CN101848877A - 玻璃片颜料和基材 - Google Patents
玻璃片颜料和基材 Download PDFInfo
- Publication number
- CN101848877A CN101848877A CN200880108146A CN200880108146A CN101848877A CN 101848877 A CN101848877 A CN 101848877A CN 200880108146 A CN200880108146 A CN 200880108146A CN 200880108146 A CN200880108146 A CN 200880108146A CN 101848877 A CN101848877 A CN 101848877A
- Authority
- CN
- China
- Prior art keywords
- sheet glass
- pigment
- particle size
- glass
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 27
- 239000011521 glass Substances 0.000 title abstract description 10
- 239000000758 substrate Substances 0.000 title abstract 2
- 239000005357 flat glass Substances 0.000 claims description 28
- 239000000463 material Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 8
- 239000004033 plastic Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 238000004043 dyeing Methods 0.000 abstract description 2
- 238000007639 printing Methods 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 239000000976 ink Substances 0.000 abstract 1
- 238000007641 inkjet printing Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C12/00—Powdered glass; Bead compositions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
- C03C17/23—Oxides
- C03C17/25—Oxides by deposition from the liquid phase
- C03C17/256—Coating containing TiO2
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/54—Particles characterised by their aspect ratio, i.e. the ratio of sizes in the longest to the shortest dimension
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/21—Oxides
- C03C2217/212—TiO2
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
- C09C2200/301—Thickness of the core
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Glass Compositions (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Cosmetics (AREA)
Abstract
由玻璃片形成的颜料，其在例如涂料、喷墨打印、织物染色、涂层、印刷油墨、塑料、化妆品、陶瓷和玻璃的釉中具有广泛应用。还提供了用于颜料的基材。
Description
发明领域
本发明涉及由玻璃片形成的颜料，所述颜料在例如涂料、喷墨打印、织物染色、涂层、印刷油墨、塑料、化妆品、陶瓷和玻璃的釉中具有的广泛应用。本发明还涉及这样的颜料的基材。
背景技术
就采用高折射率材料涂覆透明载体材料，如二氧化硅或玻璃以提供所谓的干涉或效果颜料而言，已经提出了各种建议。
涂层的组成，以及载体材料的性质、形状和尺寸对于成本效益和得到的颜料的效能是至关重要的。
发明内容
根据本发明，其中提供了一种包括至少部分涂覆高折射率材料的玻璃片的颜料，所述玻璃片包括以下组分：
二氧化硅-50至80；
氧化铝-1至20；
氧化钛-高达20。
优选的颜料包括那些具有玻璃片的，所述玻璃片包括以下组分：
二氧化硅-65至75；
氧化铝-2至5；
氧化钛-高达5；
上述量是基于玻璃片重量的，以重量％来表示。
优选地，所述玻璃片的厚度小于5μm，更优选为小于1μm，并且最优选为20至500nm。
优选地，所述涂层的折射率为至少1.5μm，更优选为至少1.6μm，并且最优选为至少1.8μm。
本发明的玻璃片可以具有包括相对高折射率层和相对低折射率层的涂层。相对低折射率的材料可以具有例如小于1.7的折射率。该层通常的折射率应该小于相对高折射率层的折射率。
可以被用于低折射率层的材料的例子为二氧化硅和氧化铝。
用于本发明的玻璃片的平均微粒尺寸优选为1至1000μm，更优选为高达500μm，最优选为高达200μm。
用于本发明的玻璃片的纵横比优选为至少20，或更优选为至少50。高折射率材料层的厚度为至少0.1nm，优选为至少5nm，并且更优选为10至200nm。
本发明的颜料可以被用于广泛的应用中，例如，印刷油墨、汽车涂层、化妆品配方以及塑料、玻璃、陶瓷产品和建筑用膜的着色。
各种方法可以用于玻璃片的涂覆以生产本发明的颜料。这些方法包括湿法化学涂覆、物理气相沉积、化学气相沉积和化学镀。
本发明还提供了用在本发明的颜料中的玻璃片的基材。
发明详述
根据本发明的颜料包括由Glassflake Ltd制造的LAG6玻璃片，所述玻璃片具有大约210nm的平均厚度和2.2m2/g的BET。这些玻璃片已经被研磨并过筛以获得尺寸为20至100微米的玻璃片。
LAG6玻璃的组成如下(基于玻璃片的重量，以重量％计)：-SiO2 69.30、TiO2 1.48、Al2O3 3.60、Fe2O3 0.15、CaO 2.10、MgO 1.22、K2O 2.00、Na2O9.44、ZrO2 0.24、B2O3 10.42、其它.05。存在的氧化铁和氧化锆是不可避免的污染物。“其它”为含量小于小数点后一位的污染元素。
采用由TiCl4溶液的沉积的氧化钛涂覆玻璃片以生产具有极佳颜色和光泽并且显示非常好的机械稳定性的平滑涂层。
Claims (12)
1.一种包括至少部分涂覆高折射率材料的玻璃片的颜料，所述玻璃片包括以下组分：
二氧化硅-50至80；
氧化铝-1至20；
氧化钛-高达20。
2.根据权利要求1所述的颜料，其中，所述玻璃片包括以下组分：
二氧化硅-65至75；
氧化铝-1至5；
氧化钛-高达5；
所述量是基于玻璃片重量的，以重量％来表示。
3.根据权利要求1或2所述的颜料，其中所述玻璃片具有以下近似组成：
SiO2 69；
TiO2 1.5；
Al2O3 3.5；
CaO 2.25；
MgO 1.25；
K2O 2；
Na2O 9.5；
B2O3 10.5；
其它 0.5；
所述量是基于玻璃片重量的，以重量来表示。
4.根据前述权利要求中任一项所述的颜料，其中所述玻璃片的厚度为至少5μm。
5.根据权利要求4所述的颜料，其中所述玻璃片的厚度为至少1μm。
6.根据权利要求4或5所述的颜料，其中所述玻璃片的厚度为20至500nm。
7.根据前述权利要求中任一项所述的颜料，其中所述玻璃片的平均颗粒尺寸为1至1000μm。
8.根据权利要求7所述的颜料，其中所述的平均颗粒尺寸为高达500μm。
9.根据权利要求7或8所述的颜料，其中所述的平均颗粒尺寸为高达200μm。
10.一种根据权利要求1以及基本如本发明所描述的颜料。
11.一种基本如本发明所示例的颜料。
12.一种包括前述权利要求中任一项所限定的玻璃片用于颜料的基材。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0718357.7A GB0718357D0 (en) | 2007-09-20 | 2007-09-20 | Glass flake pigments |
| GB0718357.7 | 2007-09-20 | ||
| PCT/GB2008/003163 WO2009037457A1 (en) | 2007-09-20 | 2008-09-22 | Glass flake pigments and substrates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101848877A true CN101848877A (zh) | 2010-09-29 |
| CN101848877B CN101848877B (zh) | 2012-11-14 |
Family
ID=38670227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008801081460A Expired - Fee Related CN101848877B (zh) | 2007-09-20 | 2008-09-22 | 玻璃片颜料和基材 |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US20100300328A1 (zh) |
| EP (1) | EP2205534A1 (zh) |
| JP (1) | JP2010540688A (zh) |
| KR (1) | KR20100071075A (zh) |
| CN (1) | CN101848877B (zh) |
| AU (1) | AU2008300416A1 (zh) |
| BR (1) | BRPI0816488A2 (zh) |
| CA (1) | CA2700076A1 (zh) |
| GB (2) | GB0718357D0 (zh) |
| RU (1) | RU2010115062A (zh) |
| WO (1) | WO2009037457A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110835481A (zh) * | 2019-11-25 | 2020-02-25 | 东来涂料技术（上海）股份有限公司 | 一种超闪烁玻璃片珠光涂料及其制备方法 |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013085049A1 (ja) | 2011-12-09 | 2013-06-13 | 日本板硝子株式会社 | 光輝性顔料と、それを含有する光輝性塗料組成物および自動車外板コート物 |
| KR101730761B1 (ko) * | 2016-02-23 | 2017-04-26 | 성애 주식회사 | 투톤 및 에칭조각효과를 갖는 연포장 인쇄물 및 그 인쇄 방법 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5753371A (en) * | 1996-06-03 | 1998-05-19 | The Mearl Corporation | Pearlescent glass pigment |
| US6045914A (en) * | 1996-06-03 | 2000-04-04 | Engelhard Corporation | Pearlescent glass pigment |
| DE19717231A1 (de) * | 1997-04-24 | 1998-10-29 | Bayer Ag | 3-Cyano-2,4,5-trifluor-benzoylfluorid |
| JP4393495B2 (ja) * | 1999-05-14 | 2010-01-06 | 日本板硝子株式会社 | ルチル型二酸化チタンが定着した基材 |
| JP4103293B2 (ja) * | 1999-05-14 | 2008-06-18 | 日本板硝子株式会社 | ルチル型二酸化チタンの製造方法 |
| US20090311209A1 (en) * | 2005-06-22 | 2009-12-17 | Patrice Bujard | Interference Pigments on the Basis of Glass Flakes |
| EP1865031B1 (en) * | 2006-06-09 | 2008-07-02 | Eckart GmbH | Effect pigments comprising glass flakes having a content of titanium oxide |
| ATE432964T1 (de) * | 2007-04-05 | 2009-06-15 | Eckart Gmbh | Effektpigmente mit einem substrat aus glasplättchen |
-
2007
- 2007-09-20 GB GBGB0718357.7A patent/GB0718357D0/en not_active Ceased
-
2008
- 2008-09-22 RU RU2010115062/03A patent/RU2010115062A/ru not_active Application Discontinuation
- 2008-09-22 CA CA2700076A patent/CA2700076A1/en not_active Abandoned
- 2008-09-22 BR BRPI0816488 patent/BRPI0816488A2/pt not_active IP Right Cessation
- 2008-09-22 JP JP2010525421A patent/JP2010540688A/ja active Pending
- 2008-09-22 CN CN2008801081460A patent/CN101848877B/zh not_active Expired - Fee Related
- 2008-09-22 EP EP08806318A patent/EP2205534A1/en not_active Withdrawn
- 2008-09-22 WO PCT/GB2008/003163 patent/WO2009037457A1/en active Application Filing
- 2008-09-22 US US12/679,256 patent/US20100300328A1/en not_active Abandoned
- 2008-09-22 GB GB0817290A patent/GB2453631A/en not_active Withdrawn
- 2008-09-22 AU AU2008300416A patent/AU2008300416A1/en not_active Abandoned
- 2008-09-22 KR KR1020107008439A patent/KR20100071075A/ko not_active Application Discontinuation
-
2012
- 2012-04-18 US US13/450,129 patent/US20120240823A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110835481A (zh) * | 2019-11-25 | 2020-02-25 | 东来涂料技术（上海）股份有限公司 | 一种超闪烁玻璃片珠光涂料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2008300416A1 (en) | 2009-03-26 |
| WO2009037457A1 (en) | 2009-03-26 |
| EP2205534A1 (en) | 2010-07-14 |
| CN101848877B (zh) | 2012-11-14 |
| CA2700076A1 (en) | 2009-03-26 |
| US20100300328A1 (en) | 2010-12-02 |
| GB0817290D0 (en) | 2008-10-29 |
| KR20100071075A (ko) | 2010-06-28 |
| BRPI0816488A2 (pt) | 2015-03-17 |
| JP2010540688A (ja) | 2010-12-24 |
| GB2453631A (en) | 2009-04-15 |
| RU2010115062A (ru) | 2011-10-27 |
| US20120240823A1 (en) | 2012-09-27 |
| GB0718357D0 (en) | 2007-10-31 |
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