CN102134392A - 一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 - Google Patents
一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 Download PDFInfo
- Publication number
- CN102134392A CN102134392A CN2011101036897A CN201110103689A CN102134392A CN 102134392 A CN102134392 A CN 102134392A CN 2011101036897 A CN2011101036897 A CN 2011101036897A CN 201110103689 A CN201110103689 A CN 201110103689A CN 102134392 A CN102134392 A CN 102134392A
- Authority
- CN
- China
- Prior art keywords
- flame
- retardant
- matrix material
- percent
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title abstract description 3
- 230000000979 retarding effect Effects 0.000 title abstract 3
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000001746 injection moulding Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 22
- 239000003063 flame retardant Substances 0.000 claims description 22
- 239000011159 matrix material Substances 0.000 claims description 17
- 239000002184 metal Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 6
- 229920002223 polystyrene Polymers 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 4
- 229910001051 Magnalium Inorganic materials 0.000 claims description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 4
- 229960001545 hydrotalcite Drugs 0.000 claims description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 8
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 2
- JVPKLOPETWVKQD-UHFFFAOYSA-N 1,2,2-tribromoethenylbenzene Chemical compound BrC(Br)=C(Br)C1=CC=CC=C1 JVPKLOPETWVKQD-UHFFFAOYSA-N 0.000 abstract 1
- 229920006351 engineering plastic Polymers 0.000 abstract 1
- 150000004679 hydroxides Chemical class 0.000 abstract 1
- -1 polytetrafluoroethylene Polymers 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- 238000013461 design Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000004377 microelectronic Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92885—Screw or gear
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及改性工程塑料领域，具体地说是一种具有高灼热丝温度的阻燃PA66复合材料及其工艺，其特征在于按照质量百分比配比如下：PA6673％，聚溴化苯乙烯20.3％，三氧化二锑4.33％，层状双羟基复合金属氧化物2.17％，聚四氟乙烯0.2％；所述复合材料的制作工艺包括以下步骤：将PA66在鼓风烘箱中于140℃下烘干4hr，按组分配方进行混合均匀；通过双螺杆挤出机中共混造粒，同时将得到的复合材料在注塑机中注塑成型；本发明优点在于：产品灼热丝起燃温度≥750℃，阻燃性94UL-V0级(0.8mm、1.6mm)，保持了常规溴系阻燃PA66材料的良好力学性能，满足白色家电领域的电子元器件材料的要求。
Description
[技术领域]
本发明涉及改性工程塑料领域，具体地说是一种具有高灼热丝温度的阻燃PA66复合材料及其工艺。
[背景技术]
目前具有高灼热丝温度的阻燃PA66复合材料基本上是通过除添加阻燃体系外再添加第三组分的树脂(如：PC)或增强材料(如：玻纤或矿粉)得到的，但由此技术配方制成的材料本质上已经改变了常规溴系阻燃PA66的良好性能，同时存在吸潮性差、冲击韧性低、密度偏高、流动性不好等问题，特别是应用在无人看管的白色家电所采用的电子元器件(厚度在1.0mm以下)很容易出现开裂、发脆现象，因此目前的技术配方无法满足无人看管的白色家电所采用的电子元器件材料性能的要求。
[发明内容]
本发明的目的是针对上述不足，设计一种具有高灼热丝温度且同时保持PA66原有良好性能的阻燃PA66复合材料。
为了实现上述目的，本发明设计一种具有高灼热丝温度的阻燃PA66复合材料，包括PA66、聚溴化苯乙烯、三氧化二锑、层状双羟基复合金属氧化物和聚四氟乙烯，其特征在于按照质量百分比配比如下：
1、PA66：73％，
2、聚溴化苯乙烯：20.3％，
3、三氧化二锑：4.33％，
4、层状双羟基复合金属氧化物：2.17％，
5、聚四氟乙烯：0.2％。
所述层状双羟基复合金属氧化物采用镁铝碳酸根型水滑石。
一种具有高灼热丝温度的阻燃PA66复合材料的制作工艺，其特征在于包括以下步骤：
a、将PA66在鼓风烘箱中于140℃下烘干4hr，按组分配方进行混合均匀；
b、通过双螺杆挤出机中共混造粒，同时将得到的复合材料在注塑机中注塑成型。
所述双螺杆挤出机的各段温度依次为：275℃、270℃、265℃、260℃、255℃、250℃、255℃、260℃、260℃、265℃，螺杆转速：300转/分；所述注塑机各段温度依次为：260℃、270℃、280℃、275℃。
所述PA66复合材料性能如下：灼热丝起燃温度(GWIT)≥750℃，拉伸屈服强度在50mm/min条件下为66.0～66.7MPa，断裂伸长率为5.88～7.01％，拉伸弹性模量为3022～3443MPa，弯曲强度在2mm/min条件下为100.3～101.8MPa，弯曲模量为2618～2736MPa，IZOD缺口冲击强度在23℃条件下为4.6～5.1KJ/m2，热变形温度在1.82MPa条件下为121.0～121.4℃，UL94阻燃性(0.8mm、1.6mm)为V0级。
本发明与现有技术相比，其优点在于：在常规溴系配方中引入一种金属氧化物，同时与三氧化二锑复配，复配后的添加量与常规溴系配方体系中的三氧化二锑添加量一致，本发明所生产的产品灼热丝起燃温度(GWIT)≥750℃，阻燃性94UL-V0级(0.8mm、1.6mm)，符合VDE标准，同时保持了常规溴系阻燃PA66材料的良好的力学性能，完全满足了无人看管的白色家电领域的电子元器件材料的要求。
[附图说明]
图1为本发明的具有高灼热丝温度的阻燃PA66复合材料的性能测试数据表；
图2为由本发明生产的具有高灼热丝温度的阻燃PA66复合材料，在不同厚度的状况下所获得的灼热丝起燃温度(GWIT)测试数据表。
[具体实施方式]
以下结合附图对本发明做进一步说明，这种制造技术对本专业的人士来说是清楚的。
本发明提供一种具有高灼热丝温度的阻燃PA66复合材料的配方，成份配比为：
1.PA66(聚酰胺PA66)：73％，
2.聚溴化苯乙烯：20.3％，
3.三氧化二锑：4.33％，
4.层状双羟基复合金属氧化物(镁铝碳酸根型水滑石)：2.17％，
5.聚四氟乙烯：0.2％。
本发明的工艺为：先按照配比将各组分混合均匀，通过同向双螺杆挤出机共混、挤出、冷却、切粒，同时将得到的复合材料在注塑机中注塑成标准样条。通过测试，完全满足制件厚度在0.8mm以上的灼热丝起燃温度(GWIT)≥750℃，阻燃性94UL-V0级(0.8mm、1.6mm)，符合VDE要求，完全满足应用在无人看管的白色家电领域的电子元器件的材料要求，同时完全满足薄壁产品(厚度在0.8mm以下)的韧性要求和注塑工艺要求，比目前市面上的材料更加优异。
实施例：
1、原材料：
①PA66：A27，德国巴斯夫公司
②聚溴化苯乙烯：PBS-64HW，美国大湖公司
③三氧化二锑：云南木利锑业有限公司
④层状双羟基复合金属氧化物(镁铝碳酸根型水滑石)：AC-106，广州呈和科技有限公司
⑤聚四氟乙烯：A100，四川晨光化工研究院
2、设备与仪器：
①
35同向双螺杆挤出机：SHJ-65B，南京广达化工设备有限公司
②熔体流动速率仪：XNR-400，承德金建检测仪器有限公司
③漏电起痕试验仪：LDQ-2，上海埃微电子科技有限公司
④水平垂直燃烧试验仪：HVL-75，上海埃微电子科技有限公司
⑤灼热丝试验仪：ZRF-JT，上海竞田电子科技有限公司
⑥塑料摆锤冲击试验机：ZGC7501-2，美特斯工业系统(中国)有限公司
⑦电子万能试验机：CMT6104，美特斯工业系统(中国)有限公司
⑧热变形维卡软化点试验机：ZWK1302-1，美特斯工业系统(中国)有限公司
⑨注塑机：PT80，宁波力劲有限公司
3、试样制备：
将PA66在鼓风烘箱中于140℃下烘干4hr，按发明内容的技术配方的组分配方进行混合均匀，然后通过双螺杆挤出机中共混造粒，同时将得到的复合材料在注塑机中注塑成标准样条。其中双螺杆挤出机的各段温度依次为：275℃、270℃、265℃、260℃、255℃、250℃、255℃、260℃、260℃、265℃，螺杆转速：300转/分。
注塑成型条件：注塑机各段温度依次为260℃、270℃、280℃、275℃。
制得的标准样条性能测试如图1、图2所示，灼热丝起燃温度(GWIT)≥750℃，拉伸屈服强度在50mm/min条件下为66.0～66.7MPa，断裂伸长率为5.88～7.01％，拉伸弹性模量为3022～3443MPa，弯曲强度在2mm/min条件下为100.3～101.8MPa，弯曲模量为2618～2736MPa，IZOD缺口冲击强度在23℃条件下为4.6～5.1KJ/m2，热变形温度在1.82MPa条件下为121.0～121.4℃，UL94阻燃性(0.8mm、1.6mm)为V0级。
Claims (5)
1.一种具有高灼热丝温度的阻燃PA66复合材料，包括PA66、聚溴化苯乙烯、三氧化二锑、层状双羟基复合金属氧化物和聚四氟乙烯，其特征在于按照质量百分比配比如下：
PA66：73％，
聚溴化苯乙烯：20.3％，
三氧化二锑：4.33％，
层状双羟基复合金属氧化物：2.17％，
聚四氟乙烯：0.2％。
2.如权利要求1所述的一种具有高灼热丝温度的阻燃PA66复合材料，其特征在于所述层状双羟基复合金属氧化物采用镁铝碳酸根型水滑石。
3.一种具有高灼热丝温度的阻燃PA66复合材料的制作工艺，其特征在于包括以下步骤：
a、将PA66在鼓风烘箱中于140℃下烘干4hr，按组分配方进行混合均匀；
b、通过双螺杆挤出机中共混造粒，同时将得到的复合材料在注塑机中注塑成型。
4.如权利要求3所述的一种具有高灼热丝温度的阻燃PA66复合材料的制作工艺，其特征在于所述双螺杆挤出机的各段温度依次为：275℃、270℃、265℃、260℃、255℃、250℃、255℃、260℃、260℃、265℃，螺杆转速：300转/分；所述注塑机各段温度依次为：260℃、270℃、280℃、275℃。
5.如权利要求1或3所述的一种具有高灼热丝温度的阻燃PA66复合材料及其制作工艺，所述PA66复合材料性能如下：灼热丝起燃温度≥750℃，拉伸屈服强度在50mm/min条件下为66.0～66.7MPa，断裂伸长率为5.88～7.01％，拉伸弹性模量为3022～3443MPa，弯曲强度在2mm/min条件下为100.3～101.8MPa，弯曲模量为2618～2736MPa，IZOD缺口冲击强度在23℃条件下为4.6～5.1KJ/m2，热变形温度在1.82MPa条件下为121.0～121.4℃，0.8mm和1.6mm厚度UL94阻燃性为V0级。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101036897A CN102134392B (zh) | 2011-04-25 | 2011-04-25 | 一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101036897A CN102134392B (zh) | 2011-04-25 | 2011-04-25 | 一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102134392A true CN102134392A (zh) | 2011-07-27 |
| CN102134392B CN102134392B (zh) | 2012-07-04 |
Family
ID=44294331
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101036897A Expired - Fee Related CN102134392B (zh) | 2011-04-25 | 2011-04-25 | 一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102134392B (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000022036A1 (de) * | 1998-10-15 | 2000-04-20 | L. Brüggemann KG | Mit kupfersalz und aromatischer halogenverbindung stabilisierte polyamidzusammensetzung |
| CN101200591A (zh) * | 2006-12-15 | 2008-06-18 | 上海杰事杰新材料股份有限公司 | 一种快速流动的耐高温尼龙复合材料 |
| CN101218305A (zh) * | 2005-07-08 | 2008-07-09 | 宝理塑料株式会社 | 阻燃性树脂组合物 |
| CN101802098A (zh) * | 2007-05-17 | 2010-08-11 | 三菱工程塑料株式会社 | 阻燃性聚酰胺树脂组合物 |
-
2011
- 2011-04-25 CN CN2011101036897A patent/CN102134392B/zh not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000022036A1 (de) * | 1998-10-15 | 2000-04-20 | L. Brüggemann KG | Mit kupfersalz und aromatischer halogenverbindung stabilisierte polyamidzusammensetzung |
| CN101218305A (zh) * | 2005-07-08 | 2008-07-09 | 宝理塑料株式会社 | 阻燃性树脂组合物 |
| CN101200591A (zh) * | 2006-12-15 | 2008-06-18 | 上海杰事杰新材料股份有限公司 | 一种快速流动的耐高温尼龙复合材料 |
| CN101802098A (zh) * | 2007-05-17 | 2010-08-11 | 三菱工程塑料株式会社 | 阻燃性聚酰胺树脂组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102134392B (zh) | 2012-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110452502B (zh) | 一种低翘曲良外观高耐热聚酯复合材料及其制备方法 | |
| CN101311223B (zh) | 高抗冲玻纤增强阻燃工程塑料及制备方法 | |
| CN102816384B (zh) | 一种浅缩痕低翘曲的玻纤增强聚丙烯材料及其制法与应用 | |
| CN102108181B (zh) | 一种热塑性合金及其制备方法 | |
| CN101311221A (zh) | 一种玻纤增强阻燃工程塑料及制备方法 | |
| CN113121962B (zh) | 聚四氟乙烯/液晶聚合物复合材料及其制备方法 | |
| CN102061076A (zh) | 一种超韧pc/pbt/pet合金及其制备方法 | |
| CN102993668A (zh) | 一种聚碳酸酯/丙烯腈-丁二烯-苯乙烯/聚丙烯三元合金材料及其制备方法 | |
| CN104559152A (zh) | 超支化聚酯在pa6中的应用 | |
| CN111621123A (zh) | 一种低翘曲pet/pbt复合材料及其制备方法 | |
| CN102766320A (zh) | 耐高温低成本pet/pbt合金材料及其制备方法 | |
| CN102942736B (zh) | 一种高玻纤含量增强聚丙烯材料及其制备方法 | |
| CN113105723A (zh) | 一种增强耐热可降解聚乳酸眼镜框及其制备方法 | |
| CN109320959B (zh) | 一种无卤高温尼龙pa6t增强阻燃复合材料及其制备方法 | |
| CN102120867B (zh) | 一种具有高cti的阻燃增强pbt复合材料及其生产工艺 | |
| CN108047705B (zh) | 一种阻燃聚酰胺组合物及其制备方法 | |
| CN102219995B (zh) | 具有高灼热丝温度的阻燃增强共聚尼龙复合材料及其工艺 | |
| CN102532821A (zh) | 一种改善耐热性能的合金材料 | |
| CN102234412A (zh) | 高性能阻燃pla/pc合金 | |
| CN102321347A (zh) | 高漏电起痕指数聚酯复合材料及其制备方法 | |
| CN112280292A (zh) | 一种高温热稳定性阻燃尼龙66复合材料及其制备方法 | |
| CN102134392B (zh) | 一种具有高灼热丝温度的阻燃pa66复合材料及其工艺 | |
| CN104086971A (zh) | 一种高流动性阻燃聚碳酸酯-聚苯乙烯组合物及其制备方法 | |
| CN107974079B (zh) | 一种尼龙abs合金复合材料及其制备方法 | |
| CN102838853A (zh) | 一种耐翘曲玻纤增强阻燃pbt材料及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170928 Address after: 201602 Shanghai Songjiang District Sheshan Town Road No. 701 Building 5 Tao Patentee after: Shanghai Tisma polymer composite material Co.,Ltd. Address before: 201602 No. 8158-1 Qing Qing highway, Sheshan Town, Shanghai, Songjiang District Patentee before: SHANGHAI FANHE POLYMER MATERIAL Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190115 Address after: Room 8-1, Building 9, 4888 Yuanjiang Road, Minhang District, Shanghai 201108 Patentee after: SHANGHAI PUGONG MATERIAL TECHNOLOGY Co.,Ltd. Address before: No. 701 Taogan Road, Sheshan Town, Songjiang District, Shanghai, 2010 Patentee before: Shanghai Tisma polymer composite material Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120704 |