CN102155564B - Enhanced ceramic metal water tap and preparation method thereof - Google Patents
Enhanced ceramic metal water tap and preparation method thereof Download PDFInfo
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- CN102155564B CN102155564B CN 201110047526 CN201110047526A CN102155564B CN 102155564 B CN102155564 B CN 102155564B CN 201110047526 CN201110047526 CN 201110047526 CN 201110047526 A CN201110047526 A CN 201110047526A CN 102155564 B CN102155564 B CN 102155564B
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- water tap
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- ceramic
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 127
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 61
- 239000002184 metal Substances 0.000 title claims abstract description 61
- 239000000919 ceramic Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 16
- 239000011707 mineral Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 33
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 11
- 239000000395 magnesium oxide Substances 0.000 claims description 11
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 11
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 11
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 11
- 235000019796 monopotassium phosphate Nutrition 0.000 claims description 11
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000010935 stainless steel Substances 0.000 claims description 7
- 229910001220 stainless steel Inorganic materials 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 230000002708 enhancing effect Effects 0.000 claims description 5
- 239000008399 tap water Substances 0.000 claims description 5
- 235000020679 tap water Nutrition 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 238000001771 vacuum deposition Methods 0.000 claims description 5
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 238000007747 plating Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000004381 surface treatment Methods 0.000 claims description 3
- 229910001051 Magnalium Inorganic materials 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229960004643 cupric oxide Drugs 0.000 claims description 2
- 238000004080 punching Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229910001651 emery Inorganic materials 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 8
- 238000011049 filling Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 4
- 229920003023 plastic Polymers 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 abstract 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000005516 engineering process Methods 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 10
- 230000000694 effects Effects 0.000 description 8
- 238000009413 insulation Methods 0.000 description 8
- 238000010409 ironing Methods 0.000 description 7
- 239000007769 metal material Substances 0.000 description 5
- 229910000906 Bronze Inorganic materials 0.000 description 3
- 239000010974 bronze Substances 0.000 description 3
- 238000005266 casting Methods 0.000 description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000004512 die casting Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
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- Domestic Plumbing Installations (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses an enhanced ceramic metal water tap and a preparation method thereof, and relates to a water tap. The enhanced metal-like water tap comprises an ABS (acrylonitrile-butadiene-styrene) plastic shell and matched components, wherein the matched components comprise a valve plug, a handle, a water outlet net, a seal ring, a fastening screw, and the like. The preparation method comprises the following steps: assembling the metal water channel of the water tap according to the water channel requirements of the water tap; placing the assembled water channel in a mold of the metal outer shell of the water tap, and fixing; and mixing ceramic mineral power with an enhancement additive agent, filling the mixture in the mold of the outer shell of the water tap after adding water and stirring, taking out from the mold after molding, installing the mold in the metal outer shell of the water tap, and assembling the prepared matched components of the water tap into the enhanced-type ceramic metal water tap according to a normal assembly method, wherein the matched components of the water tap are manufactured according to a normal technology and comprises the valve plug, the handle, the water outlet net, the seal ring, the fastening screw, and the like, and the weight ratio of the ceramic mineral power to the enhancement additive agent is 1 to (0.1-1.5).
Description
Technical field
The present invention relates to a kind of water tap, especially relate to a kind of enhancement mode Ceramic metal water tap and preparation method thereof.
Background technique
Plastic faucet on the existing market mostly is as shell take ABS plastic, and carry out surface treatment (plating, vacuum coating etc.) and be the metal appearance of Gao Guang, its internal water channel skeleton then adopts POM or the resins such as PPS or PPO to be reacted into type through the injection moulding room temperature.The shortcoming of this kind plastic faucet is that quality is inadequate, and the anti-burst pressure intensity of water channel is also not enough, can't satisfy client's requirement fully.
Metal faucet on the existing market, its body portion adopts copper product, zinc alloy, stainless steel material, and the castings such as metal process, the component such as the spool of then packing into, valve rod, handle.This result has a lot of shortcomings: 1. because housing is casting, and material expends seriously, and complicated casting technique does not meet the needs that conservation-minded society's development is built so that energy consumption is high; 2. metal shell is thicker, and the good consumption of metal is high, so that the cost of whole water tap is high.3. because metal has good heat-conducting property, therefore, the water tap that uses metal-made to cause can not reach good effect of heat insulation, and heat energy directly passes to the surface of water tap, irons easily the user.
Chinese patent ZL200920307175.1 discloses a kind of water tap that adopts the metallic material preparation, its valve body, handle, water outlet piece all are metallic material, its advantage is that this water tap adopts the metallic material preparation, and Water tap parts has heat resistance, wear resistance, corrosion resistance after by polishing, sandblast and anodic oxidation; Surface easy coloring and the advantages such as bright-colored difficult drop-off.The total quality that obvious its shortcoming is water tap is heavy not, and water outlet piece adopts the metallic material corrosion-resistant.
Summary of the invention
The object of the invention is to for existing water tap total quality heavyly not, the metallic material corrosion resistance that water outlet piece adopts is relatively poor to be waited not enoughly, and a kind of enhancement mode Ceramic metal water tap and preparation method thereof is provided.
The imitative metallo-plastic water tap of described enhancement mode comprises ABS plastic shell and matching parts, and described matching parts comprises spool, handle, goes out the network of rivers, seal ring, fastening screw trip bolt, and the preparation method of described a kind of enhancement mode Ceramic metal water tap may further comprise the steps:
1) first the metal water channel of the water tap water route according to water tap is required to combine;
2) will combine in the mould of metal shell that water channel is placed in water tap, and fix;
In step 2) in, the metal shell of described water tap is by moulding such as punching press or die casting; The metal shell of described water tap can be a kind of in aluminum alloy casing, magnalium shell, stainless steel casing, copper alloy shell, the zinc alloy shell etc.; The surface of the metal shell of described water tap can be by surface treatment, and described surface-treated mode can be at least a in plating, vacuum coating, spraying, the anodic oxidation etc.
3) ceramic mineral powder is mixed with the enhancing additive, after adding the entry stirring, be filled in the mould of swivel body, from mould, take out after the moulding, and be installed in the metal shell of water tap, water tap matching parts with ready routinely explained hereafter, comprise spool, handle, go out the network of rivers, seal ring, fastening screw trip bolt etc. are assembled into enhancement mode Ceramic metal water tap according to the assembling mode of routine, described ceramic mineral powder is 1 with the mass ratio that strengthens additive: (0.1~1.5).
In step 3) in, described ceramic mineral powder can be selected from least a in ceramic powder, the cement etc.; Described ceramic powder can be the mixture of silicate, magnesium oxide and potassium dihydrogenphosphate, and the mass percent of described silicate, magnesium oxide and potassium dihydrogenphosphate can be silicate 30%~40%, magnesium oxide 30%~40% and potassium dihydrogenphosphate 20%~40%; Described enhancing additive can be selected from least a in metal powder, metallic oxide powder, Buddha's warrior attendant sand, cement, quartz sand, the glass fibre etc.; Described metal powder can be selected from least a in iron powder, tungsten powder, zinc powder, the copper powder etc.; Described metallic oxide powder can be selected from ferrite, oxidation tungsten powder, at least a in zine oxide, the cupric oxide powder etc.; The addition of described water can be ceramic mineral powder and strengthens 5%~30% of additive gross mass, and the temperature of described water can be 10~25 ℃, and the time of described stirring can be 2~10min.
Compared with prior art, the present invention has following outstanding advantages:
1) weight ratio of the prepared enhancement mode Ceramic metal water tap of the present invention is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.
2) the prepared enhancement mode Ceramic metal water tap of the present invention, the stupalith of packed layer for mixing in the middle of it, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment
Embodiment 1
1. first water tap required combining according to the water route of water tap without the lead bronze water channel;
2. will combine in the mould that water channel is placed in swivel body, and fix;
3. the ceramic mineral powder that with quality is 1000g (is ceramic powder, it is 30% silicate by mass percent, the mixture of 30% magnesium oxide and 40% potassium dihydrogenphosphate three combination) mix with the 1500g ferrite after, and adding mass percent 20% temperature is after 25 ℃ of water fully stir 10min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, water tap matching parts with ready routinely explained hereafter, comprise spool, handle, go out the network of rivers, seal ring, fastening screw trip bolts etc. are installed in the metallic copper alloy shell (electroplating processes is carried out on the surface) of water tap according to the assembling mode of routine, are assembled into a whole set of water tap.The weight amount of the enhancement mode Ceramic metal water tap that the present invention is prepared is relatively near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment 2
1) first water tap required combining according to the water route of water tap without the lead bronze water channel;
2) will combine in the mould that water channel is placed in swivel body, and fix;
3) be that the ceramic mineral powder of 1000g is (for ceramic powder with quality, it is 40% silicate by mass percent, the mixture of 40% magnesium oxide and 20% potassium dihydrogenphosphate three combination) mix with the 100G tungsten powder after, and adding mass percent 5% temperature is after 10 ℃ of water fully stir 2min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, and the middle water tap matching parts with ready routinely explained hereafter of the metallic aluminium alloy shell (anodic oxidation is carried out on the surface) that is installed in water tap, comprise spool, handle, go out the network of rivers, seal ring, fastening screw trip bolts etc. are assembled into a whole set of water tap according to the assembling mode of routine.The mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment 3
1) first the stainless steel water channel of the water tap water route according to water tap is required to combine;
2) will combine in the mould that water channel is placed in water tap, and fix;
3) be after ceramic mineral powder A (cement) and the 1000g silica sand of 1000g mixes with quality, and adding mass ratio 20% temperature is after 15 ℃ of water fully stir 5min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, and be installed in the metal stainless steel casing of water tap, water tap matching parts with ready routinely explained hereafter comprises spool, handle, goes out the network of rivers, seal ring, fastening screw trip bolt etc. be assembled into a whole set of water tap according to the assembling mode of routine.The mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near metal faucet and the cost skeleton lower than metal faucet.In addition, because high-strength ceramic has humidification to the water channel skeleton, the mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment 4
1) first the stainless steel water channel of the water tap water route according to water tap is required to combine;
2) will combine in the mould that water channel is placed in water tap, and fix;
3) be that the ceramic mineral powder of 1000g is (for ceramic powder with quality, be 35% silicate by mass percent, the mixture of 35% magnesium oxide and 30% potassium dihydrogenphosphate three combination) mix with 500g Buddha's warrior attendant sand after, and adding mass percent 20% temperature is after 15 ℃ of water fully stir 8min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, and be installed in the metallic zinc alloy shell (surface is electroplated with vacuum coating and processed) of water tap, water tap matching parts with ready routinely explained hereafter comprises spool, handle, go out the network of rivers, seal ring, fastening screw trip bolts etc. are assembled into a whole set of water tap according to the assembling mode of routine.The mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment 5
1) first water tap required combining according to the water route of water tap without the lead bronze water channel;
2) will combine in the mould that water channel is placed in water tap, and fix;
3) be that the ceramic mineral powder of 1000g is (for ceramic powder with quality, be 30% silicate by mass percent, the mixture of 40% magnesium oxide and 30% potassium dihydrogenphosphate three combination) mix with the 300g glass fibre after, and adding mass percent 15% temperature is after 10 ℃ of water fully stir 5min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, and be installed in the magnesium metal aluminum alloy casing (surface sprays with vacuum coating and processes) of water tap, water tap matching parts with ready routinely explained hereafter comprises spool, handle, go out the network of rivers, seal ring, fastening screw trip bolts etc. are assembled into a whole set of water tap according to the assembling mode of routine.The mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Embodiment 6
1) first the stainless steel water channel of the water tap water route according to water tap is required to combine;
2) will combine in the mould that water channel is placed in water tap, and fix;
3) be that the ceramic mineral powder of 1000g is (for ceramic powder with quality, be 40% silicate by mass percent, the mixture of 40% magnesium oxide and 20% potassium dihydrogenphosphate three combination) mix with 100g epoxy resin after, and adding mass percent 20% temperature is after 10 ℃ of water fully stir 8min, it is filled in the above-mentioned mould, after its room temperature forming, it is taken out from mould, water tap matching parts with ready routinely explained hereafter, comprise spool, handle, go out the network of rivers, seal ring, fastening screw trip bolts etc. are according to the assembling mode of routine and be installed in the metallic aluminium alloy shell (spraying treatmen is carried out on the surface) of water tap, are assembled into a whole set of water tap.The mass ratio of the enhancement mode Ceramic metal water tap that the present invention is prepared is near same size zinc alloy water tap, and its cost is more much lower than zinc alloy water tap, has the identical performance of metal faucet.The stupalith of intermediate filling layer for mixing, its heat-conducting property is relatively poor, so good heat-insulation effect can avoid ironing the user.
Claims (5)
1. enhancement mode Ceramic metal water tap, described enhancement mode Ceramic metal water tap comprises metal shell and matching parts, described matching parts comprises spool, handle, goes out the network of rivers, seal ring, fastening screw trip bolt, it is characterized in that the preparation method of described a kind of enhancement mode Ceramic metal water tap may further comprise the steps:
1) first the metal water channel of the water tap water route according to water tap is required to combine;
2) will combine in the mould of metal shell that water channel is placed in water tap, and fix;
3) ceramic mineral powder is mixed with the enhancing additive, after adding the entry stirring, be filled in the mould of swivel body, from mould, take out after the moulding, and be installed in the metal shell of water tap, water tap matching parts with ready routinely explained hereafter comprises spool, handle, goes out the network of rivers, seal ring, fastening screw trip bolt be assembled into enhancement mode Ceramic metal water tap according to the assembling mode of routine that described ceramic mineral powder is 1: 0.1~1.5 with the mass ratio that strengthens additive; Described ceramic mineral powder is selected from least a in ceramic powder, the cement; Described ceramic powder is the mixture of silicate, magnesium oxide and potassium dihydrogenphosphate, and the mass percent of described silicate, magnesium oxide and potassium dihydrogenphosphate is silicate 30%~40%, magnesium oxide 30%~40% and potassium dihydrogenphosphate 20%~40%;
Described enhancing additive is selected from least a in metal powder, metallic oxide powder, emery, cement, silica sand, the glass fibre; Described metal powder is selected from least a in iron powder, tungsten powder, zinc powder, the copper powder; Described metallic oxide powder chosen from Fe oxysome, oxidation tungsten powder, at least a in zine oxide, the cupric oxide powder;
The addition of described water is 5%~20% of ceramic mineral powder and enhancing additive gross mass, and the temperature of described water is 10~25 ℃, and the time of described stirring is 2~10min.
2. a kind of enhancement mode Ceramic metal water tap as claimed in claim 1 is characterized in that in step 2) in, the metal shell of described water tap is by punching press or die cast.
3. a kind of enhancement mode Ceramic metal water tap as claimed in claim 1 is characterized in that in step 2) in, the metal shell of described water tap is a kind of in aluminum alloy casing, magnalium shell, stainless steel casing, copper alloy shell, the zinc alloy shell.
4. a kind of enhancement mode Ceramic metal water tap as claimed in claim 1 is characterized in that in step 2) in, the surface of the metal shell of described water tap is by surface treatment.
5. a kind of enhancement mode Ceramic metal water tap as claimed in claim 4 is characterized in that described surface-treated mode is at least a in plating, vacuum coating, spraying, the anodic oxidation.
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CN 201110047526 CN102155564B (en) | 2011-02-28 | 2011-02-28 | Enhanced ceramic metal water tap and preparation method thereof |
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CN 201110047526 CN102155564B (en) | 2011-02-28 | 2011-02-28 | Enhanced ceramic metal water tap and preparation method thereof |
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CN102155564B true CN102155564B (en) | 2013-03-27 |
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CN104975287B (en) * | 2014-11-21 | 2016-08-24 | 湖南振辉管业有限公司 | A kind of enviroment protective ceramic coating and preparation method and application |
CN108019532A (en) * | 2016-10-31 | 2018-05-11 | 大田精密工业股份有限公司 | Faucet device, the faucet body component and its manufacture method with anti-scald design |
CN107214814A (en) * | 2017-07-12 | 2017-09-29 | 合肥信亚达智能科技有限公司 | A kind of manufacturing process of ceramic water channel tap |
CN107354490B (en) * | 2017-07-12 | 2019-08-06 | 合肥汇之新机械科技有限公司 | A kind of production technology of the wear-resisting enhanced tap of low cost |
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CN2091390U (en) * | 1991-05-15 | 1991-12-25 | 王炳暄 | Armoured ceramics ball valve |
CN2773432Y (en) * | 2005-01-19 | 2006-04-19 | 厦门建霖卫浴工业有限公司 | Tap body |
CN101324287A (en) * | 2008-07-18 | 2008-12-17 | 张谭伟 | Baking-free artificial stone tap valve and manufacturing process thereof |
CN201202835Y (en) * | 2008-05-26 | 2009-03-04 | 秦红 | Full lining ceramic adjusting type ball valve |
CN101381219A (en) * | 2008-10-09 | 2009-03-11 | 上海交通大学 | Phosphate fast repairing building material |
CN101381220A (en) * | 2008-10-16 | 2009-03-11 | 上海交通大学 | Multifunctional gelation material |
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- 2011-02-28 CN CN 201110047526 patent/CN102155564B/en not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2091390U (en) * | 1991-05-15 | 1991-12-25 | 王炳暄 | Armoured ceramics ball valve |
CN2773432Y (en) * | 2005-01-19 | 2006-04-19 | 厦门建霖卫浴工业有限公司 | Tap body |
CN201202835Y (en) * | 2008-05-26 | 2009-03-04 | 秦红 | Full lining ceramic adjusting type ball valve |
CN101324287A (en) * | 2008-07-18 | 2008-12-17 | 张谭伟 | Baking-free artificial stone tap valve and manufacturing process thereof |
CN101381219A (en) * | 2008-10-09 | 2009-03-11 | 上海交通大学 | Phosphate fast repairing building material |
CN101381220A (en) * | 2008-10-16 | 2009-03-11 | 上海交通大学 | Multifunctional gelation material |
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