CN101982165A - Modified pearl moisturizer - Google Patents
Modified pearl moisturizer Download PDFInfo
- Publication number
- CN101982165A CN101982165A CN 201010519563 CN201010519563A CN101982165A CN 101982165 A CN101982165 A CN 101982165A CN 201010519563 CN201010519563 CN 201010519563 CN 201010519563 A CN201010519563 A CN 201010519563A CN 101982165 A CN101982165 A CN 101982165A
- Authority
- CN
- China
- Prior art keywords
- margarita
- modification
- margarita powder
- phase
- emollient cream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a moisturizer containing modified pearl powder in the field of cosmetics and a preparation method thereof. Because of having large specific surface area, easily aggregated property and hydrophilic and oleophobic performances, the nanometer pearl powder in the prior art can not be fully absorbed by skins. The preparation method comprises the following steps: activating the pearl powder through tetrabutyl titanate coupling agent, polymerizing the activated pearl powder with the soapfree emulsion of methacrylic acid methyl ester to form a polymer film on the surface of the pearl powder; transforming the surface of the pearl surface from hydrophily to hydrophobicity, so as to improve the affinity of the pearl powder and the organic medium; and adding various moisture substances and nutrient substances in the formula of the moisturizer to prepare into the modified pearl moisturizer. The modified pearl moisturizer solves the drawbacks that the systems can not be distributed evenly because of poor pearl powder dispersibility, and the product has poor stability caused by the damage on the emulsifying agent due to high surface free energy in the emulsifying process, has multiple functions of cleaning, moisturizing, whitening, wrinkling resisting and the like, and is suitable for multi-type skins.
Description
Technical field
The present invention relates to a kind of Margarita emollient cream, particularly a kind of emollient cream that contains the modification Margarita powder and preparation method thereof.
Background technology
Margarita is exactly classical beauty treatment medical material since ancient times, and successive dynasties medical science monumental works such as Compendium of Material Medica, " Mingyi Bielu ", " opening precious vegetation " point out all that Margarita has and calm the nerves, detoxify, preserve youthful looks, and makes us that gloss is pure white, the correcting and skin moisturizing and rejuvenating effect.
In the 70-80 age in last century, ZHENZHUSHUANG is monopolized literary excellence on the cosmetics market, and certain best brand of product pearl cream of south has been given prominence to the glamour of Margarita, and is on both sides of the Changjiang River fashionable.ZHENZHUSHUANG series of products quality does not only improve in recent years, instead because personation ZHENZHUSHUANG of poor quality floods market, cause the Margarita cosmetics to decline the market of progressively fading out by containing to change.
The traditional application mode of Margarita powder in cosmetics mainly contains, and the one, pulverize Margarita and become the 150-200 order, directly be added among the cosmetics, because particle diameter slightly is not easy absorption, even stops up pore easily and cause folliculitis; The 2nd, become Margarita hydrolyzed solution to be added in emollient cream with acid hydrolysis or enzymolysis Margarita powder, but destroyed original All Pure Nature of Margarita and integrity through chemical treatment, thereby loss greatly on effect.And by patent ZL200510050303.5 " preparation method of full natural Nano pearl powder " though the preparation Margarita powder kept original All Pure Nature of Margarita and integrity, but because of the nanometer Margarita powder specific surface area big, easily reunite, and feature, so still can not solve the problem that allows skin fully absorb with hydrophilic oleophobic.
Summary of the invention
The present invention handles by nanometer Margarita powder in the prior art being carried out modification, be equipped with multiple active ingredient again, be prepared into Margarita emollient cream, can overcome that Margarita powder is difficult for being absorbed and the ruined defective of hydrolyzed solution Margarita effective ingredient in the prior art, can improve Margarita powder dispersion in emollient cream again, eliminate the drawback of traditional Margarita emollient cream poor stability, give full play to preserve moisture, whiten, crease-resistant function.
One of the object of the invention provides a kind of prescription that contains modification Margarita emollient cream.
Two of the object of the invention provides a kind of preparation method of modification Margarita powder.
Three of the object of the invention provides a kind of preparation method that contains emollient cream of modification Margarita powder.
Composition of modification Margarita emollient cream of the present invention and content thereof following (by weight percentage):
The A phase:
Ceteareth-21 0.1-5% cetearyl alcohol 1-5%
Caprylic/capric triglyceride 5-15% polydimethylsiloxane 0.1-5%
Cetyl polydimethylsiloxane 0.1-2% isopropyl palmitate 1-10%
The B phase:
Butanediol 5-15% dipropylene glycol 1-10%
Stearoyl-glutamic acid sodium 0.1-5% co-emulsifier 1-5%
The C phase:
Thickening agent 1-10% modification Margarita powder 1-5%
Antiseptic, essence appropriate amount of deionized water surplus
Further, modification Margarita emollient cream of the present invention is formed and content following (by weight percentage) preferably:
The A phase:
Ceteareth-21 0.5-2% cetearyl alcohol 2-4%
Caprylic/capric triglyceride 8-12% polydimethylsiloxane 1-3%
Cetyl polydimethylsiloxane 0.8-1.2% isopropyl palmitate 4-8%
The B phase:
Butanediol 8-12% dipropylene glycol 4-7%
Stearoyl-glutamic acid sodium 0.5-1.5% co-emulsifier 2-4%
The C phase:
Thickening agent 4-7% modification Margarita powder 1-3%
Antiseptic, essence appropriate amount of deionized water surplus
Wherein, described thickening agent is glycerol polymethacrylates or propylene glycol, antiseptic is diazolidinyl urea, methyl hydroxybenzoate, propyl hydroxybenzoate or their complex, and co-emulsifier is polyacrylamide/C13-14 isoparaffin/laureth-7, is commercially available cosmetic material.
Described modification Margarita powder is a nanoscale, and average particle size range is the 40-100 nanometer, and its preparation method is:
(1) take by weighing nanometer Margarita powder, being mixed with mass fraction with deionized water is the 10-30% suspension;
(2) add the butyl titanate coupling agent of Margarita powder dry weight 1.5-2.0% in the suspension, 10-30min makes its activation with the middle-grade stirring of magnetic stirring apparatus;
(3) Margarita powder after will activating and the soap-free emulsion of methyl methacrylate mix 5-15min under room temperature, form the uniform polymeric film because of polyreaction makes the Margarita powder surface, and the soap-free emulsion mass fraction of used methyl methacrylate is 0.5%;
(4) polymer is at 60-80 ℃ of freeze-day with constant temperature, obtain the modification Margarita powder through comminution by gas stream again.
Modification Margarita emollient cream of the present invention prepares by the following method:
(1) the modification Margarita powder is dissolved in the B phase, it is biphase to 85-95 ℃ to heat A (except the co-emulsifier) and B more respectively, and keeps the 20min sterilization;
(2) when A, B are biphase when being cooled to 70-80 ℃, B is slowly moved into the A phase mutually, constantly stir, homogenizing, in 5-15min, add co-emulsifier and thickening agent successively;
(3) continue to stir and cool off Emulsion to 40-50 ℃, add antiseptic and essence more one by one, continue to be stirred to room temperature with chuck recirculated water.
The present invention handles by the coupling agent butyl titanate, and the emulsifier-free emulsion polymerization technology of methyl methacrylate makes the Margarita powder surface change hydrophobicity into by hydrophilic, has improved the affinity of Margarita powder and organic media.Modification Margarita emollient cream by the present invention's preparation, having solved the Margarita powder bad dispersibility brings the system skewness and because of the surface free energy height causes in emulsion process emulsifying agent is destroyed the drawback that causes the product stability difference, multiple functions such as having cleaning, preserve moisture, whiten, be crease-resistant is fit to polytype skin and uses.On probation by 600 people, modification Margarita emollient cream that relatively the present invention relates to and the exquisiteness and the stability of traditional Margarita emollient cream reflect that all effect is fine, and the result sees table 1 for details.
Below in conjunction with embodiment the present invention is specifically described, the present invention also can realize by other embodiments that does not break away from its spirit or essential feature.Therefore, below embodiment, just illustrate, be not only, all are within the scope of the present invention or be equal to that change all is included in the invention in the scope of the present invention.
Table 1:
The specific embodiment
Embodiment 1
1. by the following method Margarita powder being carried out modification handles:
Take by weighing nanometer Margarita powder earlier, add deionized water and be mixed with mass fraction 10% suspension, move into again and stir activation 30min down in the butyl titanate solution that accounts for Margarita powder dry weight 1.5%, then with the emulsifier-free emulsion polymerization of methyl methacrylate, make the Margarita powder surface form uniform polymeric, 60 ℃ of dryings, comminution by gas stream obtain composite granule and are modified nanometer Margarita powder.The soap-free emulsion mass fraction of used methyl methacrylate is 0.5%.
2. in following ratio batching and preparation 100kg modification ZHENZHUSHUANG:
The A phase:
Ceteareth-21 0.5kg cetearyl alcohol 3kg
Caprylic/capric triglyceride 10kg polydimethylsiloxane 2kg
Cetyl polydimethylsiloxane 1kg isopropyl palmitate 5kg
The B phase:
Butanediol 10kg dipropylene glycol 5kg
Stearoyl-glutamic acid sodium 0.3kg co-emulsifier 2kg
The C phase:
Thickening agent 5kg modification Margarita powder 1kg
Antiseptic, essence appropriate amount of deionized water surplus
The modification Margarita powder is dissolved in the B phase mixture, heats A (except the co-emulsifier) and ℃ dissolving of B two-phase mixture to 85 respectively, and keep 20min sterilization, be cooled to 80 ℃ then, mixing and emulsifying, stir, add co-emulsifier and thickening agent, continuation homogenizing 5min.Under agitation be cooled to 50 ℃ again, add antiseptic and essence, room temperature to be chilled to shifts out censorship.
Embodiment 2
1. by the following method Margarita powder being carried out modification handles:
Take by weighing nanometer Margarita powder earlier, add deionized water and be mixed with mass fraction 25% suspension, move into again and stir activation 10min down in the butyl titanate solution that accounts for Margarita powder dry weight 1.8%, then with the emulsifier-free emulsion polymerization of methyl methacrylate, make the Margarita powder surface form uniform polymeric, 80 ℃ of dryings, comminution by gas stream obtain composite granule and are modified nanometer Margarita powder.The soap-free emulsion mass fraction of used methyl methacrylate is 0.5%.
2. in following ratio batching and preparation 100kg modification ZHENZHUSHUANG:
The A phase:
Ceteareth-21 1kg cetearyl alcohol 5kg
Caprylic/capric triglyceride 13kg polydimethylsiloxane 1kg
Cetyl polydimethylsiloxane 0.5kg isopropyl palmitate 8kg
The B phase:
Butanediol 7kg dipropylene glycol 4kg
Stearoyl-glutamic acid sodium 1kg co-emulsifier 5kg
The C phase:
Thickening agent 8kg modification Margarita powder 1.8kg
Antiseptic, essence appropriate amount of deionized water surplus
Modification Margarita powder among the C is dissolved in B, heats A (except the co-emulsifier) and B to 90 ℃ of dissolving respectively, and keep 20min sterilization, be cooled to 75 ℃ then, mixing and emulsifying, stir, add co-emulsifier and thickening agent, continuation homogenizing 5min.Under agitation be cooled to 45 ℃ again, add antiseptic and essence, room temperature to be chilled to shifts out censorship.
Claims (8)
1. modification Margarita emollient cream, its prescription by weight percentage is:
The A phase:
Ceteareth-21 0.1-5% cetearyl alcohol 1-5%
Caprylic/capric triglyceride 5-15% polydimethylsiloxane 0.1-5%
Cetyl polydimethylsiloxane 0.1-2% isopropyl palmitate 1-10%
The B phase:
Butanediol 5-15% dipropylene glycol 1-10%
Stearoyl-glutamic acid sodium 0.1-5% co-emulsifier 1-5%
The C phase:
Thickening agent 1-10% modification Margarita powder 1-5%
Antiseptic, essence appropriate amount of deionized water surplus
2. modification Margarita emollient cream as claimed in claim 1, its prescription by weight percentage is:
The A phase:
Ceteareth-21 0.5-2% cetearyl alcohol 2-4%
Caprylic/capric triglyceride 8-12% polydimethylsiloxane 1-3%
Cetyl polydimethylsiloxane 0.8-1.2% isopropyl palmitate 4-8%
The B phase:
Butanediol 8-12% dipropylene glycol 4-7%
Stearoyl-glutamic acid sodium 0.5-1.5% co-emulsifier 2-4%
The C phase:
Thickening agent 4-7% modification Margarita powder 1-3%
Antiseptic, essence appropriate amount of deionized water surplus
3. modification Margarita emollient cream as claimed in claim 1 is characterized in that described thickening agent is glycerol polymethacrylates or propylene glycol.
4. modification Margarita emollient cream as claimed in claim 1 is characterized in that described antiseptic is a kind of in diazolidinyl urea, methyl hydroxybenzoate, three kinds of raw materials of propyl hydroxybenzoate or their complex.
5. modification Margarita emollient cream as claimed in claim 1 is characterized in that co-emulsifier is polyacrylamide/C13-14 isoparaffin/laureth-7.
6. modification Margarita emollient cream as claimed in claim 1, the mean diameter that it is characterized in that described modification Margarita powder is the 40-100 nanometer.
7. modification Margarita emollient cream as claimed in claim 6 is characterized in that the preparation method of described modification Margarita powder comprises the steps:
(1) take by weighing nanometer Margarita powder, being mixed with mass fraction with deionized water is the 10-30% suspension;
(2) add the butyl titanate coupling agent of Margarita powder dry weight 1.5-2.0% in the suspension, 10-30min makes its activation with the middle-grade stirring of magnetic stirring apparatus;
(3) Margarita powder after will activating and the soap-free emulsion of methyl methacrylate mix 5-15min under room temperature, and the soap-free emulsion mass fraction of used methyl methacrylate is 0.5%;
(4) polymer is at 60-80 ℃ of freeze-day with constant temperature, obtain the modification Margarita powder through comminution by gas stream again.
8. as the preparation method of claim 1,2 or 6 described modification Margarita emollient cream, it is characterized in that comprising the steps:
(1) mixes the biphase raw material of A, B respectively;
(2) the modification Margarita powder is dissolved in B mutually in, add respectively again beyond the evanescence of heat co-emulsifier A mutually and B to 85-95 ℃, and keep 20min and sterilize;
(3) when A, B are biphase when being cooled to 70-80 ℃, B is slowly moved into the A phase mutually, constantly stir, homogenizing, in 5-15min, add co-emulsifier and thickening agent successively;
(4) continue to stir and cooling Emulsion to 40-50 ℃, add antiseptic and essence more one by one, continue to be stirred to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010519563A CN101982165B (en) | 2010-10-26 | 2010-10-26 | Modified pearl moisturizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010519563A CN101982165B (en) | 2010-10-26 | 2010-10-26 | Modified pearl moisturizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101982165A true CN101982165A (en) | 2011-03-02 |
| CN101982165B CN101982165B (en) | 2012-10-10 |
Family
ID=43619089
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010519563A Active CN101982165B (en) | 2010-10-26 | 2010-10-26 | Modified pearl moisturizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101982165B (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104473847A (en) * | 2014-11-27 | 2015-04-01 | 浙江长生鸟珍珠生物科技有限公司 | Pearl skin-whitening BB cream and preparation method thereof |
| CN105125471A (en) * | 2015-10-13 | 2015-12-09 | 王丹 | Oil-control anti-wrinkle skin care product and preparing method thereof |
| CN106667883A (en) * | 2016-11-26 | 2017-05-17 | 无锡市汉方八珍科技有限公司 | Pearl honey and preparation method thereof |
| CN106806249A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of skin cream containing grape pip ginkgo biloba p.e and preparation method thereof |
| CN106806247A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of skin cream containing red pomegranate gadol extract and preparation method thereof |
| CN106806298A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of aloe ferment skin cream and preparation method thereof |
| CN106821837A (en) * | 2016-11-01 | 2017-06-13 | 田鹏新 | A kind of skin cream of the medicament extract of the root of herbaceous peony containing centella and preparation method thereof |
| CN109464383A (en) * | 2019-01-09 | 2019-03-15 | 湖南大湖生物技术有限公司 | A kind of pearl ammonia sugar nourishing cream and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300821A (en) * | 2002-04-08 | 2003-10-21 | Mikimoto Pharmaceut Co Ltd | Skin care preparation for external use |
| WO2007031167A1 (en) * | 2005-09-12 | 2007-03-22 | Austriamicrosystems Ag | Magnetic rotary encoder and method for iteratively aligning magnet relative to magnetic sensors |
| CN101695471A (en) * | 2009-10-19 | 2010-04-21 | 海南京润珍珠生物技术股份有限公司 | Liquid foundation added with pearl powder |
| CN101849897A (en) * | 2010-06-07 | 2010-10-06 | 贵阳高新瑞得科技开发有限公司 | Eye creams and production method thereof |
-
2010
- 2010-10-26 CN CN201010519563A patent/CN101982165B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003300821A (en) * | 2002-04-08 | 2003-10-21 | Mikimoto Pharmaceut Co Ltd | Skin care preparation for external use |
| WO2007031167A1 (en) * | 2005-09-12 | 2007-03-22 | Austriamicrosystems Ag | Magnetic rotary encoder and method for iteratively aligning magnet relative to magnetic sensors |
| CN101695471A (en) * | 2009-10-19 | 2010-04-21 | 海南京润珍珠生物技术股份有限公司 | Liquid foundation added with pearl powder |
| CN101849897A (en) * | 2010-06-07 | 2010-10-06 | 贵阳高新瑞得科技开发有限公司 | Eye creams and production method thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104473847A (en) * | 2014-11-27 | 2015-04-01 | 浙江长生鸟珍珠生物科技有限公司 | Pearl skin-whitening BB cream and preparation method thereof |
| CN105125471A (en) * | 2015-10-13 | 2015-12-09 | 王丹 | Oil-control anti-wrinkle skin care product and preparing method thereof |
| CN105125471B (en) * | 2015-10-13 | 2018-01-23 | 佛山市万盈化妆品有限公司 | A kind of crease-resistant skin care item of oil-control and preparation method thereof |
| CN106806249A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of skin cream containing grape pip ginkgo biloba p.e and preparation method thereof |
| CN106806247A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of skin cream containing red pomegranate gadol extract and preparation method thereof |
| CN106806298A (en) * | 2016-11-01 | 2017-06-09 | 田鹏新 | A kind of aloe ferment skin cream and preparation method thereof |
| CN106821837A (en) * | 2016-11-01 | 2017-06-13 | 田鹏新 | A kind of skin cream of the medicament extract of the root of herbaceous peony containing centella and preparation method thereof |
| CN106667883A (en) * | 2016-11-26 | 2017-05-17 | 无锡市汉方八珍科技有限公司 | Pearl honey and preparation method thereof |
| CN109464383A (en) * | 2019-01-09 | 2019-03-15 | 湖南大湖生物技术有限公司 | A kind of pearl ammonia sugar nourishing cream and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101982165B (en) | 2012-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101982165B (en) | Modified pearl moisturizer | |
| JP4823296B2 (en) | Carbon dioxide external preparation preparation composition | |
| JP4472170B2 (en) | Dry emollient composition | |
| TW589194B (en) | Cosmetic composition for keeping moisture | |
| CN1235617C (en) | Skin lightening composition containing magnesium ascorbyl phosphate and uniontan-U34 TM (extract formulation of cucumber extract and lemon extract) | |
| CN101842078A (en) | Gel sheet and cosmetic preparation in sheet form using the same | |
| WO2014117316A1 (en) | Multi-function aloe gel and preparation method thereof | |
| CN104473847A (en) | Pearl skin-whitening BB cream and preparation method thereof | |
| CN1682690A (en) | Bathing liquid composition and its preparing method | |
| CN107613950A (en) | Sebum adsorbent and the cosmetic preparation containing the sebum adsorbent | |
| CN112089644A (en) | Acne-removing and skin-refreshing soft mask powder composition and preparation and use methods thereof | |
| CN111920742A (en) | Chitosan multi-effect repair mask and preparation method thereof | |
| CN104546589A (en) | Skin moisturizer with components from natural food and application of skin moisturizer | |
| US20040191283A1 (en) | Texturizing composition for cosmetics or pharmaceuticals | |
| CN103284895B (en) | Essence lotion with slow release function and preparation method thereof | |
| JP2006063062A (en) | Cosmetic composition | |
| CN102697696B (en) | Pearl powder sun cream | |
| CN104352356A (en) | Humectant as well as preparation method and application thereof | |
| CN102266275B (en) | Application of refined deer oil in preparation of anti-wrinkle cosmetics | |
| CA2596733A1 (en) | Solid cosmetic and therapeutic compositions applicable to the human skin and gellable on contact with water | |
| CN101982163B (en) | Omega-3 fatty acid oil body lotion and preparation method thereof | |
| WO2016195141A1 (en) | Method for producing natural cosmetic liquid soap | |
| CN101966130A (en) | Silybin nano crystal cosmetics and preparation method thereof | |
| CN117137834A (en) | Blackhead-dispelling cosmetic composition and preparation method thereof | |
| CN103876961A (en) | Aloe massage cream |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 311804 Zhejiang Province, Zhuji city Jiyang street street, Sha Sha Road No. 48 Patentee after: Zhejiang changshengniao health Polytron Technologies Inc Address before: 311804 Zhejiang province Shanxiahu town Zhuji City, Pearl Industrial Park (Zhejiang changshengniao pearl biotechnology Co Ltd) Patentee before: Zhejiang Changshengniao Pearl Biotechnology Co., Ltd. |
|
| CP03 | Change of name, title or address |