CN101157829B - Heat-proof polychloroethylene transparent adhesive tape - Google Patents
Heat-proof polychloroethylene transparent adhesive tape Download PDFInfo
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- CN101157829B CN101157829B CN2007101516050A CN200710151605A CN101157829B CN 101157829 B CN101157829 B CN 101157829B CN 2007101516050 A CN2007101516050 A CN 2007101516050A CN 200710151605 A CN200710151605 A CN 200710151605A CN 101157829 B CN101157829 B CN 101157829B
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- polyvinyl chloride
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- polychloroethylene
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Abstract
A transparent polyvinyl chloride coated fabric for heat insulation is made by the processing method of non-coating. The coated fabric has the function of shading infrared and ultraviolet. The preparation method is that polyvinyl chloride colophony containing special formula, plasticizer, inorganic thermal insulation particles and other mixtures of adding addition agent are used directly in the traditional process of making the polyvinyl chloride coated fabric, as a result, the transparent polyvinyl chloride coated fabric for thermal insulation not only has the existing physical properties of polyvinyl chloride, but also transparency, little fog, and excellent screening effect against infrared and ultraviolet.
Description
Technical field
The present invention relates to a kind of heat-proof polychloroethylene transparent adhesive tape, relate in particular to a kind of making and have the heat-proof polychloroethylene transparent adhesive tape that covers infrared rays and characteristic ultraviolet with non-coating processing mode.
Background technology
Known heat-insulation transparent glued membrane 10 as shown in Figure 1, be that not only the tolerable visible light penetrated but also can intercept the heat-insulation transparent article of infrared light, generally paste at glass of building or above the vehicle glass, make glass of building or vehicle glass reach effect of heat insulation and the transparent vision requirement of maintenance.
But the UV-light screening effect of known heat-insulation transparent glued membrane 10 is not good.For this reason, all can add UV-light (UV) absorption agent in the material of building glass or vehicle glass, make building glass or vehicle glass possess the ability of ultraviolet shielding, avoid being subjected to the injury of UV-light with the protection human body.
The method for making of known heat-insulation transparent glued membrane has two kinds of dry type coating method for making and wet type coating method for makings, all coating one deck thermal isolation film and make and have heat insulation and heat-insulation transparent glued membrane transparent characteristic on plastic rubber substrate.
As shown in Figure 1, with the heat-insulation transparent glued membrane 10 that the dry type coating is processed into, be with vacuum splashing and plating or evaporation mode, inorganic materials such as metal or metal oxide 12 are evenly formed thermal isolation film attached to the top of plastic rubber substrate 11.
As shown in Figure 2, with the heat-insulation transparent glued membrane 20 that wet type coating is processed into, be that the inorganic particle 22 that will have heat insulating function is dispersed in appropriate resin 23 and the solvent, after being mixed with the suitable coating fluid of viscosity, be coated on again plastic rubber substrate 21 above; After drying was removed solvent, inorganic particle 22 and resin 23 just formed attached to the thermal isolation film above the plastic rubber substrate 21.
But, no matter be to adopt dry type to be coated with method for making or wet type coating method for making, all comprise the twice production process, that is, after necessary elder generation makes plastic rubber substrate, above made plastic rubber substrate, be coated with one deck thermal isolation film again.So known heat-insulation transparent adhesive plaster adopts the shortcoming of dry type coating method for making or wet type coating method for making, is exactly that the processing and fabricating operation is many, and equipment cost is high and product speed is on the low side.And, adopt wet type coating method for making to also have the environmental issue of solvent slop.
Summary of the invention
Main purpose of the present invention is to provide a kind of heat-proof polychloroethylene transparent adhesive tape and method for making thereof, compound with special formulation is a raw material, and the traditional fabrication process of directly adopt making the polyvinyl chloride adhesive plaster, needn't use coating processing, just can make and have the heat-proof polychloroethylene transparent adhesive tape that covers infrared rays and characteristic ultraviolet.
Its method for making is: in the traditional fabrication process of making the polyvinyl chloride adhesive plaster, directly use the compound of the polyvinyl chloride (PVC) RESINS, softening agent, inorganic insulation particle and other interpolation auxiliary agent that contain special formulation, through rolling press or T-Die machine or blowing moulding machine, make a kind of heat-proof polychloroethylene transparent adhesive tape with rolling processing or the T-Die processing or the processing of blowing.This heat-proof polychloroethylene transparent adhesive tape not only has the existing rerum natura of polyvinyl chloride, more has the transparency, low haze and excellent infrared rays and ultraviolet screening effect concurrently.
Heat-proof polychloroethylene transparent adhesive tape method for making of the present invention, because the traditional fabrication process of direct use polyvinyl chloride adhesive plaster, except that needn't using coating processing, and the solvent slop environmental issue that can save the facility investment of coating method for making and can avoid wet type coating method for making.Therefore, method for making of the present invention has that making processes is simple, low processing cost, product speed is fast and the advantage of environmental protection.
Description of drawings
Fig. 1 is a section amplification figure of processing the heat-insulation transparent glued membrane that makes with known dry type coating.
Fig. 2 is a section amplification figure of processing the heat-insulation transparent glued membrane that makes with known wet type coating.
Fig. 3 is the section amplification figure that has the heat-proof polychloroethylene transparent adhesive tape that covers infrared rays and ultraviolet effect with the present invention that non-coating processing makes.
Fig. 4 is the synoptic diagram that heat-proof polychloroethylene transparent adhesive tape of the present invention uses with multilayer build-up together.
Fig. 5 is the synoptic diagram that heat-proof polychloroethylene transparent adhesive tape of the present invention and another sheet plastic rubber substrate are superimposed together and use.
Description of reference numerals:
10...... heat-insulation transparent glued membrane 11...... plastic rubber substrate
12...... inorganics such as metal or metal oxide 20...... heat-insulation transparent glued membrane
21...... plastic rubber substrate 22...... inorganic particle
23...... resin 30...... heat-proof polychloroethylene transparent adhesive tape
31...... the inorganic insulation particle of polyvinyl chloride adhesive plaster 32......
40...... plastic rubber substrate
Embodiment
As shown in Figure 3, heat-proof polychloroethylene transparent adhesive tape 30 shown in the present is that thickness is between 0.02～1.0mm and have the transparency and cover infrared rays and the transparent flexible of characteristic ultraviolet or semi-rigid or hard adhesive plaster; Its constitutional features is: is base material with thickness between the polyvinyl chloride adhesive plaster 31 of 0.02～1.0mm, and in the tissue of described polyvinyl chloride adhesive plaster 31, comprises the inorganic insulation particle 32 of uniformly dispersing.
The method for making of heat-proof polychloroethylene transparent adhesive tape 30 of the present invention, be that compound with special formulation is a raw material, needn't use coating processing, directly adopt the traditional fabrication process of making the polyvinyl chloride adhesive plaster, just can make and have the heat-proof polychloroethylene transparent adhesive tape 30 that covers infrared rays and characteristic ultraviolet, and it is simple to have processing and making process, the advantage that equipment cost is cheap and product speed is fast.
Therefore, heat-proof polychloroethylene transparent adhesive tape 30 of the present invention is obtained by the method for making that comprises the following steps:
(1) polyvinyl chloride (PVC) RESINS 100PHR, softening agent 0～85PHR, inorganic insulation particle 0.3～15PHR, stablizer 0.1～15 PHR, lubricant 0.1～15 PHR, auxiliary agent (comprising properties-correcting agent, tensio-active agent, dispersion agent and UV light absorber) 0.3～25 PHR and colorant 0.0～12 PHR are mixed with mixing machine after, it is evenly mixing to introduce ten thousand horsepowers of machines;
(2) the material temperature control is at 160～180 ℃, after the gel of running roller machine, with the compound that fully reacts, with the hot melt adhesive plaster of rolling press machine-shaping gauge control between 0.05mm～1.0mm, after the moulding, introduce temperature hardening by cooling in 20～85 ℃ water immediately, to improve the transparency of polyvinyl chloride adhesive plaster, through after dewatering, introduce step (3) again; Or, after the moulding, directly introduce step (3) with the hot melt adhesive plaster of T-Die machining moulding gauge control between 0.05mm～1.0mm; Or, after the moulding, directly introduce step (3) with the hot melt adhesive plaster of blowing moulding machining moulding gauge control between 0.02mm～0.8mm;
(3) adhesive plaster is introduced cooling wheels cooling and shaping, made heat-proof polychloroethylene transparent adhesive tape 30 of the present invention through batching.
In step (1), employed polyvinyl chloride (PVC) RESINS can be selected from wherein one or more the composition with mass polymerization (BulkPolymerization), solution polymerization (Solution Polymerization), suspension polymerization (SuspensionPolymerization) or letex polymerization (Emulsion Polymerization) prepared polyvinyl chloride polymer or multipolymer.
In step (1), employed softening agent, can be selected from phosphoric acid ester, phthalic acid salt (Phthalate), trimellitate class (Trimellitate), epoxies, polyester, chlorinated hydrocarbons or aliphatic diacid ester plasticizer wherein one or more.For example: phthalic acid salt softening agent comprises diisononyl phthalate (DINP, Diisononyl Phthalate) softening agent.
In step (1), employed inorganic insulation particle 32, particle diameter is looked the demand of different rerum naturas such as transparency, mist degree between 0.005～2 μ m, can be selected from titanium dioxide (TiO
2), zinc oxide (ZnO), vanadium oxide (V
2O
5), Indium sesquioxide (In
2O
3), cerium oxide (CeO
2), stannic oxide (SnO
2), weisspiessglanz (Sb
2O
3), zinc sulphide (ZnS), titanium tetrachloride (ATO), indium tin oxide (ITO), metalloid oxide compound wherein one or more.
In step (1), employed stablizer can be selected from one or more one package stabilizers of Ba-Zn system or Ca-Zn system or organotin etc.
In step (1), employed lubricant can be the lubricant of the sour system of hard ester, fatty acid series, fatty acid acyl amine, ester system, metal crystal soda class, silicon-type etc.Can utilize a kind of, the multiple even whole mixing wherein of above-mentioned different types of lubricant to use all can.
In step (1), employed auxiliary agent, can be coupler, tensio-active agent, dispersion agent, high molecular polymer properties-correcting agent or UV light absorber wherein one or more mix.Add the purpose of dispersion agent and auxiliary agent, be to impel the inorganic insulation particle 32 in the tissue of made polyvinyl chloride adhesive plaster 31 to reach aim of even dispersion.
Wherein, described coupler, optional wherein a kind of from organic silane compound, organic zirconium aluminum compound or organic titanium aluminum compound.Described dispersion agent, can be selected from the copolymer dispersant of polymer, siliceous composition dispersion agent or fluorine-containing composition dispersion agent wherein one or more mix.Described UV light absorber, can be selected from hydroxy-phenyl-benzotriazole UV light absorber or hydroxy benzophenone ketone UV light absorber wherein one or more.
In step (1), employed colorant, the form and aspect demand of visual product is given interpolation as one thinks fit, or is the organic system colorant, or for inorganic be colorant, also can adopt inorganic, organic toner hybrid mode.
In the use, heat-proof polychloroethylene transparent adhesive tape 30 of the present invention can also use with multilayer build-up outside can individual layer using as shown in Figure 4 together, and perhaps, being superimposed together with other kinds plastic rubber substrate 40 as shown in Figure 5 used.
Below, specify characteristic with embodiment, and the assessment mode of heat-proof polychloroethylene transparent adhesive tape 30 every rerum naturas is according to following testing method with the made heat-proof polychloroethylene transparent adhesive tape 30 of method for making of the present invention.
(1) visible light transmissivity and mist degree test:
Adopt Japanese trader Tokyo Denshoku Co., the model that Ltd. makes is light transmission rate and the mist degree test machine (Haze Meter) of TC-HIII, according to JIS K7705 testing standard, and the light transmission rate and the haze value of test polyvinyl chloride adhesive plaster.
Test result is that visible light transmissivity is high more, haze value is low more, then represents the transparency of polyvinyl chloride adhesive plaster good more.
(2) infrared rays and ultraviolet isolating rate test:
The model that adopts Japanese trader HOYA to make is a LT-3000 infrared rays rejection rate test machine, according to the JISR3106 testing standard, and the infrared rays rejection rate of test polyvinyl chloride adhesive plaster.
Test result is higher for the infrared rays rejection rate, represents the effect of heat insulation of polyvinyl chloride adhesive plaster good more; The ultraviolet ray penetration coefficient is lower, represents obstruct ultraviolet ray (UV) effect of polyvinyl chloride adhesive plaster good more.
(embodiment 1)
Produce the heat-proof polychloroethylene transparent adhesive tape 30 of thickness 0.2mm softness 40PHR, its method for making is:
(1) according to the special formulation of table 1, after former materials such as polyvinyl chloride (PVC) RESINS, softening agent, inorganic insulation particle, auxiliary agent (comprising properties-correcting agent, tensio-active agent, dispersion agent and UV light absorber), stablizer, lubricant were mixed with mixing machine, it was evenly mixing to introduce ten thousand horsepowers of machines;
(2) the material temperature control is at 160～180 ℃, and after the gel of running roller machine, the compound that will fully react with rolling processing is made the hot melt adhesive plaster of thickness 0.2mm, introduces temperature hardening by cooling in 20～85 ℃ water immediately;
(3), adhesive plaster is introduced cooling wheels cooling and shaping, through batching the heat-proof polychloroethylene transparent adhesive tape 30 that promptly makes thickness 0.2mm softness 40PHR through after dewatering.
Test result is as shown in table 1, show that prepared thickness 0.2mm heat-proof polychloroethylene transparent adhesive tape 30 possesses the good transparency, infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 2)
Except that thickness was 0.3mm, the former material formula of prepared heat-proof polychloroethylene transparent adhesive tape 30 and method for making were all with embodiment 1.
Test result is as shown in table 1, show that prepared thickness 0.3mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the good transparency, infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 3)
Except that using the processing of blowing,, use the heat-proof polychloroethylene transparent adhesive tape 30 of the method for making production thickness 0.02mm softness 40PHR of embodiment 1 according to the special formulation of table 1.
Test result is as shown in table 1, show that prepared thickness 0.02mm heat-proof polychloroethylene transparent adhesive tape 30 possesses the good transparency, infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 4)
Except that thickness was 1.0mm, the former material formula of prepared heat-proof polychloroethylene transparent adhesive tape 30 and method for making were all with embodiment 1.
Test result is as shown in table 1, show that prepared thickness 1.0mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the transparency and possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 5)
Except that using T-Die processing,, use the heat-proof polychloroethylene transparent adhesive tape 30 of the method for making production thickness 0.2mm softness 40PHR of embodiment 1 according to the special formulation of table 1.
Test result is as shown in table 1, show that prepared thickness 0.2mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the transparency and possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 6)
Except that thickness was 0.3mm, the former material formula of prepared heat-proof polychloroethylene transparent adhesive tape 30 and method for making were all with embodiment 5.
Test result is as shown in table 1, show that prepared thickness 0.3mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the transparency and possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 7)
According to the special formulation of table 1, use the heat-proof polychloroethylene transparent adhesive tape 30 of the method for making production thickness 0.2mm softness 40PHR of embodiment 1.
Test result is as shown in table 1, show that prepared thickness 0.2mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the transparency and possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(embodiment 8)
Except that thickness was 0.3mm, the former material formula of prepared heat-proof polychloroethylene transparent adhesive tape 30 and method for making were all with embodiment 7.
Test result is as shown in table 1, show that prepared thickness 0.3mm heat-proof polychloroethylene transparent adhesive tape 30 still possesses the transparency and possesses quite excellent infrared rays screening rate and ultraviolet isolating rate, and ATO does not have the phenomenon of separating out in the course of processing.
(comparative example 1)
Produce the polyvinyl chloride transparent adhesive plaster of thickness 0.2mm softness 40PHR, its former material formula is not except that containing inorganic insulation particle, properties-correcting agent, tensio-active agent, dispersion agent, and its method for making is all with embodiment 1.
Test result is as shown in table 1, show prepared thickness 0.2mm polyvinyl chloride transparent adhesive plaster, because it is do not contain inorganic insulation particle in the composition of raw materials, many than embodiment 1,5 and 7 prepared heat-proof polychloroethylene transparent adhesive tape 30 deteriorations aspect the infrared rays screening rate.
(comparative example 2)
Produce the polyvinyl chloride transparent adhesive plaster of thickness 0.2mm softness 40PHR, its former material formula is not except that containing properties-correcting agent, tensio-active agent, dispersion agent, and all the other are all with embodiment 1.
Test result is as shown in table 1, shows prepared thickness 0.2mm polyvinyl chloride transparent adhesive plaster, and is because do not use properties-correcting agent, tensio-active agent, dispersion agent, all many than embodiment 1,5 and 7 deteriorations aspect infrared rays screening rate and ultraviolet isolating rate.And, have in the course of processing and separate out phenomenon, and then influence the processibility and the quality of polyvinyl chloride transparent adhesive plaster product.
(comparative example 3)
Colourless transparent glass with size 100mm * 100mm * 0.3mm is the contrast object, measures its light transmission rate, mist degree, infrared rays screening rate and ultraviolet isolating rate.
Test result is as shown in table 1, shows that the infrared rays screening rate and the ultraviolet isolating rate of colourless transparent glass is not good really, and is mutually far short of what is expected than embodiment 2,4,6 and 8.
Table 1
| Title | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Comparative example 1 | Comparative example 2 | Comparative example 3 | ||
| Prescription | Base material | Polyvinyl chloride | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | - |
| Glass | - | - | - | - | - | - | - | - | - | - | Colourless transparent glass | ||
| Softening agent | DINP | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | 40 | - | |
| Inorganic insulation particle | ATO | 2.2 | 2.2 | 0.3 | 2.2 | 6.0 | 6.0 | 15 | 15 | - | 2.2 | - | |
| Stablizer | Barium zinc system | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | 3 | - | |
| Lubricant | Hard ester acid | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | 0.4 | - | |
| Auxiliary agent | Properties-correcting agent | 3.2 | 3.2 | 0.44 | 3.2 | 5.73 | 5.73 | 7.18 | 7.18 | - | - | - | |
| Tensio-active agent | 0.82 | 0.82 | 0.11 | 0.82 | 1.24 | 1.24 | 3.59 | 3.59 | - | - | - | ||
| Dispersion agent | 0.75 | 0.75 | 0.10 | 0.75 | 0.95 | 0.95 | 2.61 | 2.61 | - | - | - | ||
| UV light absorber | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | 0.8 | - | ||
| Rerum natura | Base material thickness (mm) | 0.2 | 0.3 | 0.02 | 1.0 | 0.2 | 0.3 | 0.2 | 0.3 | 0.2 | 0.2 | 0.3 | |
| Light transmission rate (%) | 69 | 58 | 85 | 49 | 40 | 26 | 19 | 17 | 86 | 50 | 93 | ||
| Mist degree (%) | 2.2 | 2.5 | 1.2 | 3.1 | 8.7 | 10.3 | 10.4 | 12.7 | 1.4 | 12.0 | 0.6 | ||
| Infrared rays screening rate (%) | 43 | 61 | 14 | 70 | 73 | 87 | 92 | 95 | 8 | 29 | 22 | ||
| Ultraviolet isolating rate (%) | 99 | 99 | 98 | 99 | 99 | 99 | 99 | 99 | 98 | 98 | 27 | ||
| Whether course of processing ATO separates out | Not | Not | Not | Not | Not | Not | Not | Not | Not | Meeting | - | ||
Prescription consumption unit is: PHR (per hundred parts of weight resins).
Claims (3)
1. one kind is attached to the heat-proof polychloroethylene transparent adhesive tape that infrared rays and ultraviolet purposes are covered in conduct on glass, is base material with thickness between the polyvinyl chloride adhesive plaster of 0.02～1.0mm, and in the tissue of described polyvinyl chloride adhesive plaster, the inorganic insulation particle that comprises uniformly dispersing, it is characterized in that described polyvinyl chloride transparent adhesive plaster is composed of the following components:
Polyvinyl chloride (PVC) RESINS 100PHR is selected from wherein one or more the composition with prepared polyvinyl chloride polymer of mass polymerization, solution polymerization, suspension polymerization or letex polymerization or multipolymer;
Softening agent 0～85PHR, be selected from phosphoric acid ester, phthalic acid salt, trimellitate class, epoxies, polyester, chlorinated hydrocarbons or aliphatic diacid ester plasticizer wherein one or more;
Inorganic insulation particle 0.3～15PHR, particle diameter be between 0.005～2 μ m, and be selected from titanium dioxide (TiO
2), zinc oxide (ZnO), vanadium oxide (V
2O
5), Indium sesquioxide (In
2O
3), cerium oxide (CeO
2), stannic oxide (SnO
2), weisspiessglanz (Sb
2O
3), zinc sulphide (ZnS), titanium tetrachloride (ATO) or indium tin oxide (ITO) wherein one or more;
Stablizer 0.1～15PHR;
Lubricant 0.1～15PHR;
Auxiliary agent 0.3～25PHR, by UV light absorber and properties-correcting agent, tensio-active agent, dispersion agent or coupler wherein one or more mix, and described UV light absorber, be selected from hydroxy-phenyl-benzotriazole UV light absorber or hydroxy benzophenone ketone UV light absorber wherein one or more; And
Colorant 0.0～12PHR.
2. heat-proof polychloroethylene transparent adhesive tape as claimed in claim 1 is characterized in that, described dispersion agent, be selected from the copolymer dispersant of polymer, siliceous composition dispersion agent or fluorine-containing composition dispersion agent wherein one or more.
3. heat-proof polychloroethylene transparent adhesive tape as claimed in claim 1 is characterized in that, described coupler is selected from the wherein a kind of of organic silane compound coupler, organic zirconium aluminum compound coupler or organic titanium aluminum compound coupler.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007101516050A CN101157829B (en) | 2007-09-21 | 2007-09-21 | Heat-proof polychloroethylene transparent adhesive tape |
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|---|---|---|---|
| CN2007101516050A CN101157829B (en) | 2007-09-21 | 2007-09-21 | Heat-proof polychloroethylene transparent adhesive tape |
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| CN101157829A CN101157829A (en) | 2008-04-09 |
| CN101157829B true CN101157829B (en) | 2010-07-07 |
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| TWI458803B (en) * | 2009-02-16 | 2014-11-01 | Nanya Plastics Corp | A transparent pvc film or sheet for cutting off uv & ir light and its process |
| CN101885218B (en) * | 2009-05-15 | 2016-02-10 | 南亚塑胶工业股份有限公司 | A kind of non-PVC series is through the calendering polyolefin adhesive plaster made of machining and method for making thereof |
| CN101962516B (en) * | 2009-07-22 | 2013-10-09 | 南亚塑胶工业股份有限公司 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
| CN102702648B (en) * | 2012-06-19 | 2014-06-25 | 上海交通大学 | Preparation method of heat-conducting polyvinyl chloride composite material with microwave absorption characteristic |
| CN102816396B (en) * | 2012-08-27 | 2015-03-18 | 南亚塑胶工业（南通）有限公司 | Low heat absorption PVC product and method of preparing adhesive tape and the rubber sheet from it |
| CN103408863B (en) * | 2013-07-19 | 2015-12-09 | 广东天安新材料股份有限公司 | A kind of infrared reflective material and obtained film thereof |
| CN107286496B (en) * | 2016-04-11 | 2020-05-29 | 太原市誉远涂料有限公司 | Composition for preparing heat insulation material and heat insulation material |
| TWI604029B (en) * | 2016-08-25 | 2017-11-01 | Nanya Plastics Corp | Transparent insulation PVC tape and its preparation method |
| CN109913140B (en) * | 2019-02-21 | 2021-10-26 | 宁波激智科技股份有限公司 | Transparent paint protective film with high environmental stability and application thereof |
| CN110615959A (en) * | 2019-09-29 | 2019-12-27 | 奎达高分子材料科技(宜兴)有限公司 | Nano Indium Tin Oxide (ITO) super-heat-insulation polyvinyl butyral (PVB) intermediate film material and preparation method thereof |
| CN110982192A (en) * | 2019-12-09 | 2020-04-10 | 江苏巨麦新材料科技有限公司 | Heat insulation type PVC sheet and preparation method thereof |
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| CN1115361C (en) * | 1999-01-05 | 2003-07-23 | 东营田园塑业有限公司 | Polychloroethylene high efficiency fog-free film |
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