CN101880354B - 高分子乳液聚合物及其制备方法 - Google Patents
高分子乳液聚合物及其制备方法 Download PDFInfo
- Publication number
- CN101880354B CN101880354B CN2010102116697A CN201010211669A CN101880354B CN 101880354 B CN101880354 B CN 101880354B CN 2010102116697 A CN2010102116697 A CN 2010102116697A CN 201010211669 A CN201010211669 A CN 201010211669A CN 101880354 B CN101880354 B CN 101880354B
- Authority
- CN
- China
- Prior art keywords
- high molecular
- parts
- emulsion polymer
- preparation
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004908 Emulsion polymer Substances 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims abstract description 19
- 239000003999 initiator Substances 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000004945 emulsification Methods 0.000 claims description 12
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 10
- 230000002829 reductive effect Effects 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 9
- 230000002452 interceptive effect Effects 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 235000010265 sodium sulphite Nutrition 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid group Chemical group S(O)(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 5
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- 238000004821 distillation Methods 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 claims description 4
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 claims description 4
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009775 high-speed stirring Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 3
- FGRJGEWVJCCOJJ-UHFFFAOYSA-N 2,2-dimethylaziridine Chemical compound CC1(C)CN1 FGRJGEWVJCCOJJ-UHFFFAOYSA-N 0.000 claims description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- GZVUWANWWQXKQR-UHFFFAOYSA-N 2-methylpropanamide;hydrochloride Chemical class Cl.CC(C)C(N)=O GZVUWANWWQXKQR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 claims description 2
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 claims description 2
- 235000010263 potassium metabisulphite Nutrition 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 claims description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- 239000007790 solid phase Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 8
- 238000005553 drilling Methods 0.000 abstract description 7
- 239000012530 fluid Substances 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 abstract 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000003002 pH adjusting agent Substances 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 239000002512 suppressor factor Substances 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 238000007348 radical reaction Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000012688 inverse emulsion polymerization Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 239000012966 redox initiator Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010102116697A CN101880354B (zh) | 2010-06-29 | 2010-06-29 | 高分子乳液聚合物及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010102116697A CN101880354B (zh) | 2010-06-29 | 2010-06-29 | 高分子乳液聚合物及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101880354A CN101880354A (zh) | 2010-11-10 |
CN101880354B true CN101880354B (zh) | 2012-05-30 |
Family
ID=43052514
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2010102116697A Expired - Fee Related CN101880354B (zh) | 2010-06-29 | 2010-06-29 | 高分子乳液聚合物及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101880354B (zh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102432734A (zh) * | 2011-08-24 | 2012-05-02 | 辉县市航天化工一厂 | 钻井液用聚合物的生产方法 |
CN104250344B (zh) * | 2013-06-28 | 2016-09-21 | 中国石油化工股份有限公司 | 一种聚丙烯酰胺乳液的制备方法 |
CN104418975B (zh) * | 2013-09-11 | 2016-09-21 | 中国石油化工股份有限公司 | 一种聚丙烯酰胺乳液的制备方法 |
CN104418974B (zh) * | 2013-09-11 | 2016-08-17 | 中国石油化工股份有限公司 | 一种聚丙烯酰胺乳液的制备方法 |
CN104418973B (zh) * | 2013-09-11 | 2017-03-29 | 中国石油化工股份有限公司 | 一种聚丙烯酰胺乳液的制备方法 |
CN104559962A (zh) * | 2013-12-06 | 2015-04-29 | 崇礼县石油科技有限公司 | 一种钻井液用多元包被抑制剂及其制备方法 |
CN103755869B (zh) * | 2014-01-03 | 2016-04-06 | 克拉玛依市金鑫科技有限公司 | Am/aak/amps三元共聚物和聚合物乳液强包被剂及其制备方法 |
CN104710969B (zh) * | 2015-04-03 | 2016-04-20 | 中国石油大学(北京) | 一种油基钻井液增粘剂及其制备方法 |
US10501625B2 (en) * | 2015-06-29 | 2019-12-10 | Ecolab Usa Inc. | Methods of making acrylamide-acrylic acid copolymers |
CN105238383A (zh) * | 2015-10-21 | 2016-01-13 | 西安长庆化工集团有限公司 | 一种油井压裂用的降阻剂及其制备方法 |
CN105254822B (zh) * | 2015-11-20 | 2018-05-08 | 科之杰新材料集团有限公司 | 一种聚羧酸减水剂的制备方法 |
CN113388377B (zh) * | 2020-03-11 | 2022-09-13 | 中石化石油工程技术服务有限公司 | 一种降滤失剂及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6465587B1 (en) * | 2000-12-08 | 2002-10-15 | Hercules Incorporated | Polymeric fluid loss additives and method of use thereof |
CN100360635C (zh) * | 2006-05-23 | 2008-01-09 | 濮阳市诚信钻采助剂有限公司 | 钻井液用乳液聚合物 |
-
2010
- 2010-06-29 CN CN2010102116697A patent/CN101880354B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN101880354A (zh) | 2010-11-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101880354B (zh) | 高分子乳液聚合物及其制备方法 | |
CN104788345A (zh) | 一种高纯度盐酸二甲双胍的生产方法 | |
US10385147B2 (en) | Method for producing polyvinylamine crosslinked polymer particles | |
WO2016106964A1 (zh) | 一种聚氯乙烯的悬浮聚合制备方法及加料装置 | |
CN102633943A (zh) | 一种淀粉高吸水树脂的制备方法 | |
CN103483499A (zh) | 一种工业及医疗检查手套浸渍用羧基丁腈胶乳的制备方法 | |
CN103012630A (zh) | 用磺酰氯作氯磺化剂制备氯磺化聚乙烯的方法 | |
CN105566189B (zh) | 一种低杂质固体福美钠生产工艺 | |
CN104513174A (zh) | 一种球痢灵生产过程中的废酸的循环利用工艺及装置 | |
CN102675509B (zh) | 一种非离子聚丙烯酰胺的制备方法 | |
CN113083253A (zh) | 一种提取维生素b12用弱酸阳树脂及其合成方法 | |
CN107474171B (zh) | 高粘度阳离子聚电解质干粉及其制备方法 | |
CN107011539A (zh) | 一种四元共聚物表面改性纳米碳酸钙的方法 | |
CN105017452A (zh) | 高相对分子质量pdmc的制备方法 | |
CN110804018A (zh) | 一种己内酰胺的精制方法及精制系统 | |
CN205838897U (zh) | 一种聚丙烯酸钠的制备装置 | |
CN106883331A (zh) | 一种微悬浮法制备聚氯乙烯糊树脂的方法 | |
CN103601842A (zh) | 聚丙烯酸类大粒径珠状吸水树脂的制备方法 | |
CN101475665A (zh) | 一种高性能碳纤维用聚丙烯腈的制备方法 | |
CN102219879A (zh) | 一种聚丙烯酰胺乳液的生产方法 | |
Liying et al. | Dissolution of fir powder and its graft copolymer in ionic liquid | |
CN105111342A (zh) | 一种高浓度丙烯酰胺水溶液聚合方法 | |
CN104944737A (zh) | 污泥脱水剂及其脱水方法 | |
JP2019143158A (ja) | 粉末状n−ビニルカルボン酸アミド重合体組成物及びポリビニルアミン水溶液の製造方法 | |
CN103554375A (zh) | 聚丙烯酸盐型高吸水树脂的制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High molecular emulsion polymer and preparation method thereof Effective date of registration: 20160518 Granted publication date: 20120530 Pledgee: Bank of China Limited by Share Ltd. Zhongyuan Oilfield Branch of Puyang Pledgor: Puyang Chengxin Drilling & Production Agents Co.,Ltd. Registration number: 2016990000404 |
|
PLDC | Enforcement, change and cancellation of contracts on pledge of patent right or utility model | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20170919 Granted publication date: 20120530 Pledgee: Bank of China Limited by Share Ltd. Zhongyuan Oilfield Branch of Puyang Pledgor: Puyang Chengxin Drilling & Production Agents Co.,Ltd. Registration number: 2016990000404 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High molecular emulsion polymer and preparation method thereof Effective date of registration: 20170922 Granted publication date: 20120530 Pledgee: Bank of China Limited by Share Ltd. Zhongyuan Oilfield Branch of Puyang Pledgor: Puyang Chengxin Drilling & Production Agents Co.,Ltd. Registration number: 2017990000896 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20181029 Granted publication date: 20120530 Pledgee: Bank of China Limited by Share Ltd. Zhongyuan Oilfield Branch of Puyang Pledgor: Puyang Chengxin Drilling & Production Agents Co.,Ltd. Registration number: 2017990000896 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High molecular emulsion polymer and preparation method thereof Effective date of registration: 20190121 Granted publication date: 20120530 Pledgee: Guangfa Bank Co.,Ltd. Beijing Branch Pledgor: Puyang Chengxin Drilling & Production Agents Co.,Ltd. Registration number: 2019990000068 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20201223 Granted publication date: 20120530 Pledgee: Guangfa Bank Co.,Ltd. Beijing Branch Pledgor: PUYANG CHENGXIN DRILLING & PRODUCTION AGENTS Co.,Ltd. Registration number: 2019990000068 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120530 |
|
CF01 | Termination of patent right due to non-payment of annual fee |