CN1019796B - A kind of slow effect on packaged fertilizer - Google Patents
A kind of slow effect on packaged fertilizerInfo
- Publication number
- CN1019796B CN1019796B CN89102295A CN89102295A CN1019796B CN 1019796 B CN1019796 B CN 1019796B CN 89102295 A CN89102295 A CN 89102295A CN 89102295 A CN89102295 A CN 89102295A CN 1019796 B CN1019796 B CN 1019796B
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- sustained release
- packaged
- release dosage
- core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
Slow effect on packaged fertilizer is to be core with the water soluble fertilizer, is sustained release dosage with vegetables oil, animal oil or its greasy filth or its modifier, under the effect of natural and inorganic adhesive, and a kind of fertilizer that makes with parcel such as fused(calcium magnesium)phosphate or thomas phosphate.Plant nutrient ingredient such as potash fertilizer, trace element can be used as the wrapping inner layer of core.
Slow effect on packaged fertilizer is the inorganic of a kind of multi-nutrient a---organic composite fertilizer, can provide an amount of organic matter to soil, helps preservation of fertility.Sustained release dosage has the rate of release of slowing down soluble component, cheap and to characteristics such as soil is pollution-free.
Description
The invention belongs to slow effect on packaged fertilizer.
The slow-release fertilizer that is occurred in the world at present can be divided into this build and Envelope type two classes basically.The former is the slow-release fertilizer of directly making by chemical synthesis, as urinate formaldehyde fertilizer, IBDU and polyacrylamide etc., the latter is to be core with water-soluble granular fertilizer, and the outside coats various inorganicss (as sulphur etc.) or organic compound (as various natural or synthetic resins etc.).
The slow effect of this build slow-release fertilizer is relatively good, but costs an arm and a leg.Coated fertilizer is many as core, for example to wrap Thio Urea with single fertilizer (mainly being nitrogenous fertilizer).In recent years, for adapting to the requirement of crop, occurred again the coated fertilizer that is core with granular NPK compound manure to various nutrient elements.This fertilizer mostly with sulphur, paraffin and various petroleum resin or synthetic resins (for example polyethylene, polypropylene, polyvinyl chloride, acrylate and urethane etc.) as coating layer.Because costing an arm and a leg of most of coating materials causes fertilizer to bring a high price, and limited using of field crop, be used for garden crop at present more.With regard to the coated fertilizer that occurs at present, most of coated fertilizers are not the nutritive elements of plant, do not have the effect of improving the soil yet.In addition, this build slow-release fertilizer and coated fertilizer generally all can cause soil pollution in various degree.
The Wrapped fertilizer of Chinese patent CN851010083 is to be core with ammonium nitrate, urea, phosphorus ammonium or ammonium chloride, is binding agent with nitrogen phosphorus mud, with fused(calcium magnesium)phosphate, precipitated superphosphate or bone meal said core is wrapped up, and makes Wrapped fertilizer.Compare with general mixed fertilizer, Wrapped fertilizer has uniform particles, is difficult for moisture absorption and caking, is convenient to store and mechanized application, and utilization rate of fertilizer is than advantages such as height, compare with coated fertilizer, the core of Wrapped fertilizer is a water-soluble granular fertilizer, and the binding agent and the integument itself that adopt also are the main nutrient elements of plant, are a kind of polyelement composite fertilizers therefore.
But aspect the water-soluble nutritive ingredient of slow release, Wrapped fertilizer is then not ideal.Though the fused(calcium magnesium)phosphate itself as integument is water-fast, can observe the powdered calcium magnesium-phosphorus fertilizer under electron microscope is sheet structure, and many holes that differ in size (0.2-0.5 μ m) are arranged on its surface.When using the powdered calcium magnesium-phosphorus fertilizer, between particle, still there are many holes as integument.Because the existence of these holes, crackle and hole, can not hinder the infiltration of water molecules effectively, therefore, water soluble fertilizer in the core still can be released in the soil with speed faster, once in the laboratory Wrapped fertilizer had been carried out the immersion dissolution test, promptly in the beaker that is filled with water, put into Wrapped fertilizer, take out through the regular hour and observe whether still existence of core.Through experiment, straight fertilizers such as ammonium nitrate, urea are i.e. all dissolvings through 1-2 minute, and urea, ammonium nitrate in the above-mentioned Wrapped fertilizer core, its soaking time 1.5-2 hour only.
The dissolution rate that the objective of the invention is to make a kind of soluble component slowly, contain the inorganic-organic composite type slow effect on packaged fertilizer of various nutrient elements.This fertilizer can provide an amount of organic matter to soil, helps preservation of fertility, and can control the release rate of water soluble fertilizer according to the needs of different areas, Different Crop.
The present invention is to be core with the water soluble fertilizer, with the vegetables oil, animal oil or its greasy filth that plant are had certain trophism or its mixture or its modifier as sustained release dosage, under the effect of natural and inorganic adhesive, with fused(calcium magnesium)phosphate or thomas phosphate said core is wrapped up, make slow effect on packaged fertilizer.Nutritive ingredient such as potash fertilizer, trace element can be used as the wrapping inner layer of core.Slow effect on packaged fertilizer be a kind of inorganic-organic composite type fertilizer.
The core of slow effect on packaged fertilizer accounts for the 20-50% of fertilizer gross weight, and integument accounts for the 40-77% of fertilizer gross weight, can regulate the NPK proportioning according to the needs of crop.Sustained release dosage accounts for the 3-10% of fertilizer gross weight, regulates the slow effect on packaged fertilizer that sustained release dosage consumption and integument thickness just can make different rates of release.When the sustained release dosage consumption was 3-10%, the soaking time that core is kept perfectly was 15-30 days.In the soil that is embedded in certain humidity, after three months, observe, still have part particulate core to exist.The particle mean compressive strength of slow effect on packaged fertilizer is 10-30N.
Sustained release dosage of the present invention is: (1) each vegetable oil, as oleum gossypii seminis, rape seed oil, sesame oil, peanut oil and tung oil etc.; (2) greasy filth of above-mentioned each vegetable oil or residual oil; (3) various animal oil are as lard and butter etc.; (4) mixture of above-mentioned vegetables oil, animal oil or greasy filth; (5) vegetables oil after the modification, animal oil or its greasy filth.Sustained release dosage itself has certain nutritive ingredient, as the about 8-12% of NPK content of plant greasy filth.
The properties-correcting agent of sustained release dosage has starch and Mierocrystalline cellulose and the various organic waste materials etc. after vegetable wax, beeswax, butyl oleate, aluminium oleate, casein food grade, the modification.
Binding agent used in the present invention is natural glue and inorganic adhesive, rosin resin adhesive for example, and phosphoric acid salt tackiness agent etc., binder dosage is about the 5-15% of fertilizer gross weight.
The manufacture method of slow effect on packaged fertilizer: (1) is placing a certain amount of potash fertilizer (can add trace element as required) in the packing machine earlier continuously, other takes by weighing water soluble fertilizers such as the urea of some amount or ammonium nitrate, mix earlier with top said sustained release dosage, to particle surface all wetting till, pour into then in the continuous packing machine of continuous rotation; (2) spray into above-mentioned sustained release dosage equably by nozzle, and be sprinkled into pulverous fused(calcium magnesium)phosphate or thomas phosphate etc.; (3) alternately spray into H
3PO
4And Al(OH)
3Mixing solutions, and be sprinkled into fused(calcium magnesium)phosphate, until obtaining the granulated fertilizer that particle diameter is 2-4mm.After the slow effect on packaged fertilizer drying that makes, pack and get product.
Embodiment 1
Take by weighing raw material (weight) by following proportioning:
Urea 100
KCl 25
Fused(calcium magnesium)phosphate 200
Rape seed oil and greasy filth 18 thereof
Dilute phosphoric acid solution 12
Aluminium hydroxide 0.1
Earlier KCl is placed in the packing machine, mix and stir urea with vegetable seeds greasy filth, after treating that the surface is fully wetting, pour in the packing machine of continuous rotation, continue to spray into rape seed oil, and be sprinkled into fused(calcium magnesium)phosphate, and then alternately spray into the dilute phosphoric acid solution that is dissolved with aluminium hydroxide and be sprinkled into fused(calcium magnesium)phosphate, until obtaining the granulated fertilizer that particle diameter is 2-4mm, pack after the drying promptly getting slow effect on packaged fertilizer.
Embodiment 2
Take by weighing raw material (weight) by following proportioning:
Urea 100
KCl 30
MnSO
40.5
ZnSO
4·7H
2O 0.5
(NH
4)
6Mo
7O
24·4H
2O 0.003
Thomas phosphate 200
Boron mud 15
Oleum gossypii seminis and greasy filth 18 thereof
Dilute phosphoric acid solution 12
Earlier with KCl, MnSO
47H
2O, (NH
4)
6Mo
7O
244H
2O and boron mud mix and are placed in the packing machine, mix and stir urea with cotton seed greasy filth, after treating that the surface is fully wetting, pour in the packing machine of continuous rotation, spray into oleum gossypii seminis continuously, and be sprinkled into thomas phosphate, and then alternately spray into dilute phosphoric acid solution and be sprinkled into thomas phosphate, until obtaining the granulated fertilizer that particle diameter is 2-4mm, pack after the drying promptly getting slow effect on packaged fertilizer.
The present invention can be released in the soil solubility plant nutrient with different rates of release owing to used sustained release dosage lentamente, and therefore, it is a kind of multi-elements composite fertilizer material of slow excellent property.
Claims (2)
1, a kind of slow effect on packaged fertilizer, it is characterized in that it is with 20~50% (weight %, water soluble fertilizer down together) is a core, its external parcel layer is 40~77% fused(calcium magnesium)phosphate, contain 3~10% vegetables oil, animal oil in the integument, or its greasy filth sustained release dosage or be added with the sustained release dosage of properties-correcting agent and 5~15% Gum Rosin and phosphate binder.
2, according to the slow effect on packaged fertilizer of claim (1), the properties-correcting agent that it is characterized in that said sustained release dosage is starch and the Mierocrystalline cellulose after vegetable wax, beeswax, butyl oleate, aluminium oleate, casein food grade, the modification.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN89102295A CN1019796B (en) | 1989-04-12 | 1989-04-12 | A kind of slow effect on packaged fertilizer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN89102295A CN1019796B (en) | 1989-04-12 | 1989-04-12 | A kind of slow effect on packaged fertilizer |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1040781A CN1040781A (en) | 1990-03-28 |
CN1019796B true CN1019796B (en) | 1992-12-30 |
Family
ID=4854631
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN89102295A Expired CN1019796B (en) | 1989-04-12 | 1989-04-12 | A kind of slow effect on packaged fertilizer |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1019796B (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1040096C (en) * | 1995-08-17 | 1998-10-07 | 郑州乐喜施磷复肥技术研究推广中心 | Releasion controlled fertilizer |
CN100522894C (en) * | 2006-04-30 | 2009-08-05 | 中国科学院过程工程研究所 | Degradable natural organic matter bundled slow-releasing fertilizer and preparation method and usage thereof |
CN103724062A (en) * | 2012-10-10 | 2014-04-16 | 刘书起 | Large-grained inorganic coated fertilizer and production method thereof |
CN104151520B (en) * | 2014-07-22 | 2016-09-07 | 武汉诺唯凯生物材料有限公司 | A kind of modified starch preparation method based on vegetable fat plasticizer |
CN104151073B (en) * | 2014-08-11 | 2016-04-27 | 中国地质大学(武汉) | A kind of preparation method of film-coated and slow release fertilizer |
CN104446813A (en) * | 2014-12-11 | 2015-03-25 | 砀山县春源肥业有限公司 | Bioorganic fertilizer and preparation method thereof |
CN104496598B (en) * | 2014-12-11 | 2017-02-08 | 砀山县春源肥业有限公司 | Special organic fertilizer for watermelons and preparation method of special organic fertilizer |
CN105565974A (en) * | 2015-12-16 | 2016-05-11 | 湖北富邦科技股份有限公司 | Environment-friendly efficient multifunctional fertilizer wrapping agent as well as preparation method and application |
CN106995325A (en) * | 2016-01-26 | 2017-08-01 | 武汉金铭生物工程有限公司 | A kind of special fertilizer for Chinese goosebeery and preparation method thereof |
CN105948991A (en) * | 2016-05-14 | 2016-09-21 | 安徽新天地生物肥业有限公司 | Special organic controlled-release fertilizer for wheat |
CN106922356A (en) * | 2017-03-14 | 2017-07-07 | 凤冈县领益昕中药材种植有限公司 | The implantation methods of radix polygonati officinalis |
CN107337521A (en) * | 2017-07-17 | 2017-11-10 | 山东新朝阳作物营养有限公司 | A kind of long-acting Water soluble fertilizer of novel controlled release and preparation method thereof |
CN108358680A (en) * | 2018-01-19 | 2018-08-03 | 湖北富邦科技股份有限公司 | The micro- anti-dusting type phosphate fertilizer coating method of moisture-proof anti-caking in a kind of addition |
-
1989
- 1989-04-12 CN CN89102295A patent/CN1019796B/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
CN1040781A (en) | 1990-03-28 |
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