gas produces some toxic products under the high-temperature electric arc effect; Its two, the SF in the electrical equipment
6Gas analyte and the moisture in it or electrode, insulating materials reaction generate some noxious material.In case these toxic gases and powder leak out, can stimulate people's skin, eyes, human respiratory is caused certain injury.At present, in order to monitor gaseous mass in the operation sulfur hexafluoride electrical equipment, utilize sulfur hexafluoride catabolite instrument that gas is detected, even if in the testing process in the emission gases catabolite of trace also can constitute injury to the staff, this brings certain threat for personal safety of testing staff.
The utility model content
Problem to be solved by this invention provide a kind of simple to operate, easy to use and guarantee the staff personal safety be used for exhaust gas cleaner and the method that the sulfur hexafluoride catabolite detects.
The present invention adopts following technical scheme:
The present invention is used for the exhaust gas cleaner that the sulfur hexafluoride catabolite detects and comprises absorption bottle, is arranged on the sealing-plug on the absorption bottle bottleneck and is arranged on air inlet pipe and blast pipe in the absorption bottle by sealing-plug, it is the 0.1mol/L sodium hydroxide solution that concentration is housed in the described absorption bottle, described air inlet pipe end stretches in the 0.1mol/L sodium hydroxide solution, in the space of blast pipe end between 0.1mol/L sodium hydroxide solution liquid level and sealing-plug.
The exhaust purifying method that is used for the detection of sulfur hexafluoride catabolite of the present invention may further comprise the steps:
(1). preparation 0.1mol/L sodium hydroxide solution:
Analytically pure NaOH is inserted in the deionized water, in course of dissolution, stir, add deionized water amount to make the concentration of sodium hydroxide solution be 0.1mol/L, it is exothermic reaction that NaOH is analyzed pure reaction of dissolving in deionized water, treats that solution temperature reduces to can put into to the room temperature describedly to be used for the exhaust gas cleaner that the sulfur hexafluoride catabolite detects and to be used as sulfur hexafluoride catabolite absorption liquid;
(2). the tail gas that the sulfur hexafluoride catabolite is detected feeds in the 0.1mol/L sodium hydroxide solution by air inlet pipe and reacts the catabolite SOF in the sulfur hexafluoride gas
2, SO
2, HF, H
2S is absorbed by the 0.1mol/L sodium hydroxide solution, and reaction equation is:
SOF
2+H
2O＝SO
2+2HF
SO
2+H
2O=H
2SO
3
H
2SO
3+2NaOH=Na
2SO
3+2H
2O
HF+NaOH=NaF+?H
2O
H
2S?+2NaOH=Na
2S+2H
2O；
(3). the nontoxic sulfur hexafluoride gas that reaction generates is discharged by blast pipe;
(4). the sulfuric acid solution with 0.1mol/L is neutralized to the discharging of neutral back with used 0.1mol/L sodium hydroxide solution.
Good effect of the present invention is as follows:
Apparatus of the present invention and method are used in transformer station's electrical equipment sulfur hexafluoride gas catabolite process of the test, when carrying out the test of sulfur hexafluoride catabolite at the scene device is connected catabolite instrument end, the toxic gas that detects in the waste gas can be absorbed fully, guarantee on-the-spot detection and staff's personal safety, the present invention is simple to operate, use reliably, having solved at the scene, sulfur hexafluoride catabolite gas has improved operating efficiency to the problem that human body damages.
Description of drawings
Accompanying drawing 1 structural representation of the present invention;
Accompanying drawing 2 is the syndeton schematic diagram of sealing-plug of the present invention and air inlet pipe and blast pipe.
In the accompanying drawings: 1 air inlet pipe, 2 sealing-plugs, 3 blast pipes, 4 0.1mol/L sodium hydroxide solutions, 5 absorption bottles.
The specific embodiment
As accompanying drawing 1, shown in 2, the exhaust gas cleaner that the present invention is used for the detection of sulfur hexafluoride catabolite comprises absorption bottle 5, be arranged on the sealing-plug 2 on absorption bottle 5 bottlenecks and be arranged on air inlet pipe 1 and blast pipe 3 in the absorption bottle 5 by sealing-plug 2, described sealing-plug can be rubber stopper, described air inlet pipe 1 and blast pipe 3 can be glass tube, plastic tube or pvc pipe etc., it is 0.1mol/L sodium hydroxide solution 4 that concentration is housed in the described absorption bottle 5, described air inlet pipe 1 end is arranged in the 0.1mol/L sodium hydroxide solution 4, and blast pipe 3 ends are arranged in the space between 0.1mol/L sodium hydroxide solution 4 liquid levels and the sealing rubber plug 2.
The exhaust purifying method that is used for the detection of sulfur hexafluoride catabolite of the present invention may further comprise the steps:
(1). preparation 0.1mol/L sodium hydroxide solution:
Getting 4 gram NaOH analyzes pure, it is even to insert 1 liter of deionized water for stirring, it is exothermic reaction that NaOH is analyzed pure reaction of dissolving in deionized water, treats that solution temperature reduces to can put into to the room temperature describedly to be used for the exhaust gas cleaner that the sulfur hexafluoride catabolite detects and to be used as sulfur hexafluoride catabolite absorption liquid;
(2). the tail gas that the sulfur hexafluoride catabolite is detected feeds in the 0.1mol/L sodium hydroxide solution 4 by air inlet pipe 1 and reacts the catabolite SOF in the sulfur hexafluoride gas
2, SO
2, HF, H
2S is absorbed by 0.1mol/L sodium hydroxide solution 4, and reaction equation is:
SOF
2+H
2O＝SO
2+2HF
SO
2+H
2O=H
2SO
3
H
2SO
3+2NaOH=Na
2SO
3+2H
2O
HF+NaOH=NaF+?H
2O
H
2S?+2NaOH=Na
2S+2H
2O
(3). the nontoxic sulfur hexafluoride gas that reaction generates is discharged by blast pipe 3;
(4). the sulfuric acid solution with 0.1mol/L is neutralized to the discharging of neutral back with used 0.1mol/L sodium hydroxide solution 4.
As shown in Figure 1, when carrying out the test of sulfur hexafluoride catabolite at the scene air inlet pipe 1 is connected catabolite instrument end, then can be absorbed fully, on blast pipe 3, connect plastic flexible pipe and cause the SF after the discharging detection outside 3 meters by the toxic gas that 0.1mol/L sodium hydroxide solution 4 will detect in the waste gas
6Gas; 0.1mol/L sodium hydroxide solution 4 is used to absorb the sulfur hexafluoride gas catabolite, if concentration is too high, then is spread across on the human body and can causes burn, the too low absorption cleaning effect that then do not have of concentration.
The present invention is used in transformer station's electrical equipment sulfur hexafluoride gas catabolite process of the test, when carrying out the test of sulfur hexafluoride catabolite at the scene air inlet pipe 1 is connected catabolite instrument end, can absorb fully by the toxic gas that 0.1mol/L sodium hydroxide solution 4 will detect in the waste gas, guarantee on-the-spot detection and staff's personal safety, the present invention is simple to operate, use reliable, having solved at the scene, sulfur hexafluoride catabolite gas has improved operating efficiency to the problem that human body damages.
Claims (2)
1. one kind is used for the exhaust gas cleaner that the sulfur hexafluoride catabolite detects, it is characterized in that it comprises absorption bottle (5), be arranged on the sealing-plug (2) on absorption bottle (5) bottleneck and be arranged on air inlet pipe (1) and blast pipe (3) in the absorption bottle (5) by sealing-plug (2), it is 0.1mol/L sodium hydroxide solution (4) that concentration is housed in the described absorption bottle (5), described air inlet pipe (1) end stretches in 0.1mol/L sodium hydroxide solution (4), and blast pipe (3) end is positioned at the space between 0.1mol/L sodium hydroxide solution (4) liquid level and the sealing-plug (2).
2. one kind according to claim 1ly is used for the exhaust purifying method that the sulfur hexafluoride catabolite detects, and it is characterized in that it may further comprise the steps:
(1). preparation 0.1mol/L sodium hydroxide solution:
Analytically pure NaOH is inserted in the deionized water, in course of dissolution, stir, add deionized water amount to make the concentration of sodium hydroxide solution be 0.1mol/L, it is exothermic reaction that NaOH is analyzed pure reaction of dissolving in deionized water, treats that solution temperature reduces to can put into to the room temperature describedly to be used for the exhaust gas cleaner that the sulfur hexafluoride catabolite detects and to be used as sulfur hexafluoride catabolite absorption liquid;
(2). the tail gas that the sulfur hexafluoride catabolite is detected is by reacting the catabolite SOF in the sulfur hexafluoride gas in air inlet pipe (1) the feeding 0.1mol/L sodium hydroxide solution (4)
2, SO
2, HF, H
2S is absorbed by 0.1mol/L sodium hydroxide solution (4), and reaction equation is:
SOF
2+H
2O＝SO
2+2HF
SO
2+H
2O=H
2SO
3
H
2SO
3+2NaOH=Na
2SO
3+2H
2O
HF+NaOH=NaF+?H
2O
H
2S?+2NaOH=Na
2S+2H
2O；
(3). the nontoxic sulfur hexafluoride gas that reaction generates is discharged by blast pipe (3);
(4). the sulfuric acid solution with 0.1mol/L is neutralized to the discharging of neutral back with used 0.1mol/L sodium hydroxide solution (4).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100777399A CN102179150A (en) | 2011-03-30 | 2011-03-30 | Tail gas purification device for detecting sulfur hexafluoride decomposition products and method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011100777399A CN102179150A (en) | 2011-03-30 | 2011-03-30 | Tail gas purification device for detecting sulfur hexafluoride decomposition products and method thereof |
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|---|---|
| CN102179150A true CN102179150A (en) | 2011-09-14 |
Family
ID=44565552
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011100777399A Pending CN102179150A (en) | 2011-03-30 | 2011-03-30 | Tail gas purification device for detecting sulfur hexafluoride decomposition products and method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102698553A (en) * | 2012-06-05 | 2012-10-03 | 力合科技（湖南）股份有限公司 | Gas washing bottle |
| CN105762674A (en) * | 2016-04-29 | 2016-07-13 | 句容华源电器设备有限公司 | Explosion-proof insulating box |
| CN107561209A (en) * | 2017-08-03 | 2018-01-09 | 国网安徽省电力公司电力科学研究院 | Sulfur hexafluoride gas acidity detection method and device |
| CN108731880A (en) * | 2018-05-03 | 2018-11-02 | 北京华电中试电力工程有限责任公司 | SF in a kind of high-voltage isulation equipment6Gas detection method and system |
| CN110927340A (en) * | 2019-12-06 | 2020-03-27 | 西安锐驰电器有限公司 | Method for detecting concentration of gas decomposition product in high-voltage power equipment |
| CN112403174A (en) * | 2020-10-30 | 2021-02-26 | 湖北工业大学 | Insulating gas degradation device |
| CN118594204A (en) * | 2024-08-08 | 2024-09-06 | 福州亿得隆电气技术有限公司 | Multistage purification device for recycling sulfur hexafluoride and perfluoroisobutyronitrile gas |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2487440Y (en) * | 2001-06-16 | 2002-04-24 | 浦晴岘 | Closed device for preparing toxic gas |
| CN101607171A (en) * | 2009-07-07 | 2009-12-23 | 吉林农业大学 | Be used for being absorbed in odor generated triple-combined absorption liquid of composting production process and application process thereof |
| CN201545698U (en) * | 2009-05-12 | 2010-08-11 | 常州海立普电力科技有限公司 | SF6 gas recovery device |
| CN202061542U (en) * | 2011-03-30 | 2011-12-07 | 河北省电力研究院 | Tail-gas purification device for sulfur hexafluoride catabolite detection |
-
2011
- 2011-03-30 CN CN2011100777399A patent/CN102179150A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2487440Y (en) * | 2001-06-16 | 2002-04-24 | 浦晴岘 | Closed device for preparing toxic gas |
| CN201545698U (en) * | 2009-05-12 | 2010-08-11 | 常州海立普电力科技有限公司 | SF6 gas recovery device |
| CN101607171A (en) * | 2009-07-07 | 2009-12-23 | 吉林农业大学 | Be used for being absorbed in odor generated triple-combined absorption liquid of composting production process and application process thereof |
| CN202061542U (en) * | 2011-03-30 | 2011-12-07 | 河北省电力研究院 | Tail-gas purification device for sulfur hexafluoride catabolite detection |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102698553A (en) * | 2012-06-05 | 2012-10-03 | 力合科技（湖南）股份有限公司 | Gas washing bottle |
| CN105762674A (en) * | 2016-04-29 | 2016-07-13 | 句容华源电器设备有限公司 | Explosion-proof insulating box |
| CN107561209A (en) * | 2017-08-03 | 2018-01-09 | 国网安徽省电力公司电力科学研究院 | Sulfur hexafluoride gas acidity detection method and device |
| CN108731880A (en) * | 2018-05-03 | 2018-11-02 | 北京华电中试电力工程有限责任公司 | SF in a kind of high-voltage isulation equipment6Gas detection method and system |
| CN110927340A (en) * | 2019-12-06 | 2020-03-27 | 西安锐驰电器有限公司 | Method for detecting concentration of gas decomposition product in high-voltage power equipment |
| CN112403174A (en) * | 2020-10-30 | 2021-02-26 | 湖北工业大学 | Insulating gas degradation device |
| CN118594204A (en) * | 2024-08-08 | 2024-09-06 | 福州亿得隆电气技术有限公司 | Multistage purification device for recycling sulfur hexafluoride and perfluoroisobutyronitrile gas |
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Owner name: HEBEI ELECTRIC POWER CORPORATION ELECTRIC POWER RE Free format text: FORMER OWNER: HEBEI ELECTRIC POWER RESEARCH INSTITUTE Effective date: 20121219 Owner name: STATE GRID CORPORATION OF CHINA HEBEI ELECTRIC POW Effective date: 20121219 |
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Effective date of registration: 20121219 Address after: 050021 No. 238 South Sports street, Yuhua Road, Hebei, Shijiazhuang Applicant after: Electric Power Research Institute of Hebei Electric Power Corporation Applicant after: State Grid Corporation of China Applicant after: Hebei Electric Power Construction & Adjustment Research Institute Address before: 050021 No. 238 South Sports street, Hebei, Shijiazhuang Applicant before: Hebei Electric Power Research Institute |
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Application publication date: 20110914 |