CN101969125A - Cathode lead plaster formula - Google Patents
Cathode lead plaster formula Download PDFInfo
- Publication number
- CN101969125A CN101969125A CN2010102879566A CN201010287956A CN101969125A CN 101969125 A CN101969125 A CN 101969125A CN 2010102879566 A CN2010102879566 A CN 2010102879566A CN 201010287956 A CN201010287956 A CN 201010287956A CN 101969125 A CN101969125 A CN 101969125A
- Authority
- CN
- China
- Prior art keywords
- percent
- lead plaster
- cathode lead
- fiber
- lignin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011505 plaster Substances 0.000 title claims abstract description 21
- 239000000835 fiber Substances 0.000 claims abstract description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 26
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 26
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004021 humic acid Substances 0.000 claims abstract description 13
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920005610 lignin Polymers 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 3
- 229920001197 polyacetylene Polymers 0.000 claims description 3
- 229920000128 polypyrrole Polymers 0.000 claims description 3
- 229920000123 polythiophene Polymers 0.000 claims description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a cathode lead plaster formula, which comprises the following components in percentage by weight: 80 to 85 percent of lead powder, 7 to 9 percent of deionized water, 7 to 10 percent of 45 mass percent sulfuric acid solution, 0.05 to 0.1 percent of conductive fiber, 0.5 to 1 percent of barium sulfate, 0.1 to 0.3 percent of lignin and 0.1 to 0.2 percent of humic acid. The formula has the advantages that: the internal resistance of a battery with the same structure is reduced by 10 percent by using the lead plaster, the n value in a 2-hour rate Peukert formula is less than 1.20, and the capacity discharged at high current is not greatly reduced.
Description
Technical field
The present invention relates to a kind of cathode lead plaster prescription.
Background technology
The composition of the paste spread type negative plate of preparation lead acid accumulator generally comprises at present: lead powder, water, sulfuric acid solution, can add such as various additives such as short fiber, barium sulfate, acetylene black, carbon black, humic acid, lignins, can cause the internal resistance of storage battery bigger with short fiber as the adhesion that additive increases between the lead plaster, the capacity of emitting during heavy-current discharge declines by a big margin, be that the Peukert resistance is bigger, such pole plate is relatively poor in the application power of motive-power battery.
Summary of the invention
The object of the present invention is to provide a kind of cathode lead plaster prescription, can effectively solve existing motive-power battery and make the problem that cathode lead plaster causes the battery applications ability as additive with short fiber.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions: a kind of cathode lead plaster prescription, comprise following component, the each component percentage by weight is: lead powder 80～85%, deionized water 7～9%, the sulfuric acid solution 7～10% of mass percent concentration 45%, conductive fiber 0.05～0.1%, barium sulfate 0.5～1%, lignin 0.1～0.3%, humic acid 0.1～0.2%.
Preferably, the each component percentage by weight is: lead powder 80%, deionized water 9%, the sulfuric acid solution 10% of mass percent concentration 45%, conductive fiber 0.1%, barium sulfate 0.6%, lignin 0.1%, humic acid 0.2%; Reach the cathode lead plaster prescription of optimum performance.
Preferably, the each component percentage by weight is: lead powder 85%, deionized water 7%, the sulfuric acid solution 7% of mass percent concentration 45%, conductive fiber 0.07%, barium sulfate 0.5%, lignin 0.3%, humic acid 0.13%; The cathode lead plaster prescription of optimality price ratio.
Preferably, the each component percentage by weight is: lead powder 83%, deionized water 8%, the sulfuric acid solution 8% of mass percent concentration 45%, conductive fiber 0.05%, barium sulfate 0.65%, lignin 0.2%, humic acid 0.1%; Most economical cathode lead plaster prescription.
Preferably, described conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber; Conductive fiber with excellent conductive performance.
Compared with prior art, advantage of the present invention is: the battery of same structure, use lead plaster of the present invention, and the internal resistance of battery has reduced n value in 10%, the 2 hour rate Peukert formula less than 1.20, and the capacity of emitting at big electric current also has no substantial decline.
Embodiment
Embodiment one:
A kind of cathode lead plaster prescription, the each component percentage by weight is: lead powder 80%, deionized water 9%, the sulfuric acid solution 10% of mass percent concentration 45%, conductive fiber 0.1%, barium sulfate 0.6%, lignin 0.1%, humic acid 0.2%.
Embodiment two:
A kind of cathode lead plaster prescription, the each component percentage by weight is: lead powder 85%, deionized water 7%, the sulfuric acid solution 7% of mass percent concentration 45%, conductive fiber 0.07%, barium sulfate 0.5%, lignin 0.3%, humic acid 0.13%.
Embodiment three:
A kind of cathode lead plaster prescription, the each component percentage by weight is: lead powder 83%, deionized water 8%, the sulfuric acid solution 8% of mass percent concentration 45%, conductive fiber 0.05%, barium sulfate 0.65%, lignin 0.2%, humic acid 0.1%.
More than among three kinds of embodiment, conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber.
The above only is specific embodiments of the invention, but technical characterictic of the present invention is not limited thereto, and any those skilled in the art is in the field of the invention, and the variation of being done or modify all is encompassed among the claim of the present invention.
Claims (5)
1. cathode lead plaster prescription, it is characterized in that: comprise following component, the each component percentage by weight is: lead powder 80～85%, deionized water 7～9%, the sulfuric acid solution 7～10% of mass percent concentration 45%, conductive fiber 0.05～0.1%, barium sulfate 0.5～1%, lignin 0.1～0.3%, humic acid 0.1～0.2%.
2. a kind of cathode lead plaster prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 80%, deionized water 9%, the sulfuric acid solution 10% of mass percent concentration 45%, conductive fiber 0.1%, barium sulfate 0.6%, lignin 0.1%, humic acid 0.2%.
3. a kind of cathode lead plaster prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 85%, deionized water 7%, the sulfuric acid solution 7% of mass percent concentration 45%, conductive fiber 0.07%, barium sulfate 0.5%, lignin 0.3%, humic acid 0.13%.
4. a kind of cathode lead plaster prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 83%, deionized water 8%, the sulfuric acid solution 8% of mass percent concentration 45%, conductive fiber 0.05%, barium sulfate 0.65%, lignin 0.2%, humic acid 0.1%.
5. as each described a kind of cathode lead plaster prescription in the claim 1 to 4, it is characterized in that: described conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102879566A CN101969125A (en) | 2010-09-15 | 2010-09-15 | Cathode lead plaster formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102879566A CN101969125A (en) | 2010-09-15 | 2010-09-15 | Cathode lead plaster formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101969125A true CN101969125A (en) | 2011-02-09 |
Family
ID=43548244
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102879566A Pending CN101969125A (en) | 2010-09-15 | 2010-09-15 | Cathode lead plaster formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101969125A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102522529A (en) * | 2011-12-30 | 2012-06-27 | 美美电池有限公司 | Manufacturing method for lead acid storage cell conductive polymer polar plate |
| CN102931412A (en) * | 2012-11-14 | 2013-02-13 | 徐永生 | Formula of cathode lead plaster of lead-acid storage battery |
| CN103384004A (en) * | 2013-07-05 | 2013-11-06 | 超威电源有限公司 | Storage battery cathode formula and preparation technology thereof |
| CN103943910A (en) * | 2014-03-12 | 2014-07-23 | 超威电源有限公司 | Regeneration method for lead slime produced in coating of lead acid battery plates |
| CN104253274A (en) * | 2014-08-22 | 2014-12-31 | 超威电源有限公司 | Lead-acid storage battery negative electrode lead paste |
| CN104681879A (en) * | 2013-11-29 | 2015-06-03 | 株式会社杰士汤浅国际 | Lead accumulator |
| CN106129339A (en) * | 2016-06-30 | 2016-11-16 | 济源市万洋绿色能源有限公司 | A kind of negative pole and cream technique |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030091898A1 (en) * | 2001-09-26 | 2003-05-15 | Dexter Derek Richard | Tuning battery electrode porosity technical field |
| JP2006120573A (en) * | 2004-10-25 | 2006-05-11 | Furukawa Battery Co Ltd:The | Negative electrode plate for control valve type lead-acid battery, and control valve type lead-acid battery using the above negative electrode plate |
| JP2007234507A (en) * | 2006-03-03 | 2007-09-13 | Furukawa Battery Co Ltd:The | Manufacturing method of negative electrode paste for lead-acid battery |
| CN101556997A (en) * | 2009-05-25 | 2009-10-14 | 长兴昌盛电气有限公司 | Super battery plate |
| CN101764264A (en) * | 2010-01-12 | 2010-06-30 | 李庆余 | Lead-acid ultra-battery |
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
-
2010
- 2010-09-15 CN CN2010102879566A patent/CN101969125A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030091898A1 (en) * | 2001-09-26 | 2003-05-15 | Dexter Derek Richard | Tuning battery electrode porosity technical field |
| JP2006120573A (en) * | 2004-10-25 | 2006-05-11 | Furukawa Battery Co Ltd:The | Negative electrode plate for control valve type lead-acid battery, and control valve type lead-acid battery using the above negative electrode plate |
| JP2007234507A (en) * | 2006-03-03 | 2007-09-13 | Furukawa Battery Co Ltd:The | Manufacturing method of negative electrode paste for lead-acid battery |
| CN101556997A (en) * | 2009-05-25 | 2009-10-14 | 长兴昌盛电气有限公司 | Super battery plate |
| CN101764264A (en) * | 2010-01-12 | 2010-06-30 | 李庆余 | Lead-acid ultra-battery |
| CN101807723A (en) * | 2010-03-24 | 2010-08-18 | 衡阳瑞达电源有限公司 | Lead-acid battery and manufacturing method thereof |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102522529A (en) * | 2011-12-30 | 2012-06-27 | 美美电池有限公司 | Manufacturing method for lead acid storage cell conductive polymer polar plate |
| CN102522529B (en) * | 2011-12-30 | 2014-09-17 | 美美电池有限公司 | Manufacturing method for lead acid storage cell conductive polymer polar plate |
| CN102931412A (en) * | 2012-11-14 | 2013-02-13 | 徐永生 | Formula of cathode lead plaster of lead-acid storage battery |
| CN103384004B (en) * | 2013-07-05 | 2015-09-23 | 超威电源有限公司 | Storage battery cathode formula and preparation technology thereof |
| CN103384004A (en) * | 2013-07-05 | 2013-11-06 | 超威电源有限公司 | Storage battery cathode formula and preparation technology thereof |
| CN104681879B (en) * | 2013-11-29 | 2020-07-10 | 株式会社杰士汤浅国际 | Lead-acid battery |
| CN104681879A (en) * | 2013-11-29 | 2015-06-03 | 株式会社杰士汤浅国际 | Lead accumulator |
| CN103943910A (en) * | 2014-03-12 | 2014-07-23 | 超威电源有限公司 | Regeneration method for lead slime produced in coating of lead acid battery plates |
| CN103943910B (en) * | 2014-03-12 | 2016-02-03 | 超威电源有限公司 | The plumbous sludge regeneration method of a kind of lead acid accumulator coated plate |
| CN104253274B (en) * | 2014-08-22 | 2016-08-31 | 超威电源有限公司 | A kind of lead-acid accumulator negative pole lead paste |
| CN104253274A (en) * | 2014-08-22 | 2014-12-31 | 超威电源有限公司 | Lead-acid storage battery negative electrode lead paste |
| CN106129339A (en) * | 2016-06-30 | 2016-11-16 | 济源市万洋绿色能源有限公司 | A kind of negative pole and cream technique |
| CN106129339B (en) * | 2016-06-30 | 2018-11-02 | 济源市万洋绿色能源有限公司 | A kind of cathode and cream technique |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20110209 |