CN106047137A - Anti-sticking UV gloss oil and preparation method thereof - Google Patents
Anti-sticking UV gloss oil and preparation method thereof Download PDFInfo
- Publication number
- CN106047137A CN106047137A CN201610379454.3A CN201610379454A CN106047137A CN 106047137 A CN106047137 A CN 106047137A CN 201610379454 A CN201610379454 A CN 201610379454A CN 106047137 A CN106047137 A CN 106047137A
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- Prior art keywords
- gloss oil
- stick
- byk
- double
- oligomer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of chemical coatings, in particular to anti-sticking UV gloss oil and a preparation method thereof. The anti-sticking UV gloss oil is prepared from, by weight, polyurethane acrylate 5.0%-20%, an epoxy acrylate oligomer 5.0%-20.0%, a reactive diluent 45.0%-60.0%, an adhesion promoter 0%-2.0%, a light initiator 2.0%-10.0%, a crosslinking polyether modified siloxane 1.0%-10.0% and an additive 1.0%-5.0%. The surface tension of cured gloss oil can be reduced, the power releasing adhesive of the gloss oil is decreased, the effect same as the effect of a coated silicone oil is achieved, and finally the market requirement for multi-layer logistic labels can be met.
Description
Technical field
The present invention relates to technical field of chemical paint, particularly relate to a kind of anti-stick UV gloss oil and preparation method thereof.
Background technology
Ultraviolet light (UV) solidification is the advanced technology that a kind of material surface occurred the sixties in 20th century processes, and it is to utilize
Ultraviolet light initiation has the crosslinking of chemically active liquid material rapid polymerization, and instantaneous solidification becomes solid-state material, is a kind of efficient, ring
Guarantor, energy-conservation, the surface treatment technology of material of high-quality.UV gloss oil therein is because being environment-friendly type gloss oil, without volatile organic
(VOC free s), environmental pollution is little, and curing rate is fast, saves the energy, the leaflet wearability made and good weatherability, suitable for compound
Together in high-speed automated production, it is widely used.But the application technology of ultraviolet light polymerization still needs to further expand and perfect, especially
Being in currently a popular multilayers stream label print field, common UV gloss oil solidification rear surface tension force is higher, there is printing
Higher with the off-type force of adhesive afterwards, upper label tear-off difficulty problem, if but use coating silicone oil mode, deposit
In the higher problem not environmentally of VOC emission.
Summary of the invention
The technical problem to be solved is: the deficiency existed for prior art, it is provided that a kind of anti-stick UV gloss oil,
Higher to solve UV gloss oil solidification rear surface tension force, after printing, the off-type force with adhesive is higher, upper label tear-off difficulty
Technical problem.
For solving above-mentioned technical problem, the technical scheme is that
A kind of anti-stick UV gloss oil, includes following component according to percentage by weight:
As the preferred technical scheme of one, include following component according to percentage by weight:
As the preferred technical scheme of one, described crosslinkable polyether modified siloxane selected from BYK BYK373,
BYK371, BYK UV3530, EFKA Efka3883 and Di Gao RAD2100 at least one.
As the preferred technical scheme of one, described urethane acrylate is degree of functionality polyurethane third between 2 and 6
Olefin(e) acid fat, described urethane acrylate is selected from cyanogen special EB245, EB264, EB4858, EB270, EB5129, Sartomer
CN965, CN968, CN981, CN929, Changxing chemistry 615-100,6145-100 and 6130B-80 at least one.
As the preferred technical scheme of one, described epoxy acrylate oligomer is degree of functionality epoxy between 2 and 6
Acrylic resin oligomer, described epoxy acrylic resin oligomer selected from the special EB605 of cyanogen, EB3701, EB2958,
EB3700, Sartomer CN111 and CN118 at least one.
As the preferred technical scheme of one, described reactive diluent selected from 2-phenoxyethyl acrylate, 1,6-oneself
Diol acrylate, two contracting propylene glycol double methacrylates, tripropylene glycol double methacrylate, pentaerythritol triacrylate and
At least one in double pentaerythritol C5 methacrylate.
As the preferred technical scheme of one, described adhesion promoter refers to the acrylated oligomer of phosphoric acid modification, institute
State at least one that adhesion promoter is selected from SR9008 and SR9009 of the special EB170 of cyanogen, EB168, Sartomer.
As the preferred technical scheme of one, described light trigger is selected from 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-
In hydroxy-cyciohexyl benzophenone, double benzoylphenyl phosphorous oxide, isopropyl thioxanthone and benzophenone at least 2 kinds.
As the preferred technical scheme of one, described auxiliary agent includes levelling agent, anti-wear agent and defoamer；Wherein said levelling
Agent is selected from BYK 333 or BYK 345；Described anti-wear agent selected from enlightening high 270,2100,2500, the 991 of BYK, the 675 of SANYE,
731 or the 3620 of Clariant；Described defoamer is selected from 900,3062 or the 080 of BYK that enlightening is high.
To be solved by this invention another technical problem is that: provides the preparation method of a kind of anti-stick UV gloss oil, this legal system
Standby UV gloss oil makes the gloss oil surface tension after solidification extremely low, less with the off-type force of adhesive, reaches same with silicon-coating oil phase
Effect, be fully able to the requirement meeting market for multilayers stream label.
For solving above-mentioned technical problem, the technical scheme is that
The preparation method of a kind of anti-stick UV gloss oil, weighs urethane acrylate, epoxy third successively according to percentage by weight
Olefin(e) acid ester oligomer, reactive diluent, adhesion promoter, light trigger, crosslinkable polyether modified siloxane, auxiliary agent, mixing
After, stir 30 minutes under conditions of 1000 turns/min with dispersion machine and make it all dissolve, after then taking 120 mesh gauzes to filter both
Obtain anti-stick UV gloss oil.
After have employed technique scheme, the invention has the beneficial effects as follows:
The anti-stick gloss oil of UV prepared through the present invention mainly has the advantage that compared with commercially available mill run
1, after solidification, there is extremely low surface tension, low with the off-type force of adhesive, easily take off and tear；
2, good adhesive force, scratch-resistant, endurance is strong；
3, glossiness is high, non yellowing；
4, gloss oil does not hinder version, easy cleaning；
5, Diamond Search, low abnormal smells from the patient, more environmentally friendly.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to
Limit the present invention.
Embodiment 1
A kind of anti-stick UV gloss oil, includes following component according to percentage by weight:
Embodiment 2
A kind of anti-stick UV gloss oil, includes following components by weight percentage:
Embodiment 3
A kind of anti-stick UV gloss oil, includes following components by weight percentage:
Embodiment 4
A kind of anti-stick UV gloss oil, includes following components by weight percentage:
Embodiment 5
A kind of anti-stick UV gloss oil, includes following components by weight percentage:
Embodiment 6
A kind of anti-stick UV gloss oil, includes following components by weight percentage:
Embodiment 7
Its preparation method, weighs said components successively according to percentage by weight, after mixing, with dispersion machine at 1000 turns/min
Under conditions of stirring within 30 minutes, make it all dissolve, then take 120 mesh gauzes filter after both anti-stick UV gloss oil.
Every test rating of the anti-stick UV gloss oil obtained by above-described embodiment 1-7 is measured, wherein measures gloss
The KGZ-60 type vancometer that instrument is Tianjin Yong Lida of degree；Measure viscosity instrument and fly (BROOKFIELD) public affairs for rich Le
The LVDV-I I rotating cylinder viscometer of department；Measure the RY-320 flexographic printing that instrument is Zhejiang crane Xiang printing machinery of curing rate
Machine；Measuring the BLD-200N electron detachment force tester that peeling force instrument is Jinan blue streak, measurement result see table.
The indices recorded by upper table draws, the anti-stick UV gloss oil of the present invention is by adding the cross-linking of cross-linkable solidifying
Polyether modified siloxane and resin, can make the gloss oil surface tension after solidification reduce, and then reduces with the off-type force of adhesive, with
Reach the effect same with silicon-coating oil phase, finally can meet the market requirement for multilayers stream label.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (10)
1. an anti-stick UV gloss oil, it is characterised in that: include following component according to percentage by weight:
One the most according to claim 1 anti-stick UV gloss oil, it is characterised in that: include following group according to percentage by weight
Point:
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described crosslinkable polyether modification silica
In the RAD2100 of Efka3883 and Di Gao that alkane is selected from BYK373, BYK371, BYK UV3530 of BYK, EFKA at least 1
Kind.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described urethane acrylate is official
Energy degree polyurethane acrylic resin between 2 and 6, described urethane acrylate selected from the special EB245 of cyanogen, EB264,
EB4858, EB270, EB5129, the CN965 of Sartomer, CN968, CN981, CN929,615-100,6145-of Changxing chemistry
At least one in 100 and 6130B-80.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described epoxy acrylate oligomer
For degree of functionality epoxy acrylic resin oligomer between 2 and 6, described epoxy acrylic resin oligomer is selected from cyanogen spy's
EB605, EB3701, EB2958, EB3700, Sartomer CN111 and CN118 at least one.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described reactive diluent is selected from 2-benzene
The double acrylic acid of epoxide ethyl propylene acid esters, 1,6-HD double methacrylate, two contracting propylene glycol double methacrylates, tripropylene glycol
At least one in ester, pentaerythritol triacrylate and double pentaerythritol C5 methacrylate.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described adhesion promoter refers to phosphorus
The acrylated oligomer that acid is modified, described adhesion promoter selected from the special EB170 of cyanogen, EB168, the SR9008 of Sartomer and
At least one in SR9009.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described light trigger selected from 2-hydroxyl-
2-methyl isophthalic acid-phenyl-1-acetone, 1-hydroxy-cyciohexyl benzophenone, double benzoylphenyl phosphorous oxide, isopropyl thioxanthone and
In benzophenone at least 2 kinds.
One the most according to claim 1 and 2 anti-stick UV gloss oil, it is characterised in that: described auxiliary agent includes levelling agent, wear-resisting
Agent and defoamer；Wherein said levelling agent is selected from BYK 333 or BYK 345；Described anti-wear agent selected from enlightening high 270,2100,
2500, the 991 of BYK, the 675 of SANYE, 731 or the 3620 of Clariant；Described defoamer selected from enlightening high 900,3062 or BYK
080。
10. the preparation method of an anti-stick UV gloss oil, it is characterised in that weigh polyurethane acroleic acid according to percentage by weight successively
Ester, epoxy acrylate oligomer, reactive diluent, adhesion promoter, light trigger, polyether modified siloxane, auxiliary agent, mixed
After conjunction, stir 30 minutes under conditions of 1000 turns/min with dispersion machine and make it all dissolve, after then taking 120 mesh gauzes to filter
Both anti-stick UV gloss oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610379454.3A CN106047137A (en) | 2016-05-31 | 2016-05-31 | Anti-sticking UV gloss oil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610379454.3A CN106047137A (en) | 2016-05-31 | 2016-05-31 | Anti-sticking UV gloss oil and preparation method thereof |
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| CN106047137A true CN106047137A (en) | 2016-10-26 |
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| CN201610379454.3A Pending CN106047137A (en) | 2016-05-31 | 2016-05-31 | Anti-sticking UV gloss oil and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867292A (en) * | 2017-01-23 | 2017-06-20 | 中卫市创科知识产权投资有限公司 | A kind of production technologies of UV 202 |
| CN107652873A (en) * | 2017-10-19 | 2018-02-02 | 东莞职业技术学院 | Packaging for foodstuff printing environmental-friendly UV (Ultraviolet) gloss oil |
| CN107652874A (en) * | 2017-10-19 | 2018-02-02 | 东莞职业技术学院 | The preparation method of packaging for foodstuff printing environmental-friendly UV (Ultraviolet) gloss oil |
| CN108148493A (en) * | 2017-12-19 | 2018-06-12 | 东莞市优科印刷材料有限公司 | The tasteless ultraviolet curing coating composition directly applied |
| CN108330731A (en) * | 2018-02-05 | 2018-07-27 | 深圳市力嘉创意文化产业发展有限公司 | Uv gloss oil and its preparation method and application |
| CN109734827A (en) * | 2019-01-02 | 2019-05-10 | 华南理工大学 | For derivative photoinitiator of the cured thioxanthone of UV-LED and the preparation method and application thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106867292A (en) * | 2017-01-23 | 2017-06-20 | 中卫市创科知识产权投资有限公司 | A kind of production technologies of UV 202 |
| CN107652873A (en) * | 2017-10-19 | 2018-02-02 | 东莞职业技术学院 | Packaging for foodstuff printing environmental-friendly UV (Ultraviolet) gloss oil |
| CN107652874A (en) * | 2017-10-19 | 2018-02-02 | 东莞职业技术学院 | The preparation method of packaging for foodstuff printing environmental-friendly UV (Ultraviolet) gloss oil |
| CN108148493A (en) * | 2017-12-19 | 2018-06-12 | 东莞市优科印刷材料有限公司 | The tasteless ultraviolet curing coating composition directly applied |
| CN108330731A (en) * | 2018-02-05 | 2018-07-27 | 深圳市力嘉创意文化产业发展有限公司 | Uv gloss oil and its preparation method and application |
| CN109734827A (en) * | 2019-01-02 | 2019-05-10 | 华南理工大学 | For derivative photoinitiator of the cured thioxanthone of UV-LED and the preparation method and application thereof |
| CN109734827B (en) * | 2019-01-02 | 2020-08-18 | 华南理工大学 | Thioxanthone derivative photoinitiator for UV-LED curing, and preparation method and application thereof |
| CN110305510A (en) * | 2019-06-13 | 2019-10-08 | 广州骏捷环保科技有限公司 | A kind of method for stamping of UV gloss oil and its 3D imprinting apparatus |
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Application publication date: 20161026 |