CN104152064A - Ultrathin PVC (polyvinyl chloride) adhesive tape - Google Patents
Ultrathin PVC (polyvinyl chloride) adhesive tape Download PDFInfo
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- CN104152064A CN104152064A CN201410340227.0A CN201410340227A CN104152064A CN 104152064 A CN104152064 A CN 104152064A CN 201410340227 A CN201410340227 A CN 201410340227A CN 104152064 A CN104152064 A CN 104152064A
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Abstract
The invention discloses an ultrathin PVC (polyvinyl chloride) adhesive tape which comprises the following components in percentage by mass: 80-86% of composite PVC powder, 2.0-2.6% of composite stabilizer, 1.1-1.9% of plasticizer, 2.0-3.0% of toughener, 1.0-1.8% of processing assistant (ACR), 5.0-7.0% of composite modifier (composed of impact modifier and MBS (methyl methacrylate-butadiene-styrene)), 1.0-1.6% of composite lubricant (composed of ethylene bis stearamide and high-polymer fatty acid ester), 0.5-1.5% of antioxidant (n-octadeca-propionate) and 0.8-1.2% of opening agent (erucyl amide). The minimum thickness of the ultrathin PVC adhesive tape can reach 22 mu m, the physical properties are better than those of the existing PVC adhesive tape.
Description
Technical field
The present invention relates to PVC adhesive plaster art, refer in particular to a kind of ultra-thin PVC adhesive plaster.
Background technology
PVC(polyvinyl chloride) adhesive plaster is a kind of synthesized polymer material, its production be take polyvinyl chloride as main raw material, the characteristics such as that this product has is waterproof and dampproof, transparency is high, bright in colour, toughness is strong, corrosion-resistant, easy processing, have been widely used in extensive stock packing, stationery making, building materials and beautifying and decorating articles for use.
Yet current PVC adhesive plaster is the thinnest can only accomplish 50 μ m left and right, thickness is thicker, and physicals (as surface tension, impact strength, tensile strength etc.) is comparatively not good.
Summary of the invention
In view of this, the present invention is directed to the disappearance of prior art existence, its main purpose is to provide a kind of ultra-thin PVC adhesive plaster, and it can effectively solve the existing problem that PVC adhesive plaster thickness is thick and physicals is not good.
For achieving the above object, the present invention adopts following technical scheme:
A ultra-thin PVC adhesive plaster, includes following material component:
(1) composite PVC powder: its polyvinyl chloride powder by different polymerization degree forms, and the quality proportioning of composite PVC powder is 80～86%;
(2) compound diazepam agent: it is comprised of butyl tin, methyl tin tranquilizer, and the quality proportioning of compound diazepam agent is 2.0～2.6%;
(3) softening agent: it is trimellitic acid three monooctyl esters, and the quality proportioning of softening agent is 1.1～1.9%;
(4) toughner: it is elasticity MBS, the quality proportioning of toughner is 2.0～3.0%;
(5) processing aid: it is ACR, the quality proportioning of processing aid is 1.0～1.8%;
(6) compound modification agent: it is comprised of impact modifier and MBS, the quality proportioning of compound modification agent is 5.0～7.0%;
(7) compound lubrication prescription: it is comprised of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality proportioning of compound lubrication prescription is 1.0～1.6%;
(8) oxidation inhibitor: it is the positive octadecyl ester of propionic acid, and the quality proportioning of oxidation inhibitor is 0.5～1.5%;
(9) opening agent: it is erucicamide, the quality proportioning of opening agent is 0.8～1.2%;
The quality proportioning sum of above material component is 100%.
The present invention compared with prior art has obvious advantage and beneficial effect, particularly, and as shown from the above technical solution:
The thinnest 22 μ m that reach of ultra-thin its thickness of PVC adhesive plaster that made by above material component, and its physical properties is all better than existing PVC adhesive plaster.
Embodiment
A kind of ultra-thin PVC adhesive plaster that the present invention discloses, includes following material component:
(1) composite PVC powder: its polyvinyl chloride powder by different polymerization degree forms, for example, composite PVC powder can be the combination of model G-700, A-107 and C-1008, the quality proportioning of composite PVC powder is 80～86%;
(2) compound diazepam agent: it is comprised of butyl tin, methyl tin tranquilizer, and the quality proportioning of compound diazepam agent is 2.0～2.6%;
(3) softening agent: it is trimellitic acid three monooctyl esters, and the quality proportioning of softening agent is 1.1～1.9%;
(4) toughner: it is elasticity MBS, MBS is methyl methacrylate (M), the terpolymer of divinyl (B) and vinylbenzene (S), the quality proportioning of toughner is 2.0～3.0%;
(5) processing aid: it is ACR, ACR is the acrylic acid esters co-polymer with core-shell structure, the quality proportioning of processing aid is 1.0～1.8%;
(6) compound modification agent: it is comprised of impact modifier and MBS, the quality proportioning of compound modification agent is 5.0～7.0%;
(7) compound lubrication prescription: it is comprised of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality proportioning of compound lubrication prescription is 1.0～1.6%;
(8) oxidation inhibitor: it is the positive octadecyl ester of propionic acid, and the quality proportioning of oxidation inhibitor is 0.5～1.5%;
(9) opening agent: it is erucicamide, the quality proportioning of opening agent is 0.8～1.2%;
The quality proportioning sum of above material component is 100%.
With specific embodiment, the present invention will be described below, and " part " that following examples are used is based on weight.
Embodiment 1
After 80 weight part composite PVC powder, 2.5 weight part compound diazepam agent, 1.8 weight part softening agent, 3.0 weight part toughner, 1.8 weight part processing aids, the compound modification agent of 7.0 weight part, the compound lubrication prescription of 1.5 weight part, 1.4 weight part oxidation inhibitor and 1.0 weight part opening agents are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 2
After 81 weight part composite PVC powder, 2.6 weight part compound diazepam agent, 1.6 weight part softening agent, 2.9 weight part toughner, 1.7 weight part processing aids, the compound modification agent of 6.9 weight part, the compound lubrication prescription of 1.6 weight part, 0.5 weight part oxidation inhibitor and 1.2 weight part opening agents are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 3
After 82 weight part composite PVC powder, 2.2 weight part compound diazepam agent, 1.7 weight part softening agent, 2.0 weight part toughner, 1.3 weight part processing aids, the compound modification agent of 6.8 weight part, the compound lubrication prescription of 1.4 weight part, 1.5 weight part oxidation inhibitor and 1.1 weight part opening agents are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 4
After 83 weight part composite PVC powder, 2.3 weight part compound diazepam agent, 1.1 weight part softening agent, 2.1 weight part toughner, 1.0 weight part processing aids, the compound modification agent of 7.0 weight part, the compound lubrication prescription of 1.3 weight part, 1.3 weight part oxidation inhibitor and 0.9 weight part opening agent are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 5
After 84 weight part composite PVC powder, 2.6 weight part compound diazepam agent, 1.2 weight part softening agent, 2.2 weight part toughner, 1.2 weight part processing aids, the compound modification agent of 6.1 weight part, the compound lubrication prescription of 1.0 weight part, 0.9 weight part oxidation inhibitor and 0.8 weight part opening agent are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 6
After 85 weight part composite PVC powder, 2.0 weight part compound diazepam agent, 1.4 weight part softening agent, 3.0 weight part toughner, 1.1 weight part processing aids, the compound modification agent of 5.1 weight part, the compound lubrication prescription of 1.1 weight part, 0.5 weight part oxidation inhibitor and 0.8 weight part opening agent are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 7
After 85.5 weight part composite PVC powder, 2.0 weight part compound diazepam agent, 1.9 weight part softening agent, 2.0 weight part toughner, 1.0 weight part processing aids, the compound modification agent of 5.0 weight part, the compound lubrication prescription of 1.0 weight part, 0.8 weight part oxidation inhibitor and 0.8 weight part opening agent are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
Embodiment 8
After 86 weight part composite PVC powder, 2.0 weight part compound diazepam agent, 1.1 weight part softening agent, 2.1 weight part toughner, 1.3 weight part processing aids, the compound modification agent of 5.0 weight part, the compound lubrication prescription of 1.1 weight part, 0.5 weight part oxidation inhibitor and 0.9 weight part opening agent are mixed with mixing machine, introduce ten thousand horsepowers of machines evenly mixing, material temperature is controlled at 130～200 ℃, after rolling turbine gel, by the compound of even gel, with rolling press machine-shaping.
The ultra-thin PVC adhesive plaster formula of above embodiment 1～8 is as shown in following table 1.
The ultra-thin PVC adhesive plaster obtaining with embodiment 1～8 carries out physical property measurement, and result is as shown in table 2.
The ultra-thin PVC adhesive plaster formula of table 1 embodiment 1～8
Table 2 embodiment 1～8 physical property measurement
As shown in Table 2, the thinnest 22 μ m that reach of ultra-thin its thickness of PVC adhesive plaster that the present invention makes, and its physical properties is all better than existing PVC adhesive plaster.
The above, it is only preferred embodiment of the present invention, not technical scope of the present invention is imposed any restrictions, therefore any trickle modification, equivalent variations and modification that every foundation technical spirit of the present invention is done above embodiment all still belong in the scope of technical solution of the present invention.
Claims (1)
1. a ultra-thin PVC adhesive plaster, is characterized in that: include following material component:
(1) composite PVC powder: its polyvinyl chloride powder by different polymerization degree forms, and the quality proportioning of composite PVC powder is 80～86%;
(2) compound diazepam agent: it is comprised of butyl tin, methyl tin tranquilizer, and the quality proportioning of compound diazepam agent is 2.0～2.6%;
(3) softening agent: it is trimellitic acid three monooctyl esters, and the quality proportioning of softening agent is 1.1～1.9%;
(4) toughner: it is elasticity MBS, the quality proportioning of toughner is 2.0～3.0%;
(5) processing aid: it is ACR, the quality proportioning of processing aid is 1.0～1.8%;
(6) compound modification agent: it is comprised of impact modifier and MBS, the quality proportioning of compound modification agent is 5.0～7.0%;
(7) compound lubrication prescription: it is comprised of ethylene bis stearic acid amide and polymeric fatty acid esters, the quality proportioning of compound lubrication prescription is 1.0～1.6%;
(8) oxidation inhibitor: it is the positive octadecyl ester of propionic acid, and the quality proportioning of oxidation inhibitor is 0.5～1.5%;
(9) opening agent: it is erucicamide, the quality proportioning of opening agent is 0.8～1.2%;
The quality proportioning sum of above material component is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410340227.0A CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410340227.0A CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
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| CN104152064A true CN104152064A (en) | 2014-11-19 |
| CN104152064B CN104152064B (en) | 2016-08-17 |
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| CN201410340227.0A Active CN104152064B (en) | 2014-07-17 | 2014-07-17 | Ultra-thin PVC adhesive plaster |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647064A (en) * | 2016-03-09 | 2016-06-08 | 广州宏信塑胶工业有限公司 | Weatherable PVC (polyvinyl chloride) plastic wallpaper and preparation method thereof |
| CN105885290A (en) * | 2016-05-13 | 2016-08-24 | 佛山市天进塑胶有限公司 | Production formula of high-grade inkjet advertisement film for outdoor advertisements |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09194325A (en) * | 1996-01-22 | 1997-07-29 | Nitto Denko Corp | Tack sheet for removing stain |
| CN101962516A (en) * | 2009-07-22 | 2011-02-02 | 南亚塑胶工业股份有限公司 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
-
2014
- 2014-07-17 CN CN201410340227.0A patent/CN104152064B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09194325A (en) * | 1996-01-22 | 1997-07-29 | Nitto Denko Corp | Tack sheet for removing stain |
| CN101962516A (en) * | 2009-07-22 | 2011-02-02 | 南亚塑胶工业股份有限公司 | Transparent heat insulation polyvinyl chloride rubberized fabric and preparation method thereof |
| CN103240939A (en) * | 2013-04-25 | 2013-08-14 | 福建思嘉环保材料科技有限公司 | Anti-sticking gas mould material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647064A (en) * | 2016-03-09 | 2016-06-08 | 广州宏信塑胶工业有限公司 | Weatherable PVC (polyvinyl chloride) plastic wallpaper and preparation method thereof |
| CN105885290A (en) * | 2016-05-13 | 2016-08-24 | 佛山市天进塑胶有限公司 | Production formula of high-grade inkjet advertisement film for outdoor advertisements |
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| CN104152064B (en) | 2016-08-17 |
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Effective date of registration: 20191129 Address after: 214000 No.28, Xinzhou Road, national high tech Industrial Development Zone, Wuxi City, Jiangsu Province Patentee after: Wuxi Hongyi polymer material technology Co., Ltd Address before: 518000, No. 1, Po pan Road, Eastern Economic Development Zone, Guangdong, Guangzhou Patentee before: GUANGZHOU HAN RIGID INDUSTRIAL CO., LTD. |