CN102310455B - Preparation method for ceramic washbasin formed by reacting at normal temperature - Google Patents
Preparation method for ceramic washbasin formed by reacting at normal temperature Download PDFInfo
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- CN102310455B CN102310455B CN 201110182694 CN201110182694A CN102310455B CN 102310455 B CN102310455 B CN 102310455B CN 201110182694 CN201110182694 CN 201110182694 CN 201110182694 A CN201110182694 A CN 201110182694A CN 102310455 B CN102310455 B CN 102310455B
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Abstract
The invention discloses a preparation method for a ceramic washbasin formed by reacting at normal temperature, which relates to a daily bathroom supply. The preparation method comprises the following steps of: mixing normal-temperature reactive ceramic mineral powder with an enhanced additive; adding water and stirring; filling the mixture into a washbasin model, forming by reacting and then taking out the formed washbasin from the washbasin model; manually and finely polishing the surface of the formed ceramic washbasin to enable the surface to achieve bright and smooth effects; and carrying out surface treatment on the surface of the formed ceramic washbasin to obtain the ceramic washbasin formed by reacting at normal temperature. The ceramic washbasin has the advantages of high strength, energy saving, environment friendliness, formation by reacting at normal temperature, no low-temperature or high-temperature sintering, high production efficiency and favorable quality and artistic effect. High-grade ceramic washbasins with bright colors and exquisite patterns can be produced. The ceramic washbasin is produced by adopting a simple production process flow, is low in cost and can be produced in batches.
Description
Technical field
The present invention relates to a kind of daily bath articles, especially relate to a kind of preparation method of normal-temperature reaction forming ceramic washbowl.
Background technology
The magnesia phosphate cement Binder Materials of phosphorus (MKP) is that magnesia (MgO) with potassium dihydrogen phosphate (KH2PO4) chemical reaction takes place, and generating with potassium phosphate magnesium is the Binder Materials of main bonding phase, is a kind of of novel concrete material.MKP has the ultrafast fast rigid energy and the very high heat of hydration of coagulating; But also the same with other cement, have good wear resistance, frost resistance and volume stability.Can be used as phosphocarnic acid magnesium cement (hereinafter to be referred as MPC) and be by burning magnesia and phosphoric acid or acid phosphate and transfer gel material formulated according to a certain ratio.Compare with Portland cement, MPC has following technical performance characteristics: 1. rapid condensation sclerosis; 2. early strength height; 3. can be in-20～+ 5 ℃ low temperature environment setting and harden; 4. the ability of cohering is strong; 5. excellent in te pins of durability.Existing result of study shows: the strength development of phosphate cement is rapid more than portland cement, can reach more than the 20MPa as magnesium phosphate cement 1h compression strength, and 1d compression strength can reach more than the 60MPa, and later strength is also increasing; Phosphoric acid-vitreum cement 1d intensity can reach more than the 200MPa.It has condense fast, early strong high, bond strength is high, drying shrinkage is little, wear-resisting, freeze proof, deicer-scaling resistance and protect advantage such as muscle, therefore be widely used in the sides such as quick repairing of road, bridge, airfield runway, be a kind of new material that researching value, energy-conserving and environment-protective are arranged very much. the raw material of this novel inorganic Binder Materials, hydration mechanism and hydrated product all are different from Portland cement, can not produce Ca (OH) during its aquation
2It is acid that the hydration and hardening process system is, hardenite pH value is lower, therefore can not produce corrosion in theory to glass fibre. the glass fiber reinforced cement composite can remedy defectives such as traditional water cement concrete density is big, tensile strength is low, shock resistance difference, just has been widely used in each field since coming out.
Existing washbowl great majority all are to adopt ceramic material or glass material to make, and are the washbowl of material when preparing as existing glass, all are the moulding of advanced stove pelvic part, control cooling velocity annealing then, come out of the stove; Take off the water hole at the basin subdrilling again, heat not tempering of tempering fire once more.The same ceramic material that adopts, after its machine-shaping, high temperature sintering is carried out in glaze spraying more then, and power consumption is big, and is unfriendly to environment.Existing washbowl preparation process is comparatively complicated, wastes energy.
Chinese patent CN2617291 discloses a kind of closing component structure of ceramic washbowl bracing frame, be meant in the feet anchor ring of ceramic washbowl and be convexly equipped with several nose bars, and pass the ring body of this nose bar exposed junction with a bracing frame pipe, these bracing frame pipe two ends are locked on the wall.Above-mentioned nose bar is to be connected by a flexible cover plug with the combination of ceramic support pin, this cover plug one end inside is provided with a nut and is screwed for the screw rod with nose bar one end, to overlap plug and be set in nose bar one end, and above-mentioned cover plug is implanted in the fixing hole of ceramic support pin, and the rotation nose bar makes the cover plug move to the ring body direction of nose bar, form a stop flange and cause cover plug one end to be extruded to be deformed in feet inwall place, the cover plug can't be deviate from fixing hole, thereby nose bar is fixedly arranged on the anchor ring of ceramic support bar.
Chinese patent CN2559693 discloses the explosion-proof structure of a kind of washbowl, it is to be provided with the corrosion resistant plate of thickness 1mm by the washbowl behind the extrusion molding, it is on the mode coating idiosome surface of electroplating by high temperature that the washbowl surface is coated with enamel, and be equipped with the basin pin of structure of steel product under the washbowl, ductility and impact-resistant characteristic by steel, the phenomenon that makes washbowl not have explosion takes place, enamel by the surface, allow the user in use as level and smooth as the pottery, by the support of basin pin, make the unlikely phenomenon that drops and explosion takes place of washbowl.
Summary of the invention
The objective of the invention is to provides a kind of preparation method of normal-temperature reaction forming ceramic washbowl at existing washbowl preparation method above shortcomings.
The present invention includes following steps:
1) with normal-temperature reaction pottery mineral powder with strengthen additive and mix, add the entry stirring after, be filled in the washbowl model, treat that it reacts moulding after, from the washbowl model, take out;
In step 1), described normal-temperature reaction pottery mineral powder can be 1 with the mass ratio that strengthens additive: (0.1～1.5); Described normal-temperature reaction pottery mineral powder can be selected from least a in ceramic powder, the fast set cement etc.; Described ceramic powder can be selected from silicate, magnesia and potassium dihydrogen phosphate three's mixture, and the mass percent of described silicate, magnesia and potassium dihydrogen phosphate can be silicate 30%～40%, magnesia 30%～40% and potassium dihydrogen phosphate 20%～40%; Described enhancing additive can be selected from least a in metal powder, metal oxide powder, diamond dust, cement, quartz sand, glass fibre, epoxy resin, the unsaturated-resin etc.; Described metal powder can be selected from least a in iron powder, tungsten powder, zinc powder, the copper powder etc.; Described metal oxide powder can be selected from ferrite, oxidation tungsten powder, at least a in zinc oxide, the cupric oxide powder etc.The described amount that adds entry can be normal-temperature reaction pottery mineral powder by mass percentage and strengthens 5%～30% of additive gross mass, and the temperature of described water can be 10～25 ℃, and the described time that adds the entry stirring can be 2～10min.
2) the smart throwing of craft is carried out in type ceramic washbowl surface, made its surface reach light, smooth effect;
3) surface treatment is carried out on the smart ceramic washbowl surface well of throwing, got normal-temperature reaction forming ceramic washbowl.
In step 3), describedly smart throw good washbowl surface and carry out the surface-treated mode and can adopt at least a in the modes such as spray ceramic powder paint, vacuum coating, spray UV coating, spray low-temp ceramics glaze.
Compared with prior art, the prepared washbowl of the present invention has the following advantages:
1) novel normal-temperature reaction forming ceramic washbowl of the present invention has very high intensity, energy-conserving and environment-protective, and the normal-temperature reaction moulding does not need low temperature or high temperature sintering, production efficiency height, energy-conserving and environment-protective.
2) quality of this washbowl is good, and artistic effect is good, can make the high-grade ceramic washbowl of various bright-colored, exquisite pattern.
3) technological process of production is simple, and cost is low, can produce in batches.
The specific embodiment
Embodiment 1
With quality is that 5000g pottery mineral powder is after ceramic powder (it is the mixture of 30% silicate, 30% magnesia and 40% potassium dihydrogen phosphate three combination by mass percent) mixes with the 4500g ferrite, and adding mass percent 20% temperature is after 25 ℃ of water fully stir 10min, it is filled in the washbowl mould, after treating its room temperature reaction moulding, from mould, take out; The smart throwing of craft is carried out on molded good ceramic washbowl surface, made its surface reach light, smooth effect, at last surface treatment is carried out on the good ceramic washbowl surface of smart throwing, spray the imitative vitreous enamel powdery paints of white, make the exquisite decorative appearance of its acquisition.
Embodiment 2
With quality is that 5000g pottery mineral powder is that (by mass percent is 40% silicate to ceramic powder, the mixture of 40% magnesia and 20% potassium dihydrogen phosphate three combination) mix with the 1000g unsaturated-resin after, and adding mass percent 5% temperature is after 10 ℃ of water fully stir 2min, it is filled in the washbasin mould, after treating its room temperature reaction moulding, it is taken out from mould, the smart throwing of craft is carried out on molded good ceramic washbowl surface, make its surface reach light, smooth effect, at last surface treatment is carried out on the smart ceramic washbowl surface well of throwing, vacuum PVD chromium plating makes it obtain exquisite decorative appearance.
Embodiment 3
With quality is after the rapid solidification cement of 5000g and 1000g quartz sand mix, and to add mass percent 20% temperature be after 15 ℃ of water fully stir 5min, it to be filled in the washbasin mould, treat its room temperature reaction moulding after, it is taken out from mould; The smart throwing of craft is carried out on molded good ceramic washbowl surface, made its surface reach light, smooth effect, at last surface treatment is carried out on the good ceramic washbowl surface of smart throwing, spray the photocuring whitewash, make it obtain exquisite decorative appearance.
Embodiment 4
With quality is that the ceramic mineral powder of 2000g is after ceramic powder (is the mixture of 30% silicate, 40% magnesia and 30% potassium dihydrogen phosphate three combination by mass percent) mixes with 3000g Buddha's warrior attendant sand, and adding mass percent 20% temperature is after 15 ℃ of water fully stir 10min, it is filled in the washbasin mould, after treating its room temperature reaction moulding, it is taken out from mould; The smart throwing of craft is carried out on molded good ceramic washbowl surface, made its surface reach light, smooth effect, at last surface treatment is carried out on the good ceramic washbowl surface of smart throwing, spray low temperature glaze, make it obtain exquisite decorative appearance.
Embodiment 5
With quality is that the ceramic mineral powder of 5000g is after ceramic powder (is the mixture of 35% silicate, 35% magnesia and 30% potassium dihydrogen phosphate three combination by mass percent) mixes with the 1000g glass fibre, and adding mass percent 15% temperature is after 10 ℃ of water fully stir 5min, it is filled in the washbasin mould, after treating its room temperature reaction moulding, it is taken out from mould; The smart throwing of craft is carried out on molded good ceramic washbowl surface, made its surface reach light, smooth effect, at last surface treatment is carried out on the good ceramic washbowl surface of smart throwing, spray the imitative vitreous enamel powdery paints of white, make the exquisite decorative appearance of its acquisition.
Embodiment 6
With quality is that the ceramic mineral powder of 5000g is after ceramic powder (is the mixture of 40% silicate, 30% magnesia and 30% potassium dihydrogen phosphate three combination by mass percent) mixes with 1000g epoxy resin, and adding mass percent 20% temperature is after 10 ℃ of water fully stir 8min, it is filled in the washbasin mould, after treating its room temperature reaction moulding, it is taken out from mould; The smart throwing of craft is carried out on molded good ceramic washbowl surface, made its surface reach light, smooth effect, at last surface treatment is carried out on the good ceramic washbowl surface of smart throwing, elder generation's spray white powder coating, vacuum chromium-coated again, make it obtain the decorative appearance of fineness.
Claims (7)
1. the preparation method of a normal-temperature reaction forming ceramic washbowl is characterized in that may further comprise the steps:
1) with normal-temperature reaction pottery mineral powder with strengthen additive and mix, add the entry stirring after, be filled in the washbowl model, treat that it reacts moulding after, from the washbowl model, take out; Described normal-temperature reaction pottery mineral powder is 1: 0.1～1.5 with the mass ratio that strengthens additive; Described normal-temperature reaction pottery mineral powder is selected from least a in ceramic powder, the fast set cement; Described ceramic powder is selected from silicate, magnesia and potassium dihydrogen phosphate three's mixture, and the mass percent of described silicate, magnesia and potassium dihydrogen phosphate is silicate 30%～40%, magnesia 30%～40% and potassium dihydrogen phosphate 20%～40%;
2) the smart throwing of craft is carried out in type ceramic washbowl surface, made its surface reach light, smooth effect;
3) surface treatment is carried out on the smart ceramic washbowl surface well of throwing, got normal-temperature reaction forming ceramic washbowl.
2. the preparation method of a kind of normal-temperature reaction forming ceramic washbowl as claimed in claim 1, it is characterized in that in step 1) described enhancing additive is selected from least a in metal powder, metal oxide powder, diamond dust, cement, quartz sand, glass fibre, epoxy resin, the unsaturated-resin.
3. the preparation method of a kind of normal-temperature reaction forming ceramic washbowl as claimed in claim 2 is characterized in that described metal powder is selected from least a in iron powder, tungsten powder, zinc powder, the copper powder.
4. the preparation method of a kind of normal-temperature reaction forming ceramic washbowl as claimed in claim 2 is characterized in that described metal oxide powder chosen from Fe oxysome, oxidation tungsten powder, at least a in zinc oxide, the cupric oxide powder.
5. the preparation method of a kind of normal-temperature reaction forming ceramic washbowl as claimed in claim 1 is characterized in that in step 1), and the described amount that adds entry is 5%～30% of normal-temperature reaction pottery mineral powder and enhancing additive gross mass by mass percentage.
6. as the preparation method of claim 1 or 5 described a kind of normal-temperature reaction forming ceramic washbowls, the temperature that it is characterized in that described water is 10～25 ℃, and the described time that adds the entry stirring is 2～10min.
7. the preparation method of a kind of normal-temperature reaction forming ceramic washbowl as claimed in claim 1, it is characterized in that in step 3), describedly smart throw good washbowl surface and carry out the surface-treated mode and adopt at least a in spray ceramic powder paint, vacuum coating, spray UV coating, the spray low-temp ceramics glaze mode.
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| CN 201110182694 CN102310455B (en) | 2011-06-30 | 2011-06-30 | Preparation method for ceramic washbasin formed by reacting at normal temperature |
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| CN 201110182694 CN102310455B (en) | 2011-06-30 | 2011-06-30 | Preparation method for ceramic washbasin formed by reacting at normal temperature |
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| CN102310455B true CN102310455B (en) | 2013-07-24 |
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| CN105906327A (en) * | 2016-03-30 | 2016-08-31 | 焦汉林 | Manufacturing method for colored flowerpot |
Citations (7)
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| CN1061584A (en) * | 1990-11-22 | 1992-06-03 | 焦俊魁 | The making method of inorganic imitation of ceramic products |
| CN1102610A (en) * | 1994-08-30 | 1995-05-17 | 国家建材局苏州混凝土水泥制品研究院 | Prefabricating method and die set for decorative concrete products |
| CN1138444A (en) * | 1996-05-09 | 1996-12-25 | 王佐存 | Method for prodn. of imitation ancient health carved chair |
| CN1173474A (en) * | 1996-12-17 | 1998-02-18 | 国家建筑材料工业局苏州混凝土水泥制品研究院 | Method for prefabricating decorative concrete produts. |
| CN101324287A (en) * | 2008-07-18 | 2008-12-17 | 张谭伟 | Baking-free artificial stone tap valve and manufacturing process thereof |
| CN101823864A (en) * | 2010-04-14 | 2010-09-08 | 吴智深 | Manufacturing method of aerated concrete |
| CA2698643A1 (en) * | 2009-10-22 | 2011-04-22 | Shanghai Huda Investment & Development Co., Ltd. | A resin-based composite sanitary ware and preparation method |
-
2011
- 2011-06-30 CN CN 201110182694 patent/CN102310455B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1061584A (en) * | 1990-11-22 | 1992-06-03 | 焦俊魁 | The making method of inorganic imitation of ceramic products |
| CN1102610A (en) * | 1994-08-30 | 1995-05-17 | 国家建材局苏州混凝土水泥制品研究院 | Prefabricating method and die set for decorative concrete products |
| CN1138444A (en) * | 1996-05-09 | 1996-12-25 | 王佐存 | Method for prodn. of imitation ancient health carved chair |
| CN1173474A (en) * | 1996-12-17 | 1998-02-18 | 国家建筑材料工业局苏州混凝土水泥制品研究院 | Method for prefabricating decorative concrete produts. |
| CN101324287A (en) * | 2008-07-18 | 2008-12-17 | 张谭伟 | Baking-free artificial stone tap valve and manufacturing process thereof |
| CA2698643A1 (en) * | 2009-10-22 | 2011-04-22 | Shanghai Huda Investment & Development Co., Ltd. | A resin-based composite sanitary ware and preparation method |
| CN101823864A (en) * | 2010-04-14 | 2010-09-08 | 吴智深 | Manufacturing method of aerated concrete |
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Address after: 361000 Tianfeng Road, Jimei District, Xiamen, Fujian Province, No. 69 Patentee after: Xiamen Jian Lin health home Limited by Share Ltd Address before: Room 1208, 12th floor, Lianqian Building, 859 Lianqian Road, Xiamen City, Fujian Province Patentee before: Xiamen Runner Industrial Corporation |
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