CN101831219A - Heat insulation waterproof waterborne coating - Google Patents
Heat insulation waterproof waterborne coating Download PDFInfo
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- CN101831219A CN101831219A CN201010173637A CN201010173637A CN101831219A CN 101831219 A CN101831219 A CN 101831219A CN 201010173637 A CN201010173637 A CN 201010173637A CN 201010173637 A CN201010173637 A CN 201010173637A CN 101831219 A CN101831219 A CN 101831219A
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Abstract
The invention discloses a heat insulation waterproof waterborne coating which comprises the following compositions in percentage by weight: 40-48wt% of film forming emulsion, 41-54 wt% of pigment filler, 2.77-8 wt%of additive and the balance of clear water, wherein the film forming emulsion is ethylene-vinyl acetate copolymer EVA and acrylic copolymer emulsion, the pigment filler is one or multiple kinds of titanium dioxide, mica powder, heavy calcium powder, light calcium powder, talcum powder, kaolin, phosphatic powder and hollow tiny glass powder or all of the substances, and the additive is one or multiple kinds of dispersant, lubricant, flow agent, defoamer, plasticizer, antifreeze and preservative or all of the substances which are usually used by technicians of the field. The coating has the advantages of excellent heat insulation and waterproof performance, favorable environmental protection, difficult pulverization, fast drying and simple and convenient construction.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of insulating water-proofs such as various buildingss, wall, ground, light plate, big plate, batten, water-borne coatings of rust protection aspect of being applied to.
Background technology
Along with the raising of people's living standard, various buildingss also arise at the historic moment, and coating is widely used in the decorations such as the external and internal wall, bottom of the building aspect, pipeline of buildings, but the waterproof solar heat protection of a lot of coating is all unsatisfactory.Chinese patent CN1560142 discloses a kind of waterproof, heat insulation, anti-flaming dope, and it comprises auxiliary material, base-material, weight part is between each composition of described major ingredient: 5～16 parts of tetramethylolmethanes, 0.2～6 part of antimonous oxide, 0.2～6 part of clorafin, 2～20 parts on mica, 2～20 parts of sepiolites; Described major ingredient also has 1～11 part of trimeric cyanamide, 0.3～7 part of silica flour; Described major ingredient also has 1～18 part of phosphamide, 5～40 parts of perlites.It is widely used on body of wall, roofing, bottom of the building, vault, pipeline, plank, the metal.
Summary of the invention
It is good that the technical problem to be solved in the present invention provides a kind of insulating water-proof, the water-borne coatings of processing ease.
The technical problem to be solved in the present invention is achieved through the following technical solutions: a kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 40-48wt%, color stuffing 41～54wt%, additive 2.77～8wt%, surplus are clear water.
Further: in above-mentioned heat insulation waterproof waterborne coating, described filming emulsion is ethylene-vinyl acetate copolymer EVA and acrylic copolymer emulsion; Described color stuffing is one or more in titanium dioxide, mica powder, dicalcium powder, light calcium carbonate powder, talcum powder, kaolin, phosphorus matter powder, the hollow glass microbead powder, perhaps these total materials; Described additive is one or more in the dispersion agent used always of those skilled in the art, lubricant, flow agent, defoamer, softening agent, antifreezing agent, the sanitas, or these total materials all.In the present invention, filming emulsion makes buildings have certain color and luster, texture, plays beautifying constructure and avoids erosive effects such as atmosphere, moisture content, dust, optical radiation, microorganism.Color stuffing in aqueous architectural coating except coating is had certain opacifying power and the various color, also influential to weathering resistance, levelling property, anti-stream brush property, the hardness of coating and the texture of filming.
Further again: in above-mentioned heat insulation waterproof waterborne coating, the preferred weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.
When preparing above-mentioned heat insulation waterproof waterborne coating, earlier the dispersion agent for preparing is fully stirred in high speed dispersor, be dispersed into uniform white slurry, in ethylene-vinyl acetate copolymer EVA and acrylic copolymer emulsion, add defoamer and membrane-forming agent, and regulate pH value to slight alkalinity with aqua ammonia and become composite emulsion, again remaining color stuffing and water are added composite emulsion and stir into heat insulation waterproof waterborne coating.
Prior art is compared, and the filming emulsion 40-48wt% of above-mentioned heat insulation waterproof waterborne coating, color stuffing 41～54wt%, additive 2.77～8wt%, surplus are clear water.The appropriate proportioning of filming emulsion and color stuffing make this coating heat insulation, water resistance is very superior.Additive adds, and improves and improve the performance and the film quality of coating more.Add clear water and make coating be difficult for efflorescence, fast drying, construction simple and convenient, can on moist slightly basal plane, construct, i.e. processing ease.Coating with above-mentioned prescription gained carries out relevant test by inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint " with GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard.The cohesive strength 0.26MPa of coating, tensile strength 1.2MPa, watertightness 0.3MPa is alkaline-resisting water-fast, and heat-proof quality is for being heated 60 ℃ the time when the iron component surface, and the paint layer can reduce temperature more than 10 ℃.
Embodiment
Purport of the present invention is by the appropriate proportioning of regulation and control filming emulsion, color stuffing, additive, clear water, further selects suitable color stuffing, additive formula, make coating heat insulation, water resistance is very excellent, it is simple and easy to construct.Below in conjunction with embodiment content of the present invention is described in further detail, mentioned content is not a limitation of the invention among the embodiment, and Selection of technological conditions such as temperature, time can be suited measures to local conditions and the result be there is no substantial effect among the preparation method.
Embodiment 1
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 41wt%, color stuffing 53wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 2
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 42wt%, color stuffing 50wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 3
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 43wt%, color stuffing 44wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 4
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 44wt%, color stuffing 44wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 5
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 45wt%, color stuffing 48wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 6
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 46wt%, color stuffing 48wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 7
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 47wt%, color stuffing 44wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.With this proportioning make with coating by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Embodiment 8
A kind of heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 48wt%, color stuffing 44wt%, additive 2.77～8wt%, surplus are clear water.The weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.The weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.The coating that makes with this proportioning is by the every superior performance of inspecting standard Q/HZGC01-2006 " organic polymer waterproof paint ", and is as shown in table 1, the waterproof and heat-insulating superior performance of coating.According to GB/18582-2001 " limits of harmful substances in the indoor decorating material interior wall coating " standard carry out relevant test, this coating feature of environmental protection is good, as shown in table 2.
Table 1: the heat insulation test of coating water-proof (Q/HZGC01-2006)
Table 2: the feature of environmental protection of coating detects (GB/18582-2001)
Claims (4)
1. heat insulation waterproof waterborne coating, its weight percent consists of: filming emulsion 40-48wt%, color stuffing 41～54wt%, additive 2.77～8wt%, surplus are clear water.
2. heat insulation waterproof waterborne coating according to claim 1 is characterized in that:
Described filming emulsion is ethylene-vinyl acetate copolymer EVA and acrylic copolymer emulsion;
Described color stuffing is one or more in titanium dioxide, mica powder, dicalcium powder, light calcium carbonate powder, talcum powder, kaolin, phosphorus matter powder, the hollow glass microbead powder, perhaps these total materials;
Described additive is one or more in the dispersion agent used always of those skilled in the art, lubricant, flow agent, defoamer, softening agent, antifreezing agent, the sanitas, or these total materials all.
3. heat insulation waterproof waterborne coating according to claim 2 is characterized in that: the preferred weight percent of color stuffing in whole water-borne coatings consists of titanium dioxide 8～11wt%, mica powder 8.8～9wt%, dicalcium powder 3～4wt%, light calcium carbonate powder 7～8wt%, talcum powder 5～7wt%, kaolin 2.2～3wt%, phosphorus matter powder 2～4wt%, hollow glass microbead powder 5～8wt%.
4. heat insulation waterproof waterborne coating according to claim 3 is characterized in that: the weight percent of preferred additives in whole water-borne coatings consists of 0.1～0.2wt% dispersion agent, lubricant 0.08～0.1wt%, flow agent 0.1～1.2wt%, defoamer 0.7～1wt%, softening agent 1.0～3.2wt%, antifreezing agent 0.7～1.3wt%, sanitas 0.09～1.0wt%.
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| CN102337062A (en) * | 2011-06-03 | 2012-02-01 | 紫荆花制漆(汕头)有限公司 | Water-based thermal insulation coating and preparation method thereof |
| CN103265861A (en) * | 2013-05-31 | 2013-08-28 | 滁州市宏源喷涂有限公司 | Water-soluble low-bubble environment-friendly antiseptic coating and preparation method thereof |
| CN103555091A (en) * | 2013-10-12 | 2014-02-05 | 山西凌云聚氨酯有限公司 | Epoxy resin modified VAE composite waterproof material and preparation method thereof |
| CN103602178A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Improved difficult-flaking waterproof coating material |
| CN103740201A (en) * | 2013-12-24 | 2014-04-23 | 无锡凤凰画材有限公司 | Universal smooth clay drawing board |
| CN104109440A (en) * | 2014-07-01 | 2014-10-22 | 芜湖县双宝建材有限公司 | Waterproof weather-resistant acrylate exterior wall coating |
| CN104130646A (en) * | 2014-08-06 | 2014-11-05 | 武汉理工大学 | Infrared reflection thermal insulation coating and preparation method thereof |
| CN104151945A (en) * | 2014-08-14 | 2014-11-19 | 深圳市宜丽家生态建材有限公司 | Reversible thermochromatic aqueous interior wall coating |
| CN105038422A (en) * | 2015-07-14 | 2015-11-11 | 上海森瀚新型材料科技有限公司 | Composite functional type heat insulating coating for building wall |
| CN105255288A (en) * | 2015-11-20 | 2016-01-20 | 广东梅雁吉祥实业投资股份有限公司 | Metal product antirust coating material |
| CN106046989A (en) * | 2016-07-27 | 2016-10-26 | 张子青 | Exterior wall antifouling latex paint formula |
| CN106280778A (en) * | 2016-08-30 | 2017-01-04 | 广东东方雨虹防水工程有限公司 | A kind of aqueous sound insulation sound-absorbing, waterproof integrated coating and preparation method thereof |
| CN108017966A (en) * | 2017-12-19 | 2018-05-11 | 中山市雅乐思商住电器有限公司 | A kind of insulating water-proof environmental protection coating material paint |
| CN110157262A (en) * | 2018-04-13 | 2019-08-23 | 广东粤固建材科技有限公司 | A kind of water-proof heat-insulating paint |
| CN114133775A (en) * | 2021-12-15 | 2022-03-04 | 三间房新材料科技发展(苏州)有限公司 | Waterproof and heat-insulating building material for external wall and preparation method thereof |
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| CN1706899A (en) * | 2004-09-01 | 2005-12-14 | 孙成勋 | Multifunctional energy-saving coating for building |
| CN101153176A (en) * | 2006-09-25 | 2008-04-02 | 中宏（天津）实业有限公司 | Technique of producing one-component waterproof coating material with polymer copolymerization emulsions as base material |
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| CN102337062A (en) * | 2011-06-03 | 2012-02-01 | 紫荆花制漆(汕头)有限公司 | Water-based thermal insulation coating and preparation method thereof |
| CN103265861A (en) * | 2013-05-31 | 2013-08-28 | 滁州市宏源喷涂有限公司 | Water-soluble low-bubble environment-friendly antiseptic coating and preparation method thereof |
| CN103265861B (en) * | 2013-05-31 | 2015-12-02 | 滁州市宏源喷涂有限公司 | A kind of Water-soluble low-bubble environment-friendlyantiseptic antiseptic coating and preparation method thereof |
| CN103555091B (en) * | 2013-10-12 | 2015-07-08 | 山西凌云聚氨酯有限公司 | Epoxy resin modified VAE composite waterproof material and preparation method thereof |
| CN103555091A (en) * | 2013-10-12 | 2014-02-05 | 山西凌云聚氨酯有限公司 | Epoxy resin modified VAE composite waterproof material and preparation method thereof |
| CN103602178A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Improved difficult-flaking waterproof coating material |
| CN103602178B (en) * | 2013-11-19 | 2016-09-14 | 青岛祥嘉知识产权服务有限公司 | A kind of water-repellent paint of the difficult drop-off of improvement |
| CN103740201B (en) * | 2013-12-24 | 2015-11-11 | 无锡凤凰画材有限公司 | Smooth clay drawing board |
| CN103740201A (en) * | 2013-12-24 | 2014-04-23 | 无锡凤凰画材有限公司 | Universal smooth clay drawing board |
| CN104109440A (en) * | 2014-07-01 | 2014-10-22 | 芜湖县双宝建材有限公司 | Waterproof weather-resistant acrylate exterior wall coating |
| CN104109440B (en) * | 2014-07-01 | 2017-01-18 | 芜湖县双宝建材有限公司 | Waterproof weather-resistant acrylate exterior wall coating |
| CN104130646B (en) * | 2014-08-06 | 2017-01-11 | 武汉理工大学 | Infrared reflection thermal insulation coating and preparation method thereof |
| CN104130646A (en) * | 2014-08-06 | 2014-11-05 | 武汉理工大学 | Infrared reflection thermal insulation coating and preparation method thereof |
| CN104151945A (en) * | 2014-08-14 | 2014-11-19 | 深圳市宜丽家生态建材有限公司 | Reversible thermochromatic aqueous interior wall coating |
| CN104151945B (en) * | 2014-08-14 | 2016-09-14 | 深圳市宜丽家生态建材有限公司 | A kind of aqueous inner wall paint with reversibility temperature induced color changing |
| CN105038422A (en) * | 2015-07-14 | 2015-11-11 | 上海森瀚新型材料科技有限公司 | Composite functional type heat insulating coating for building wall |
| CN105038422B (en) * | 2015-07-14 | 2017-07-25 | 上海森瀚新型材料科技有限公司 | Complex function type construction wall heat insulation thermal insulation coatings |
| CN105255288A (en) * | 2015-11-20 | 2016-01-20 | 广东梅雁吉祥实业投资股份有限公司 | Metal product antirust coating material |
| CN106046989A (en) * | 2016-07-27 | 2016-10-26 | 张子青 | Exterior wall antifouling latex paint formula |
| CN106280778A (en) * | 2016-08-30 | 2017-01-04 | 广东东方雨虹防水工程有限公司 | A kind of aqueous sound insulation sound-absorbing, waterproof integrated coating and preparation method thereof |
| CN108017966A (en) * | 2017-12-19 | 2018-05-11 | 中山市雅乐思商住电器有限公司 | A kind of insulating water-proof environmental protection coating material paint |
| CN110157262A (en) * | 2018-04-13 | 2019-08-23 | 广东粤固建材科技有限公司 | A kind of water-proof heat-insulating paint |
| CN114133775A (en) * | 2021-12-15 | 2022-03-04 | 三间房新材料科技发展(苏州)有限公司 | Waterproof and heat-insulating building material for external wall and preparation method thereof |
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Application publication date: 20100915 |