CN108285714A - A kind of exterior wall water-proof heat-insulating paint and preparation method thereof - Google Patents

A kind of exterior wall water-proof heat-insulating paint and preparation method thereof Download PDF

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Publication number
CN108285714A
CN108285714A CN201810205581.0A CN201810205581A CN108285714A CN 108285714 A CN108285714 A CN 108285714A CN 201810205581 A CN201810205581 A CN 201810205581A CN 108285714 A CN108285714 A CN 108285714A
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CN
China
Prior art keywords
exterior wall
water
proof heat
insulating paint
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810205581.0A
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Chinese (zh)
Inventor
汪金云
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Zhuochuang New Materials Co Ltd
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Hefei Zhuochuang New Materials Co Ltd
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Publication date
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Priority to CN201810205581.0A priority Critical patent/CN108285714A/en
Publication of CN108285714A publication Critical patent/CN108285714A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of exterior wall water-proof heat-insulating paints and preparation method thereof, and the coating is made of the raw material of following mass percentage:Water polyacrylic acid lotion 35 60%, Nano filling 10 30%, silicone acrylic emulsion 2 5%, function additive 1.4 5.0%, waterproofing agent 4 6%, coalescents 0.2 0.5%, surplus is deionized water.The present invention is using water polyacrylic acid lotion as base-material, and silicone acrylic emulsion and Nano filling are equipped with as filler, painting layer gap, enhancing coating tensile strength, hardness can be filled well by adding Nano filling, and impart coating heat preservation and insulation and excellent water resistance.

Description

A kind of exterior wall water-proof heat-insulating paint and preparation method thereof
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of exterior wall water-proof heat-insulating paint and preparation method thereof.
Background technology
Coating is to be coated in the body surface protected or decorated, and can form the continuous thin of firm attachment with coated article Film adds or does not add pigment, filler typically based on resin or oil or lotion, adds corresponding additive, uses organic solvent Or the thick liquid that water is formulated.One coating of film is generally required outside wall, is played a certain protective role, exterior wall is to applying There is material very high requirement, existing coating often there is the defects of waterproof and dampproof poor performance, poor flame retardant properties.
For the powder of lacquer putty for use on that preparation water resistance and caking property are strong in patent application CN102875086A disclosed in China, adopt It is with sepiolite powder, kaolin powder, portland cement, hypromellose, polished rice gel powder, crosslinked starch, medical stone powder Raw material prepares powder of lacquer putty for use on, and powder of lacquer putty for use on obtained has extremely strong water resistance and caking property, and nothing is heaved, cracked, taking off after being made moist by water Phenomenon is fallen, and noxious material in energy adsorption chamber, service life are long.The needle in patent application CN106280657A disclosed in China The powder of lacquer putty for use on strong to acquisition water resistance and caking property, using cement, hollow glass micropearl, tetraethyl orthosilicate, absolute ethyl alcohol, salt Acid, template, emulsifier, sodium bicarbonate, Ludox, ammonium persulfate, lightweight sand, expandable polystyrene, dicalcium powder, wooden fibre Dimension, lanthanum nitrate, ethylenediamine tetra-acetic acid, ammonium chloride, urea are raw material, and putty obtained has very strong water resistance and caking property, And heat-insulated, good heat insulating.
Although currently available technology improves the caking property of powder of lacquer putty for use on to a certain extent, often there is waterproof and dampproof property Can be poor, heat-proof quality is poor the defects of.
Invention content
It is existing to overcome the main purpose of the present invention is to provide a kind of exterior wall water-proof heat-insulating paint and preparation method thereof Waterproof and dampproof poor performance existing for coating in technology, the defects of heat-proof quality is poor.
In order to achieve the above object, the present invention is achieved through the following technical solutions:
A kind of exterior wall water-proof heat-insulating paint, the coating are made of the raw material of following mass percentage::
Water polyacrylic acid lotion 35-60%
Silicone acrylic emulsion 2-5%
Nano filling 10-30%
Function additive 1.5-5.0%
Waterproofing agent 4-6%
Coalescents 0.2-0.5%
Surplus is deionized water.
Preferably, the coating is made of the raw material of following mass percentage:
Water polyacrylic acid lotion 40-55%
Silicone acrylic emulsion 2.5-4.5%
Nano filling 15-25%
Function additive 1.6-4.8%
Waterproofing agent 4.5-5.5%
Coalescents 0.3-0.4%
Surplus is deionized water.
Preferably, the Nano filling is the mixture of nano zine oxide, nano-titanium dioxide and sodium metasilicate nano wire, Wherein, the content of nano zine oxide is no less than 20% in the mixture, the weight of the nano-titanium dioxide and sodium metasilicate nano wire Amount is than being not less than 2:1.
Preferably, the waterproofing agent of organosilicon is polysiloxane-modified lotion.
Preferably, the coalescents dipropylene.
Preferably, the function additive includes thickener, dispersant, antifoaming agent, levelling agent, preservative and wetting agent.
Preferably, mass content of the thickener in the coating is 0.1-0.5%;The dispersant is described Mass content in coating is 0.2-0.7%;Mass content of the antifoaming agent in the coating is 0.5-1.5%;It is described Mass content of the levelling agent in the coating is 0.2-0.8%;Mass content of the preservative in the coating be 0.1-0.3%;Mass content of the wetting agent in the coating is 0.3-1.2%.
Preferably, the thickener is STZC-920;The dispersant is BYK-190;The antifoaming agent is TGG0920;The levelling agent is BYK-333;The preservative is STFM-1;The wetting agent is ZX-105.
The present invention also provides the preparation methods of above-mentioned exterior wall water-proof heat-insulating paint, include the following steps:
(1)Water polyacrylic acid lotion, silicone acrylic emulsion, function additive are added fully emulsified in reactor;
(2)The dispersion of reactor high speed is added in Nano filling, obtains evenly dispersed lotion;
(3)Reactor, regulation system viscosity, to get exterior wall after stable system is added in waterproofing agent, coalescents and deionized water Use water-proof heat-insulating paint.
Compared with prior art, the present invention having following advantageous effect:
(1)The present invention is and to be equipped with silicone acrylic emulsion and Nano filling as filler using water polyacrylic acid lotion as base-material, Can fill painting layer gap well by adding Nano filling, enhancing coating tensile strength, hardness, and impart coating every Hot heat-insulating property and excellent water resistance.
(2)Each paint binder of reasonable selection of the present invention and the addition that each base-material is rationally arranged, are added each in base-material Function additive is finally mixed with specific deionized water, and coating obtained is made to have excellent water resistance and heat-insulation and heat-preservation Performance, and there is excellent mechanical strength, heat resistance and corrosion resistance.
(3)The preparation process of the exterior wall water-proof heat-insulating paint of the present invention is simple, industrialized production easy to implement.
Specific implementation mode
Form by the following examples is described in further detail the above of the present invention again, but should not be by this The range for being interpreted as the above-mentioned theme of the present invention is only limitted to following embodiment, all based on the technology realized belonging to the above of the present invention It all belongs to the scope of the present invention.
Embodiment 1
A kind of exterior wall water-proof heat-insulating paint of this implementation, including the raw material components of following mass percentage are shown in Table 1:
The raw material of the exterior wall water-proof heat-insulating paint of 1 embodiment 1 of table
The specific preparation process of exterior wall water-proof heat-insulating paint of the present embodiment is as follows:
(1)Reactor is added in stirring at normal temperature 20 minutes, fully in water polyacrylic acid lotion, silicone acrylic emulsion, function additive Emulsification;
(2)Nano filling is added in reactor, mixing speed 1500rpm obtains evenly dispersed lotion;
(3)Reactor, regulation system viscosity, to get exterior wall after stable system is added in waterproofing agent, coalescents and deionized water Use water-proof heat-insulating paint.
Embodiment 2
A kind of exterior wall water-proof heat-insulating paint of this implementation, including the raw material components of following mass percentage are shown in Table 2:
The raw material of the exterior wall water-proof heat-insulating paint of 2 embodiment 2 of table
Specifically the preparation method is the same as that of Example 1 with water-proof heat-insulating paint for the exterior wall of the present embodiment.
Embodiment 3
A kind of exterior wall water-proof heat-insulating paint of this implementation, including the raw material components of following mass percentage are shown in Table 3:
The raw material of the exterior wall water-proof heat-insulating paint of 3 embodiment 3 of table
Specifically the preparation method is the same as that of Example 1 with water-proof heat-insulating paint for the exterior wall of the present embodiment.
Embodiment 4
A kind of exterior wall water-proof heat-insulating paint of this implementation, including the raw material components of following mass percentage are shown in Table 4:
The raw material of the exterior wall water-proof heat-insulating paint of 4 embodiment 4 of table
Specifically the preparation method is the same as that of Example 1 with water-proof heat-insulating paint for the exterior wall of the present embodiment.
Embodiment 5
A kind of exterior wall water-proof heat-insulating paint of this implementation, including the raw material components of following mass percentage are shown in Table 5:
The raw material of the exterior wall water-proof heat-insulating paint of 5 embodiment 5 of table
Specifically the preparation method is the same as that of Example 1 with water-proof heat-insulating paint for the exterior wall of the present embodiment.
It is merely a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned implementation described in upper Invention is explained in detail for example, for those skilled in the art, still can be to foregoing embodiments Recorded technical solution is modified or equivalent replacement of some of the technical features.All spirit in the present invention Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of exterior wall water-proof heat-insulating paint, which is characterized in that the coating by following mass percentage raw material group At::
Water polyacrylic acid lotion 35-60%
Silicone acrylic emulsion 2-5%
Nano filling 10-30%
Function additive 1.5-5.0%
Waterproofing agent 4-6%
Coalescents 0.2-0.5%
Surplus is deionized water.
2. exterior wall water-proof heat-insulating paint according to claim 1, which is characterized in that the coating is by following quality percentage The raw material of content forms:
Water polyacrylic acid lotion 40-55%
Silicone acrylic emulsion 2.5-4.5%
Nano filling 15-25%
Function additive 1.6-4.8%
Waterproofing agent 4.5-5.5%
Coalescents 0.3-0.4%
Surplus is deionized water.
3. exterior wall water-proof heat-insulating paint according to claim 1, which is characterized in that the Nano filling is nano oxidized The mixture of zinc, nano-titanium dioxide and sodium metasilicate nano wire, wherein the content of nano zine oxide is no less than in the mixture 20%, the weight ratio of the nano-titanium dioxide and sodium metasilicate nano wire is not less than 2:1.
4. exterior wall water-proof heat-insulating paint according to claim 1, which is characterized in that the waterproofing agent of organosilicon is poly- silicon Siloxane modified lotion.
5. exterior wall water-proof heat-insulating paint according to claim 1, which is characterized in that the coalescents dipropylene glycol fourth Ether.
6. exterior wall water-proof heat-insulating paint according to claim 1, which is characterized in that the function additive includes thickening Agent, dispersant, antifoaming agent, levelling agent, preservative and wetting agent.
7. exterior wall water-proof heat-insulating paint according to claim 6, which is characterized in that the thickener is in the coating Mass content be 0.1-0.5%;Mass content of the dispersant in the coating is 0.2-0.7%;The antifoaming agent Mass content in the coating is 0.5-1.5%;Mass content of the levelling agent in the coating is 0.2- 0.8%;Mass content of the preservative in the coating is 0.1-0.3%;Matter of the wetting agent in the coating Amount content is 0.3-1.2%.
8. exterior wall water-proof heat-insulating paint according to claim 7, which is characterized in that the thickener is STZC-920; The dispersant is BYK-190;The antifoaming agent is TGG0920;The levelling agent is BYK-333;The preservative is STFM- 1;The wetting agent is ZX-105.
9. a kind of preparation method according to claim 1-9 any one of them exterior wall water-proof heat-insulating paints, which is characterized in that Include the following steps:
(1)Water polyacrylic acid lotion, silicone acrylic emulsion, function additive are added fully emulsified in reactor;
(2)The dispersion of reactor high speed is added in Nano filling, obtains evenly dispersed lotion;
(3)Reactor, regulation system viscosity, to get exterior wall after stable system is added in waterproofing agent, coalescents and deionized water Use water-proof heat-insulating paint.
CN201810205581.0A 2018-03-13 2018-03-13 A kind of exterior wall water-proof heat-insulating paint and preparation method thereof Withdrawn CN108285714A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810205581.0A CN108285714A (en) 2018-03-13 2018-03-13 A kind of exterior wall water-proof heat-insulating paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810205581.0A CN108285714A (en) 2018-03-13 2018-03-13 A kind of exterior wall water-proof heat-insulating paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108285714A true CN108285714A (en) 2018-07-17

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CN201810205581.0A Withdrawn CN108285714A (en) 2018-03-13 2018-03-13 A kind of exterior wall water-proof heat-insulating paint and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133806A (en) * 2021-12-30 2022-03-04 河北雄安科筑检验认证有限公司 Heat-insulating waterproof coating and application thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133806A (en) * 2021-12-30 2022-03-04 河北雄安科筑检验认证有限公司 Heat-insulating waterproof coating and application thereof

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Application publication date: 20180717

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