CN101922129A - Paper printing environmental-friendly UV (Ultraviolet) gloss oil and preparation method thereof - Google Patents
Paper printing environmental-friendly UV (Ultraviolet) gloss oil and preparation method thereof Download PDFInfo
- Publication number
- CN101922129A CN101922129A CN 201010296806 CN201010296806A CN101922129A CN 101922129 A CN101922129 A CN 101922129A CN 201010296806 CN201010296806 CN 201010296806 CN 201010296806 A CN201010296806 A CN 201010296806A CN 101922129 A CN101922129 A CN 101922129A
- Authority
- CN
- China
- Prior art keywords
- friendly
- ultraviolet
- weight portion
- gloss oil
- paper printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000007639 printing Methods 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 7
- -1 acrylic ester Chemical class 0.000 claims description 32
- 238000002156 mixing Methods 0.000 claims description 31
- 238000003756 stirring Methods 0.000 claims description 26
- 239000007788 liquid Substances 0.000 claims description 24
- 239000013530 defoamer Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 16
- 230000008569 process Effects 0.000 claims description 15
- 239000004593 Epoxy Substances 0.000 claims description 14
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 238000012545 processing Methods 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 150000003512 tertiary amines Chemical class 0.000 claims description 12
- 239000004698 Polyethylene Substances 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 230000000977 initiatory effect Effects 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- BTJPUDCSZVCXFQ-UHFFFAOYSA-N 2,4-diethylthioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC(CC)=C3SC2=C1 BTJPUDCSZVCXFQ-UHFFFAOYSA-N 0.000 claims description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000012856 packing Methods 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 235000019504 cigarettes Nutrition 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical class C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 33
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 12
- 241000208125 Nicotiana Species 0.000 description 11
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 7
- GTELLNMUWNJXMQ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical class OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(CO)(CO)CO GTELLNMUWNJXMQ-UHFFFAOYSA-N 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000004806 packaging method and process Methods 0.000 description 5
- 230000006378 damage Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 125000004386 diacrylate group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000012855 volatile organic compound Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 208000028571 Occupational disease Diseases 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000003988 headspace gas chromatography Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000003678 scratch resistant effect Effects 0.000 description 1
- 230000000391 smoking effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
The invention relates to paper printing environmental-friendly UV (Ultraviolet) gloss oil and a preparation method thereof, belonging to the technical field of chemical industry. The paper printing environmental-friendly UV gloss oil is used for glazing various kinds of paper packing paper, such as cigarette labels, wine labels, and the like, and comprises the following raw materials in parts by weight: 10-40 parts of modified epoxy acrylate, 10-60 parts of active monomers, 2-10 parts of macromolecular photoinitiators, 1-20 parts of auxiliary initiators, 0.1-1 part of defoaming agents and 0.1-1 part of flatting agents. The invention has the advantages of reasonable formula, high gloss, good abrasion resistance, low volatile matter content, energy saving, environmental protection, low cost and stable product quality.
Description
Technical field
The present invention relates to a kind of paper printing environmental-friendly UV (Ultraviolet) gloss oil and preparation method thereof, be used for the glazing of all kinds of stationery packings, belong to chemical technology field as stationery wrapping papers such as cigarette-brand, wine marks.
Background technology
Along with the progress of society and the transformation of people's consumption concept, the safety of the consumer goods, health and environmental protection are subjected to the extensive concern of the whole society day by day.For many years, tobacco business adheres to that all the time people-oriented, makes great efforts to safeguard consumer's legitimate rights and interests.Particularly in recent years, tobacco business has been firmly established the common values of " national interests are supreme " and " consumer's interests are supreme ", in line with to country, the spirit highly responsible to the consumer, in conjunction with industry reality, in order to control the tobacco bale bar better, organic solvent residual in the box packaging paper, safeguard consumer's interests, avoid potential environmental pollution, State Tobacco Monopoly Bureau's tissue has developed and implemented YC/T207-2006 " the mensuration head space-gas chromatography of volatile organic compounds in tobacco shred and the box packaging paper " and two important industry standards of YC-2007 " volatile organic compounds limits the quantity of in tobacco shred and the box packaging paper ".These two establishments of standard not only can be improved the smoking material standards system, and unified tobacco business and packages printing industry are to the acceptance criteria and the method for inspection of tobacco shred and box packaging paper product, and there are laws to abide by in acceptance inspeciton to make both sides of supply and demand; Simultaneously; to the supervision law enforcement dynamics of further reinforcement tobacco business to tobacco shred, box packaging paper product quality; the production of standard China packages printing industry; guiding China packages printing industry is to green, environmental protection, low harm production development; protection consumer and the worker's of manufacturing enterprise is healthy, plays the facilitation of positive important.
When greatly developing economy, keep fine environment, healthy health is an important goal of current social development.The correct relation of handling " protection " and " promotion " reduces the injury of industrial production to the environment and the mankind itself, is irreversible trend, also is the responsibility that history is given us.Human only one earth is protected our home, and the problem that keeps sustainability ground to develop the economy has become global common recognition, has caused the great attention of national governments.China has also successively formulated, has put into effect many relevant laws, rules.As " Law on Environmental Protection ", " labour protection regulations ", " law on prevention and cure of occupational disease " or the like, for the development of chemical industry has proposed requirement, strict standard.Along with China entry into the World Trade Organization, our enterprise participates in competition in the international market, objectively also requires us to produce and use non-harmful product, eliminates in the world " Green Trade Barrier " to the non-trade barrier restriction of China's product.
Traditional solvent-borne type gloss oil and common gloss oil need with an organic solvent in process of production, and the organic volatile when printing and drying is many, and is very big to operating personnel's harm, also can produce pollution to environment.And rate of drying is slow, and production efficiency is low.Moreover there is the wasting of resources in the energy consumption height.
Summary of the invention
Technical problem to be solved by this invention provide a kind of prescription rationally, high glaze, ABRASION RESISTANCE be good, low volatile content, energy-conserving and environment-protective, cost are low, the paper printing environmental-friendly UV (Ultraviolet) gloss oil of constant product quality.
Another technical problem to be solved by this invention provides that a kind of technological design is reasonable, building-up process is simple and convenient, the preparation method of product safety environmental protection, paper printing environmental-friendly UV (Ultraviolet) gloss oil that energy consumption is little.
It is this paper printing environmental-friendly UV (Ultraviolet) gloss oil that the present invention solves the problems of the technologies described above the technical scheme that is adopted, and its raw material composition is:
Modified epoxy acrylic ester: 10-40 weight portion, activated monomer: 10-60 weight portion, macromolecular photoinitiator: 2-10 weight portion, aided initiating: 1-20 weight portion, defoamer: 0.1-1 weight portion, levelling agent: 0.1-1 weight portion.
As preferably, during forming, raw material of the present invention also has urethane acrylate, and the content of urethane acrylate is the 0-40 weight portion.
As preferably, during forming, raw material of the present invention also has functional aid, and functional aid is a fluorinated polyethylene wax, and the content of fluorinated polyethylene wax is the 0-5 weight portion.Play the smooth degree of increase, resist and after-tack, improve wear-resisting and anti-fog function.
As preferably, activated monomer of the present invention is one or more a mixture of hexanediyl ester, tri (propylene glycol) diacrylate, trimethylolpropane triacrylate, pentaerythrite six acrylate.Landing low viscosity and fast reaction speed participate in reaction.
As preferably; macromole evocating agent of the present invention is polyethylene glycol two (β-4-[is to (2-dimethyl amine-2-benzyl) bytyry phenyl] piperazine) propionic ester, polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) ester, ITX(isopropyl thioxanthone), 907(2-methyl isophthalic acid-(4-methyl mercapto phenyl)-2-morpholinyl-1-acetone), DETX (2, the 4-diethyl thioxanthone), a kind of or mixture.Main work to provide free radical and cause prepolymer and activated monomer reacts and reaches drying.
As preferably, aided initiating of the present invention is a P-115 tertiary amine acrylate.Cooperating initator to react, play increases the curing rate effect.
As preferably, defoamer of the present invention is the defoamer of not siliceous class material.
As preferably, levelling agent of the present invention is a polyether siloxane copolymer.
The present invention solves the problems of the technologies described above the preparation method that the technical scheme that is adopted still is a paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
A, the modified epoxy acrylic ester of preparing the 10-40 weight portion, 0-40 weight portion urethane acrylate, the activated monomer of 10-60 weight portion, the macromolecular photoinitiator of 2-10 weight portion, the aided initiating of 1-20 weight portion, the defoamer of 0.1-1 weight portion, the levelling agent of 0.1-1 weight portion, standby;
B, whole prepolymers, 70% activated monomer, initator, aided initiating are mixed, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature below 70 ℃ fully dissolving obtain transparency liquid fully to transparent;
C, in transparent liquid, add 30% remaining activated monomer, play the cooling effect, be cooled to below 50 ℃, add defoamer, levelling agent more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
As preferably, before the step c of the present invention, fluorinated polyethylene wax is pre-mixed into the slurry of 20-30% with activated monomer.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid; In step c, behind adding defoamer, the levelling agent, add the pulpous state functional aid again.
The present invention compares with existing technology, has the following advantages and characteristics: the present invention has thoroughly solved the pollution problem of organic solvent, realizes nontoxic completely.The utilization of the macromolecular photoinitiator (not containing benzene ring structure) that this patent adopts and processing are the innovative points of research and development UV environmental protection gloss oil.Use the macromolecular photoinitiator development of new environmental-friendly UV (Ultraviolet) gloss oil do not contain benzene ring structure, the ratio of reasonably combined various materials makes this gloss oil that the conventional advantage of common UV curing varnish, the residual newest standards requirement that can satisfy tobacco business of VOC simultaneously not only be arranged.Organic volatile when printing and drying is also considerably less, and this has just significantly reduced operating personnel's harm and environmental pollution.According to the difference of equipment and mode of printing, we are applicable to serial environmental-friendly UV (Ultraviolet) gloss oils such as offset printing, gravure, silk-screen, flexo at exploitation.Rate of drying is fast, the production efficiency height.The fastest print speed printing speed that can reach 200m/min.The energy consumption of production technology is low, low-carbon (LC).The properties of product brilliance, glossiness height, wear-resisting, scratch-resistant, hardness are good.The technology of the present invention had both been saved cost, and the environmental-protecting performance advanced person., application performance is good, and preparation technology is simple, has wide application prospect.Prescription of the present invention is more reasonable, and component cooperates advanced more, and properties of product are better, stable.Process is more advanced, and operability is stronger.
The specific embodiment
The present invention is described in further detail below in conjunction with embodiment, and following examples are explanation of the invention and the present invention is not limited to following examples.
Embodiment 1:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first; 20 kilograms modified epoxy acrylic esters, 15 kilograms urethane acrylate, 7 kilograms hexanediyl ester, 7 kilograms of tri (propylene glycol) diacrylates, 4 kilograms polyethylene glycol two (β-4-[is to (2-dimethyl amine-2-benzyl) bytyry phenyl] piperazine) propionic ester, 7 kilograms P-115 tertiary amine acrylate are mixed; high-speed stirred; mixing speed is 800-1500 rev/mins; the control temperature is below 70 ℃; fully dissolving to transparent, obtains transparency liquid fully.
Then, 1,5 kilogram fluorinated polyethylene wax is pre-mixed the pulp thing with 6 kilograms pentaerythrite six acrylate.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid.
At last, transparent liquid is cooled to below 50 ℃, adds the defoamer of 0.4 kilogram not siliceous class material, 0.7 kilogram polyether siloxane copolymer, pulpous state functional aid more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 2:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, with 18 kilograms modified epoxy acrylic esters, 7.5 kilograms pentaerythrite six acrylate, 10 kilograms of trimethylolpropane triacrylates, 1 kilogram ITX(isopropyl thioxanthone), 1 kilogram of polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) ester, 9 kilograms P-115 tertiary amine acrylate mix, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, the hexanediyl ester that in transparent liquid, adds 7.5 kilograms, be cooled to below 50 ℃, add the defoamer of 0.6 kilogram not siliceous class material, 0.8 kilogram polyether siloxane copolymer more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 3:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first; 12 kilograms modified epoxy acrylic esters, 19 kilograms urethane acrylate, 7 kilograms trimethylolpropane triacrylate, 7 kilograms polyethylene glycol two (β-4-[is to (2-dimethyl amine-2-benzyl) bytyry phenyl] piperazine) propionic ester, 20 kilograms P-115 tertiary amine acrylate are mixed; high-speed stirred; mixing speed is 800-1500 rev/mins; the control temperature is below 70 ℃; fully dissolving to transparent, obtains transparency liquid fully.
Then, 0,5 kilogram fluorinated polyethylene wax is pre-mixed the pulp thing with 3 kilograms pentaerythrite six acrylate.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid.
At last, transparent liquid is cooled to below 50 ℃, adds the defoamer of 1 kilogram not siliceous class material, 0.4 kilogram polyether siloxane copolymer, pulpous state functional aid more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 4:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, with 36 kilograms modified epoxy acrylic esters, 7 kilograms urethane acrylate, 7.5 kilograms pentaerythrite six acrylate, 3 kilograms of trimethylolpropane triacrylates, 5 kilograms ITX(isopropyl thioxanthone), 4 kilograms of polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) esters, 18 kilograms P-115 tertiary amine acrylate mix, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, the hexanediyl ester that in transparent liquid, adds 4.5 kilograms, be cooled to below 50 ℃, add the defoamer of 0.8 kilogram not siliceous class material, 1 kilogram polyether siloxane copolymer more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 5:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, 40 kilograms modified epoxy acrylic esters, 20 kilograms hexanediyl ester, 15 kilograms of tri (propylene glycol) diacrylates, 4 kilograms DETX, 4 kilograms 907,12 kilograms P-115 tertiary amine acrylate are mixed, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, 5 kilograms fluorinated polyethylene wax is pre-mixed the pulp thing with 15 kilograms pentaerythrite six acrylate.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid.
At last, transparent liquid is cooled to below 50 ℃, adds the defoamer of 0.7 kilogram not siliceous class material, 0.2 kilogram polyether siloxane copolymer, pulpous state functional aid more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 6:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, with 10 kilograms modified epoxy acrylic esters, 2 kilograms urethane acrylate, 7.5 kilograms pentaerythrite six acrylate, 24 kilograms of trimethylolpropane triacrylates, 5 kilograms ITX(isopropyl thioxanthone), 5 kilograms of polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) esters, 3 kilograms P-115 tertiary amine acrylate mix, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, the hexanediyl ester that in transparent liquid, adds 13.5 kilograms, be cooled to below 50 ℃, add the defoamer of 0.1 kilogram not siliceous class material, 0.6 kilogram polyether siloxane copolymer more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 7:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, 25 kilograms modified epoxy acrylic esters, 36 kilograms urethane acrylate, 15 kilograms hexanediyl ester, 6 kilograms of tri (propylene glycol) diacrylates, 6 kilograms DETX, 1 kilogram P-115 tertiary amine acrylate are mixed, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, 2 kilograms fluorinated polyethylene wax is pre-mixed the pulp thing with 9 kilograms pentaerythrite six acrylate.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid.
At last, transparent liquid is cooled to below 50 ℃, adds the defoamer of 0.3 kilogram not siliceous class material, 0.1 kilogram polyether siloxane copolymer, pulpous state functional aid more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 8:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, with 30 kilograms modified epoxy acrylic esters, 40 kilograms urethane acrylate, 30 kilograms pentaerythrite six acrylate, 12 kilograms of trimethylolpropane triacrylates, 2 kilograms ITX(isopropyl thioxanthone), 3 kilograms of polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) esters, 9 kilograms P-115 tertiary amine acrylate mix, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, the hexanediyl ester that in transparent liquid, adds 18 kilograms, be cooled to below 50 ℃, add the defoamer of 0.5 kilogram not siliceous class material, 0.5 kilogram polyether siloxane copolymer more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 9:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first; 22 kilograms modified epoxy acrylic esters, 29 kilograms urethane acrylate, 10 kilograms hexanediyl ester, 18 kilograms of tri (propylene glycol) diacrylates, 3 kilograms polyethylene glycol two (β-4-[is to (2-dimethyl amine-2-benzyl) bytyry phenyl] piperazine) propionic ester, 11 kilograms P-115 tertiary amine acrylate are mixed; high-speed stirred; mixing speed is 800-1500 rev/mins; the control temperature is below 70 ℃; fully dissolving to transparent, obtains transparency liquid fully.
Then, 3 kilograms fluorinated polyethylene wax is pre-mixed the pulp thing with 12 kilograms pentaerythrite six acrylate.High speed dispersion stirs 0.5h, and mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid.
At last, transparent liquid is cooled to below 50 ℃, adds the defoamer of 0.9 kilogram not siliceous class material, 0.3 kilogram polyether siloxane copolymer, pulpous state functional aid more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
Embodiment 10:
Present embodiment has been described a kind of preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil, and temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
At first, 15 kilograms modified epoxy acrylic esters, 23 kilograms urethane acrylate, 10.5 kilograms pentaerythrite six acrylate, 14 kilograms of trimethylolpropane triacrylates, 6 kilograms 907,2 kilograms P-115 tertiary amine acrylate are mixed, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature is below 70 ℃, fully dissolving to transparent, obtains transparency liquid fully.
Then, the hexanediyl ester that in transparent liquid, adds 10.5 kilograms, be cooled to below 50 ℃, add the defoamer of 0.2 kilogram not siliceous class material, 0.9 kilogram polyether siloxane copolymer more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
In addition, need to prove, the specific embodiment described in this specification, its prescription, title that technology is named etc. can be different.Allly conceive equivalence or the simple change that described structure, feature and principle are done, be included in the protection domain of patent of the present invention according to patent of the present invention.The technical staff of the technical field of the invention can make various modifications or replenishes or adopt similar mode to substitute described specific embodiment; only otherwise depart from structure of the present invention or surmount the defined scope of these claims, all should belong to protection scope of the present invention.
Though the present invention with embodiment openly as above; but it is not in order to limit protection scope of the present invention; any technical staff who is familiar with this technology, change and the retouching done in not breaking away from design of the present invention and scope all should belong to protection scope of the present invention.
Claims (10)
1. this paper printing environmental-friendly UV (Ultraviolet) gloss oil, its raw material are formed:
Modified epoxy acrylic ester: 10-40 weight portion, activated monomer: 10-60 weight portion, macromolecular photoinitiator: 2-10 weight portion, aided initiating: 1-20 weight portion, defoamer: 0.1-1 weight portion, levelling agent: 0.1-1 weight portion.
2. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: also have urethane acrylate during described raw material is formed, the content of urethane acrylate is the 0-40 weight portion.
3. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: also have functional aid during described raw material is formed, functional aid is a fluorinated polyethylene wax, and the content of fluorinated polyethylene wax is the 0-5 weight portion.
4. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: described activated monomer is one or more a mixture of hexanediyl ester, tri (propylene glycol) diacrylate, trimethylolpropane triacrylate, pentaerythrite six acrylate.
5. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: described macromole evocating agent is polyethylene glycol two (β-4-[is to (2-dimethyl amine-2-benzyl) bytyry phenyl] piperazine) propionic ester, polytetramethylene glycol 250 2-(2-carboxymethoxyl thioxanthones) ester, ITX(isopropyl thioxanthone), 907, one or more the mixture of DETX.
6. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: described aided initiating is a P-115 tertiary amine acrylate.
7. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: described defoamer is the defoamer of not siliceous class material.
8. paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1 is characterized in that: described levelling agent is a polyether siloxane copolymer.
9. the preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1, temperature is controlled at below 70 ℃ in the whole technical process, and its processing step is followed successively by:
A, the modified epoxy acrylic ester of preparing the 10-40 weight portion, 0-40 weight portion urethane acrylate, the activated monomer of 10-60 weight portion, the macromolecular photoinitiator of 2-10 weight portion, the aided initiating of 1-20 weight portion, the defoamer of 0.1-1 weight portion, the levelling agent of 0.1-1 weight portion, standby;
B, whole prepolymers, 70% activated monomer, initator, aided initiating are mixed, high-speed stirred, mixing speed is 800-1500 rev/mins, the control temperature below 70 ℃ fully dissolving obtain transparency liquid fully to transparent;
C, in transparent liquid, add 30% remaining activated monomer, be cooled to below 50 ℃, add defoamer, levelling agent more successively, dispersed with stirring 10 minutes, mixing speed is 800 rev/mins, obtains paper printing environmental-friendly UV (Ultraviolet) gloss oil.
10. the preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil according to claim 1, it is characterized in that: before the described step c, fluorinated polyethylene wax is pre-mixed into the slurry of 20-30% with activated monomer, high speed dispersion, stir 0.5h, mixing speed is that 1200-2000 rev/mins of backs that stir are standby, and the control temperature is no more than 50 ℃, obtains the pulpous state functional aid; In step c, behind adding defoamer, the levelling agent, add the pulpous state functional aid again.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102968061A CN101922129B (en) | 2010-09-29 | 2010-09-29 | Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102968061A CN101922129B (en) | 2010-09-29 | 2010-09-29 | Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101922129A true CN101922129A (en) | 2010-12-22 |
| CN101922129B CN101922129B (en) | 2012-01-04 |
Family
ID=43337320
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102968061A Expired - Fee Related CN101922129B (en) | 2010-09-29 | 2010-09-29 | Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101922129B (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120905A (en) * | 2011-01-06 | 2011-07-13 | 西安理工大学 | Offset printing direct injection platemaking water-based ultraviolet (UV) photosensitive glue and preparation method thereof |
| CN102176107A (en) * | 2011-01-06 | 2011-09-07 | 西安理工大学 | Offset print water-borne UV (ultraviolet) photo-sensitive resist jetting plate-making method |
| CN102251434A (en) * | 2011-06-10 | 2011-11-23 | 珠海市乐通化工股份有限公司 | Priming-free UV (ultraviolet) varnish for paper |
| CN102719159A (en) * | 2012-07-18 | 2012-10-10 | 常州华狮化工有限公司 | Preparation method of energy-saving environment-friendly low-temperature high light-retaining oil |
| CN102746721A (en) * | 2012-07-17 | 2012-10-24 | 深圳扬丰印刷有限公司 | Anti-tarnishing UV varnish and preparation method thereof |
| CN103525259A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV curing attachment printing coating and preparation method thereof |
| CN103525263A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Gildable gravure line ultraviolet (UV) gloss oil and preparation method thereof |
| CN104693995A (en) * | 2015-03-30 | 2015-06-10 | 海丰赛文（天津）包装材料有限公司 | UV metal printing gloss oil and preparation method thereof |
| CN105368271A (en) * | 2015-11-17 | 2016-03-02 | 青岛莱伊迪光电科技有限公司 | UV gloss oil for LED curing illuminator |
| CN106047137A (en) * | 2016-05-31 | 2016-10-26 | 山东力美喷墨科技有限公司 | Anti-sticking UV gloss oil and preparation method thereof |
| CN108192416A (en) * | 2018-03-13 | 2018-06-22 | 浙江美浓材料科技有限公司 | A kind of silk-screen fission ink and preparation method thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
| CN110511665A (en) * | 2019-09-27 | 2019-11-29 | 广东希贵光固化材料有限公司 | A kind of gloss oil can be used for UV printing |
| CN110949028A (en) * | 2019-11-18 | 2020-04-03 | 东莞市信彩包装有限公司 | Printing method for strengthening sprayed code adhesive force on gloss oil surface |
| CN111534224A (en) * | 2020-05-25 | 2020-08-14 | 天守(福建)超纤科技股份有限公司 | Preparation process of solvent-free leather high-brightness UV gloss oil |
| CN112920690A (en) * | 2021-03-16 | 2021-06-08 | 四川富彩科技有限公司 | UV gloss oil and preparation method and application thereof |
| CN116004043A (en) * | 2022-12-28 | 2023-04-25 | 浙江美浓材料科技有限公司 | Pure transparent high-smoothness UV offset-printing hot-stamping gloss oil and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125756A (en) * | 1994-12-26 | 1996-07-03 | 山东省费县化工总厂 | Preparation method of multi-purpose ultraviolet-solidification polish oil |
| CN1557882A (en) * | 2004-01-14 | 2004-12-29 | 惠州市华阳化工有限公司 | Ultraviolet cured paint |
| CN1580149A (en) * | 2004-05-17 | 2005-02-16 | 深圳市立美特环保油墨有限公司 | Ultraviolet light curable ink |
| CN1844229A (en) * | 2006-05-16 | 2006-10-11 | 广东工业大学 | UV curable aqueous resin composition |
| CN101348621A (en) * | 2008-09-04 | 2009-01-21 | 浙江美浓涂料有限公司 | Aqueous ultraviolet cure offset printing gloss oil |
-
2010
- 2010-09-29 CN CN2010102968061A patent/CN101922129B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125756A (en) * | 1994-12-26 | 1996-07-03 | 山东省费县化工总厂 | Preparation method of multi-purpose ultraviolet-solidification polish oil |
| CN1557882A (en) * | 2004-01-14 | 2004-12-29 | 惠州市华阳化工有限公司 | Ultraviolet cured paint |
| CN1580149A (en) * | 2004-05-17 | 2005-02-16 | 深圳市立美特环保油墨有限公司 | Ultraviolet light curable ink |
| CN1844229A (en) * | 2006-05-16 | 2006-10-11 | 广东工业大学 | UV curable aqueous resin composition |
| CN101348621A (en) * | 2008-09-04 | 2009-01-21 | 浙江美浓涂料有限公司 | Aqueous ultraviolet cure offset printing gloss oil |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120905A (en) * | 2011-01-06 | 2011-07-13 | 西安理工大学 | Offset printing direct injection platemaking water-based ultraviolet (UV) photosensitive glue and preparation method thereof |
| CN102176107A (en) * | 2011-01-06 | 2011-09-07 | 西安理工大学 | Offset print water-borne UV (ultraviolet) photo-sensitive resist jetting plate-making method |
| CN102120905B (en) * | 2011-01-06 | 2012-07-18 | 西安理工大学 | Offset printing direct injection platemaking water-based ultraviolet (UV) photosensitive glue and preparation method thereof |
| CN102176107B (en) * | 2011-01-06 | 2012-08-29 | 西安理工大学 | Offset print water-borne UV (ultraviolet) photo-sensitive resist jetting plate-making method |
| CN102251434A (en) * | 2011-06-10 | 2011-11-23 | 珠海市乐通化工股份有限公司 | Priming-free UV (ultraviolet) varnish for paper |
| CN102746721A (en) * | 2012-07-17 | 2012-10-24 | 深圳扬丰印刷有限公司 | Anti-tarnishing UV varnish and preparation method thereof |
| CN102719159A (en) * | 2012-07-18 | 2012-10-10 | 常州华狮化工有限公司 | Preparation method of energy-saving environment-friendly low-temperature high light-retaining oil |
| CN102719159B (en) * | 2012-07-18 | 2014-11-12 | 常州华狮化工有限公司 | Preparation method of energy-saving environment-friendly low-temperature high light-retaining oil |
| CN103525259A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | UV curing attachment printing coating and preparation method thereof |
| CN103525263A (en) * | 2013-09-30 | 2014-01-22 | 安徽蓝柯复合材料有限公司 | Gildable gravure line ultraviolet (UV) gloss oil and preparation method thereof |
| CN104693995A (en) * | 2015-03-30 | 2015-06-10 | 海丰赛文（天津）包装材料有限公司 | UV metal printing gloss oil and preparation method thereof |
| CN105368271A (en) * | 2015-11-17 | 2016-03-02 | 青岛莱伊迪光电科技有限公司 | UV gloss oil for LED curing illuminator |
| CN106047137A (en) * | 2016-05-31 | 2016-10-26 | 山东力美喷墨科技有限公司 | Anti-sticking UV gloss oil and preparation method thereof |
| CN108192416A (en) * | 2018-03-13 | 2018-06-22 | 浙江美浓材料科技有限公司 | A kind of silk-screen fission ink and preparation method thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
| CN110511665A (en) * | 2019-09-27 | 2019-11-29 | 广东希贵光固化材料有限公司 | A kind of gloss oil can be used for UV printing |
| CN110511665B (en) * | 2019-09-27 | 2021-08-17 | 广东希贵光固化材料有限公司 | Gloss oil for UV printing |
| CN110949028A (en) * | 2019-11-18 | 2020-04-03 | 东莞市信彩包装有限公司 | Printing method for strengthening sprayed code adhesive force on gloss oil surface |
| CN111534224A (en) * | 2020-05-25 | 2020-08-14 | 天守(福建)超纤科技股份有限公司 | Preparation process of solvent-free leather high-brightness UV gloss oil |
| CN112920690A (en) * | 2021-03-16 | 2021-06-08 | 四川富彩科技有限公司 | UV gloss oil and preparation method and application thereof |
| CN116004043A (en) * | 2022-12-28 | 2023-04-25 | 浙江美浓材料科技有限公司 | Pure transparent high-smoothness UV offset-printing hot-stamping gloss oil and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101922129B (en) | 2012-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101922129B (en) | Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil | |
| CN108059878B (en) | Curable composition, curable ink, cured product, and curable compound | |
| CN102604479B (en) | Ultraviolet radiation curing gravure freezing-point ink and preparation method thereof | |
| CN109504164A (en) | A kind of LED light curing metal decorating ink and preparation method thereof | |
| CN101348621B (en) | Aqueous ultraviolet cure offset printing gloss oil | |
| CN101671504A (en) | Soybean oil type offset printing color ink | |
| CN102925027A (en) | UV (ultraviolet) duct gloss oil | |
| CN103254757A (en) | Ultraviolet (UV) gloss oil and preparation method and application thereof | |
| CN104087063A (en) | UV (ultraviolet) photo-curable dip-coating and coloring printing ink and preparation method thereof | |
| CN103436092A (en) | Water-based UV (Ultraviolet) curing printing ink and preparation method thereof | |
| CN101397424A (en) | Ink composition | |
| CN102352173A (en) | Odorless ultraviolet-curing wood lacquer and preparation method thereof | |
| CN101864210A (en) | Alcohol-soluble printing ink and preparation method thereof | |
| TW299288B (en) | ||
| CN108410256A (en) | A kind of environment-friendly type UV cured printing inks | |
| CN103525186A (en) | UV (Ultraviolet) offset halogen-free printing ink and preparation method thereof | |
| CN109880434A (en) | A kind of curable compositions and application thereof | |
| CN108913012A (en) | Ultraviolet light solidifies high resistant matt floor paint and preparation method thereof | |
| CN105030567B (en) | Environment-friendly type UV nail polish coating compositions and preparation method thereof | |
| CN104861769B (en) | Environment-friendly type UV light-curable inks and preparation method thereof | |
| CN103821028B (en) | High-performance water-based UV cured gloss oil for paper and preparation method thereof | |
| CN107778982A (en) | A kind of Packaging Box special environment protection printing-ink and preparation method thereof | |
| CN105315782A (en) | Water-based paint gloss oil | |
| CN111218155A (en) | Antibacterial UV (ultraviolet) ink and preparation method and application thereof | |
| CN111635667A (en) | UV gravure white ink for food packaging BOPP film and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of paper printing environmental-friendly UV (Ultraviolet) gloss oil Effective date of registration: 20170728 Granted publication date: 20120104 Pledgee: Bank of Beijing, Limited by Share Ltd, Hangzhou branch Pledgor: Hangzhou ZFC New Materials Technology Co., Ltd. Registration number: 2017330000075 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20180926 Granted publication date: 20120104 Pledgee: Bank of Beijing, Limited by Share Ltd, Hangzhou branch Pledgor: Hangzhou ZFC New Materials Technology Co., Ltd. Registration number: 2017330000075 |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191113 Address after: No.30, Ninghong Road, Tianning Town, Jiashan County, Jiaxing City, Zhejiang Province Patentee after: Jiaxing Bohao Home Textile Co., Ltd Address before: Hangzhou City, Zhejiang Province, Gongshu District Cambridge 310000 Zhenkang No. 22 Zheng Lu Patentee before: Hangzhou ZFC New Materials Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120104 Termination date: 20200929 |