CN101776214B - Luminescent panel and manufacturing method thereof - Google Patents

Luminescent panel and manufacturing method thereof Download PDF

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Publication number
CN101776214B
CN101776214B CN2009100367486A CN200910036748A CN101776214B CN 101776214 B CN101776214 B CN 101776214B CN 2009100367486 A CN2009100367486 A CN 2009100367486A CN 200910036748 A CN200910036748 A CN 200910036748A CN 101776214 B CN101776214 B CN 101776214B
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China
Prior art keywords
luminous plaque
nano
luminescent layer
luminescent
titanium oxide
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Expired - Fee Related
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CN2009100367486A
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Chinese (zh)
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CN101776214A (en
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张明德
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Hebei Naming New Material Technology Co ltd
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Individual
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Abstract

The invention discloses a luminescent panel and a manufacturing method thereof. The luminescent panel is provided with a luminescent layer. The luminescent layer is prepared from the following components in percentage by weight: 10-50% of luminescent powder, 0.5-2% of nanometer titanium oxide, 0.05-2% of nanometer cerium, 0.05-0.2% of curing agent, 5-20% of flame retardant, 0.05-0.2% of accelerator, and the balance of transparent resin. The luminescent panel has the advantages of high luminescent brightness, long luminescent time, ultraviolet protection, good strength and long service life.

Description

Luminous plaque and manufacture method thereof
Technical field
The present invention relates to a kind of self-luminous product, relate in particular to a kind of luminous plaque and manufacture method thereof.
Background technology
Along with social fast development innovation and living standard improve constantly, people's environmental protection and energy saving consciousness, awareness of safety and market consciousness strengthen gradually, people also adopt the mode of setting off various patterns by contrast with light to carry out fire-fighting caution, fire-fighting publicity, advertising or beautify the environment more and more, especially the night life that present cities and towns, the view of light manufacture have not only brought safety to return people has brought many fine enjoyments.But there is several respects problem in this light that utilizes as the mode of setting off means by contrast, need a large amount of power consumptions, light fixture easily damages, has a power failure unavailable, more difficult being arranged on door, wall, corridor, ground.
For this reason, on market, occurred having the luminescent powder that holds the light function and being applied to and take the light-accumulative luminous goods that soft plastic, coating, paint and paper form as carrier various, but these light-accumulative luminous goods are due to the carrier material performance deficiency, the luminescent powder amount added is subject to certain limitation, and correspondingly the luminosity of light-accumulative luminous goods also is subject to certain limitation; In addition, these light-accumulative luminous product strengths are poor, the life-span is short, are difficult to reach people's instructions for use.
Summary of the invention
Main purpose of the present invention is the luminous plaque that a kind of luminosity is high, fluorescent lifetime long, intensity is good and the life-span is long is provided and its manufacture method is provided for the deficiency that above-mentioned prior art exists.
For achieving the above object, luminous plaque provided by the present invention has a luminescent layer, the component of this luminescent layer and the mass content of component are, luminescent powder 10-50%, nano-titanium oxide 0.5-2%, nano-cerium oxide 0.05-2%, curing agent 0.05-0.2%, promoter 0.0 5-0.2%, fire retardant 5-20%. surplus is the unsaturated transparent resin of artificial marble.
As mentioned above, luminous plaque of the present invention can be by absorbing sunshine and light accumulation of energy, without power consumption, but in the low light level or gauge without light source self-luminescence just; This luminous plaque can add the luminescent powder up to 50%, thereby its luminosity is high and fluorescent lifetime is long; And owing to adopting the unsaturated transparent resin of artificial marble, so its intensity is good and the life-span is long; Luminous plaque is due to the hardness of having added nano-titanium oxide and greatly strengthen luminous plaque, wherein nano-cerium oxide can absorb the ultraviolet ray in sunlight, produce photocatalytic effect, under the effect of light, can be by airborne organic matter, nitrogen oxide, oxidizing sulfur dioxide sex change, reaching antibiotic, self-cleaning, reduce the impact on luminous plaque of vehicle exhaust and airborne pollutant.
Figure, as further improving, in above-mentioned luminous plaque, is embedded with identification character figure body on described luminescent layer.So-called identifier word icon body can be the object with word, symbol and pattern-like of the effects such as guide, fire-fighting indication, caution.
In above-mentioned luminous plaque, can glue and be provided with identification character figure body in described luminescent layer one side.
In above-mentioned luminous plaque, be coated with a reflector layer on a side of described luminescent layer.Reflector layer can improve the light emission rate of luminous plaque.
In above-mentioned luminous plaque, described luminescent powder can be the rare earth aluminate luminescent powder.This luminescent powder has higher luminous intensity and long fluorescent lifetime.
In above-mentioned luminous plaque, the particle diameter of described nano-titanium oxide and nano-cerium oxide is the 0.3-0.8 micron.
The manufacture method of luminous plaque provided by the present invention, comprise the following steps:
(1) in transparent resin, add nano-titanium oxide and nano-cerium oxide, and stir;
(2) a certain amount of luminescent powder and fire retardant are added in the mixture of transparent resin and nano-titanium oxide, and stir;
(3) a certain amount of curing agent and promoter are added in step (2) gained mixture, and stir, obtain compound;
(4) compound is added in mould, solidify to form luminescent layer.
In the manufacture method of above-mentioned luminous plaque, before compound is added to mould, an identification character figure body can be positioned in mould.
The manufacture method of above-mentioned luminous plaque, can further carry out polishing to a side of described luminescent layer.
The manufacture method of above-mentioned luminous plaque, arrange a reflector layer on a side of described luminescent layer.
As mentioned above, luminous plaque of the present invention can be by absorbing sunshine and light accumulation of energy, without power consumption, but in the low light level or gauge without light source self-luminescence just; This luminous plaque can add the luminescent powder up to 50%, thereby its luminosity is high and fluorescent lifetime is long; And owing to adopting the unsaturated transparent resin of artificial marble, so its intensity is good and the life-span is long; Luminous plaque is owing to having added nano-titanium oxide and nano-cerium oxide, nano-titanium oxide can absorb the ultraviolet ray in sunlight, produce photocatalytic effect, under the effect of light, can be by airborne organic matter, nitrogen oxide, oxidizing sulfur dioxide sex change, reaching antibiotic, self-cleaning, reduce the impact on luminous plaque smoothness and brightness of vehicle exhaust and airborne pollutant.
The accompanying drawing explanation
Fig. 1 is a kind of forward structure schematic diagram of an embodiment of the present invention luminous plaque.
Fig. 2 is the side structure schematic diagram of luminous plaque shown in Figure 1.
The specific embodiment
For describing technology contents of the present invention, structural feature, the purpose of reaching and effect in detail, below in conjunction with embodiment and coordinate accompanying drawing to be explained in detail.
Refer to Fig. 1 and Fig. 2, luminous plaque of the present invention has the reflector layer 3 that a luminescent layer 1, some identification character figure bodies 2 and be embedded on described luminescent layer are covered in the white on a side of described luminescent layer.The component of described luminescent layer 1 and the mass content of component are: rare earth aluminate luminescent powder 10-50%, particle diameter is the nano-titanium oxide 0.5-2% of 0.3-0.8 micron, particle diameter is the nano-cerium oxide 0.05-2% of 0.3-0.8 micron, curing agent 0.05-0.2%, fire retardant 5-20%, promoter 0.05-0.2%, surplus is the unsaturated transparent resin of artificial marble.
A kind of manufacture method of the invention described above luminous plaque, comprise the following steps:
(1) in transparent resin, add nano-titanium oxide, nano-cerium oxide, and stir;
(2) a certain amount of luminescent powder and fire retardant are added in the mixture of transparent resin and nano-titanium oxide and nano-cerium oxide, and stir;
(3) a certain amount of curing agent and promoter are added in step (2) gained mixture, and stir, obtain compound;
(4) an identification character figure body is positioned in mould, compound is added in mould, solidify to form luminescent layer;
(5) polishing is carried out in a side of described luminescent layer;
(6) on a side of described luminescent layer, a reflector layer is set.
Above-mentioned luminous plaque can be by absorbing sunshine and light accumulation of energy, without power consumption, but in the low light level or gauge without light source self-luminescence just; This luminous plaque can add the luminescent powder up to 50%, thereby its luminosity is high and fluorescent lifetime is long; And owing to adopting the unsaturated transparent resin of artificial marble, so its intensity is good and the life-span is long; Luminous plaque is owing to having added nano-titanium oxide, nano-titanium oxide can absorb the ultraviolet ray in sunlight, produce photocatalytic effect, under the effect of light, can be by airborne organic matter, nitrogen oxide, oxidizing sulfur dioxide sex change, reaching antibiotic, self-cleaning, reduce the impact on luminous plaque of vehicle exhaust and airborne pollutant.Reflector layer can improve the light emission rate of luminous plaque.The rare earth aluminate luminescent powder has higher luminous intensity and long fluorescent lifetime.
The present invention is not limited to aforesaid embodiment, also can adopt printing or bonding method to stick on a side of luminescent layer as identification character figure body.

Claims (10)

1. luminous plaque, has a luminescent layer, it is characterized in that: the component of this luminescent layer and the mass content of component are, rare earth aluminate luminescent powder 10-50%, particle diameter are the nano-titanium oxide 0.5-2% of 0.3-0.8 micron, and particle diameter is the nano-cerium oxide 0.05-2% of 0.3-0.8 micron, curing agent 0.05-0.2%, promoter 0.05-0.2%, fire retardant 5-20%, surplus is the unsaturated transparent resin of artificial marble.
2. luminous plaque according to claim 1, is characterized in that: on described luminescent layer, be embedded with identification character figure body.
3. luminous plaque according to claim 1, is characterized in that: the sticky identification character figure body that is provided with in described luminescent layer one side.
4. luminous plaque according to claim 1, is characterized in that: be coated with a reflector layer on a side of described luminescent layer.
5. luminous plaque according to claim 1, it is characterized in that: described luminescent powder is the rare earth aluminate luminescent powder.
6. luminous plaque according to claim 1, it is characterized in that: the particle diameter of described nano-titanium oxide and nano-cerium oxide is the 0.3-0.8 micron.
7. the manufacture method according to the described luminous plaque of claim 1-6, comprise the following steps:
(1) in transparent resin, add nano-titanium oxide, and stir;
(2) a certain amount of luminescent powder and fire retardant are added in the mixture of transparent resin and nano-titanium oxide, and stir;
(3) a certain amount of curing agent and promoter are added in step (2) gained mixture, and stir, obtain compound;
(4) compound is added in mould, solidify to form luminescent layer.
8. the manufacture method of luminous plaque according to claim 5, is characterized in that: before compound is added to mould, an identification character figure body is positioned in mould.
9. the manufacture method of luminous plaque according to claim 5, it is characterized in that: polishing is carried out in the side to described luminescent layer.
10. the manufacture method of luminous plaque according to claim 5, is characterized in that: on a side of described luminescent layer, a reflector layer is set.
CN2009100367486A 2009-01-12 2009-01-12 Luminescent panel and manufacturing method thereof Expired - Fee Related CN101776214B (en)

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Application Number Priority Date Filing Date Title
CN2009100367486A CN101776214B (en) 2009-01-12 2009-01-12 Luminescent panel and manufacturing method thereof

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Application Number Priority Date Filing Date Title
CN2009100367486A CN101776214B (en) 2009-01-12 2009-01-12 Luminescent panel and manufacturing method thereof

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CN101776214B true CN101776214B (en) 2013-11-27

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103629621B (en) * 2013-11-21 2018-08-07 董绍品 A kind of spontaneous light scene lamp and its manufacturing method
CN103603475B (en) * 2013-11-21 2018-07-24 陈奎鹏 A kind of novel self-luminescence building brick and its manufacturing method
CN103602094A (en) * 2013-11-21 2014-02-26 董绍品 Self-cleaning self-flame-retardant self-luminous material and preparation method thereof
CN108936913A (en) * 2018-09-06 2018-12-07 天狼联盟材料科技研究(广东)有限公司 A kind of color luminous artificial tree for nighttime landscape
CN110513605B (en) * 2019-08-20 2020-12-29 西安鸿钧睿泽新材料科技有限公司 Garden landscape lamp with self-luminous function and manufacturing method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1254738A (en) * 1998-11-25 2000-05-31 孙逸龙 Multi-purposed both reflecting and luminous colour mixture for optical marks
CN101189703A (en) * 2005-05-31 2008-05-28 松下电器产业株式会社 Fluorescent lamp and process for producing the same, and illuminator

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1254738A (en) * 1998-11-25 2000-05-31 孙逸龙 Multi-purposed both reflecting and luminous colour mixture for optical marks
CN101189703A (en) * 2005-05-31 2008-05-28 松下电器产业株式会社 Fluorescent lamp and process for producing the same, and illuminator

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Effective date of registration: 20160205

Address after: 054700 No. 9 Chenguang street, Weixian County Economic Development Zone, Hebei, Xingtai

Patentee after: HEBEI NAMING NEW MATERIAL TECHNOLOGY CO.,LTD.

Address before: 523408, room 7, Songshan international student Pioneer Park, Dongguan, Guangdong 305, China

Patentee before: Zhang Mingde

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