CN102080028B - Dryopteris erythrosora/soapberry natural biomass detergent and preparation method thereof - Google Patents
Dryopteris erythrosora/soapberry natural biomass detergent and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a dryopteris erythrosora/soapberry natural biomass detergent and a preparation method thereof. The dryopteris erythrosora/soapberry natural biomass detergent is obtained through the processing technique of stewing, extraction, refining and compounding with leaves of dryopteris erythrosora and fruit of soapberry as raw materials; and the detergent can be liquid or powder. The dryopteris erythrosora/soapberry natural biomass detergent is mainly used for green cleaning, cleanliness maintaining and washing of dinnerware, fruits and vegetables, hair washing and bath, and has excellent oil stain cleaning effect, wherein the extract from the leaves of dryopteris erythrosora has the functions of natural sterilization, corrosion prevention, decontamination and itching relieving; the extract from the fruit of soapberry has the functions of natural decontamination, dandruff dispelling and itching relieving, and nutrition regulation; and the two extracts are both natural, non-toxic, safe and environment-friendly.
Description
Technical field:
The present invention relates to preparation and the method thereof of a kind of shield-fern, Seed of Chinese Soapberry natural biomass detergent, namely take the fruit of Dryopteridaceae plant leaf, soapberry as raw material, a kind of shield-fern, the Seed of Chinese Soapberry natural biomass detergent that prepare by boiling, extraction, refining, composite complete processing respectively, it can be liquiform product, also can be powder-like product.This technology belongs to household chemicals.
Background technology:
Shield-fern of the present invention, Seed of Chinese Soapberry natural biomass detergent are mainly used in green cleaning that tableware, fruits and vegetables clean, have one's hair wash, bathe, keep a public place clean, wash, its cleaning oil stain effect is rather good, wherein shield-fern plant leaf extracting solution has natural disinfection, anticorrosion, decontamination, itching-relieving action, Seed of Chinese Soapberry pulp extracting solution has natural decontamination, dandruff-removing itching-relieve, nutrition recuperating effect, and both are pure natural, nontoxic, safety, environmental protection.
Tableware, the fruits and vegetables of at home and abroad selling on the market at present washing composition that cleans, has one's hair wash, bathes, various in style, majority is to make by the raw material of chemical process acquisition take oil as raw material.Its basal component is that tensio-active agent and auxiliary agent form, mostly use chemical substance such as tensio-active agent, auxiliary agent, sanitas, white dyes, compound essence, synthetic colour, pruritus etc., because the synergy between each chemical substance, enhancement, antagonistic action, strong to the human body skin pungency, make it all exist more or less pungency and potential toxic effect to human body, HUMAN HEALTH is worked the mischief, and produce environmental pollution.
In the prior art, published washing composition take crude substance as main component also has.For example, Chinese patent 91105963 disclosed a kind of detergent composition and manufacture method thereof are made washing composition take Oil-tea-cake powder, Sodium dodecylbenzene sulfonate, perlite powder, sewage sodium sulfate etc. as raw material; Chinese patent 91106832 disclosed Withering tea powder detergents are with the washing composition of the withered powder of degreasing tea, lipid acid, glycollic amide, sanitas and essence composition; The Chinese patent 94107096 disclosed nontoxic powder of washing are a kind ofly to make tensio-active agent with natural fatty alcohol, lipid acid and other natural goodses, adopt simultaneously yellow soda ash, sal epsom, calcium carbonate, sepiolite, sodium bicarbonate etc. as the powder of washing of washing assistant; Chinese invention patent 95108213.2 " pure natural detergent and skincare product " through past foul, peeling, oven dry, pulverizing and packing, is made granularity less than the washing of 350 purposes and skincare product take soya bean as raw material.Washing and skin effect are good, and be all harmless to human body and environment.Its washing effect is undesirable, uses as disposable; Chinese invention patent 02803372.8 " active solubility cleaning composition of the native state of use soya fatty acid and preparation method thereof " discloses a kind of active water soluble natural detergent composition of soya fatty acid and Yelkin TTS and method for preparing said composition used.The method comprises stirs by natural phant lipid acid, Yelkin TTS, alkanolamide and the organic solvent mixture that forms of higher alcohols or polyvalent alcohol for example, saponification mixture is to form the microcosmic washing composition particulate that can carry out pedesis, according to humidity and pH value control gained washing composition, make the gained washing composition be in neutrality or alkaline state.This cleaning composition comprises the soya fatty acid of 14～22 weight parts, the Yelkin TTS of 2～4 weight parts, the alkanolamide of 6～14 weight parts, the iso-octyl phenoxy group polyoxy ethoxy ethanol of 15 weight parts, 42 weight part distilled water, the p-uncle of 10 weight parts-hydroxyl phenoxy group polyethoxyethanols and 3 weight part ethylenediamine tetraacetic acid (EDTA)s.Its composite is liquid, belongs to disposable product, and has added a large amount of synthetic surfactants.
At present, tableware, fruits and vegetables cleaning, hair washing, shower washing composition are being extensively understanding of people institute to the security of human body, the plant dinnerware of All Pure Nature, hair washing, shower washing composition are just having more and more wide market, and natural plant tableware of the present invention, hair washing, shower washing composition have been complied with this trend just.
Dryopteridoid ferns leaf natural plant raw material extracting solution used in the present invention, have multiple physiologically active and pharmacologically active, such as antitumor, immunological enhancement, anticoagulation, antiulcer agent, hypoglycemic, blood fat, anti-inflammatory, fatigue-resisting function, it acts on human body skin the effects such as antibiotic, sterilization and anti-inflammatory is arranged to be used for tableware, hair washing, shower washing composition.
Seed of Chinese Soapberry natural botanical extraction liquid used in the present invention, has sapindoside class Surface Active Substance, it can be used as natural stain remover, it acts on human body skin also antibiotic, antibacterial, sterilization, anti-inflammatory, moisturizing and anti-skin aging, improve the dark yellow and color spot effect of skin, be used for washing composition and have effect, it more contains many materials to the human body beneficial, can improve the problem of soapless soap injury human body, contaminate environment.Contain the abundant material to the human body beneficial in this extracting solution, such as reducing sugar, lipid acid, grease, carotenoid, riboflavin and multiple amino acids, also contain protein and multivitamin, its, opsonization nutritious to hair.
Pteridophyte claims again pteridophyte, belongs to more ancient original monoid in the vascular plant, namely is high spore plants, is again original vascular plant, is botanic important component part.Approximately there are 12000 kinds of pteridophytes in the whole world, is distributed in tropical and subtropical region more.In state-owned more than 2600 plant, but wherein 48 sections 108 that have of hyoscine belong to 396 kinds.Pteridophyte is of a great variety, widely distributed, aboundresources, always is among the people used, have edible, medicinal, industrial, the multiple use such as view and admire.
In China, the record of " in to adopt the shallow lake in apple, southern ravine " was just arranged in B.C. 6th century " Book of Songs "; Claim pyrrosia lingua to have the diuresis record of " control five retention of urines are obstructed, diuresis water channel " in 2nd century of Christian era " legendary god of farming hundred grass through "; Mid-term in 11st century, " the good book on Chinese herbal medicine of helping " claimed scouring rush Equisetum hiemale the nontoxic order disease of controlling.Ming Dynasty LI Shi-Zhen monumental work Compendium of Material Medica record " sweet cold, nontoxic, the lower aqueous vapor of apple, diuresis, only quench one's thirst " this shows that pteridophyte is long at the medicinal history of China.Over the years, pteridophyte is used for treating various diseases by among the people.There are some researches show, the pteridophyte polysaccharide compound has multiple physiologically active and pharmacologically active, such as antitumor, immunological enhancement, anticoagulation, antiulcer agent, hypoglycemic, blood fat, anti-inflammatory fatigue-resisting function.
Chemical composition to pteridophyte is studied, and finds its complicated component, wherein has bioactive composition and mainly contains phenolic compound, such as the chlorogenic acid of Phenylpropanoid Glycosides phenols, coffic acid, forulic acid etc.Two former phenol have the acid of chlorine unit, coffic acid etc., and the effect of antibiotic, hemostasis, diuresis is all arranged.The ternary phenols has bracken acids and pannol etc., is effective anthelmintic ingredient.Also contain simultaneously flavonoid, alkaloid and three note compounds.Butyryl radicals Phloroglucinol derivative often is present in the Dryopteris plant, and the pyrrosia lingua platymiscium contains xanthones compounds, and Rhizome of Fortune's Drynaria contains hesperidine and narigin.Alkaloids extensively is present in the microphyll type fern, as containing piliganine, lycopod poison alkali etc. in the Lycopodium.Steroidal and triterpene compound contain Herba Lycopodii serrati alcohol, Tuo Hening alcohol such as serrate clubmoss herb, and osmund contains insect molting and swashs rope.In addition, still contain tannin, multiple amino acids, lipid acid in the pteridophyte, fiddlehead contains 15 seed amino acids, and total amount is 136g/100g.Wherein essential amino acid has 7 kinds, and 15 kinds in lipid acid take linolic acid as main, is palmitinic acid, behenic acid, linolenic acid, oleic acid secondly, remaining amount micro element, and its saturated fatty acid content is a little more than unsaturated fatty acids.Hence one can see that: the large weight organic compounds that pteridophyte contains has special medicinal efficacy, also has the chemical composition of many Ferns Medicinals to await further to analyze and research.
Pteridophyte and the mankind's relation is very close, and except the pteridophyte in ancient times that has formed coal provides the mass energy for the mankind, existing pteridophyte is except the akee fern, and great majority are perennial herbs of being born in the mountain area, and multiple use is arranged economically.
Pteridophyte is more and more extensive in industrial purposes.As containing the number of chemical compositions such as piliganine in the lycopod, can provide blue dyes.Its spore oleaginousness approximately 40% is nondrying oil, is the good releasing agent of foundary industry.Spore is removed on the wall of machinery casting mould, can be prevented from casting liquid and attach on the wall of mould, can make the smooth surface of foundry goods, reduce sand holes.As glitter, can be used for rocket, signal flare, star shell etc., also can make the dressing of pill.Its stem floor file is overgrow and is several meters, is the quality matetrial of making various fabric.The scouring rush is as causing suddenly fuel on fire, contains siliceous a lot, can replace rubber friction woodenware and metallic weapon, is fabulous polishing agent.The petiole of Herba Pteridis creticae class, but the fiber rope making cable in the root stock, water-fast wet, be used for papermaking, can do pulp board, artificial cotton and beaver board.The starch that it is processed into can be used for sizing or slurry cloth, also can make wine or extracts alcohol.Complete stool contains tannin, can extract tannin extract, and tannin extract is the raw material with extensive use.Some kinds of Dryopteris contain the tanning matter of pyrocatechol, can extract the tannin processing leather.Bracken fern in the Aspidiaceae also contains abundant tannin.In addition, Stenoloma chusana can be cooked orchil.The blade of fiddlehead can be done green colouring material, and its rhizome can be done the khaki color dyestuff.
Sapindus Sapindaceae (Sapindaceae), formal name used at school: Seed of Chinese Soapberry (Sapindus mukurossi Gaertn), be commonly called as oil and suffer from son, fertile pearl etc., also cry soap tree or the fruit of washing one's hands, be a kind of deciduous tree of Sapindaceae Sapindus, all there is distribution the each province in the Taiwan Province of Southeast Asian countries, China and on the south the Huaihe River.
Seed of Chinese Soapberry contains many materials to the human body beneficial, such as reducing sugar, lipid acid, grease, oleic acid, thunder carotene, Bamboo-with-thin-wide-leaves acid, riboflavin, protein, vitamins C, vitamin-E, vitamins B and 10 multiple amino acids such as Methionin, phenylalanine, L-glutamic acid, glycine and Histidine, the glucosides class material that wherein enriches, be mainly triterpene saponin and hemiterpene glucosides class, has very strong surface-active action, for human body skin antibiotic, sterilization and anti-inflammatory effect are arranged, be natural nonionic surface active agent.Be rich in the triterpenoid saponins such as saponin(e in the arillus of Seed of Chinese Soapberry, have good whipability and detergency ability, can be used as natural active matter and be used for shampoo and various cleaning and protecting skin makeup; It also has the physiological functions such as antibiotic and antipruritic, can be used for the treatment of the ringworm of the foot and ringworm; It can make " natural nuisance-free washing composition ", is used for daily washing clothes.Washing effect is fine, can effectively remove spot, is rich in abundant foam, can sterilization; Can also beautify skin, also have whitening, nti-freckle is controlled the acne effect, can effectively prevent and treat dermatosis; Sapindoside or good farm chemical emulgent all have preferably killing effect to cotton aphid, red spider and sweet potato Jinhua worm etc.Pharmacological research shows, saponin constituent that the Seed of Chinese Soapberry pericarp closes has the multiple biological activitys such as anti-dermatophyte and candidiasis effect, inhibition tumor cell propagation, anti Helicobacter pylori activity, hepatoprotective effect.Because Seed of Chinese Soapberry contains the natural mild non-ionic surface active material of high-content, decontamination, scourability are fine, and contain simultaneously a large amount of natural nutrition conditioning materials, and be non-stimulated to human body, is desirable natural surface active agent.Because of its pure natural, 100% degradable, life-time service for human body and environment all without harm.
The outstanding medical scholar's LI Shi-Zhen of the Ming Dynasty is said: recluse exhale and are fertile pearl, and oil droplet is fertile such as the oil circle such as pearl also because of it." Seed of Chinese Soapberry is commonly called as.Fruit of Chinese Coffeetree has better clean effect than Chinese honey locust.Record in " a chicken ribs piece of writing ": few Chinese honey locust in the Zhejiang, bath face. wash clothes and all use fertile pearl.Wood is also tall and big, Ye Ruhuai and thin, and only three several cun of the male character types in Chinese operas, usu. referring tov the bearded character elders, the son circle is black loose, and meat is also thick, and cream moistens in Chinese honey locust, therefore a soap.The name of soap is come therefrom.Along with the reach of science, the appearance of chemical, soap of today has not had the composition of this class natural phant of Fruit of Chinese Coffeetree basically the sixth of the twelve Earthly Branches.Current environmental pollution, the requirement that impels people to propose to go back to nature should take full advantage of the Nature product, pollutes to reduce, and the to protect mankind environment is significant the sixth of the twelve Earthly Branches.
The Seed of Chinese Soapberry tree all has distribution in 13 provinces of China, autonomous region, and resource is wide.Think after deliberation, have on the CHANGQINGTENG sapogenin in the Seed of Chinese Soapberry extracting solution-COOR1 or-the COOH group ,-COOR1 can be hydrolyzed generation-COOH, plumbous wait heavy metal and-COOH generates Pb (COO)
2Deng and by wash-out; Also have a large amount of hydroxyls arranged on saponin and the phytomelin that (OH), the plumbous heavy metal that waits may (OH) form complex compound, inner complex and is pulled away with hydroxyl; In addition, saponin has similar soap sample cleaning action, is similar to surfactant properties.
Seed of Chinese Soapberry has another name called Fructus Sapindi Mukouossi, is nature surface-active agent and the natural washing raw material of the active and washing effect of tool in the newfound plant.Now caused the concern of cosmetics production firm all over the world, market outlook are considerable.Seed of Chinese Soapberry is fit to southern china Hills and garden planting, under the inspiration of huge potential market, the development of Seed of Chinese Soapberry planting base is very fast, according to incompletely statistics, the cultivated area of Seed of Chinese Soapberry is above 100,000 mu, can produce the Seed of Chinese Soapberry fruit after several years and reach 100,000 tons, but present maturation process and the production unit that there is no the sapindoside scale production both at home and abroad.
The EDTA that the present invention adds use is a kind of complexing agent, simultaneously again as a kind of sanitas, also can play efficient inhibition and soil washing to heavy metals such as lead.
Summary of the invention:
1, preparation and the method thereof of a kind of shield-fern, Seed of Chinese Soapberry natural biomass detergent is characterized in that may further comprise the steps:
The first step, the selection of forest tree kind: shield-fern leaf, soapberry fruit.
Second step, a kind of shield-fern, Seed of Chinese Soapberry natural biomass detergent contain shield-fern biomass extract, Seed of Chinese Soapberry biomass extract.It can be liquiform product, also can be powder-like product.
The 3rd step, the preparation of shield-fern biomass extract or powder
Take by weighing the bright leaf chopping of shield-fern, making beating or mummification leaf and pulverize, the shield-fern raw material can through too high comminution ratio crushing material, be got the raw materials ready.
The shield-fern got ready making beating material or crushed material are put into to extract and are filled with, and add deionized water, carry out three tanks, three steps countercurrent extraction, and solid-to-liquid ratio is controlled at 1: 5～and 10,80～95 ℃ of extraction temperatures, extraction time is controlled at 1.0～2.0 hours.Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is complete, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain shield-fern lixiviate scavenging solution.
Shield-fern lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60～65 ℃ of vacuum-concentrcteds are to 1/2～1/5 of original volume,, obtain shield-fern and purify concentrated solution, even the shield-fern extract.Shield-fern leaf extraction and cleaning concentrated solution requires solids content 20～35%.
Can be with concentrated shield-fern concentrated solution with the high pressure steam sterilization tank 15min that under 120 ℃ of conditions, sterilizes, for subsequent use.
Shield-fern extraction and cleaning concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery shield-fern extract.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 110～250 ℃, 65～90 ℃ of exhaust temperatures.
The 4th step, the preparation of Seed of Chinese Soapberry biomass extract or powder
Take by weighing fresh Seed of Chinese Soapberry fruit, add 2 times of deionized water making beating and pulverize, produce Seed of Chinese Soapberry making beating liquid.Maybe do constant weight with the Seed of Chinese Soapberry Exposure to Sunlight of collection or with drier (60～65 ℃) to gas.The dried Seed of Chinese Soapberry dry fruit to constant weight of gas carries out meat nuclear lock out operation, and the skin and flesh that is separated can through too high comminution ratio crushing material, be got the raw materials ready.
The Seed of Chinese Soapberry for preparing making beating liquid squeezed into to extract fills with, add deionized water to solid-to-liquid ratio in 1: 5～10 scope; Maybe the Seed of Chinese Soapberry crushed material for preparing is added to extract and fills with, add deionized water to solid-to-liquid ratio to be controlled at 1: 5～10 scope in, carry out three steps of three tanks and pass stream and extract, 80～102 ℃ of extraction temperatures, extraction time is controlled at 1.0～2.0 hours.Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is complete, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain Seed of Chinese Soapberry lixiviate scavenging solution.
Seed of Chinese Soapberry lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume,, obtain Seed of Chinese Soapberry and purify concentrated solution, even the Seed of Chinese Soapberry extract.Seed of Chinese Soapberry extraction and cleaning concentrated solution requires solids content 20～35%.
Seed of Chinese Soapberry extraction and cleaning concentrated solution is tasteless little Huang, connects diaphanous viscous liquid.Can be with concentrated shield-fern concentrated solution with the high pressure steam sterilization tank 10～15min that under 120 ℃ of conditions, sterilizes, for subsequent use.
Seed of Chinese Soapberry extraction and cleaning concentrated solution also can carry out press atomization or centrifugal spray drying, further makes powdery Seed of Chinese Soapberry extract.Press atomization or centrifugal spray drying inlet air temperature can be controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures.
The 5th step, to prepare according to a certain ratio aqueous or powdery shield-fern, Seed of Chinese Soapberry natural biomass detergent, its prescription is composed as follows:
Liquiform product: Seed of Chinese Soapberry is adopted extract, solids content 20～35%, consumption 30～80%; Dryopteridaceae plant leaf extracting solution, solids content 20～35%, consumption 10～40%; Deionized water: surplus.
Take by weighing respectively Seed of Chinese Soapberry extraction and cleaning concentrated solution, shield-fern extraction and cleaning concentrated solution by said ratio, and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling.
The deionized water quality requires to meet standard GB/T 6682-2000.
Powder-like product: Seed of Chinese Soapberry pulp extract, solids content 90～95%, consumption 20～75%; Dryopteridaceae plant leaf extract, solids content 90～95%, consumption 20～50%.
Take by weighing respectively Seed of Chinese Soapberry extraction and cleaning enriched material, shield-fern extraction and cleaning enriched material by said ratio, add an amount of plant auxiliary agent and natural essence, after the mixing and stirring, detect discharging, packing.
Description of drawings:
Fig. 1 is the flow process circle of the embodiment of the invention.
Embodiment:
Embodiment 1:
Get respectively each 5 kilograms of fresh shield-fern leaf, fresh Seed of Chinese Soapberry fruits, respectively add 20 kilograms in water and boil, filter, make with extra care, filtrate is placed the filtration of spending the night again respectively through being concentrated into 10 kilograms.Then get respectively 20 parts, 40 parts of above shield-fern, Seed of Chinese Soapberry aqueous extracts, 4 parts of EDTA, 36 parts of deionized waters add an amount of spices again and stir and namely obtain shield-fern of the present invention, the aqueous Betengent product of Seed of Chinese Soapberry biomass.
Embodiment 2:
Get respectively each 5 kilograms of the dried shield-fern leaf of gas, the dried Seed of Chinese Soapberry fruits of virgin gas, respectively add 30 kilograms in water and boil, filter, make with extra care, filtrate is placed the filtration of spending the night again respectively through being concentrated into 10 kilograms.Then get respectively 30 parts, 30 parts of above shield-fern, Seed of Chinese Soapberry aqueous extracts, 4 parts of EDTA, 36 parts of deionized waters add an amount of spices again and stir and namely obtain shield-fern of the present invention, the aqueous Betengent product of Seed of Chinese Soapberry biomass.
Embodiment 3.
Claims (2)
1. the preparation method of a shield-fern, Seed of Chinese Soapberry natural biomass washings is characterized in that may further comprise the steps:
The first step, the preparation of shield-fern biomass extract:
Take by weighing the bright leaf chopping of shield-fern, making beating or mummification leaf through too high comminution ratio crushing material, get the raw materials ready;
The shield-fern got ready making beating material or crushed material to be put into to extract fill with, add deionized water, carry out three tanks, three steps countercurrent extraction, solid-to-liquid ratio is controlled at 1: 5～and 10, extraction temperature is 80～95 ℃, extraction time is controlled at 1.0～2.0 hours; Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is finished, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain shield-fern lixiviate scavenging solution; Shield-fern lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60 ℃～65 ℃ vacuum-concentrcteds obtain shield-fern extraction and cleaning concentrated solution to 1/2～1/5 of original volume, and shield-fern extraction and cleaning concentrated solution requires solids content 20～35%;
Concentrated shield-fern extraction and cleaning concentrated solution is with the high pressure steam sterilization tank 15min that sterilizes under 120 ℃ of conditions, for subsequent use;
Second step, the preparation of Seed of Chinese Soapberry biomass extract:
Take by weighing fresh Seed of Chinese Soapberry fruit, add 2 times of deionized water making beating and pulverize, produce Seed of Chinese Soapberry making beating liquid; Maybe be dried to the dried constant weight of gas with the Seed of Chinese Soapberry Exposure to Sunlight of collection or with dryer at 60～65 ℃; The dried Seed of Chinese Soapberry dry fruit to constant weight of gas carries out meat nuclear lock out operation, and the skin and flesh that is separated is got the raw materials ready through too high comminution ratio crushing material;
The Seed of Chinese Soapberry for preparing making beating liquid squeezed into to extract fills with, add deionized water to solid-to-liquid ratio in 1: 5～10 scope; Maybe the Seed of Chinese Soapberry crushed material for preparing is added to extract and fills with, add deionized water to solid-to-liquid ratio to be controlled at 1: 5～10 scope in, carry out three tanks, three steps countercurrent extraction, extraction temperature is 80～102 ℃, extraction time is controlled at 1.0～2.0 hours; Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is complete, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain Seed of Chinese Soapberry lixiviate scavenging solution;
Seed of Chinese Soapberry lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, obtain Seed of Chinese Soapberry extraction and cleaning concentrated solution, and Seed of Chinese Soapberry extraction and cleaning concentrated solution requires solids content 20～35%;
Concentrated shield-fern extraction and cleaning concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use;
The 3rd step, the preparation of shield-fern, Seed of Chinese Soapberry natural biomass washings:
Take by weighing respectively according to a certain ratio above-mentioned Seed of Chinese Soapberry extraction and cleaning concentrated solution, shield-fern extraction and cleaning concentrated solution, and squeeze in the stirred vessel, add a certain amount of deionized water, and add an amount of plant auxiliary agent and natural essence, after stirring, detect discharging, bottling, namely get shield-fern, Seed of Chinese Soapberry natural biomass washings; Wherein said proportioning is: Seed of Chinese Soapberry extraction and cleaning concentrated solution, solids content 20～35%, consumption 30～80%; Shield-fern extraction and cleaning concentrated solution, solids content 20～35%, consumption 10～40%; Deionized water: surplus; Wherein the deionized water quality requires to meet standard GB/T 6682-2000.
2. the preparation method of a shield-fern, Seed of Chinese Soapberry natural biomass washing powder is characterized in that may further comprise the steps:
The first step, the preparation of shield-fern biomass extract powder:
Take by weighing the bright leaf chopping of shield-fern, making beating or mummification leaf through too high comminution ratio crushing material, get the raw materials ready;
The shield-fern got ready making beating material or crushed material to be put into to extract fill with, add deionized water, carry out three tanks, three steps countercurrent extraction, solid-to-liquid ratio is controlled at 1: 5～and 10, extraction temperature is 80～95 ℃, extraction time is controlled at 1.0～2.0 hours; Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is finished, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain shield-fern lixiviate scavenging solution; Shield-fern lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60 ℃～65 ℃ vacuum-concentrcteds obtain shield-fern and purify concentrated solution to 1/2～1/5 of original volume, and shield-fern purifies concentrated solution and requires solids content 20～35%;
Concentrated shield-fern is purified concentrated solution with the high pressure steam sterilization tank 15min that sterilizes under 120 ℃ of conditions, for subsequent use;
Above-mentioned shield-fern extraction and cleaning concentrated solution is carried out press atomization or centrifugal spray drying, further make shield-fern biomass extract powder, wherein press atomization or centrifugal spray drying inlet air temperature are controlled at 110～250 ℃, 65～90 ℃ of exhaust temperatures;
Second step, the preparation of Seed of Chinese Soapberry biomass extract powder:
Take by weighing fresh Seed of Chinese Soapberry fruit, add 2 times of deionized water making beating and pulverize, produce Seed of Chinese Soapberry making beating liquid; Maybe be dried to the dried constant weight of gas with the Seed of Chinese Soapberry Exposure to Sunlight of collection or with dryer at 60～65 ℃; The dried Seed of Chinese Soapberry dry fruit to constant weight of gas carries out meat nuclear lock out operation, and the skin and flesh that is separated is got the raw materials ready through too high comminution ratio crushing material;
The Seed of Chinese Soapberry for preparing making beating liquid squeezed into to extract fills with, add deionized water to solid-to-liquid ratio in 1: 5～10 scope; Maybe the Seed of Chinese Soapberry crushed material for preparing is added to extract and fills with, add deionized water to solid-to-liquid ratio to be controlled at 1: 5～10 scope in, carry out three tanks, three steps countercurrent extraction, extraction temperature is 80～102 ℃, extraction time is controlled at 1.0～2.0 hours; Carry out press filtration or the centrifugal discharge lock out operation of lixiviate feed liquid after lixiviate is complete, the head vat liquor that obtains reduces pressure or pressurization or millipore filtration purifying treatment, and elimination part insolubles and lixiviate material residue namely obtain Seed of Chinese Soapberry lixiviate scavenging solution;
Seed of Chinese Soapberry lixiviate scavenging solution carries out vacuum concentration and steams unnecessary water, and 60 ℃～65 ℃ are evaporated to 1/2～1/5 of original volume, obtain Seed of Chinese Soapberry extraction and cleaning concentrated solution, and Seed of Chinese Soapberry extraction and cleaning concentrated solution requires solids content 20～35%;
Concentrated Seed of Chinese Soapberry extraction and cleaning concentrated solution is with the high pressure steam sterilization tank 10～15min that sterilizes under 120 ℃ of conditions, for subsequent use;
Seed of Chinese Soapberry extraction and cleaning concentrated solution is carried out press atomization or centrifugal spray drying, further make Seed of Chinese Soapberry biomass extract powder; Wherein press atomization or centrifugal spray drying inlet air temperature are controlled at 115～250 ℃, 65～90 ℃ of exhaust temperatures;
The 3rd step, the preparation of shield-fern, Seed of Chinese Soapberry natural biomass washing powder:
Take by weighing respectively according to a certain ratio above-mentioned Seed of Chinese Soapberry powdery biomass extract, shield-fern powdery biomass extract, add an amount of plant auxiliary agent and natural essence, after the mixing and stirring, detect discharging, packing, namely get shield-fern, Seed of Chinese Soapberry natural biomass washing powder; Wherein said proportioning is: Seed of Chinese Soapberry powdery biomass extract, solids content 90～95%, consumption 20～75%; Shield-fern powdery biomass extract, solids content 90～95%, consumption 20～50%.
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| CN102604750A (en) * | 2012-01-12 | 2012-07-25 | 中国林业科学研究院林产化学工业研究所 | Method for preparing forest herbaceous plant biomass detergent |
| CN103205316A (en) * | 2013-03-13 | 2013-07-17 | 辽宁瑞达石油技术有限公司 | Purely natural botanic detergent and method for manufacturing same |
| CN105616195A (en) * | 2016-01-12 | 2016-06-01 | 洛阳和梦科技有限公司 | Environment-friendly sterilizing type shampoo |
| CN106214814A (en) * | 2016-07-28 | 2016-12-14 | 南京正宽医药科技有限公司 | The extracting method of a kind of Fructus Sapindi Mukouossi extracting solution and liquid soap |
| CN108283591A (en) * | 2018-03-13 | 2018-07-17 | 赵坚 | A kind of reparation water and preparation method thereof with skin repair function after shining |
| CN108294988A (en) * | 2018-03-13 | 2018-07-20 | 赵坚 | After-sun water and preparation method thereof made of one Plant Extracts |
| CN108283592A (en) * | 2018-03-13 | 2018-07-17 | 赵坚 | A kind of after-sun water and preparation method thereof containing plant extracts |
| CN108186467A (en) * | 2018-03-13 | 2018-06-22 | 赵坚 | Water and preparation method thereof is repaired made of a kind of pure plant |
| CN108186468A (en) * | 2018-03-13 | 2018-06-22 | 赵坚 | A kind of reparation water for repairing sun-damaged skin and preparation method thereof |
| KR102240480B1 (en) * | 2019-09-10 | 2021-04-23 | 주식회사 아이비웰니스 | An anti-acne composition comprising dryopteris erythrosora extracts as an active ingredient |
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| CN101225349A (en) * | 2007-01-18 | 2008-07-23 | 郭景龙 | Liquid detergent and method for preparing same |
| CN102031205A (en) * | 2009-10-01 | 2011-04-27 | 湖南益阳中信农林科技开发有限公司 | Natural plant washing preparation and preparation method thereof |
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| CN102031205A (en) * | 2009-10-01 | 2011-04-27 | 湖南益阳中信农林科技开发有限公司 | Natural plant washing preparation and preparation method thereof |
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