CN103606658A - High-energy-storage environmental-protection lead-acid storage battery lead plasters containing regenerated lead - Google Patents
High-energy-storage environmental-protection lead-acid storage battery lead plasters containing regenerated lead Download PDFInfo
- Publication number
- CN103606658A CN103606658A CN201310522722.9A CN201310522722A CN103606658A CN 103606658 A CN103606658 A CN 103606658A CN 201310522722 A CN201310522722 A CN 201310522722A CN 103606658 A CN103606658 A CN 103606658A
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- China
- Prior art keywords
- lead
- parts
- battery
- acid
- graphene
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
- H01M4/57—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead of "grey lead", i.e. powders containing lead and lead oxide
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
High-energy-storage environmental-protection lead-acid storage battery lead plasters containing regenerated lead comprise an anode lead plaster and a cathode lead plaster. The anode lead plaster comprises the following components in parts by weight: 19 to 21 parts of regenerated lead powder, 55 to 65 parts of electronic grade rare earth red lead, 8 to 12 parts of deionized water, 3 to 5 parts of graphene, and 5 to 7 parts of dilute sulfuric acid. The cathode lead plaster comprises the following components in parts by weight: 10 to 22 parts of regenerated lead powder, 50 to 60 parts of electronic grade rare earth red lead, 8 to 12 parts of deionized water, 4 to 6 parts of graphene, 4 to 6 parts of dilute sulfuric acid, 1 to 3 parts of carbon black, and 2 to 4 parts of barium stearate. After a storage battery is prepared from the prepared lead plasters, the initial capacity and the cycle life are quite high, the charge speed and the discharge speed of the lead-acid battery are improved, at the same time, because of the graphene own structural strength and network connection, the battery polar plate strength is greatly improved, softening and shedding of polar plate activity materials during long time charge-discharge cycles of the lead-acid battery are avoided, and thus the service life of the lead-acid battery is greatly improved.
Description
Technical field
The present invention relates to battery technology field, be specifically related to a kind of high energy storage environmental protection lead acid accumulator lead plaster that contains reviver.
Background technology
Lead-acid battery has had the history of 130 years, has dependable performance, and mature production technology, compared with Ni-MH battery and lithium battery low cost and other advantages.The current electric motor car overwhelming majority adopts sealing-type lead-acid battery.Sealing-type lead-acid battery is that positive and negative pole plate interfolded is arranged in battery case, between positive and negative pole plate, with insulating barrier, isolates, and in electrolyte is filled with battery case, the lead on electrolyte and positive and negative pole plate carries out chemical reaction.When battery charges, the lead becoming on the positive and negative two-plate of lead sulfate is discharged into the sulfuric acid composition being fixed therein in electrolyte, becomes respectively lead and lead oxide, and the sulfuric acid concentration in electrolyte is constantly increased, and voltage rises, savings energy; During electric discharge, lead oxide in positive plate and the lead on negative plate and the sulfuric acid in electrolyte react and become lead sulfate, sulfuric acid concentration in electrolyte is constantly reduced, voltage drop, energy is reduced, battery is externally exported energy, therefore the cycle charge-discharge of battery is the process that electric energy and chemical energy are constantly changed, finally realizes storage and the release of energy.
Electric boosted automobile-used lead acid accumulator is the core component that is applied to Moped Scooter field, and the Performance and quality of storage battery is directly connected to normally travelling of Moped Scooter, and the Performance and quality of lead acid accumulator is mainly subject to the impact of lead paste formula.At present, the lead paste formula of domestic electric boosted automobile-used lead acid accumulator is different, mostly directly uses the formula of common valve-regulated lead-acid battery, and the formula of common valve control storage battery cannot solve resistance to over-discharge property and the poor problem of charge acceptance of storage battery.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of over-discharge property and poor problem of charge acceptance that overcomes electric boosted automobile-used lead acid accumulator, improves the high energy storage environmental protection lead acid accumulator lead plaster that contains reviver in its useful life.
Technical problem to be solved by this invention realizes by the following technical solutions:
A high energy storage environmental protection lead acid accumulator lead plaster that contains reviver, is comprised of anode diachylon and cathode lead plaster, and described anode diachylon is comprised of the component of following parts by weight,
Described cathode lead plaster is comprised of the component of following parts by weight,
The invention has the beneficial effects as follows: the lead plaster that adopts the present invention to prepare, make after storage battery, there is very high initial capacity and cycle life, charging rate and the velocity of discharge of lead-acid battery have been improved, simultaneously due to Graphene self structure intensity and network connection thereof, the intensity of battery pole plates is greatly improved, and has avoided the softening and shedding of lead-acid battery plate active material when long-time charge and discharge cycles, so greatly improved the useful life of lead-acid battery.
Embodiment
For technological means, creation characteristic that the present invention is realized, reach object and effect is easy to understand, below in conjunction with specific embodiment, further set forth the present invention.
A high energy storage environmental protection lead acid accumulator lead plaster that contains reviver, is comprised of anode diachylon and cathode lead plaster, and described anode diachylon is comprised of the component of following parts by weight,
Described cathode lead plaster is comprised of the component of following parts by weight,
More than show and described basic principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (1)
1. a high energy storage environmental protection lead acid accumulator lead plaster that contains reviver, is comprised of anode diachylon and cathode lead plaster, it is characterized in that: described anode diachylon is comprised of the component of following parts by weight,
Described cathode lead plaster is comprised of the component of following parts by weight,
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310522722.9A CN103606658B (en) | 2013-10-29 | 2013-10-29 | A kind of high energy storage environmental protection lead acid accumulator lead plaster containing reviver |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310522722.9A CN103606658B (en) | 2013-10-29 | 2013-10-29 | A kind of high energy storage environmental protection lead acid accumulator lead plaster containing reviver |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103606658A true CN103606658A (en) | 2014-02-26 |
| CN103606658B CN103606658B (en) | 2015-09-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310522722.9A Active CN103606658B (en) | 2013-10-29 | 2013-10-29 | A kind of high energy storage environmental protection lead acid accumulator lead plaster containing reviver |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103606658B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106654257A (en) * | 2016-12-06 | 2017-05-10 | 天能集团（河南）能源科技有限公司 | Positive lead paste for lead-acid storage battery and preparation method of positive lead paste |
| TWI583043B (en) * | 2014-03-31 | 2017-05-11 | 長興材料工業股份有限公司 | Electrolyte composition |
| CN108428889A (en) * | 2018-03-21 | 2018-08-21 | 孟婷婷 | A kind of lead-acid accumulator negative pole lead paste containing rare earth red lead |
| CN109904448A (en) * | 2019-01-24 | 2019-06-18 | 汉和新能源有限公司 | A kind of super alkene macromolecule lead storage battery green plate lead plaster |
| CN110265663A (en) * | 2019-06-25 | 2019-09-20 | 深圳中天烯源科技有限公司 | Electri forklift carbene valve-regulated sealed lead-acid batteries and production technology |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000021394A (en) * | 1998-06-30 | 2000-01-21 | Yuasa Corp | Manufacture of paste type positive electrode plate for lead-acid battery |
| JP2003031217A (en) * | 2001-07-12 | 2003-01-31 | Shin Kobe Electric Mach Co Ltd | Lead-acid battery |
| CN101388479A (en) * | 2008-11-07 | 2009-03-18 | 莫绚宗 | Renovating method for lead-acid accumulator |
| CN102810694A (en) * | 2012-08-13 | 2012-12-05 | 奇瑞汽车股份有限公司 | Lead acid battery and preparation method thereof |
| CN102899500A (en) * | 2012-10-16 | 2013-01-30 | 安徽骏马再生铅产业工程技术研究中心 | Preparation method for producing electronic-grade rare earth red lead by using lead plaster of waste lead-acid storage battery |
-
2013
- 2013-10-29 CN CN201310522722.9A patent/CN103606658B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000021394A (en) * | 1998-06-30 | 2000-01-21 | Yuasa Corp | Manufacture of paste type positive electrode plate for lead-acid battery |
| JP2003031217A (en) * | 2001-07-12 | 2003-01-31 | Shin Kobe Electric Mach Co Ltd | Lead-acid battery |
| CN101388479A (en) * | 2008-11-07 | 2009-03-18 | 莫绚宗 | Renovating method for lead-acid accumulator |
| CN102810694A (en) * | 2012-08-13 | 2012-12-05 | 奇瑞汽车股份有限公司 | Lead acid battery and preparation method thereof |
| CN102899500A (en) * | 2012-10-16 | 2013-01-30 | 安徽骏马再生铅产业工程技术研究中心 | Preparation method for producing electronic-grade rare earth red lead by using lead plaster of waste lead-acid storage battery |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI583043B (en) * | 2014-03-31 | 2017-05-11 | 長興材料工業股份有限公司 | Electrolyte composition |
| CN106654257A (en) * | 2016-12-06 | 2017-05-10 | 天能集团（河南）能源科技有限公司 | Positive lead paste for lead-acid storage battery and preparation method of positive lead paste |
| CN106654257B (en) * | 2016-12-06 | 2018-12-28 | 天能集团（河南）能源科技有限公司 | A kind of lead-acid accumulator anode diachylon and preparation method thereof |
| CN108428889A (en) * | 2018-03-21 | 2018-08-21 | 孟婷婷 | A kind of lead-acid accumulator negative pole lead paste containing rare earth red lead |
| CN109904448A (en) * | 2019-01-24 | 2019-06-18 | 汉和新能源有限公司 | A kind of super alkene macromolecule lead storage battery green plate lead plaster |
| CN109904448B (en) * | 2019-01-24 | 2021-11-30 | 汉和新能源有限公司 | Super-energy alkene polymer lead storage battery green plate lead plaster |
| CN110265663A (en) * | 2019-06-25 | 2019-09-20 | 深圳中天烯源科技有限公司 | Electri forklift carbene valve-regulated sealed lead-acid batteries and production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103606658B (en) | 2015-09-30 |
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