CN102139876B - 一种硅纳米管的制备方法 - Google Patents
一种硅纳米管的制备方法 Download PDFInfo
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- CN102139876B CN102139876B CN201110111770A CN201110111770A CN102139876B CN 102139876 B CN102139876 B CN 102139876B CN 201110111770 A CN201110111770 A CN 201110111770A CN 201110111770 A CN201110111770 A CN 201110111770A CN 102139876 B CN102139876 B CN 102139876B
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- silicon nanotube
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- 238000000034 method Methods 0.000 title abstract description 7
- 239000002620 silicon nanotube Substances 0.000 title abstract 8
- 229910021430 silicon nanotube Inorganic materials 0.000 title abstract 8
- 239000007790 solid phase Substances 0.000 claims abstract description 8
- 230000009471 action Effects 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 6
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims abstract description 6
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 6
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 5
- 239000003054 catalyst Substances 0.000 claims abstract description 5
- 239000002071 nanotube Substances 0.000 claims description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 13
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000012046 mixed solvent Substances 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 239000013543 active substance Substances 0.000 claims description 3
- 238000005352 clarification Methods 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 2
- 239000002070 nanowire Substances 0.000 abstract description 17
- 239000000843 powder Substances 0.000 abstract description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 8
- 239000002086 nanomaterial Substances 0.000 abstract description 8
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 4
- 239000002243 precursor Substances 0.000 abstract description 4
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 229910052681 coesite Inorganic materials 0.000 abstract 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract 3
- 229910052682 stishovite Inorganic materials 0.000 abstract 3
- 229910052905 tridymite Inorganic materials 0.000 abstract 3
- 239000011807 nanoball Substances 0.000 abstract 2
- 230000002194 synthesizing effect Effects 0.000 abstract 2
- 230000001603 reducing effect Effects 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 22
- 229910052710 silicon Inorganic materials 0.000 description 22
- 239000010703 silicon Substances 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000005406 washing Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical group C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 101100373011 Drosophila melanogaster wapl gene Proteins 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910019443 NaSi Inorganic materials 0.000 description 1
- 230000010748 Photoabsorption Effects 0.000 description 1
- 229910003902 SiCl 4 Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000004483 pasc Anatomy 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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CN102139876B true CN102139876B (zh) | 2012-10-17 |
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Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102616730A (zh) * | 2011-02-01 | 2012-08-01 | 成功大学 | 中空纳米管结构的制造方法 |
CN107352544A (zh) * | 2017-08-11 | 2017-11-17 | 贵州大学 | 一种用于锂离子电池尺寸可控硅纳米管的合成方法 |
CN107597107A (zh) * | 2017-08-30 | 2018-01-19 | 重庆中邦科技有限公司 | 一种2,3‑二氯吡啶生产用催化剂及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3985044B2 (ja) * | 2003-11-07 | 2007-10-03 | 独立行政法人物質・材料研究機構 | 単結晶珪素ナノチューブとその製造方法 |
WO2007145406A1 (en) * | 2006-06-15 | 2007-12-21 | Electronics And Telecommunications Research Institute | Method of manufacturing silicon nanotubes using doughnut-shaped catalytic metal layer |
CN101224887A (zh) * | 2008-02-03 | 2008-07-23 | 山东大学 | 一种硅纳米管/纳米线的制备工艺 |
CN101284667A (zh) * | 2008-05-29 | 2008-10-15 | 复旦大学 | 一种硅纳米管的制备方法 |
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- 2011-04-30 CN CN201110111770A patent/CN102139876B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3985044B2 (ja) * | 2003-11-07 | 2007-10-03 | 独立行政法人物質・材料研究機構 | 単結晶珪素ナノチューブとその製造方法 |
WO2007145406A1 (en) * | 2006-06-15 | 2007-12-21 | Electronics And Telecommunications Research Institute | Method of manufacturing silicon nanotubes using doughnut-shaped catalytic metal layer |
CN101224887A (zh) * | 2008-02-03 | 2008-07-23 | 山东大学 | 一种硅纳米管/纳米线的制备工艺 |
CN101284667A (zh) * | 2008-05-29 | 2008-10-15 | 复旦大学 | 一种硅纳米管的制备方法 |
Non-Patent Citations (2)
Title |
---|
JP特许第3985044号B2 2007.10.03 |
唐元洪等.硅纳米管的理论及制备研究进展.《材料导报》.2009,第23卷(第12期),1-5. * |
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Address after: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee after: trina solar Ltd. Patentee after: NANJING University Address before: 210093 Hankou Road, Jiangsu, China, No. 22, No. Co-patentee before: CHANGZHOU TRINA SOLAR ENERGY Co.,Ltd. Patentee before: Nanjing University |
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Address after: 210093 No. 22, Hankou Road, Nanjing, Jiangsu Co-patentee after: TRINASOLAR Co.,Ltd. Patentee after: NANJING University Address before: 210093 No. 22, Hankou Road, Nanjing, Jiangsu Co-patentee before: trina solar Ltd. Patentee before: Nanjing University |