CN101962516B - Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof - Google Patents
Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof Download PDFInfo
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- CN101962516B CN101962516B CN 200910161602 CN200910161602A CN101962516B CN 101962516 B CN101962516 B CN 101962516B CN 200910161602 CN200910161602 CN 200910161602 CN 200910161602 A CN200910161602 A CN 200910161602A CN 101962516 B CN101962516 B CN 101962516B
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- adhesive plaster
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Abstract
The invention relates to a transparent heat insulation polyvinyl chloride rubberized fabric prepared in a non-coating processing mode and a preparation method thereof. The prepared rubberized fabric has the infrared and ultraviolet blocking energy-saving effect. The preparation method comprises the following steps of: mixing a heat insulation material and an auxiliary agent for modification and stirring the mixture uniformly, properly dispersing the heat insulation granules, and mixing the dispersed heat insulation granules, polyvinyl chloride resin, plasticizer and auxiliary agent in turn; and directly guiding the rubberized mixture to a rubberized fabric machine for rolling and the like. The rubberized fabric produced by the method has the physical properties of good heat insulation effect, transparency and the like.
Description
Technical field
The present invention is its method for making of transparent heat-insulating energy-saving type polyvinyl chloride adhesive plaster that a kind of non-coating processing mode makes, and has good infrared rays and UV-light screening effect, and then reaches purpose heat insulation and protection.This finished product is fit to be applied to glass of building, automobile window, showcase and the product of energy-conservation demand etc. is arranged keeps in cold storage.
Background technology
The source that sunlight produces heat energy mainly contains two, comprise that wavelength is between the visible light of 400nm～700nm and the wavelength region infrared light (belonging to non-visible light scope) between 700nm～1800nm, and generally be applied in glass of building, automobile window, showcase and the product that province can demand is arranged keeps in cold storage, except must possessing visually transparent requirement, also must have the effect that intercepts the heat energy that infrared light produces concurrently, so must select for use and possess the optical wavelength selective material, ability is the Infrared of filtering 700nm～1800nm effectively, reach heat insulation effect, and allow the visible rays of 400nm～700nm see through, to possess visually transparent requirement.In addition; the ultraviolet light range of 200nm～400nm in the sunlight; can be subdivided into UVA (310nm～400nm), UVB (285nm～310nm) and UVC (three kinds of wave bands of 200nm～285nm) again according to wavelength; wherein UVA, UVB can cause to a certain degree injury to human body; therefore all can add organic UV absorption agent in building glass or automobile window in material; make this material possess the ability that UV covers, and then reach the function of protection human body.
Traditional heat insulation material, as: poly terephthalic acid second two fat (polyethylene terephthhalate is called for short PET), polycarbonate (polycarbonate), polyacrylate or poly-methyl acrylate (polyacrylate or polymethacrylate), ring-type alkene (cyclicolefin), polystyrene (polystyrene) etc. are to be coated with the heat insulation material with heat insulating function with dry type or wet type to be constituted on plastic basis material.
Before, the known heat-insulation transparent glued membrane of being processed into dry type coating 10 is with vacuum splashing and plating or evaporation mode as shown in Figure 1, inorganic materials such as metal or metal oxide 12 evenly are attached to the top of plastic basis material 11 and form thermal isolation film.
The heat-insulation transparent glued membrane of being processed into wet type coating 20 as shown in Figure 2, is that the inorganic particle 22 with the tool heat insulating function is dispersed in appropriate resin 23 and the solvent, after being mixed with the suitable coating fluid of viscosity, be coated on again plastic basis material 21 above; After drying was removed solvent, inorganic particle 22 and resin 23 just formed the thermal isolation film that is attached to above the plastic basis material 21.
The traditional preparation process process of " dry type coating " or " wet type coating ", its common trait is: at least must be via the twice program.One of program is to make sheet material earlier or film is used as base material; Two of program is to utilize the mode of outer (Off-line) " the dry type coating " of line or " wet type coating " to apply in the made substrate surface of one of program, makes it have the function of infrared rays obstruct or UV-preventing.The problem that this coating method is derived has:
With the processing of wet type coating method, solvent evaporates in the technology, polluted air influences healthy;
With the processing of wet type coating method, the environmental issue that the solvent slop that the coating fluid preparation produces is handled;
Wet type coating, the equipment of need setting up comprise and extra roll out, be coated with, drying, rolling, cut etc., and dry type is coated with and need sets up sputter machine or evaporator, processing unit and tooling cost height; And
Many one coating processes except being unfavorable for the finished product yield, also comprise after the coating cutting the surplus waste material that increases.
Summary of the invention
The purpose of this invention is to provide transparent heat-insulated polyvinyl chloride adhesive plaster and method for making thereof that a kind of non-coating processing mode is made.
Second purpose of the present invention provide a kind of its insulation particle adopt in addition manner be dispersed in the in-house transparent heat-insulated polyvinyl chloride adhesive plaster of polyvinyl chloride adhesive plaster.
Because with dry type or wet type coating processing mode thermal insulation inorganic materials such as metal or metal oxide are attached to traditional thermal isolation film that the plastic basis material surface forms, just like above-mentioned every disappearance and problem of deriving, the inventor etc. are through long-term thinking, research and constantly test, when making the polyvinyl chloride polymer adhesive plaster, earlier with UV light absorber such as modification agents, inorganic insulation particle, after stirring, drops into plasticizer mixing upgrading polyvinyl chloride (PVC) RESINS more in regular turn, plasticizer, tranquilizer, lubrication prescription and colorant etc. mix and find that the inorganic insulation particle in the tissue of made PVC adhesive plaster can evenly disperse to reach the effect of dispersion during gel, the disappearance that the conventional prior art that can diminish is derived and problem, and make transparent heat-insulating film.
Because do not re-use traditional coating working method, directly insulation particle is stirred with auxiliary agent mixing upgrading earlier, after insulation agent is dispersed in the polyvinyl chloride adhesive plaster tissue, do not have disappearance and the problem of traditional method for making and can produce transparent heat-insulating film or adhesive plaster, low processing cost is produced the fast advantage that reaches soon again in the tool environmental protection.
The coating complete processing of not using of the present invention, change in the prescription that the mode of adding evenly makes an addition to the polyvinyl chloride adhesive plaster in adopting with its inorganic insulation particle, preparation has the polyvinyl chloride adhesive plaster of mass propertys such as the transparency, low haze, good effect of heat insulation, UV-preventing concurrently.
Be prepared the polyvinyl chloride adhesive plaster according to the present invention and have following advantage:
Save the wet type coating process required roll out, be coated with, the facility investment of dry, rolling and dry type sputter, evaporation.The product speed of sputter, evaporation is slow, and the present invention can cut down finished cost.The environmental issue of avoiding the complete processing solvent to cause.
Adopting non-coating process mode will possess materials with function such as heat insulation and UV-preventing doses in polyvinyl chloride adhesive plaster prescription, except effects such as the transparency that can possess the polyvinyl chloride adhesive plaster, low haze, heat insulation and UV-preventing, and can overcome the problem of separating out.
Prescription component part feature of the present invention is: be main raw material with the polyvinyl chloride, other still comprises: a) plasticizer, b) heat insulation material, c) tranquilizer, d) lubrication prescription, e) auxiliary agent and f) colorant.Wherein heat insulation material is earlier through auxiliary agent mixing upgrading.
Preparation method of the present invention is: use the mixing upgrading material that contains the plasticizer of special formulation, inorganic insulation particle and other interpolation auxiliary agent earlier, utilize rolling press or T-Die machine or the blowing moulding machining of traditional polyvinyl chloride adhesive plaster, make a kind of heat-proof polychloroethylene transparent adhesive tape.This heat-proof polychloroethylene transparent adhesive tape is not only possessed the existing rerum natura of polyvinyl chloride, more has the transparency, low haze and excellent infrared rays and ultraviolet screening effect concurrently.
The present invention directly uses the traditional processing technology of polyvinyl chloride adhesive plaster, can make heat-proof polychloroethylene transparent adhesive tape, except needn't use coating processing, the facility investment that more can save the coating method for making also can be avoided the solvent slop environmental issue of wet type coating method for making.Therefore, simple, the low processing cost of method for making tool technology of the present invention, product speed is fast and the advantage of environmental protection.
Description of drawings
Fig. 1 is the section amplification figure of processing the transparent heat-insulated glued membrane that makes with known dry type coating.
Fig. 2 is the section amplification figure of processing the transparent heat-insulated glued membrane that makes with known wet type coating.
Fig. 3 is the section amplification figure that covers the transparent heat-insulated polyvinyl chloride adhesive plaster of infrared rays and ultraviolet effect with the tool of the present invention that non-coating processing makes.
Fig. 4 is the synoptic diagram that transparent heat-insulated polyvinyl chloride adhesive plaster of the present invention uses with multilayer superimposition together.
Fig. 5 is the synoptic diagram that transparent heat-insulated polyvinyl chloride adhesive plaster of the present invention and another sheet plastic basis material coincide and use together.
Primary clustering nomenclature in the accompanying drawing
10... transparent heat-insulated glued membrane 11... plastic basis material
12... inorganics such as metal or metal oxide
20... transparent heat-insulated glued membrane 21... plastic basis material
22... inorganic insulation particle 23... resin
30... transparent heat-insulated polyvinyl chloride adhesive plaster
31... the inorganic insulation particle of polyvinyl chloride adhesive plaster 32...
40... plastic basis material
Embodiment
Transparent heat-insulated polyvinyl chloride adhesive plaster 30 of the present invention as shown in Figure 3, is thickness between 0.02～2.0mm tool transparency and covers transparent flexible or semi-rigid or the hard adhesive plaster of infrared rays and characteristic ultraviolet; Its constitutional features is: thickness is base material between the polyvinyl chloride adhesive plaster 31 of 0.02～2.0mm, and its inorganic insulation particle 32 is dispersed in the tissue of described polyvinyl chloride adhesive plaster 31.
The technology of transparent heat-insulated polyvinyl chloride adhesive plaster 30 of the present invention comprises the following steps:
Modification agent 0.01～15.0PHR, UV light absorber 0.01～5.0PHR, dispersion agent 0.01～5.0PHR, inorganic insulation particle 0.01～15.0PHR, plasticizer 0～45PHR are dropped into mixing machine mixing upgrading earlier to stir, and then drop into polyvinyl chloride (PVC) RESINS 100PHR, plasticizer 0～85PHR, tranquilizer 0.1～15.0PHR, lubrication prescription 0.1～15.0PHR, colorant 0.0～12.0PHR in regular turn after mixing machine mixes, it is evenly mixing to introduce ten thousand horsepowers of machines;
After the further gel of running roller machine, to rolling press, the machine-shaping gauge control is introduced temperature hardening by cooling in 20～85 ℃ water immediately in 0.05mm～1.0mm 150～190 ℃ of feedings in the material temperature control, then through dewatering again; Or behind the hot melt adhesive molding with cloth, or with T-Die machining moulding gauge control between 0.05mm～2.0mm; Or with blowing moulding machining moulding gauge control behind the hot melt adhesive plaster of 0.02mm～0.8mm, directly introduce step (3); And
Adhesive plaster is introduced cooling wheels cooling and shaping, make transparent heat-insulated polyvinyl chloride adhesive plaster 30 of the present invention through batching.
The polyvinyl chloride (PVC) RESINS in step (1) that the present invention uses can be selected from wherein one or more the composition with block polymerization (BulkPolymerization), solution polymerization (Solution Polymerization), suspension polymerization (SuspensionPolymerization) or emulsion polymerization (Emulsion Polymerization) prepared polyvinyl chloride polymer or multipolymer.
Plasticizer; Be selected from phosphoric acid ester, phthalandione system, benzenetricarboxylic acid ester class, epoxies trioctyl trimellitate (TOTM), citrate, adipic acid ester plasticizer polyester or aliphatic diacid ester class plasticizer wherein one or more.
Inorganic insulation particle; Particle diameter for looking the demand of different rerum naturas such as transparency, mist degree, can be selected from titanium dioxide (TiO between 0.005～2 μ m
2), zinc oxide (ZnO), vanadium oxide (V
2O
5), Indium sesquioxide (In
2O
3), cerium oxide (CeO
2), stannic oxide (SnO
2), weisspiessglanz (Sb
2O
3), indium tin oxide (ITO), titanium tetrachloride (ATO), antimony zinc oxide (AZO) and metalloid oxide compound, zinc sulphide (ZnS) wherein one or more.
And hexaboride (comprising: lanthanum hexaborane (LaB
6), six cerium boride (CeB
6), praseodymium boride (PrB
6), neodymium hexaboride (NdB
6), six samarium boride (SmB
6), europium boride (EuB
6), six boronation gadolinium (GdB
6), Liu Pengization Shi (TbB
6), six dysprosium boride (DyB
6), six boronation holmium (HoB
6), six boronation erbium (ErB
6), six thulium boride (TmB
6), six ytterbium boride (YbB
6), six boronation gold-plating (LuB
6), six strontium boride (SrB
6), six calcium boride (CaB
6), six yttrium boride (YB
6)) wherein one or more.
Inorganic insulation particle is selected from one or more mixture of above-mentioned metal oxide or hexaboride.
Tranquilizer, can be selected from barium zinc system (Ba-Zn system) or calcium zinc system (Ca-Zn system) or organotin is spicy thioalcohol tin (Octyl Tin Mercaptide) etc., for example one or more compound tranquilizers of the product LQX-3K-8T of South Asia company, SD-8032S.
Lubrication prescription; It can be the lubrication prescription of stearic acid system, fatty acid ester system, fatty acid acyl amine, metal crystal soda class, silicon-type etc.Can utilize above-mentioned different types of lubrication prescription wherein one or more in addition all collocation use and all can.
Auxiliary agent comprises that wherein one or more collocation of modification agent, dispersion agent or UV light absorber form.Add the purpose of auxiliary agent, be to impel the inorganic insulation particle 32 in the tissue of polyvinyl chloride adhesive plaster 31 to reach aim of even dispersion.
Wherein said modification agent is selected from wherein a kind of (for example Amino silane Coupling AgentKBM-603 of company of SHIN-ETSU HANTOTAI) of organic silane compound, organic zirconium aluminum compound or organic titanium aluminum compound.Described dispersion agent, wherein one or more collocation that are selected from the copolymer dispersant of polymer, siliceous composition dispersion agent or fluorine-containing composition dispersion agent form (for example Disper byk-185 of BYK company).Described UV light absorber, be selected from hydroxy-phenyl-benzotriazole UV light absorber or hydroxy benzophenone ketone UV light absorber wherein one or more.
Colorant; The form and aspect demand of visual product is given interpolation as one thinks fit, or is the organic system colorant, or for inorganic be colorant, also can adopt inorganic, organic toner hybrid mode.
Outside transparent heat-insulated polyvinyl chloride adhesive plaster 30 of the present invention can individual layer uses, looking purposes can be as shown in Figure 4, and multilayer polyvinyl chloride adhesive plaster coincides and uses together, perhaps, as shown in Figure 5, planted plastic basis material 40 with him and coincided and use together.
To be described more specifically the present invention with embodiment below, though described in detail with the preferred embodiment description, technology of the present invention and interest field are not limited by it.Every rerum natura appraisal procedure of the present invention is as follows:
Visible light penetration coefficient and mist degree test:
Adopt Tokyo Denshoku Co., Ltd.Haze Meter, model is TC-HIII, light transmission rate and the haze value of the polyvinyl chloride adhesive plaster of the following embodiment of test, its method meets JIS K7705 standard.The visible light penetration coefficient is more high, the transparency of the more low representative polyvinyl chloride of haze value adhesive plaster is more good.
The test of infrared rays screening rate:
Adopt the HOYA board, model is LT-3000, the heat insulation adhesive plaster of test implementation example, and its method meets JIS R3106 standard.The infrared rays rejection rate is higher, and to represent the effect of heat insulation of polyvinyl chloride adhesive plaster more good.
The test of ultraviolet isolating rate:
Adopt the HOYA board, model is LT-3000, the heat insulation adhesive plaster of test implementation example, and its method meets JIS R3106 standard.The ultraviolet isolating rate is higher, and to represent the obstruct UV effect of polyvinyl chloride adhesive plaster more good.
Embodiment 1
Produce the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of thickness 0.2mm softness 40PHR, its method for making is:
Special formulation according to table 1, earlier former materials such as inorganic insulation particle LaB6 addition 0.25PHR, modification agent 0.81PHR, dispersion agent 0.17PHR, UV light absorber 0.8PHR, tranquilizer 3PHR, plasticizer 40PHR and polyvinyl chloride (PVC) RESINS 100PHR are dropped into mixing machine (HenschelMixer N.P.C system in regular turn, 300L) mix after, it is evenly mixing to introduce ten thousand horsepowers of machines (N.P.C system, 100L fall gate-type);
After two roller type running roller machines (N.P.C system, running roller speed differed from 1: 1.15) gel, the material temperature control is at 150～190 ℃ again, and feeding is to the contrary L type calender (N.P.C system, specification 24 " * 72 ") of four-wheel, and thickness control is at the hot melt adhesive plaster of 0.2mm.Introduce temperature hardening by cooling in 20～85 ℃ water immediately, again through after dewatering;
Adhesive plaster is introduced cooling wheels cooling and shaping, through batching the heat-proof polychloroethylene transparent adhesive tape 30 that namely makes thickness 0.2mm softness 40PHR.
Test result is as shown in table 1, and light transmission rate is up to 72%, and mist degree 1.7% shows that prepared transparent heat-insulated polyvinyl chloride adhesive plaster 30 possesses the transparency, its infrared rays screening rate 67%, ultraviolet isolating rate 99%.
Embodiment 2
According to the special formulation of table 1, with inorganic insulation particle CeB
6Raw materials such as addition 0.25PHR, modification agent 0.81PHR use the method for making of embodiment 1 to produce the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of thickness 0.2mm softness 40PHR.
Test result is as shown in table 1, light transmission rate is up to 70%, mist degree 2.0%, show that prepared transparent heat-insulated polyvinyl chloride adhesive plaster 30 possesses the transparency, its light transmission rate slightly is inferior to embodiment 1, and its infrared rays screening rate 64% also is only second to embodiment 1, its ultraviolet isolating rate 99%, and inorganic insulation particle does not have the phenomenon of separating out in the course of processing.
Embodiment 3
According to the special formulation of table 1, with inorganic insulation particle ATO addition 1.8PHR and LaB
6Raw materials such as addition 0.25PHR, modification agent addition 6.97PHR, the method for making of use embodiment 1 is produced the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of thickness 0.2mm softness 40PHR.
Test result is as shown in table 1, light transmission rate is up to 69%, mist degree 2.6%, show that prepared transparent heat-insulated polyvinyl chloride adhesive plaster 30 possesses the transparency, its infrared rays screening rate 91%, ultraviolet isolating rate 99%, show that prepared transparent heat-insulated polyvinyl chloride adhesive plaster 30 possesses excellent light transmission rate, suitable with comparative example 1, but its infrared rays screening rate then is much better than comparative example 1, and inorganic insulation particle does not have the phenomenon of separating out in its course of processing.
Comparative example 1
According to the special formulation of table 1, use the method for making of embodiment 1 to produce the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of thickness 0.2mm softness 40PHR raw materials such as inorganic insulation particle ATO 15PHR, modification agent 10.77PHR.
Test result is as shown in table 1, light transmission rate 19%, mist degree 10.4%, its infrared rays screening rate 91%, ultraviolet isolating rate 99% shows that the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of obtained thickness 0.2mm possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, but its light transmission rate is low, the mist degree height is its main drawback, due to demonstration ATO addition is higher.
Comparative example 2
Except thickness was 0.2mm, the former material formula of prepared transparent heat-insulated polyvinyl chloride adhesive plaster 30 and method for making be all with embodiment 1, inorganic insulation particle ATO addition 2.2PHR.
Test result is as shown in table 1, light transmission rate 69%, mist degree 2.6%, its infrared rays screening rate 43%, ultraviolet isolating rate 99% shows that the transparent heat-insulated polyvinyl chloride adhesive plaster 30 of obtained thickness 0.2mm possesses the transparency and possesses moderate infrared rays screening rate, but poor than embodiment 1～3, inorganic insulation particle does not have the phenomenon of separating out in its course of processing.
Comparative example 3
Produce the polyvinyl chloride transparent adhesive plaster of thickness 0.2mm softness 40PHR, its former material formula is not except containing inorganic insulation particle, modification agent, dispersion agent, and its method for making is all with embodiment 1.
Test result is as shown in table 1, and light transmission rate is up to 86%, mist degree 1.4%, its infrared rays screening rate only 8%, and ultraviolet isolating rate 98%, comparing embodiment 1～3 shows: light transmission rate is higher, but the infrared rays screening rate is nearly unavailable, and is identical with general adhesive plaster.
Comparative example 4
Produce the polyvinyl chloride transparent adhesive plaster of thickness 0.2mm softness 40PHR, its former material formula except not containing modification agent, dispersion agent, inorganic insulation particle ATO addition 2.2PHR, all the other are all with comparative example 2.
Test result is as shown in table 1, light transmission rate is up to 50%, mist degree 12.0%, its infrared rays screening rate only 29%, ultraviolet isolating rate 98%, show prepared thickness 0.2mm polyvinyl chloride transparent adhesive plaster because do not use modification agent, dispersion agent, aspect infrared rays screening rate and ultraviolet isolating rate all than embodiment 1～3 deterioration.And, have in the course of processing and separate out phenomenon, and then influence processibility and the dispersed quality of polyvinyl chloride transparent adhesive plaster product.
Comparative example 5
Colourless transparent glass with size 100mm*100mm*0.3mm is the contrast object, measures its light transmission rate, mist degree, infrared rays screening rate and ultraviolet isolating rate.
Test result is as shown in table 1, shows that infrared rays screening rate and the ultraviolet isolating rate of colourless transparent glass is not good really, and is mutually far short of what is expected than embodiment 1～3.
Described in detail though the present invention reveals with preferred embodiment, only technology of the present invention and interest field are not limited by it, are defined by the claim scope of applying for.
Table 1: embodiment
Prescription consumption unit is: PHR (per hundred parts of weight resins)
Claims (5)
1. transparent heat-insulated polyvinyl chloride adhesive plaster, its thickness is between 0.05mm～1.0mm, transparent heat-insulated adhesive plaster includes inorganic insulation particle, it is characterized in that this inorganic insulation particle, by the mixture that metal oxide and hexaboride are formed, this transparent heat-insulated polyvinyl chloride adhesive plaster is obtained by following method for making:
(1) modification agent 0.01～15.0PHR, UV light absorber 0.01～5.0PHR, dispersion agent 0.01～5.0PHR, inorganic insulation particle 0.01～15.0PHR, plasticizer 1～45PHR being dropped into mixing machine mixing upgrading earlier stirs, drop into polyvinyl chloride (PVC) RESINS 100PHR, plasticizer 1～85PHR, tranquilizer 0.1～15.0PHR, lubrication prescription 0.1～15.0PHR, colorant 0.0～12.0PHR then in regular turn again, after mixing machine mixed, it was evenly mixing to introduce ten thousand horsepowers of machines;
(2) again after the further gel of running roller machine, to rolling press, the machine-shaping gauge control is introduced temperature hardening by cooling in 20～85 ℃ water immediately in 0.05mm～1.0mm, dewaters then 150～190 ℃ of feedings in the material temperature control; Again adhesive plaster is introduced cooling wheels cooling and shaping.
2. transparent heat-insulated polyvinyl chloride adhesive plaster as claimed in claim 1, wherein, described inorganic insulation particle, particle diameter is between 0.005～2 μ m, and its metal oxide is selected from: titanium tetrachloride, antimony zinc oxide; Hexaboride is selected from: lanthanum hexaborane, six cerium borides.
3. transparent heat-insulated polyvinyl chloride adhesive plaster as claimed in claim 1, wherein, modification agent includes organic silane compound coupler, organic zirconium aluminum compound coupler or organic titanium aluminum compound coupler.
4. transparent heat-insulated polyvinyl chloride adhesive plaster as claimed in claim 1, wherein, dispersion agent be selected from the copolymer dispersant of polymer, siliceous composition dispersion agent or fluorine-containing composition dispersion agent wherein one or more.
5. transparent heat-insulated polyvinyl chloride adhesive plaster as claimed in claim 1, wherein, UV light absorber be selected from hydroxy-phenyl-benzotriazole UV light absorber or hydroxy benzophenone ketone UV light absorber wherein one or more.
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| CN 200910161602 CN101962516B (en) | 2009-07-22 | 2009-07-22 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
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| CN 200910161602 CN101962516B (en) | 2009-07-22 | 2009-07-22 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102816396B (en) * | 2012-08-27 | 2015-03-18 | 南亚塑胶工业（南通）有限公司 | Low heat absorption PVC product and method of preparing adhesive tape and the rubber sheet from it |
| CN103254613A (en) * | 2013-03-08 | 2013-08-21 | 许清水 | RVAC synthetic adhesive plaster |
| CN104015421A (en) * | 2014-06-13 | 2014-09-03 | 苏州汉力新材料有限公司 | Hot galvanized thermal insulation metal material |
| CN104152064B (en) * | 2014-07-17 | 2016-08-17 | 广州宏信塑胶工业有限公司 | Ultra-thin PVC adhesive plaster |
| TWI604029B (en) * | 2016-08-25 | 2017-11-01 | Nanya Plastics Corp | Transparent insulation PVC tape and its preparation method |
| JP6747324B2 (en) | 2017-02-06 | 2020-08-26 | 三菱マテリアル株式会社 | Method for producing fine metal oxide particles |
| JP6933156B2 (en) * | 2018-02-14 | 2021-09-08 | 三菱マテリアル株式会社 | Method for producing metal oxide dispersion |
| JP7020223B2 (en) | 2018-03-22 | 2022-02-16 | 三菱マテリアル株式会社 | Metal oxide fine particles and their manufacturing method, dispersion liquid for forming an infrared shielding film and its manufacturing method, a method for forming an infrared shielding film, and a base material with an infrared shielding film. |
| CN110540814B (en) * | 2018-10-29 | 2021-06-15 | 天津包钢稀土研究院有限责任公司 | High-permeability rare earth nano heat insulation slurry and preparation method thereof |
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| CN1259543A (en) * | 1999-01-05 | 2000-07-12 | 东营日江塑料制品有限公司 | Polychloroethylene high efficiency fog-free film |
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| CN101323774A (en) * | 2008-07-28 | 2008-12-17 | 公安部四川消防研究所 | Expansion type fireproofing glue strip for construction |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1259543A (en) * | 1999-01-05 | 2000-07-12 | 东营日江塑料制品有限公司 | Polychloroethylene high efficiency fog-free film |
| CN101157829A (en) * | 2007-09-21 | 2008-04-09 | 南亚塑胶工业股份有限公司 | Heat-proof polychloroethylene transparent adhesive tape |
| CN101323774A (en) * | 2008-07-28 | 2008-12-17 | 公安部四川消防研究所 | Expansion type fireproofing glue strip for construction |
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