CN101969126A - Formula of positive lead paste - Google Patents
Formula of positive lead paste Download PDFInfo
- Publication number
- CN101969126A CN101969126A CN201010287959XA CN201010287959A CN101969126A CN 101969126 A CN101969126 A CN 101969126A CN 201010287959X A CN201010287959X A CN 201010287959XA CN 201010287959 A CN201010287959 A CN 201010287959A CN 101969126 A CN101969126 A CN 101969126A
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- lead
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Abstract
The invention discloses a formula of positive lead paste. The formula comprises the following components in percentage by weight: 75 to 80 percent of lead powder, 2 to 6 percent of oxide of lead, 0.05 to 0.1 percent of conducting fibers, 7 to 10 percent of deionized water and 7 to 10 percent of sulfuric acid solution of which the mass percentage concentration is 45 percent. The formula of the invention has the advantages that: the internal resistance of a cell using the lead paste and having the same structure is reduce by 20 percent; n in a two-hour rate Peukert formula is less than 1.10; and the capacity discharged by a high current is not greatly reduced.
Description
Technical field
The present invention relates to a kind of anode diachylon prescription.
Background technology
China national Department of Intellectual Property discloses by name long and narrow type valve controlled sealed lead acid battery positive electrode plumbic acid paste formulation and the curing process of publication number CN1482696A on March 17th, 2004, a kind of long and narrow type valve controlled sealed lead-acid accumulator anode diachylon prescription is wherein disclosed, by lead powder, red lead, short fiber, sulfuric acid, water is formed, can cause the internal resistance of storage battery bigger with short fiber as the adhesion that additive increases between the lead plaster, the capacity of emitting during heavy-current discharge declines by a big margin, be that the Peukert resistance is bigger, such pole plate is relatively poor in the application power of motive-power battery.
Summary of the invention
The object of the present invention is to provide a kind of anode diachylon prescription, can effectively solve existing motive-power battery and make the problem that anode diachylon causes the battery applications ability as additive with short fiber.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions: a kind of anode diachylon prescription, comprise following component, the each component percentage by weight is: lead powder 75～80%, plumbous oxide 2～6%, conductive fiber 0.05%～0.1%, deionized water 7～10%, mass percent concentration are 45% sulfuric acid solution 7～10%.
Preferably, the oxide of described lead is brown lead oxide or red lead; Red lead chemical name lead orthoplumbate, the material after anode diachylon changes into is a brown lead oxide, directly adding brown lead oxide or red lead (can be regarded PbO as in lead plaster
2+ 2PbO=Pb
3O
4), as the nucleus at the initial stage of changing into, reduce changing into resistance.
Preferably, described conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber; Conductive fiber with excellent conductive performance.
Preferably, the each component percentage by weight is: lead powder 75%, plumbous oxide 6%, conductive fiber 0.1%, deionized water 8.9%, mass percent concentration are 45% sulfuric acid solution 10%; Reach the anode diachylon prescription of optimum performance.
Preferably, the each component percentage by weight is: lead powder 77%, plumbous oxide 4%, conductive fiber 0.07%, deionized water 10%, mass percent concentration are 45% sulfuric acid solution 8.93%; The anode diachylon prescription of optimality price ratio.
Preferably, the each component percentage by weight is: lead powder 80%, plumbous oxide 2%, conductive fiber 0.05%, deionized water 9.95%, mass percent concentration are 45% sulfuric acid solution 8%; Most economical anode diachylon prescription.
Compared with prior art, advantage of the present invention is: the battery of same structure, use lead plaster of the present invention, and the internal resistance of battery has reduced n value in 20%, the 2 hour rate Peukert formula less than 1.10, makes the capacity width of cloth of emitting under the heavy-current discharge condition fall less.
Embodiment
Embodiment one:
A kind of anode diachylon prescription comprises following component, and the each component percentage by weight is: lead powder 75%, plumbous oxide 6%, conductive fiber 0.1%, deionized water 8.9%, mass percent concentration are 45% sulfuric acid solution 10%.
Embodiment two:
A kind of anode diachylon prescription comprises following component, and the each component percentage by weight is: lead powder 77%, plumbous oxide 4%, conductive fiber 0.07%, deionized water 10%, mass percent concentration are 45% sulfuric acid solution 8.93%.
Embodiment three:
A kind of anode diachylon prescription comprises following component, and the each component percentage by weight is: lead powder 80%, plumbous oxide 2%, conductive fiber 0.05%, deionized water 9.95%, mass percent concentration are 45% sulfuric acid solution 8%.
Oxide plumbous described in above-mentioned three kinds of embodiment is brown lead oxide or red lead, and described conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber.
The above only is specific embodiments of the invention, but technical characterictic of the present invention is not limited thereto, and any those skilled in the art is in the field of the invention, and the variation of being done or modify all is encompassed among the claim of the present invention.
Claims (6)
1. anode diachylon prescription, it is characterized in that: comprise following component, the each component percentage by weight is: lead powder 75～80%, plumbous oxide 2～6%, conductive fiber 0.05%～0.1%, deionized water 7～10%, mass percent concentration are 45% sulfuric acid solution 7～10%.
2. a kind of anode diachylon prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 75%, plumbous oxide 6%, conductive fiber 0.1%, deionized water 8.9%, mass percent concentration are 45% sulfuric acid solution 10%.
3. a kind of anode diachylon prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 77%, plumbous oxide 4%, conductive fiber 0.07%, deionized water 10%, mass percent concentration are 45% sulfuric acid solution 8.93%.
4. a kind of anode diachylon prescription as claimed in claim 1, it is characterized in that: the each component percentage by weight is: lead powder 80%, plumbous oxide 2%, conductive fiber 0.05%, deionized water 9.95%, mass percent concentration are 45% sulfuric acid solution 8%.
5. as each described a kind of anode diachylon prescription in the claim 1 to 4, it is characterized in that: the oxide of described lead is brown lead oxide or red lead.
6. as each described a kind of anode diachylon prescription in the claim 1 to 4, it is characterized in that: described conductive fiber is the polyacetylene fiber, polypyrrole fiber, at least a in the polythiophene fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010287959XA CN101969126A (en) | 2010-09-15 | 2010-09-15 | Formula of positive lead paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010287959XA CN101969126A (en) | 2010-09-15 | 2010-09-15 | Formula of positive lead paste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101969126A true CN101969126A (en) | 2011-02-09 |
Family
ID=43548245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010287959XA Pending CN101969126A (en) | 2010-09-15 | 2010-09-15 | Formula of positive lead paste |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101969126A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102664256A (en) * | 2012-04-27 | 2012-09-12 | 天能电池集团有限公司 | Anode lead plaster of power lead-acid storage battery polar plate |
| CN102723483A (en) * | 2012-06-21 | 2012-10-10 | 上海锦众信息科技有限公司 | Method for preparing positive pole lead plaster for lead-acid storage battery |
| CN102931410A (en) * | 2012-10-24 | 2013-02-13 | 超威电源有限公司 | High-capacity formation lead paste and preparation method thereof |
| CN103682330A (en) * | 2013-11-15 | 2014-03-26 | 超威电源有限公司 | Internal formation lead plaster preparation process |
| CN103700893A (en) * | 2013-10-15 | 2014-04-02 | 双登集团股份有限公司 | High temperature resisting middle-sealing battery |
| CN103715425A (en) * | 2013-12-07 | 2014-04-09 | 河南超威电源有限公司 | Lead paste for battery of electric vehicle, and use method thereof |
| CN103855399A (en) * | 2012-12-02 | 2014-06-11 | 天能集团（河南）能源科技有限公司 | Lead storage battery positive electrode lead plaster |
| CN104485454A (en) * | 2014-12-10 | 2015-04-01 | 天能电池集团有限公司 | Positive electrode lead plaster of lead acid storage battery |
| CN109273712A (en) * | 2018-10-25 | 2019-01-25 | 天能电池集团有限公司 | A kind of positive electode of lead battery lead plaster and preparation method thereof |
| WO2019114435A1 (en) * | 2017-12-12 | 2019-06-20 | 双登集团股份有限公司 | Lead paste formulation of cyclic lead-acid storage battery for communication and preparation method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101371385A (en) * | 2006-01-25 | 2009-02-18 | Dic株式会社 | Fuel cell separator, process for producing the same, and fuel cell including the separator |
| CN101694886A (en) * | 2009-10-16 | 2010-04-14 | 黄山市美达电器有限公司 | Preparation technique of silica gel battery used for solar photovoltaic and wind energy system |
-
2010
- 2010-09-15 CN CN201010287959XA patent/CN101969126A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101371385A (en) * | 2006-01-25 | 2009-02-18 | Dic株式会社 | Fuel cell separator, process for producing the same, and fuel cell including the separator |
| CN101694886A (en) * | 2009-10-16 | 2010-04-14 | 黄山市美达电器有限公司 | Preparation technique of silica gel battery used for solar photovoltaic and wind energy system |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102664256A (en) * | 2012-04-27 | 2012-09-12 | 天能电池集团有限公司 | Anode lead plaster of power lead-acid storage battery polar plate |
| CN102723483A (en) * | 2012-06-21 | 2012-10-10 | 上海锦众信息科技有限公司 | Method for preparing positive pole lead plaster for lead-acid storage battery |
| CN102931410A (en) * | 2012-10-24 | 2013-02-13 | 超威电源有限公司 | High-capacity formation lead paste and preparation method thereof |
| CN103855399A (en) * | 2012-12-02 | 2014-06-11 | 天能集团（河南）能源科技有限公司 | Lead storage battery positive electrode lead plaster |
| CN103700893B (en) * | 2013-10-15 | 2016-01-20 | 双登集团股份有限公司 | High temperature resistant middle density battery |
| CN103700893A (en) * | 2013-10-15 | 2014-04-02 | 双登集团股份有限公司 | High temperature resisting middle-sealing battery |
| CN103682330A (en) * | 2013-11-15 | 2014-03-26 | 超威电源有限公司 | Internal formation lead plaster preparation process |
| CN103682330B (en) * | 2013-11-15 | 2016-04-06 | 超威电源有限公司 | One is internalized into lead plaster and closes technique processed |
| CN103715425A (en) * | 2013-12-07 | 2014-04-09 | 河南超威电源有限公司 | Lead paste for battery of electric vehicle, and use method thereof |
| CN103715425B (en) * | 2013-12-07 | 2015-11-18 | 河南超威电源有限公司 | Battery of electric vehicle lead plaster and using method thereof |
| CN104485454A (en) * | 2014-12-10 | 2015-04-01 | 天能电池集团有限公司 | Positive electrode lead plaster of lead acid storage battery |
| WO2019114435A1 (en) * | 2017-12-12 | 2019-06-20 | 双登集团股份有限公司 | Lead paste formulation of cyclic lead-acid storage battery for communication and preparation method |
| CN109273712A (en) * | 2018-10-25 | 2019-01-25 | 天能电池集团有限公司 | A kind of positive electode of lead battery lead plaster and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20110209 |