CN101851453A - Heat reflection-emission lamina simulated-brick thermal insulation coating and preparation method thereof - Google Patents
Heat reflection-emission lamina simulated-brick thermal insulation coating and preparation method thereof Download PDFInfo
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- 239000011248 coating agent Substances 0.000 title claims abstract description 44
- 238000000576 coating method Methods 0.000 title claims abstract description 44
- 239000011449 brick Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims description 7
- 238000009413 insulation Methods 0.000 title abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000000919 ceramic Substances 0.000 claims abstract description 30
- 239000002131 composite material Substances 0.000 claims abstract description 30
- 239000000945 filler Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000002086 nanomaterial Substances 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 23
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 18
- 239000011737 fluorine Substances 0.000 claims description 18
- 229920000126 latex Polymers 0.000 claims description 18
- 230000004048 modification Effects 0.000 claims description 18
- 238000012986 modification Methods 0.000 claims description 18
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- 239000004065 semiconductor Substances 0.000 claims description 16
- 239000004816 latex Substances 0.000 claims description 15
- 229910000859 α-Fe Inorganic materials 0.000 claims description 15
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000013078 crystal Substances 0.000 claims description 14
- 229910052596 spinel Inorganic materials 0.000 claims description 14
- 239000011029 spinel Substances 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- 238000004581 coalescence Methods 0.000 claims description 13
- 239000013530 defoamer Substances 0.000 claims description 13
- 230000008719 thickening Effects 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 11
- 235000012239 silicon dioxide Nutrition 0.000 claims description 11
- 229960001866 silicon dioxide Drugs 0.000 claims description 11
- 239000000080 wetting agent Substances 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- 239000005995 Aluminium silicate Substances 0.000 claims description 8
- 241000276489 Merlangius merlangus Species 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 238000009775 high-speed stirring Methods 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 6
- LVHCMNFBKQKHIH-UHFFFAOYSA-N [Mg].[Ca].[B] Chemical compound [Mg].[Ca].[B] LVHCMNFBKQKHIH-UHFFFAOYSA-N 0.000 claims description 5
- 229920000555 poly(dimethylsilanediyl) polymer Polymers 0.000 claims description 5
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- GDYIECFAOXKNRJ-UHFFFAOYSA-N [B].[Ca].[Li].[Mg] Chemical compound [B].[Ca].[Li].[Mg] GDYIECFAOXKNRJ-UHFFFAOYSA-N 0.000 claims description 4
- IPTCVCQWAVMWBX-UHFFFAOYSA-N [B].[Ca].[Ti].[Mg] Chemical compound [B].[Ca].[Ti].[Mg] IPTCVCQWAVMWBX-UHFFFAOYSA-N 0.000 claims description 4
- UYWXKHRLBUGUDQ-UHFFFAOYSA-N [Mg].[Ca].[Na].[B] Chemical compound [Mg].[Ca].[Na].[B] UYWXKHRLBUGUDQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- -1 pH stablizer Substances 0.000 claims description 4
- 229920000570 polyether Polymers 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- GTUNMKRGRHOANR-UHFFFAOYSA-N [B].[Ca] Chemical compound [B].[Ca] GTUNMKRGRHOANR-UHFFFAOYSA-N 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229920003086 cellulose ether Polymers 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000004005 microsphere Substances 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000003112 inhibitor Substances 0.000 description 5
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 4
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UIUXUFNYAYAMOE-UHFFFAOYSA-N methylsilane Chemical compound [SiH3]C UIUXUFNYAYAMOE-UHFFFAOYSA-N 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008451 emotion Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- KCWYOFZQRFCIIE-UHFFFAOYSA-N ethylsilane Chemical compound CC[SiH3] KCWYOFZQRFCIIE-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Abstract
The invention discloses a heat-reflecting-emission lamina simulated-brick thermal insulation coating, which consists of the following raw materials in percentage by weight: 10 to 20 percent of fluorine-modified silicon-acrylic emulsion, 10 to 15 percent of hollow composite ceramic microspheres, 10 to 15 percent of infrared emission pigment and filler, 5 to 10 percent of infrared reflection nanomaterial, 0.5 to 2 percent of molecular bridge modifying material, 20 to 30 percent of other filler, 4 to 6 percent of aid and the balance of water. The simulated-brick thermal insulation coating has the functions of improving thermal reflection of sunlight and converting phonon-photon energy, converts the thermal energy of the sunlight into infrared in an atmospheric window and emits the infrared into the air, and simultaneously can reduce the thermal conductivity of the coating; and the coating greatly reduces the sunlight energy absorption of walls and has the energy saving effect.
Description
Technical field
The present invention relates to a kind of thermal insulating coating, the imitative brick of particularly a kind of heat reflection-emission type thin layer is heat insulation and preparation method thereof.
Background technology
People are difficult to forget the emotion of that part to " Qin brick and Han tile " cultural tradition when replacing the wall brick external wall decorative material with coating; In order to satisfy people to decorating aesthstic requirement, so developed the texture lacquer of " sand wall paint " series; By construction technology it has been prepared the various patterns of " brick and tile and stone material ", this has also overcome the weight shortcoming of decorative wall brick and the potential safety hazard that comes off and cause simultaneously, but anti-the solarization with the trap heat transmission problem still is not resolved.Solar irradiation is mapped to body surface, produces to reflect, reflect, absorb and see through, if the solar heat ray is absorbed by object, then radiating capacity changes into heat energy, and the body surface temperature is raise; If can make a large amount of reflections of body surface and radiant heat ray, can stop hotly simultaneously to inner heat conduction, then can avoid or reduce the interior of articles temperature and raise because of the radiation of solar radiation or foreign radiation sources.Chinese patent CN101565581A discloses a kind of emission thermal insulating coating and preparation method thereof, and this coating focuses on the solar radiation invisible heat is reflected and intercepts to inner heat conduction, thereby the temperature that reduces object plays certain heat insulation effect; But its heat insulation effect is unsatisfactory, has limited applying of this coating to a certain extent.
Summary of the invention
The object of the present invention is to provide a kind of heat reflection-emission type thin layer to imitate the brick thermal insulating coating, this coating can increase the solar heat energy reflection, and the infrared rays that the solar heat energy that absorbs is converted into atmospheric window is transmitted in the air, the while can stop heat energy to interior of articles heat conduction.
Another object of the present invention is to provide the preparation method of the imitative brick thermal insulating coating of a kind of above-mentioned heat reflection-emission type thin layer.
The present invention seeks to realize like this:
A kind of heat reflection-emission type thin layer is imitated the brick thermal insulating coating, this thermal insulating coating is made by following raw materials by weight percent: 10～20% fluorine modification organosilicon crylic acid latexs, 10～15% hollow composite ceramics microballons, 10～15% infrared emission color stuffings, 5～10% infrared external reflection nano materials, 0.5 the bridge modified material of～2% molecule, 20～30% other fillers, 4～6% auxiliary agents and excess water.
Above-mentioned infrared external reflection nano material is preferably nanometer Sb doping SnO
2The semi-conductor powder is or/and nanometer In doping SnO
2Semi-conductor powder infra-red material.
The bridge modified material of above-mentioned molecule is preferably silicane molecule bridge, and more preferably first, second, third, fourth, octyl group silane molecule bridge are or/and polydimethyl silane molecule bridge etc.
Above-mentioned hollow composite ceramics microballon is preferably sial magnesium calcium boron hollow composite ceramics microballon, sial magnesium sodium calcium boron hollow composite ceramics microballon, sial magnesium, potassium and calcium boron hollow composite ceramics microballon, sial magnesium lithium calcium boron hollow composite ceramics microballon or/and sial magnesium titanium calcium boron hollow composite ceramics microballon.
Above-mentioned infrared emission color stuffing is preferably the Mn-Zn ferrite of Zn ferrite, spinel crystal structure of Mn ferrite, the spinel crystal structure of ferrite, the spinel crystal structure of spinel crystal structure or/and the γ ferric oxide.
Above-mentioned other fillers comprise silicon-dioxide; Described other fillers can also add kaolin or/and coarse whiting.
Above-mentioned auxiliary agent comprises film coalescence aid, thickening material, wetting agent, defoamer and the agent of pH value stabilization; Described film coalescence aid is lipidol-12 a class film coalescence aid, and defoamer is the silicone defoamer, and described thickening material is the cellulose ethers thickening material.
Above-mentioned auxiliary agent can also comprise polyacrylic ester amine salt class dispersion agent and organic silicon modified by polyether class flow agent.
Raw materials such as above-mentioned fluorine modification organosilicon crylic acid latex, infrared external reflection nano material, hollow composite ceramics microballon, infrared emission color stuffing, the bridge modified material of molecule, auxiliary agent and other fillers are commercially available.
In order further to increase coating to sun reflection of light with to the conversion of solar heat energy, each raw material of above-mentioned coating is preferably: 15% fluorine modification organosilicon crylic acid latex, 13% hollow composite ceramics microballon, 13% infrared emission color stuffing, 8% infrared external reflection nano material, the bridge modified material of 1.5% molecule, 25% other fillers, 5% auxiliary agent and surplus deionized water, by weight percentage.
A kind of method for preparing above-mentioned coating, its raw material is 10～20% fluorine modification organosilicon crylic acid latexs, 10～15% above-mentioned hollow composite ceramics microballons, 10～15% above-mentioned infrared emission color stuffings, 5～10% above-mentioned infrared external reflection nano materials, 0.5 the bridge modified material of～2% above-mentioned molecule, 20～30% above-mentioned other fillers, 4～6% above-mentioned auxiliary agents and surplus deionized water; Make by following step:
(1). above-mentioned infrared external reflection nano material, infrared emission color stuffing, fluorine modification organosilicon crylic acid latex, hollow composite ceramics microballon are carried out coupling, mix with the molecule bridge, add above-mentioned other fillers, auxiliary agent and surplus deionized water high-speed stirring again and mix;
(2). uniform each raw material of above-mentioned high-speed stirring is sheared decentralized system get.
Coating of the present invention can adopt spraying in use, brush, scrapes multiple coating modes such as figure or roller coating.
The present invention has following beneficial effect:
1, the imitative brick thermal insulating coating of the present invention not only has the solar heat energy of increasing reflection function, but also has phonon-photon energy transition function, and the infrared rays that solar heat energy is transformed into atmospheric window is transmitted in the air; Simultaneously, also can lower the coating thermal conductivity; Coating of the present invention greatly reduces the absorption of body of wall to solar energy, has possessed energy-conservation effect.
2, the nanometer Sb doping SnO in the thermal insulating coating component of the present invention
2Semi-conductor powder or nanometer In doping SnO
2Semi-conductor powder infra-red material major function is for increasing coating to the ultrared reflection of sunlight, and the infrared emission color stuffing also has both infrared conversion of solar heat energy and emission function except aesthstic color function.
3, the solar ray energy calorimetric of thermal insulating coating of the present invention emission is than 〉=0.83; Hemispherical emissivity 〉=0.91; The heat insulation temperature difference 〉=10 ℃.
4, coating of the present invention has alleviated the weight per unit area of heat preservation energy-saving system greatly, has effectively avoided because of the weight shortcoming of wall brick and the potential safety hazard that comes off and cause; The present invention simultaneously utilizes fluorine modification organosilicon crylic acid latex to be equipped with the bridge modified material of silicane molecule, has promoted the adherence of coating, acidproof, anti-sassafras, anti-soil and weathering resistance etc.Preparation method's flow process of the present invention is simple, be convenient to promote.
Embodiment
Embodiment 1
A kind of heat reflection-emission type thin layer is imitated the brick thermal insulating coating, by making: 15% fluorine modification organosilicon crylic acid latex SD-5681 by following raw materials by weight percent component, 13% sial magnesium calcium boron composite ceramics hollow beads, the ferric oxide of 13% spinel crystal structure, 8% nanometer Sb doping SnO
2Semi-conductor powder infra-red material, 1.5% methyl-monosilane molecule bridge, 25% silicon-dioxide, kaolin and coarse whiting, 5.0%Texanel film coalescence aid, silicone defoamer, pH stablizer DMAE, CP-117 thickening material, PE100 wetting agent and dispersion agent H30-A, surplus deionized water; Make by the following method:
1. incite somebody to action 8% nanometer Sb doping SnO by weight percentage
2The ferric oxide of semi-conductor powder infra-red material, 13% spinel crystal structure, 13% sial magnesium calcium boron composite ceramics hollow beads and 15% fluorine modification organosilicon crylic acid latex SD-5681 carry out coupling, mix with 1.5% methylsiloxane molecule bridge, add 25% silicon-dioxide, kaolin and coarse whiting again, 5.0%Texanel film coalescence aid, silicone defoamer, pH stablizer DMAE, CP-117 thickening material, PE100 wetting agent and dispersion agent H30-A, surplus deionized water high-speed stirring mixes;
2. uniform each raw material of above-mentioned high-speed stirring being sheared decentralized system gets.
The solar ray energy calorimetric of the above-mentioned imitative brick thermal insulating coating that makes emission is than being 0.95; Hemispherical emissivity is 0.92; The heat insulation temperature difference is 12.
Embodiment 2～8: undertaken by following raw material and proportion relation thereof, other is all identical with embodiment 1.The imitative brick thermal insulating coating solar ray energy calorimetric emission that makes is than 〉=0.83; Hemispherical emissivity 〉=0.91; The heat insulation temperature difference 〉=10 ℃, following material all by weight percentage.
| Embodiment | Fluorine modification organosilicon crylic acid latex | Hollow composite ceramics microballon | The infrared emission color stuffing | The infrared external reflection nano material | The bridge modified material of molecule | Other fillers | Auxiliary agent |
| ??2 | Fluorine modification organosilicon crylic acid latex SD-5681,10% | Sial magnesium calcium boron and sial magnesium sodium calcium boron hollow composite ceramics microballon 15% | The ferrite 10% of spinel crystal structure | Nanometer Sb doping SnO 2Semi-conductor powder 10% | Octyl group silane molecule bridge 1% | Kaolin and silicon-dioxide 20% | Film coalescence aid Texanel, pH stablizer Amp-95, silicone defoamer, thickening material CP-117, antifreezing agent 1.2 propylene glycol, flow agent organic silicon modified by polyether L436, mould inhibitor DF-19, wetting agent PE100 and dispersion agent H-30A 6% |
[0032]
| ??3 | Fluorine modification organosilicon crylic acid latex TRF-60,20% | Sial magnesium lithium calcium boron hollow composite ceramics microballon 10% | The Mn ferrite 15% of spinel crystal structure | Nanometer In doping SnO 2Semi-conductor powder 5% | Methyl-monosilane molecule bridge 2% | Kaolin, coarse whiting and silicon-dioxide 30% | Film coalescence aid Texanel, pH stablizer DMAE, silicone defoamer, wetting agent CF-10, thickening material CP-117 and mould inhibitor LXE 4% |
| ??4 | Fluorine modification organosilicon crylic acid latex JRJ-6028,12% | With sial magnesium titanium calcium boron hollow composite ceramics microballon 13.5% | The Zn ferrite 11.5% of spinel crystal structure | Nanometer In doping SnO 2Semi-conductor powder and nanometer Sb doping SnO 2Semi-conductor powder 7.5% | Ethylsilane molecule bridge 1.5% | Coarse whiting and silicon-dioxide 25% | Lipidol-12 film coalescence aid, pH stablizer Amp-95, silicone defoamer, wetting agent PE100, mould inhibitor DF-19 and thickening material CP-1175% |
| ??5 | Fluorine modification organosilicon crylic acid latex SD-5681,18% | Sial magnesium, potassium and calcium boron hollow composite ceramics microballon 12% | γ ferric oxide 12% | Nanometer In doping SnO 2Semi-conductor powder 6% | Polydimethyl silane molecule bridge 2% | Silicon-dioxide and kaolin 28% | Film coalescence aid Texanel, pH stablizer Amp-95, silicone defoamer, ether of cellulose thickening material, wetting agent CF-10, antifreezing agent 1.2 propylene glycol and dispersion agent H-30A 5.5% |
| ??6 | Fluorine modification organosilicon crylic acid latex JRJ-6028,16% | Sial magnesium sodium calcium boron hollow composite ceramics microballon 14% | The Mn ferrite of spinel crystal structure, Zn ferrite and γ ferric oxide 13% | Nano Sb doping SnO 2Semi-conductor powder and nanometer In doping SnO 2Semi-conductor powder 8% | Octyl group and polydimethyl silane molecule bridge 1.8% | Silicon-dioxide and coarse whiting 22% | Lipidol-12 film coalescence aid, pH stablizer DMAE, silicone defoamer, wetting agent PE100, thickening material CP-117 and mould inhibitor LXE 4.8% |
| ??7 | Fluorine modification organosilicon crylic acid latex TRF-60,17.5% | Sial magnesium lithium calcium boron and sial magnesium titanium calcium boron hollow composite ceramics microballon 11.5% | The ferrite of spinel crystal structure and Mn ferrite 14.5% | Nano Sb doping SnO 2Semi-conductor powder 9% | Propyl group and polydimethyl silane molecule bridge 0.5% | Kaolin, silicon-dioxide and coarse whiting 26% | Film coalescence aid Texanel, pH stablizer Amp-95, silicone defoamer, thickening material CP-117, flow agent organic silicon modified by polyether L436, mould inhibitor LXE, wetting agent CF-10 and dispersion agent H-30A 5.2% |
Claims (10)
1. heat reflection-emission type thin layer is imitated the brick thermal insulating coating, described coating is by making by following raw materials by weight percent component: 10～20% fluorine modification organosilicon crylic acid latexs, 10～15% hollow composite ceramics microballons, 10～15% infrared emission color stuffings, 5～10% infrared external reflection nano materials, 0.5 the bridge modified material of～2% molecule, 20～30% other fillers, 4～6% auxiliary agents and excess water.
2. coating as claimed in claim 1 is characterized in that: described infrared external reflection nano material is nanometer Sb doping SnO
2The semi-conductor powder is or/and nanometer In doping SnO
2Semi-conductor powder infra-red material.
3. coating as claimed in claim 1 or 2 is characterized in that: the bridge modified material of described molecule is a silicane molecule bridge.
4. coating as claimed in claim 3 is characterized in that: described silicane molecule bridge is that first, second, third, fourth, octyl group are or/and polydimethyl silane molecule bridge.
5. as claim 1,2 or 4 described coating, it is characterized in that: the Zn ferrite of the ferrite that described infrared emission color stuffing is the spar crystalline structure, the Mn ferrite of spinel crystal structure, spinel crystal structure, the Mn-Zn ferrite of spinel crystal structure are or/and the γ ferric oxide.
6. coating as claimed in claim 5 is characterized in that: described hollow composite ceramics microballon is that sial magnesium calcium boron hollow composite ceramics microballon, sial magnesium sodium calcium boron hollow composite ceramics microballon, sial magnesium, potassium and calcium boron hollow composite ceramics microballon, sial magnesium lithium calcium boron hollow composite ceramics microballon are or/and sial magnesium titanium calcium boron hollow composite ceramics microballon.
7. coating as claimed in claim 6 is characterized in that: described auxiliary agent comprises film coalescence aid, defoamer, thickening material, wetting agent and pH stablizer; Described other fillers comprise silicon-dioxide.
8. coating as claimed in claim 7 is characterized in that: described auxiliary agent is lipidol-12 class film coalescence aid, silicone defoamer, cellulose ethers thickening material, pH stablizer, wetting agent, polyacrylic ester amine salt class dispersion agent and organic silicon modified by polyether class flow agent; Described other fillers are silicon-dioxide, kaolin and coarse whiting.
9. as claim 5 or 8 described coating, it is characterized in that: each raw material of described coating is: 15% fluorine modification organosilicon crylic acid latex, 13% hollow composite ceramics microballon, 13% infrared emission color stuffing, 8% infrared external reflection nano material, the bridge modified material of 1.5% molecule, 25% other fillers, 5.0% auxiliary agent and surplus deionized water, by weight percentage.
10. as the preparation method of claim 1～9 coating as described in each, it is characterized in that:
Adopt described raw material to make by following step:
(1) described fluorine modification organosilicon crylic acid latex, infrared external reflection nano material, hollow composite ceramics microballon, infrared emission color stuffing are carried out coupling, mixes with molecule bridge raw material, add described other fillers again, described auxiliary agent and surplus deionized water high-speed stirring mix;
(2) uniform each raw material of described high-speed stirring being sheared decentralized system gets.
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| CN2010101996100A CN101851453B (en) | 2010-06-12 | 2010-06-12 | Heat reflection-emission lamina simulated-brick thermal insulation coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101996100A CN101851453B (en) | 2010-06-12 | 2010-06-12 | Heat reflection-emission lamina simulated-brick thermal insulation coating and preparation method thereof |
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| Publication Number | Publication Date |
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| CN101851453A true CN101851453A (en) | 2010-10-06 |
| CN101851453B CN101851453B (en) | 2011-12-28 |
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| CN102115620A (en) * | 2011-01-28 | 2011-07-06 | 上海安能捷节能技术有限公司 | Colored ternary thermal insulation paint |
| CN103896536A (en) * | 2012-12-25 | 2014-07-02 | 深圳市嘉达高科产业发展有限公司 | Building external wall thermal insulating powder coating, and preparation method thereof |
| CN104263172A (en) * | 2014-09-05 | 2015-01-07 | 安徽桑瑞斯环保新材料有限公司 | Energy-saving heat-insulating waterproof paint |
| CN105130353A (en) * | 2015-07-10 | 2015-12-09 | 贵州大学 | Infrared high-emissivity coating filling material and preparation method of same |
| CN106085093A (en) * | 2016-06-20 | 2016-11-09 | 武汉源脉科技股份有限公司 | High temperature high efficiency heat insulating coatings, its preparation method and high temperature high efficiency heat-insulating heat-preserving material |
| CN112126270A (en) * | 2020-09-27 | 2020-12-25 | 深圳市嘉达高科产业发展有限公司 | Road surface environment-friendly functional coating for reducing urban heat island effect and preparation method thereof |
| CN112341931A (en) * | 2020-10-16 | 2021-02-09 | 中国铁道科学研究院集团有限公司金属及化学研究所 | Water-based reflective heat-insulating coating and preparation method and application thereof |
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| CN102115620A (en) * | 2011-01-28 | 2011-07-06 | 上海安能捷节能技术有限公司 | Colored ternary thermal insulation paint |
| CN103896536A (en) * | 2012-12-25 | 2014-07-02 | 深圳市嘉达高科产业发展有限公司 | Building external wall thermal insulating powder coating, and preparation method thereof |
| CN104263172A (en) * | 2014-09-05 | 2015-01-07 | 安徽桑瑞斯环保新材料有限公司 | Energy-saving heat-insulating waterproof paint |
| CN105130353A (en) * | 2015-07-10 | 2015-12-09 | 贵州大学 | Infrared high-emissivity coating filling material and preparation method of same |
| CN106085093A (en) * | 2016-06-20 | 2016-11-09 | 武汉源脉科技股份有限公司 | High temperature high efficiency heat insulating coatings, its preparation method and high temperature high efficiency heat-insulating heat-preserving material |
| CN106085093B (en) * | 2016-06-20 | 2018-10-12 | 武汉源脉科技股份有限公司 | High temperature high efficiency heat insulating coatings, preparation method and high temperature high efficiency heat-insulating heat-preserving material |
| CN112126270A (en) * | 2020-09-27 | 2020-12-25 | 深圳市嘉达高科产业发展有限公司 | Road surface environment-friendly functional coating for reducing urban heat island effect and preparation method thereof |
| CN112341931A (en) * | 2020-10-16 | 2021-02-09 | 中国铁道科学研究院集团有限公司金属及化学研究所 | Water-based reflective heat-insulating coating and preparation method and application thereof |
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