CN104152064B - Ultra-thin PVC adhesive plaster - Google Patents
Ultra-thin PVC adhesive plaster Download PDFInfo
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- CN104152064B CN104152064B CN201410340227.0A CN201410340227A CN104152064B CN 104152064 B CN104152064 B CN 104152064B CN 201410340227 A CN201410340227 A CN 201410340227A CN 104152064 B CN104152064 B CN 104152064B
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Abstract
The present invention discloses a kind of ultra-thin PVC adhesive plaster, includes following material component: composite PVC powder 80～86%；Compound diazepam agent 2.0～2.6%；Plasticizer 1.1～1.9%；Toughener 2.0～3.0%；Processing aid: it is ACR, the quality proportioning of processing aid is 1.0～1.8%；Compound modification agent: it is made up of impact modifier and MBS, the quality proportioning of compound modification agent is 5.0～7.0%；Compound lubrication prescription: it is made up of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality proportioning of compound lubrication prescription is 1.0～1.6%；Antioxidant: it is the positive octadecyl ester of propanoic acid, the quality proportioning of antioxidant is 0.5～1.5%；Opening agent: it is erucyl amide, the quality proportioning of opening agent is 0.8～1.2%；The quality proportioning sum of above material component is 100%.Ultra-thin its thickness of PVC adhesive plaster prepared by above material component is the thinnest up to 22 μm, and its physical properties is better than existing PVC adhesive plaster.
Description
Technical field
The present invention relates to PVC adhesive plaster art, refer in particular to a kind of ultra-thin PVC adhesive plaster.
Background technology
PVC(polrvinyl chloride) adhesive plaster is a kind of synthesis macromolecular material, its production, should with polrvinyl chloride as primary raw material
Product have waterproof and dampproof, transparency is high, bright in colour, toughness is strong, corrosion-resistant, the characteristic such as be easily worked, be widely used
In extensive stock packaging, stationery making, building materials and beautifying and decorating articles for use.
But, current PVC adhesive plaster is the thinnest can only accomplish that about 50 μm, thickness is thicker, and physical property is (as surface is opened
Power, impact strength, tensile strength etc.) the best.
Summary of the invention
In view of this, the present invention is directed to the disappearance of prior art existence, its main purpose is to provide a kind of ultra-thin PVC glue
Cloth, it can effectively solve the problem that existing PVC adhesive plaster thickness is thick and physical property is the best.
For achieving the above object, the present invention uses such as purgation technical scheme:
A kind of ultra-thin PVC adhesive plaster, includes following material component:
(1) composite PVC powder: it is made up of the polrvinyl chloride powder of different polymerization degree, the quality proportioning of composite PVC powder be 80～
86%；
(2) compound diazepam agent: it is made up of butyl tin, methyl stannum tranquilizer, the quality proportioning of compound diazepam agent be 2.0～
2.6%；
(3) plasticizer: it is trimellitic acid three monooctyl ester, the quality proportioning of plasticizer is 1.1～1.9%；
(4) toughener: it is elastic MBS, and the quality proportioning of toughener is 2.0～3.0%；
(5) processing aid: it is ACR, the quality proportioning of processing aid is 1.0～1.8%；
(6) compound modification agent: it is made up of impact modifier and MBS, the quality proportioning of compound modification agent be 5.0～
7.0%；
(7) compound lubrication prescription: it is made up of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality of compound lubrication prescription is joined
Ratio is 1.0～1.6%；
(8) antioxidant: it is the positive octadecyl ester of propanoic acid, the quality proportioning of antioxidant is 0.5～1.5%；
(9) opening agent: it is erucyl amide, the quality proportioning of opening agent is 0.8～1.2%；
The quality proportioning sum of above material component is 100%.
The present invention compared with prior art has clear advantage and beneficial effect, specifically, by technique scheme
Understand:
Ultra-thin its thickness of PVC adhesive plaster prepared by above material component is the thinnest up to 22 μm, and its physical properties
Better than existing PVC adhesive plaster.
Detailed description of the invention
The one ultra-thin PVC adhesive plaster that the present invention discloses, includes following material component:
(1) composite PVC powder: it is made up of the polrvinyl chloride powder of different polymerization degree, such as, composite PVC powder can be model
The combination of G-700, A-107 and C-1008, the quality proportioning of composite PVC powder is 80～86%；
(2) compound diazepam agent: it is made up of butyl tin, methyl stannum tranquilizer, the quality proportioning of compound diazepam agent be 2.0～
2.6%；
(3) plasticizer: it is trimellitic acid three monooctyl ester, the quality proportioning of plasticizer is 1.1～1.9%；
(4) toughener: its be elastic MBS, MBS be methyl methacrylate (M), butadiene (B) and the three of styrene (S)
Membered copolymer, the quality proportioning of toughener is 2.0～3.0%；
(5) processing aid: its be ACR, ACR be the acrylic acid esters co-polymer with nucleocapsid structure, processing aid
Quality proportioning is 1.0～1.8%；
(6) compound modification agent: it is made up of impact modifier and MBS, the quality proportioning of compound modification agent be 5.0～
7.0%；
(7) compound lubrication prescription: it is made up of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality of compound lubrication prescription is joined
Ratio is 1.0～1.6%；
(8) antioxidant: it is the positive octadecyl ester of propanoic acid, the quality proportioning of antioxidant is 0.5～1.5%；
(9) opening agent: it is erucyl amide, the quality proportioning of opening agent is 0.8～1.2%；
The quality proportioning sum of above material component is 100%.
With specific embodiment, the present invention will be described below, and " part " that following example use is based on weight.
Embodiment 1
By toughness reinforcing to 80 weight portion composite PVC powder, 2.5 weight portion compound diazepam agent, 1.8 parts by weight of plasticizer, 3.0 weight portions
Agent, 1.8 weight portion processing aids, 7.0 weight portions are combined modification agent, 1.5 weight portions are combined lubrication prescription, 1.4 weight portion antioxidant with
And 1.0 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 2
By toughness reinforcing to 81 weight portion composite PVC powder, 2.6 weight portion compound diazepam agent, 1.6 parts by weight of plasticizer, 2.9 weight portions
Agent, 1.7 weight portion processing aids, 6.9 weight portions are combined modification agent, 1.6 weight portions are combined lubrication prescription, 0.5 weight portion antioxidant with
And 1.2 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 3
By toughness reinforcing to 82 weight portion composite PVC powder, 2.2 weight portion compound diazepam agent, 1.7 parts by weight of plasticizer, 2.0 weight portions
Agent, 1.3 weight portion processing aids, 6.8 weight portions are combined modification agent, 1.4 weight portions are combined lubrication prescription, 1.5 weight portion antioxidant with
And 1.1 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 4
By toughness reinforcing to 83 weight portion composite PVC powder, 2.3 weight portion compound diazepam agent, 1.1 parts by weight of plasticizer, 2.1 weight portions
Agent, 1.0 weight portion processing aids, 7.0 weight portions are combined modification agent, 1.3 weight portions are combined lubrication prescription, 1.3 weight portion antioxidant with
And 0.9 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 5
By toughness reinforcing to 84 weight portion composite PVC powder, 2.6 weight portion compound diazepam agent, 1.2 parts by weight of plasticizer, 2.2 weight portions
Agent, 1.2 weight portion processing aids, 6.1 weight portions are combined modification agent, 1.0 weight portions are combined lubrication prescription, 0.9 weight portion antioxidant with
And 0.8 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 6
By toughness reinforcing to 85 weight portion composite PVC powder, 2.0 weight portion compound diazepam agent, 1.4 parts by weight of plasticizer, 3.0 weight portions
Agent, 1.1 weight portion processing aids, 5.1 weight portions are combined modification agent, 1.1 weight portions are combined lubrication prescription, 0.5 weight portion antioxidant with
And 0.8 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 7
85.5 weight portion composite PVC powder, 2.0 weight portion compound diazepam agent, 1.9 parts by weight of plasticizer, 2.0 weight portions are increased
Tough dose, 1.0 weight portion processing aids, 5.0 weight portions are combined modification agent, 1.0 weight portions are combined lubrication prescription, 0.8 weight portion antioxidant
And 0.8 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
Embodiment 8
By toughness reinforcing to 86 weight portion composite PVC powder, 2.0 weight portion compound diazepam agent, 1.1 parts by weight of plasticizer, 2.1 weight portions
Agent, 1.3 weight portion processing aids, 5.0 weight portions are combined modification agent, 1.1 weight portions are combined lubrication prescription, 0.5 weight portion antioxidant with
And 0.9 weight portion opening agent with after mixer mix homogeneously, introduce ten thousand horsepowers of machines the most mixing, material temperature controls 130～200
DEG C, after rolling turbine gel, by the compound of uniform gel, with calender machine-shaping.
The ultra-thin PVC adhesive plaster formula of above example 1～8 is as shown in table 1 below.
The ultra-thin PVC adhesive plaster obtained by embodiment 1～8 carries out physical property measurement, and result is as shown in table 2.
The ultra-thin PVC adhesive plaster formula of table 1 embodiment 1～8
Table 2 embodiment 1～8 physical property measurement
As shown in Table 2, ultra-thin its thickness of PVC adhesive plaster that the present invention prepares is the thinnest up to 22 μm, and its every physical property
Existing PVC adhesive plaster can be better than.
The above, be only presently preferred embodiments of the present invention, not impose any restrictions the technical scope of the present invention,
Therefore any trickle amendment, equivalent variations and modification that above example is made by every technical spirit according to the present invention, the most still
Belong in the range of technical solution of the present invention.
Claims (1)
1. a ultra-thin PVC adhesive plaster, it is characterised in that: include following material component:
(1) composite PVC powder: it is made up of the polrvinyl chloride powder of different polymerization degree, the quality proportioning of composite PVC powder is 80～86%；
(2) compound diazepam agent: it is made up of butyl tin, methyl stannum tranquilizer, the quality proportioning of compound diazepam agent be 2.0～
2.6%；
(3) plasticizer: it is trimellitic acid three monooctyl ester, the quality proportioning of plasticizer is 1.1～1.9%；
(4) toughener: it is elastic MBS, and the quality proportioning of toughener is 2.0～3.0%；
(5) processing aid: it is ACR, the quality proportioning of processing aid is 1.0～1.8%；
(6) compound modification agent: it is made up of impact modifier and MBS, the quality proportioning of compound modification agent is 5.0～7.0%；
(7) compound lubrication prescription: it is made up of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality proportioning of compound lubrication prescription is
1.0～1.6%；
(8) antioxidant: it is the positive octadecyl ester of propanoic acid, the quality proportioning of antioxidant is 0.5～1.5%；
(9) opening agent: it is erucyl amide, the quality proportioning of opening agent is 0.8～1.2%；
The quality proportioning sum of above material component is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410340227.0A CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410340227.0A CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
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| Publication Number | Publication Date |
|---|---|
| CN104152064A CN104152064A (en) | 2014-11-19 |
| CN104152064B true CN104152064B (en) | 2016-08-17 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410340227.0A Active CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647064B (en) * | 2016-03-09 | 2018-02-13 | 广州宏信塑胶工业有限公司 | A kind of weather-proof PVC plastic wallpaper and preparation method thereof |
| CN105885290A (en) * | 2016-05-13 | 2016-08-24 | 佛山市天进塑胶有限公司 | Production formula of high-grade inkjet advertisement film for outdoor advertisements |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09194325A (en) * | 1996-01-22 | 1997-07-29 | Nitto Denko Corp | Tack sheet for removing stain |
| CN101962516A (en) * | 2009-07-22 | 2011-02-02 | 南亚塑胶工业股份有限公司 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
-
2014
- 2014-07-17 CN CN201410340227.0A patent/CN104152064B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09194325A (en) * | 1996-01-22 | 1997-07-29 | Nitto Denko Corp | Tack sheet for removing stain |
| CN101962516A (en) * | 2009-07-22 | 2011-02-02 | 南亚塑胶工业股份有限公司 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
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| CN104152064A (en) | 2014-11-19 |
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Effective date of registration: 20191129 Address after: 214000 No.28, Xinzhou Road, national high tech Industrial Development Zone, Wuxi City, Jiangsu Province Patentee after: Wuxi Hongyi polymer material technology Co., Ltd Address before: 518000, No. 1, Po pan Road, Eastern Economic Development Zone, Guangdong, Guangzhou Patentee before: GUANGZHOU HAN RIGID INDUSTRIAL CO., LTD. |
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