CN101945823B - 大晶体分子筛及其制备 - Google Patents

大晶体分子筛及其制备 Download PDF

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Publication number
CN101945823B
CN101945823B CN2009801059086A CN200980105908A CN101945823B CN 101945823 B CN101945823 B CN 101945823B CN 2009801059086 A CN2009801059086 A CN 2009801059086A CN 200980105908 A CN200980105908 A CN 200980105908A CN 101945823 B CN101945823 B CN 101945823B
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CN
China
Prior art keywords
molecular sieve
reaction mixture
source
molar ratio
amorphous material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2009801059086A
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English (en)
Chinese (zh)
Other versions
CN101945823A (zh
Inventor
W·J·鲁斯
C·L·肯尼迪
T·约克
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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Publication of CN101945823A publication Critical patent/CN101945823A/zh
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Publication of CN101945823B publication Critical patent/CN101945823B/zh
Expired - Fee Related legal-status Critical Current
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C01B39/38—Type ZSM-5
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
CN2009801059086A 2008-02-22 2009-01-19 大晶体分子筛及其制备 Expired - Fee Related CN101945823B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US3070608P 2008-02-22 2008-02-22
US61/030,706 2008-02-22
EP08158024.3 2008-06-11
EP08158024 2008-06-11
PCT/EP2009/000388 WO2009103394A2 (en) 2008-02-22 2009-01-19 Large crystal molecular sieves and their manufacture

Publications (2)

Publication Number Publication Date
CN101945823A CN101945823A (zh) 2011-01-12
CN101945823B true CN101945823B (zh) 2013-07-03

Family

ID=40091847

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2009801059086A Expired - Fee Related CN101945823B (zh) 2008-02-22 2009-01-19 大晶体分子筛及其制备

Country Status (7)

Country Link
US (1) US9296619B2 (https=)
EP (1) EP2262732B1 (https=)
JP (1) JP5717447B2 (https=)
CN (1) CN101945823B (https=)
SG (1) SG188173A1 (https=)
WO (1) WO2009103394A2 (https=)
ZA (1) ZA201005377B (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2260000B8 (en) * 2008-02-22 2016-06-01 ExxonMobil Chemical Patents Inc. High aluminum content aluminosilicate molecular sieves and their manufacture
KR101858310B1 (ko) * 2011-12-01 2018-05-15 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 고활성의 큰 결정 zsm-5의 합성
CN104918886B (zh) * 2012-11-13 2018-08-10 巴斯夫欧洲公司 沸石材料的制备和在将氧合物转化成烯烃的方法中的用途

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375458A (en) * 1977-08-17 1983-03-01 Mobil Oil Corporation Synthesis of large crystallite zeolites
CN1732127A (zh) * 2002-12-30 2006-02-08 Sk株式会社 在没有有机模板下采用可变温度制备zsm－5的方法
CN101112996A (zh) * 2007-07-09 2008-01-30 南京工业大学 一种快速合成NaY分子筛的方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ193928A (en) 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
CA1150712A (en) * 1979-12-07 1983-07-26 William J. Ball Process for the production of crystalline aluminosilicates and their use as catalysts and catalyst supports
DK164097C (da) * 1982-09-20 1992-10-05 Tosoh Corp Fremgangsmaade til fremstilling af zeoliter
JPS5954620A (ja) * 1982-09-20 1984-03-29 Toyo Soda Mfg Co Ltd ゼオライトを製造する方法
NZ215434A (en) * 1985-04-08 1988-11-29 Mobil Oil Corp Method of producing a zeolite
US4908342A (en) 1985-09-04 1990-03-13 Mobil Oil Corporation ZSM-5 zeolites having uniformly large crystals
JP2564581B2 (ja) * 1987-12-28 1996-12-18 水澤化学工業株式会社 高シリカ含有量ゼオライトの製法
JP3537908B2 (ja) * 1995-03-23 2004-06-14 三井造船株式会社 Ｙ型ゼオライト膜製造法及び液体混合物分離膜
DE69620612T2 (de) * 1995-06-06 2003-02-06 Exxonmobil Oil Corp., Fairfax Grosskristalliner zeolith zsm-5, seine synthese und verwendung
ZA979264B (en) * 1996-10-17 1998-12-29 Exxon Chemical Patents Inc Synthesis of large crystal zeolites
US6180550B1 (en) * 1998-12-22 2001-01-30 Mobile Oil Corporation Small crystal ZSM-5, its synthesis and use
JP4541156B2 (ja) * 2002-12-30 2010-09-08 エスケー エナジー 株式会社 有機テンプレートなしで可変温度を用いてｚｓｍ−５を製造する方法
EP2260000B8 (en) * 2008-02-22 2016-06-01 ExxonMobil Chemical Patents Inc. High aluminum content aluminosilicate molecular sieves and their manufacture

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375458A (en) * 1977-08-17 1983-03-01 Mobil Oil Corporation Synthesis of large crystallite zeolites
CN1732127A (zh) * 2002-12-30 2006-02-08 Sk株式会社 在没有有机模板下采用可变温度制备zsm－5的方法
CN101112996A (zh) * 2007-07-09 2008-01-30 南京工业大学 一种快速合成NaY分子筛的方法

Also Published As

Publication number Publication date
EP2262732A2 (en) 2010-12-22
CN101945823A (zh) 2011-01-12
US20110207983A1 (en) 2011-08-25
US9296619B2 (en) 2016-03-29
JP5717447B2 (ja) 2015-05-13
WO2009103394A3 (en) 2010-04-22
JP2011523393A (ja) 2011-08-11
EP2262732B1 (en) 2017-05-24
WO2009103394A2 (en) 2009-08-27
ZA201005377B (en) 2011-04-28
SG188173A1 (en) 2013-03-28

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Granted publication date: 20130703

Termination date: 20210119

CF01 Termination of patent right due to non-payment of annual fee