CN109370039A - A kind of thickening master batch and preparation method thereof - Google Patents
A kind of thickening master batch and preparation method thereof Download PDFInfo
- Publication number
- CN109370039A CN109370039A CN201811197450.9A CN201811197450A CN109370039A CN 109370039 A CN109370039 A CN 109370039A CN 201811197450 A CN201811197450 A CN 201811197450A CN 109370039 A CN109370039 A CN 109370039A
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- master batch
- polyisobutene
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- thickening
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2457/00—Characterised by the use of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C08J2457/02—Copolymers of mineral oil hydrocarbons
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
A kind of thickening master batch and preparation method thereof, its raw material is weighed according to following percentage of weight formula: random polypropylene: 35%~45%, polyolefin elastomer: 10%~16%, tackifying resin: 1%~5%, polyisobutene: 30%~40%, polyethylene wax: 1~3%, suffocated amine antioxidant: 0.1~0.5%, nickel system light stabilizer: 0.1~0.5%.Thickening master batch of the invention pollutes environment there is no the volatilization of solvent when institute's film is protected in production, has better environmentally protective performance, while its tackifier will not be precipitated, and residue glue will not be left on item to be protected.In addition, it is using simply, production procedure is short, and production cost is low, has preferably comprehensive using effect.
Description
Technical field
The present invention relates to a kind of thickening master batches and preparation method thereof, belong to plastic master batch production field.
Background technique
Protective film is a kind of film material with surface protecting function, and the effect of protective film is to store and transport to circulate in commodity
In the process or between the process of substrate processing, the provisional safeguard procedures of the one kind taken to prevent surface scratching.Protective film
It is widely used in aluminium sheet, composited aluminum and plastic decking, mirror steel plate, colored steel, poly (methyl methacrylate) plate, decorative panel and aluminum profile, plastic-steel section bar, no
The surface protection of rust coil of strip material, marble and display screen etc..Currently, the industrialized production method of protective film is predominantly coated with
Method.Rubbing method includes solvent type, emulsion-type, heat molten type and ray curing, wherein solvent type ratio is maximum.Solvent type exists
Pollute environment and the higher problem of production cost.
The disadvantage is that:
Using solvent type rubbing method, the solvent volatilization of drying course is difficult to collect reuse, be easy to cause environmental pollution.Together
When, it is higher using the production cost of the technique.
Lead to reason:
It using rubbing method, first has to carry out sided corona treatment to basement membrane, the surface tension of basement membrane is allowed to be greater than 38 dynes per centimeters,
Then gluing is carried out again, and followed by drying, in the process, production environment is had no idea to accomplish totally-enclosed, therefore is had certain
The solvent of amount can be discharged into ambient enviroment, be polluted.Further, since its production process is complicated, production energy consumption is high, therefore its
Production cost is also higher.
Summary of the invention
The present invention overcomes the disadvantages of the prior art, provides thickening master batch and its system required for a kind of plastic film
Preparation Method can produce the protective film product with preferable adhesion strength.
In order to solve the above-mentioned technical problem, the present invention is achieved by the following technical solutions:
A kind of thickening master batch, raw material are weighed according to following percentage of weight formula: random polypropylene: 35%~
45%, polyolefin elastomer: 10%~16%, tackifying resin: 1%~5%, polyisobutene: 30%~40%, polyethylene wax: 1
~3%, suffocated amine antioxidant: 0.1~0.5%, nickel system light stabilizer: 0.1~0.5%.
Further, the melt index of the random polypropylene is 50~100g/min.
Further, the polyolefin elastomer melt index is 10~30g/min.
Further, the tackifying resin is C5 tackifying resin.
Further, the number-average molecular weight of the polyisobutene are as follows: 5~60,000.
Further, the PE wax molecular weight is 20000~50000.
It is a kind of viscosify master batch preparation method, which is characterized in that itself the following steps are included:
1) random polypropylene, polyolefin elastomer, tackifying resin, polyethylene wax, suffocated amine antioxidant, nickel system light are stablized
Agent carries out agitating mixing in corresponding ratio investment mixing device；
2) raw material after mixing is put into powder hopper, its blanking velocity is controlled by feed screw, is sent to
Extruding pelletization is carried out on double screw extruder, polyisobutene is individually sent into double screw extruder；
3) plastic strip after squeezing out first passes through sink cooling of the water temperature lower than 15 DEG C, residence time of the plastic strip in the sink
Greater than 0.5min, last pelletizing.
Wherein, in step 1), incorporation time 15min mixes revolving speed less than 100 revs/min.
Wherein, in step 2), the polyisobutene of high molecular weight is blocks, and block-like polyisobutene is knocked down melting tank
Interior, heating melting, heating melting temperature is 150~200 DEG C, and heating process needs logical nitrogen to be protected, to polyisobutene
After fusing, feeding valve is beaten, polyisobutene enters receiver, then is measured through metering pump, and double screw extruder is quantitatively sent to
It is interior.
Wherein, in step 2), various components mixed melting in twin-screw is granulated, and the temperature in each area of twin-screw is respectively as follows:
One 80~100 DEG C of area, 110~130 DEG C of 2nd area, 120~145 DEG C of 3rd area, 140~155 DEG C of 4th area, 150~160 DEG C of 5th area, six
155~175 DEG C of area, 150~165 DEG C of head.
Compared with prior art, the beneficial effects of the present invention are:
Thickening master batch of the invention pollutes environment there is no the volatilization of solvent when institute's film is protected in production, has better
Environmentally protective performance, while its tackifier will not be precipitated, and residue glue will not be left on item to be protected.In addition, it is used simply,
Production procedure is short, and production cost is low, has preferably comprehensive using effect.
Detailed description of the invention
Attached drawing is used to provide further understanding of the present invention, and is used to explain the present invention together with embodiments of the present invention,
It is not construed as limiting the invention, in the accompanying drawings:
Fig. 1 is a kind of device structure schematic diagram of preparation method for viscosifying master batch of the present invention.
In figure, 1 --- powder hopper；2 --- feed screw；
3 --- double screw extruder；4 --- melting tank；
5 --- nitrogen inlet；6 --- nitrogen outlet；
7 --- material valve；8 --- receiver；
9 --- metering pump.
Specific embodiment
Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings, it should be understood that preferred reality described herein
Apply example only for the purpose of illustrating and explaining the present invention and is not intended to limit the present invention.
Raw material is weighed according to following formulation weight percentage: random polypropylene 43%, polyolefin elastomer:
14%, C5 tackifying resin 4%, polyisobutene (PIB): 36%, PE wax: 2.5%, suffocated amine antioxidant weight accounts for 0.2%, nickel
It is that light stabilizer accounts for 0.3%.
Wherein:
Random polypropylene is used as the matrix resin of master batch, since it is amorphous polymer, to other compositions
There is good receiving to act on, can be improved the content of effective ingredient in master batch, reduce the additive amount of master batch, reduce the use of master batch
Cost, simultaneously because its amorphous structure, can reduce the crystallinity of film in the film production process, increase the bullet of film
Property.In the present invention, the melt index of random polypropylene preferably 50~100g/min.
The presence of POE elastomer can increase the compatibility between master batch matrix resin and film resin, reduce master batch addition
Influence to processing film stability.Its melt index preferably 10~30g/min.
C5 tackifying resin is the auxiliary agent that uses as the bonding force for increasing film, destroys the effect between macromolecule
Power increases its viscosity to reduce high molecular crystallinity.
Polyisobutene is used as main tackifier, and the two can increase the mobility of strand in film, thus
Make film that there is good viscoplasticity and preferable bonding force is presented.The number-average molecular weight of polyisobutene is preferred are as follows: 5~60,000.
PE wax used as lubricant and meanwhile also have certain plasticization, molecular weight be 20000~
50000, molecular weight is too low, is easy that the pollution caused to production equipment is precipitated, the excessively high then lubricant effect of molecular weight is deteriorated.
Key point of the invention, for main tackifier, and is carried out in the polyisobutene for using high molecular weight by a variety of tackifier
Compounding, since the molecular weight of polyisobutene is very high, will not generate precipitation phenomenon, in use so as to avoid protective film
On there is residue glue.Since polyisobutene is blocks, it is difficult to which directly the processing of progress twin-screw is granulated, and the present invention is by by its fritting
Melt and be re-fed into twin-screw granulation after the metering of metering pump 9 again, solves the processing difficulties of high molecular weight polyisobutylene.
Meanwhile the present invention has chosen the matrix that random polypropylene makees master batch, effective content for improving tackifier is reduced
A possibility that tackifier are precipitated, along with a variety of tackifier compounded technology with and extrusion plastic item chilling technique, effectively
Precipitation of the tackifier in master batch in production and storage is reduced, the final using effect of thickening master batch is improved.
Firstly, random polypropylene, POE, tackifying resin, PE wax, suffocated amine antioxidant, nickel system light stabilizer are by corresponding
Ratio is put into mixing device, carries out agitating mixing, and incorporation time 15min mixes revolving speed less than 100 revs/min.
Then, refering to fig. 1, raw material after mixing is put into powder hopper 1, is controlled under it by feed screw 2
Expect speed, it is sent on double screw extruder 3 according to a certain amount and carries out extruding pelletization.
The polyisobutene of high molecular weight is blocks, block-like polyisobutene is knocked down in melting tank 4, heating melting,
Heating melting temperature is 150~200 DEG C, and heating process needs logical nitrogen to be protected, and melting 4 top two sides of tank are respectively nitrogen
Entrance 5 and nitrogen outlet 6 beat feeding valve 7 after polyisobutene fusing, and polyisobutene enters receiver 8, then through metering pump 9 into
Row metering, is quantitatively sent in double screw extruder 3, by the measure control of feed screw 2 and metering pump 9, can flexibly adjust
The ratio for saving polyisobutene and other compositions is allowed to meet technique requirement.
Various components in twin-screw mixed melting be granulated, the temperature in each area of twin-screw be respectively as follows: 80~100 DEG C of an area,
Two 110~130 DEG C of areas, 120~145 DEG C of 3rd area, 140~155 DEG C of 4th area, 150~160 DEG C of 5th area, 155~175 DEG C of 6th area, machine
First 150~165 DEG C.
Finally, the plastic strip after squeezing out first passes through sink cooling of the water temperature lower than 15 DEG C, stop of the plastic strip in the sink
Time is greater than 0.5min, last pelletizing.
The present invention by selection have thickening plasticization effect auxiliary agent pre-production become plastic master batch, add the master batch with
Matrix resin carries out the production of film after being blended, can be produced by film manufacturing process such as traditional blow molding, curtain coatings in this way
Protective film product with preferable adhesion strength.Its simple production process, production procedure is short, and production cost is low, and production process is to ring
Border is pollution-free, has the preferable feature of environmental protection.
The present invention is protected with polyolefin blend extrusion again by the way that master batch is made in the auxiliary agent with Efficient Adhesive Promotion in advance
Film, production process are consistent with the production process of traditional films.
Protective film occurs small molecule precipitation in use or generates residue glue in order to prevent, and one aspect of the present invention passes through
Using random polypropylene as matrix, and increase POE as auxiliary, effective content for improving tackifier in master batch.Separately
Outer one side is then to select the polyisobutene of high molecular weight as main tackifier, by advance melting the polyisobutene of high molecular weight
It is sent into twin-screw after accurately being measured by metering pump 9 again after melting and enters processing, overcomes high molecular weight polyisobutylene and is difficult to
Directly carry out the difficult point of twin-screw extrusion processing.Simultaneously by the compounding of a variety of tackifier, and film bonding force can improved
While prevent it from residue glue occur on the surface of protected object body.In addition, being used lower when extrusion plastic item is cooling
Water temperature cooled down, so as to effectively reduce precipitation of the tackifier in production and storage in master batch, improve thickening master batch
Final using effect.
Finally, it should be noted that these are only the preferred embodiment of the present invention, it is not intended to restrict the invention, although
Referring to embodiment, invention is explained in detail, for those skilled in the art, still can be to aforementioned
Technical solution documented by each embodiment is modified or equivalent replacement of some of the technical features, but it is all
Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention
Within the scope of.
Claims (10)
1. a kind of thickening master batch, which is characterized in that its raw material is weighed according to following percentage of weight formula: random poly- third
Alkene: 35%~45%, polyolefin elastomer: 10%~16%, tackifying resin: 1%~5%, polyisobutene: 30%~40%,
Polyethylene wax: 1~3%, suffocated amine antioxidant: 0.1~0.5%, nickel system light stabilizer: 0.1~0.5%.
2. a kind of thickening master batch according to claim 1, which is characterized in that the melt index of the random polypropylene be 50~
100g/min。
3. a kind of thickening master batch according to claim 1, which is characterized in that the polyolefin elastomer melt index be 10~
30g/min。
4. a kind of thickening master batch according to claim 1, which is characterized in that the tackifying resin is C5 tackifying resin.
5. a kind of thickening master batch according to claim 1, which is characterized in that the number-average molecular weight of the polyisobutene are as follows: 5~
60000.
6. a kind of thickening master batch according to claim 1, which is characterized in that the PE wax molecular weight is 20000~50000.
7. according to claim 1 it is a kind of viscosify master batch preparation method, which is characterized in that itself the following steps are included:
1) random polypropylene, polyolefin elastomer, tackifying resin, polyethylene wax, suffocated amine antioxidant, nickel system light stabilizer are pressed
In corresponding ratio investment mixing device, agitating mixing is carried out；
2) raw material after mixing is put into powder hopper, its blanking velocity is controlled by feed screw, be sent to double spiral shells
Extruding pelletization is carried out on bar extruder, polyisobutene is individually sent into double screw extruder；
3) plastic strip after squeezing out first passes through sink cooling of the water temperature lower than 15 DEG C, and plastic strip is greater than in the residence time of the sink
0.5min, last pelletizing.
8. a kind of preparation method for viscosifying master batch according to claim 7, which is characterized in that in step 1), incorporation time is
15min mixes revolving speed less than 100 revs/min.
9. a kind of preparation method for viscosifying master batch according to claim 7, which is characterized in that in step 2), high molecular weight
Polyisobutene is blocks, by block-like polyisobutene knock down melting tank in, heating melting, heating melting temperature be 150~
200 DEG C, heating process needs logical nitrogen to be protected, and after polyisobutene fusing, beats feeding valve, polyisobutene enters reservoir
Tank, then measured through metering pump, quantitatively it is sent in double screw extruder.
10. a kind of preparation method for viscosifying master batch according to claim 7, which is characterized in that in step 2), various components exist
Mixed melting is granulated in twin-screw, and the temperature in each area of twin-screw is respectively as follows: 80~100 DEG C of an area, 110~130 DEG C of 2nd area, 3rd area
120~145 DEG C, 140~155 DEG C of 4th area, 150~160 DEG C of 5th area, 155~175 DEG C of 6th area, 150~165 DEG C of head.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811197450.9A CN109370039A (en) | 2018-10-15 | 2018-10-15 | A kind of thickening master batch and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811197450.9A CN109370039A (en) | 2018-10-15 | 2018-10-15 | A kind of thickening master batch and preparation method thereof |
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| Publication Number | Publication Date |
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| CN109370039A true CN109370039A (en) | 2019-02-22 |
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ID=65400416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201811197450.9A Pending CN109370039A (en) | 2018-10-15 | 2018-10-15 | A kind of thickening master batch and preparation method thereof |
Country Status (1)
| Country | Link |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698775A (en) * | 2019-11-22 | 2020-01-17 | 怀化东庆科技有限公司 | Food-grade high-filling polyisobutylene carrier barium sulfate master batch and preparation method thereof |
| CN110845804A (en) * | 2019-11-22 | 2020-02-28 | 怀化东庆科技有限公司 | Polyisobutylene talcum powder master batch and preparation method thereof |
| CN111057295A (en) * | 2019-11-25 | 2020-04-24 | 怀化东庆科技有限公司 | Foaming master batch and preparation method thereof |
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| CN105017600A (en) * | 2014-12-10 | 2015-11-04 | 淄博龙沙高分子材料科技有限公司 | Tackifying master batch production process |
| CN106752994A (en) * | 2016-12-06 | 2017-05-31 | 淄博龙沙高分子材料科技有限公司 | Self-adhesive film/diaphragm thickening masterbatch |
| CN107531929A (en) * | 2015-06-08 | 2018-01-02 | 株式会社钟化 | The manufacture method of thermoplastic elastomer foaming body |
| CN107698883A (en) * | 2017-10-30 | 2018-02-16 | 天津泽恒包装制品有限公司 | A kind of high viscous diaphragm thickening masterbatch preparation process of noresidue |
| CN108276724A (en) * | 2018-03-02 | 2018-07-13 | 广州禾工材料科技有限公司 | A kind of thickening master batch and preparation method thereof for protective film |
-
2018
- 2018-10-15 CN CN201811197450.9A patent/CN109370039A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105017600A (en) * | 2014-12-10 | 2015-11-04 | 淄博龙沙高分子材料科技有限公司 | Tackifying master batch production process |
| CN107531929A (en) * | 2015-06-08 | 2018-01-02 | 株式会社钟化 | The manufacture method of thermoplastic elastomer foaming body |
| CN106752994A (en) * | 2016-12-06 | 2017-05-31 | 淄博龙沙高分子材料科技有限公司 | Self-adhesive film/diaphragm thickening masterbatch |
| CN107698883A (en) * | 2017-10-30 | 2018-02-16 | 天津泽恒包装制品有限公司 | A kind of high viscous diaphragm thickening masterbatch preparation process of noresidue |
| CN108276724A (en) * | 2018-03-02 | 2018-07-13 | 广州禾工材料科技有限公司 | A kind of thickening master batch and preparation method thereof for protective film |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698775A (en) * | 2019-11-22 | 2020-01-17 | 怀化东庆科技有限公司 | Food-grade high-filling polyisobutylene carrier barium sulfate master batch and preparation method thereof |
| CN110845804A (en) * | 2019-11-22 | 2020-02-28 | 怀化东庆科技有限公司 | Polyisobutylene talcum powder master batch and preparation method thereof |
| CN111057295A (en) * | 2019-11-25 | 2020-04-24 | 怀化东庆科技有限公司 | Foaming master batch and preparation method thereof |
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