CN102121570B - Self-luminous tube and its manufacture method - Google Patents
Self-luminous tube and its manufacture method Download PDFInfo
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- CN102121570B CN102121570B CN 201010019455 CN201010019455A CN102121570B CN 102121570 B CN102121570 B CN 102121570B CN 201010019455 CN201010019455 CN 201010019455 CN 201010019455 A CN201010019455 A CN 201010019455A CN 102121570 B CN102121570 B CN 102121570B
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- luminescent layer
- cerium oxide
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000000034 method Methods 0.000 title description 3
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 13
- -1 rare-earth aluminate Chemical class 0.000 claims abstract description 13
- 239000011521 glass Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000005498 polishing Methods 0.000 claims abstract description 8
- 230000002269 spontaneous effect Effects 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 15
- 239000000428 dust Substances 0.000 claims description 9
- 239000003063 flame retardant Substances 0.000 claims description 9
- 230000001681 protective effect Effects 0.000 claims description 8
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 235000019260 propionic acid Nutrition 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000005286 illumination Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000010410 layer Substances 0.000 abstract 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 abstract 3
- 239000011241 protective layer Substances 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 239000012757 flame retardant agent Substances 0.000 abstract 1
- 238000009825 accumulation Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
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Abstract
The invention discloses a self-luminous tube and a manufacturing method thereof. The self-luminous tube comprises a base tube (1), wherein a luminous layer (2) is cladded on the base tube (1); the luminous layer (2) comprises the following components in percentage by weight: 10-65 percent of rare-earth aluminate luminous powder, 5-30 percent of glass powder, 0.05-3 percent of hardening agent, 5-30 percent of flame retardant agent, 0.05-1 percent of nano cerium oxide, 0.05-1 percent of nano titanium oxide and a corresponding mass of unsaturated transparent resin. A transparent protective layer (3) is cladded outside the luminous layer (2). The surface of the base tube (1) is subjected to polishing treatment and then the luminous layer (2) is directly coated on the outside of the base tube (1). The transparent protective layer (3) consists of nano cerium oxide and PU gloss oil. The mass ratio of the PU gloss oil to nano cerium oxide is 10:0.05-10:0.1 and the outer profile thereof is in the shape of a polygon. The self-luminous tube can store energy by absorbing sunlight and lamplight without consuming electricity, can emit out light under a weak light condition, can be used for manufacturing guardrails with illumination and indication effects and better eliminate potential safety hazards when used on rugged mountain roads, and is safer and more reliable to use.
Description
Technical field
The present invention relates to a kind of luminous tube, relate in particular to a kind of spontaneous light pipe and manufacturing approach thereof.
Background technology
Current tubing is applied in many occasions, as can be applicable to as guardrail the intermountain road on both sides of the road, the loke shore limit, river at scenic spot and the occasions such as next door of stair, with protection people's action safety.But current tubing at dim light at present and be not easy to see, helps thereby be not easy to people, thereby can bring potential safety hazard to use when on bumpy rugged mountain path, using.For addressing this problem; Usually the method that adopts is that various electric light class lightings are set; Yet, electric light class lighting is set, not only need the labor electric energy; Do not meet the demand for development of current low-carbon economy, and these electric light class lightings can't play a role at all under situation about having a power failure.
Summary of the invention
The objective of the invention is provides a kind of energy that do not expend to the defective that above-mentioned prior art exists, can be luminous voluntarily in the place that light is dark, thus spontaneous light pipe and manufacturing approach thereof that use can be safe and reliable.
For realizing above-mentioned order, spontaneous light pipe provided by the present invention comprises a parent tube, is coated with a luminescent layer on the said parent tube; The component of this luminescent layer and the mass content of component are: rare earth aluminate luminescent powder 10-65%, glass dust 5-30%, curing agent 0.05-3%; Fire retardant 5-30%; Nano-cerium oxide 0.05-1% and nano-titanium oxide 0.05-1%, and the unsaturated transparent resin of respective quality, said luminescent layer is coated with a protective clear layer; Said parent tube surface is through polishing, said luminescent layer) directly be coated on this parent tube surface; Said protective clear layer is processed by nano-cerium oxide and PU gloss oil, and the mass ratio of PU gloss oil and nano-cerium oxide is 10: 0.05-10: 0.1; Said outline is polygon-shaped; Said parent tube is processed by metal material.
Contain luminescent powder in the luminescent layer of the spontaneous light pipe of the present invention, make it can be by absorbing sunshine and light accumulation of energy, without power consumption; Just can be luminous voluntarily in a little less than light; Can make guardrail, can eliminate safe hidden trouble better, thereby use safety and reliability with illumination and indicative function; And do not need integrated circuit and battery, thereby simple in structure, easy to manufacture, make and use cost cheap, and luminescent layer difficult drop-off and be full of cracks, hardness height, life-span are long.The parent tube polishing can be increased light emission rate.This protective clear layer can strengthen the absorptive of luminescent layer, prevents that effectively luminescent layer receives factor affecting such as moisture, ultraviolet ray in the environment, thereby can slow down aging and the look change, prolongs life of product.
In the above-mentioned spontaneous light pipe; The component of said luminescent layer and the mass content of component are: rare earth aluminate luminescent powder 25-40%; Glass dust 10-28%, curing agent 1-2%, fire retardant 10-25%; Nano-cerium oxide 0.5-1% and nano-titanium oxide 0.5-1%, and the unsaturated transparent resin of respective quality.This proportioning raw materials scope of luminescent layer can prolong due luminous intensity of product and fluorescent lifetime.
The manufacturing approach of spontaneous light pipe provided by the present invention comprises the steps:
1) will add in the unsaturated transparent resin by the mixture of the curing agent preparation of the nano-cerium oxide of the nano-titanium oxide of the fire retardant of the glass dust of the iron rare earth aluminate luminescent powder of mass ratio 25-40%, 10-28%, 10-25%, 0.5-1%, 0.5-1% and 1-2%, stir into liquid thing with certain flowability;
2) aforesaid liquid shape thing is injected in the die cavity of the mould that is equiped with parent tube in the die cavity, be placed on then and make the curing of liquid state thing on the oscillator, thereby form luminescent layer;
3) with after the polishing of luminescent layer outer surface, clean the luminescent layer outer surface with propionic acid ketone liquid;
4) will be by PU gloss oil and nano-cerium oxide with 10: 0.05-10: 0.1 quality be sprayed at the luminescent layer surface than liquid mixture prepared with spray gun, is placed in the baking box under 300-350 ℃ temperature roasting 1-2 minute then, can be made into luminous tube.
The manufacturing approach of the spontaneous light pipe of the present invention, manufacturing cost is lower, and luminescent layer difficult drop-off and be full of cracks, hardness is high, the life-span is long.
The manufacturing approach of above-mentioned spontaneous light pipe is in step 2) can on parent tube, apply a reflector layer before.
Description of drawings
Below in conjunction with accompanying drawing and embodiment the present invention is described in further detail.
Fig. 1 is the schematic cross-section of a kind of embodiment of the spontaneous light pipe of the present invention.
Fig. 2 is the schematic cross-section of the another kind of embodiment of the spontaneous light pipe of the present invention.
Fig. 3 is the schematic cross-section of spontaneous the third embodiment of light pipe of the present invention.
The specific embodiment
See also Fig. 1; A kind of embodiment of the spontaneous light pipe of the present invention comprises the parent tube 1 of the circle processed by metal material (also can be pottery, glass etc.); Parent tube 1 is coated with the reflector layer 4 of a white, is coated with a luminescent layer 2 on this reflector layer 4, and said luminescent layer 2 is coated with a protective clear layer 3.The component of said luminescent layer 2 and the mass content of component are: rare earth aluminate luminescent powder 10-65%; Glass dust 5-30%, curing agent 0.05-3%, fire retardant 5-30%; Nano-cerium oxide 0.05-1% and nano-titanium oxide 0.05-1%, and the unsaturated transparent resin of respective quality.As preferably, the component of said luminescent layer 2 and the mass content of component are: rare earth aluminate luminescent powder 25-40%, glass dust 10-28%; Curing agent 1-2%; Fire retardant 10-25%, nano-cerium oxide 0.5-1% and nano-titanium oxide 0.5-1%, and the unsaturated transparent resin of respective quality.During practical implementation, the component of said luminescent layer 2 and the mass content of component can be any a group in the following table.Said protective clear layer 3 is processed by nano-cerium oxide and PU gloss oil, and wherein the mass ratio of PU gloss oil and nano-cerium oxide is 10: 0.05-10: 0.1.
The mass content combination table of the component of luminescent layer and component
Contain luminescent powder in the luminescent layer 2 of the spontaneous light pipe of the present invention, make it can be by absorbing sunshine and light accumulation of energy, without power consumption; Just can be luminous voluntarily in a little less than light; Thereby the guardrail of making has illumination and indicative function, can eliminate safe hidden trouble better, thereby uses safety and reliability; And do not need integrated circuit and battery, thereby simple in structure, easy to manufacture, manufacturing and use cost are cheap.Wherein, the effect of reflector layer 4 is to increase light emission rate, and protective clear layer 3 can strengthen the suction optical activity of luminescent layer 2, prevents that effectively luminescent layer 2 receives factor affecting such as moisture, ultraviolet ray in the environment, thereby can slow down aging and the look change, prolongs life of product.
The manufacturing approach of above-mentioned spontaneous light pipe comprises the steps:
1) solidify under about 120 ℃ temperature with silica gel and process, self-luminous pipe mold, mould comprise separable and the upper die and lower die that fasten;
2) will add in the unsaturated transparent resin by iron rare earth aluminate luminescent powder, glass dust, fire retardant, nano-titanium oxide and curing agent mixture, stir into liquid thing with certain flowability with the preparation of certain mass ratio; On parent tube 1, apply a reflector layer 4 and make its dry solidification;
3) parent tube 1 is placed in the die cavity of the mould that upper die and lower die fasten to form, aforesaid liquid shape thing is injected in the die cavity inside cavity, be placed on then the liquid state thing is solidified, thereby form luminescent layer 2;
4) with after the polishing of luminescent layer 2 outer surfaces, cleaned luminescent layer 2 outer surface 1-5 hours with propionic acid ketone liquid;
5) will be sprayed at luminescent layer 2 surfaces with spray gun by PU gloss oil and nano-cerium oxide with certain mass ratio liquid mixture prepared, be placed in the baking box under 300-350 ℃ temperature roasting 1-2 minute then, can be made into luminous tube.
The manufacturing approach of the spontaneous light pipe of manufacturing approach the present invention of the spontaneous light pipe of the present invention, manufacturing cost is lower, and luminescent layer 2 difficult drop-offs and be full of cracks, hardness is high, the life-span is long.
The present invention is not limited to the above-mentioned specific embodiment, also can be polygon-shaped like the outline of spontaneous light pipe.Can not apply reflector layer 4 outside the said parent tube 1, and directly polishing carried out on the surface of parent tube 1, more said luminescent layer 2 directly is coated on this parent tube 1 surface.
Certainly, the above embodiment is merely preferred embodiment of the present invention, does not therefore limit protection scope of the present invention, so the equivalence that all shapes according to the present invention, structure and principle are done changes, all should be covered by in protection scope of the present invention.
Claims (3)
1. a spontaneous light pipe comprises a parent tube (1), it is characterized in that; Be coated with a luminescent layer (2) on the said parent tube (1), the component of this luminescent layer (2) and the mass content of component are: rare earth aluminate luminescent powder 10-65%, glass dust 5-30%; Curing agent 0.05-3%, fire retardant 5-30%, nano-cerium oxide 0.05-1% and nano-titanium oxide 0.05-1%; And the unsaturated transparent resin of respective quality, said luminescent layer (2) is coated with a protective clear layer (3); Said parent tube (1) surface is through polishing, and said luminescent layer (2) directly is coated on this parent tube (1) surface; Said protective clear layer (3) is processed by nano-cerium oxide and PU gloss oil, and the mass ratio of PU gloss oil and nano-cerium oxide is 10: 0.05-10: 0.1; Said spontaneous light pipe outline is polygon-shaped; Said parent tube (1) is processed by metal material.
2. spontaneous light pipe as claimed in claim 1; It is characterized in that the component of said luminescent layer (2) and the mass content of component are: rare earth aluminate luminescent powder 25-40%, glass dust 10-28%; Curing agent 1-2%; Fire retardant 10-25%, nano-cerium oxide 0.5-1% and nano-titanium oxide 0.5-1%, and the unsaturated transparent resin of respective quality.
3. the manufacturing approach of a spontaneous light pipe is characterized in that, comprises the steps:
1) will add in the unsaturated transparent resin by the mixture of the curing agent preparation of the nano-cerium oxide of the nano-titanium oxide of the fire retardant of the glass dust of the iron rare earth aluminate luminescent powder of mass ratio 25-40%, 10-28%, 10-25%, 0.5-1%, 0.5-1% and 1-2%, stir into liquid thing with certain flowability;
2) aforesaid liquid shape thing is injected in the die cavity of the mould that is equiped with parent tube (1) in the die cavity, be placed on then and make the curing of liquid state thing on the oscillator, thereby form luminescent layer (2);
3) with after the polishing of luminescent layer (2) outer surface, clean luminescent layer (2) outer surface with propionic acid ketone liquid;
4) will be by PU gloss oil and nano-cerium oxide with 10: 0.05-10: 0.1 quality be sprayed at luminescent layer (2) surface than liquid mixture prepared with spray gun, is placed in the baking box under 300-350 ℃ temperature roasting 1-2 minute then, can be made into luminous tube.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019455 CN102121570B (en) | 2010-01-11 | 2010-01-11 | Self-luminous tube and its manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019455 CN102121570B (en) | 2010-01-11 | 2010-01-11 | Self-luminous tube and its manufacture method |
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| Publication Number | Publication Date |
|---|---|
| CN102121570A CN102121570A (en) | 2011-07-13 |
| CN102121570B true CN102121570B (en) | 2012-12-05 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN 201010019455 Expired - Fee Related CN102121570B (en) | 2010-01-11 | 2010-01-11 | Self-luminous tube and its manufacture method |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8667993B2 (en) | 2011-07-26 | 2014-03-11 | Flexmaster Canada Ltd. | Composite hose with luminescent exterior portions |
| CN104110643B (en) * | 2013-04-22 | 2017-02-15 | 广东纳明新材料科技有限公司 | Luminous plate |
| CN104110644B (en) * | 2013-04-22 | 2017-05-31 | 广东纳明新材料科技有限公司 | A kind of luminous tube |
| CN103627199A (en) * | 2013-11-21 | 2014-03-12 | 陈奎鹏 | High-temperature resistant self-cleaning self-luminous material and preparation method thereof |
| CN110048031B (en) * | 2019-04-16 | 2021-01-01 | 深圳市华星光电半导体显示技术有限公司 | OLED panel light-emitting layer processing method, OLED panel preparation method and OLED panel |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084535A (en) * | 1992-09-19 | 1994-03-30 | 杨丽馨 | Luminescent coating |
| CN1843780A (en) * | 2006-01-26 | 2006-10-11 | 李昌海 | Novel functional decorative material inlaid with luminous material pattern and method for manufacturing the same |
| CN1971124A (en) * | 2006-11-30 | 2007-05-30 | 东莞市明光科技有限公司 | Passive night light |
| CN101231933A (en) * | 2007-01-25 | 2008-07-30 | 台达电子工业股份有限公司 | Cold cathode light tube |
-
2010
- 2010-01-11 CN CN 201010019455 patent/CN102121570B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084535A (en) * | 1992-09-19 | 1994-03-30 | 杨丽馨 | Luminescent coating |
| CN1843780A (en) * | 2006-01-26 | 2006-10-11 | 李昌海 | Novel functional decorative material inlaid with luminous material pattern and method for manufacturing the same |
| CN1971124A (en) * | 2006-11-30 | 2007-05-30 | 东莞市明光科技有限公司 | Passive night light |
| CN101231933A (en) * | 2007-01-25 | 2008-07-30 | 台达电子工业股份有限公司 | Cold cathode light tube |
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| Publication number | Publication date |
|---|---|
| CN102121570A (en) | 2011-07-13 |
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Owner name: GUANGDONG NAMING NEW MATERIAL SCIENCE + TECHNOLOGY Free format text: FORMER OWNER: ZHANG MINGDE Effective date: 20130809 |
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Inventor after: Zhang Mingde Inventor after: Ye Jinhua Inventor after: Liu Ruhuai Inventor after: Guo Qinghua Inventor before: Zhang Mingde |
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Free format text: CORRECT: INVENTOR; FROM: ZHANG MINGDE TO: ZHANG MINGDE YE JINHUA LIU RUHUAI GUO QINGHUA |
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Effective date of registration: 20130809 Address after: 523808 Guangdong province Dongguan City Songshan Lake Science and Technology Industrial Park Building No. 7 Room 305 Keyuan pine Patentee after: GUANGDONG NAMING NEW MATERIAL SCI. & TECH. Co.,Ltd. Address before: 523808 Guangdong province Dongguan City Songshan Lake Science and Technology Industrial Park Building 7, Room 305, Wan Pinaceae Patentee before: Zhang Mingde |
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