CN101817615A - 厌氧-序批式膜生物反应器-人工湿地处理猪场废水的方法 - Google Patents
厌氧-序批式膜生物反应器-人工湿地处理猪场废水的方法 Download PDFInfo
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- CN101817615A CN101817615A CN 201010124744 CN201010124744A CN101817615A CN 101817615 A CN101817615 A CN 101817615A CN 201010124744 CN201010124744 CN 201010124744 CN 201010124744 A CN201010124744 A CN 201010124744A CN 101817615 A CN101817615 A CN 101817615A
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- 239000002351 wastewater Substances 0.000 title claims abstract description 43
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- CVTZKFWZDBJAHE-UHFFFAOYSA-N [N].N Chemical compound 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[N].N CVTZKFWZDBJAHE-UHFFFAOYSA-N 0.000 claims description 5
- 239000012528 membrane Substances 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound 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[P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 230000015556 catabolic process Effects 0.000 claims description 4
- 230000004059 degradation Effects 0.000 claims description 4
- 238000006731 degradation reaction Methods 0.000 claims description 4
- 230000001105 regulatory Effects 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound 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- 239000000463 material Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group 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Abstract
一种厌氧-序批式膜生物反应器-人工湿地处理猪场废水的方法，其特征是方法步骤为：(1)废水经污水收集管网收集后；(2)水解酸化池池内的厌氧环境使有机废物发生生物降解；(3)SBBR调节池能起到调节水质水量的作用；(4)使废水达到GB18596-2001《畜禽养殖业污染物排放标准》要求；(5)使SBBR反应器运行效果与能耗量达到最优组合。本发明的优点是：①减少占地面积；②厌氧器可以省掉污泥稳定所需的操作单元，进一步减少占地面积和处理费用；③处理废水效果更好；④脱氮效率高，并且处理效果稳定；⑤最后充分利用组合型人工湿地的处理效能，进行脱氮除磷的深度处理，同时起到降低SBBR系统的能耗作用。
Description
厌氧-序批式膜生物反应器-人工湿地处理猪场废水的方法
技术领域
[0001] 本发明涉及一种处理猪场废水的方法，尤其涉及一种厌氧-序批式膜生物反应 器-人工湿地处理猪场废水的方法。
背景技术
[0002] 近二十年，尤其是自九十年代以来，我国的畜牧业发展迅速。畜牧业已成为中国农 村经济中最活跃的增长点和主要的支柱产业。过去畜牧业以分散的农家畜牧养殖业为主， 现在，规模化养殖场生产已占主要地位。畜禽规模化集中饲养，有利于提高饲养技术、防疫 能力和管理水平，与传统饲养方式（农户散养）相比，规模化饲养能够大大提高生产效率和 饲料转换率，降低生产成本，从而增加经济效益。
[0003] 规模化养殖场数量的迅速增加导致了畜禽排放大量粪尿污水，这些污水未经处置 直接排放，对生态环境造成了严重的污染，尤其是对农业生态环境产生极其不良的影响。规 模化畜禽养殖场排放的污染物量大，畜禽排放的大量粪尿与养殖场的大量废水，所含氮、磷 及COD等污染物浓度非常高，含有大量有机物、氨氮，有关资料表明，猪场废水中BOD高达 2000 〜5000mg/L，COD 5000 〜20000mg/L，NH4+_N 400 〜1500mg/L，TN 600 〜2000mg/L， TPlOO〜300mg/L，可见猪场废水中氮的浓度基本上是生活污水的20〜50倍。2003年，猪、 牛、鸡三大类畜禽粪便排放总量达30. 87亿吨、粪便中COD (化学需氧量）含量7741万吨， 是全国工业和生活污水COD排放量的5. 07倍。然而，由于粪污处理技术的相对落后，约有 80%养殖场粪污未经处理直接排放，造成了日益严重的环境污染，构建适合不同养殖规模 的养殖废弃物污染治理模式成为解决养殖废弃物环境污染的关键。
[0004] 目前规模化畜禽养殖场所带来的严重污染已引起政府、养殖场业主和环保研究单 位的重视，相继开发了不同处理工艺，并建立了各式养殖废水处理工程。
[0005] 针对猪场废水富含氮、磷有机物的水质特点，目前采用的处理工艺主要有生态化 处理与生物反应器处理两种模式。生态化处理处理模式主要包括人工湿地系统、土地处理 系统和稳定塘系统，建设费用较低，运行成本低廉，需要耗费大量的土地资源；生物反应器 处理模式主要包括厌氧、好氧及它们的组合工艺，具有占地少、工艺运行可控等优点。
[0006] 现在我国部分地区，规模化养猪场已建成的污水处理大部分都采用了 “猪-沼-果”等模式，该具有一定的生态和经济效益，但由于只利用了沼气池处理养猪废 水，仅对有机污染物（COD)具有较好的去除效果，而对养猪废水中大量的氮、磷等能使水体 发生严重富营养化几乎没有去除的能力。
[0007] 目前国内外虽然对养殖场废水的处理有许多研究，也存在诸多的处理方法，但是， 从已有的报导资料综合分析，目前无论哪种方法处理效果都不理想，或是出水水质达不到 排放要求，或是成本太高而无法在我国推广应用。规模化猪场废水是一种有机质和氨氮浓 度都很高的废水，单独的厌氧或好氧工艺对处理规模化猪场废水都是不适合的，单独厌氧 工艺的出水达不到排放要求，单独的好氧工艺不能承受如此高浓度、高负荷的废水，必然出现污泥膨胀等一系列问题，而且运行费用较高。
[0008] 规模养殖场周边生态环境消纳养殖废弃物能力有限，国家限养区和禁养区的界 定，土地资源日趋紧张，严重制约了生态化处理模式的推广。另外，受季节变化、地理环境等 因素影响，生态化处理工艺很难达到城市周边环境质量控制要求。为实现畜禽养殖业的可 持续性发展，有必要在推进规模化养殖的同时大力推广养殖废水生物反应器组合新技术。
发明内容
[0009] 本发明的目的在于提供一种厌氧_序批式膜生物反应器_人工湿地处理猪场废水 的方法，以解决上述废水处理方法存在的问题.针对猪场废水水质水量变化大、营养元素 比例失调、氨氮含量高的特点，同时考虑深度脱氮、深度去除有机物的问题，养殖废水在经 过处理后，其排放废水达到GB 18596-2001《畜禽养殖业污染物排放标准》。
[0010] 本发明是这样来实现的，其特征是方法步骤为：
[0011] 1、废水经污水收集管网收集后，经过机械格栅的截留，去除污水中的大颗粒污染 物质和漂浮物，保护水泵及其他处理设施能正常运行，废水进入水解酸化池；
[0012] 2、水解酸化池池内的厌氧环境使有机废物发生生物降解，同时起到对养殖废水水 质水量均质调节的作用，水解酸化池设置在为地下式；
[0013] 3、废水水平流入厌氧器、沼气池或I0C反应器中，经过高效厌氧消解，在去除大部 分COD后溢流进入SBBR调节池，由于SBBR反应器为间断式进水，SBBR调节池能起到调节 水质水量的作用；
[0014] 4、SBBR反应器的进水从SBBR调节池泵入，经过好氧/兼氧硝化反硝化反应后，进 一步的去除废水水的COD、氨氮和磷等污染物，使废水达到GB 18596-2001《畜禽养殖业污 染物排放标准》要求；
[0015] 5、SBBR反应器的出水再经过人工湿地的深度处理，利用人工湿地系统中基质-水 生植物-微生物的物理、化学、生物三重协同作用，通过基质过滤、吸附、沉淀、离子交换、植 物吸收和微生物分解来实现对污水的高效净化，同时也可以根据人工湿地的处理能力，调 整SBBR反应器的曝气量，使SBBR反应器运行效果与能耗量达到最优组合。
[0016] 废水经处理后，出水水质达到GB 18596-2001《畜禽养殖业污染物排放标准》要求， 即：
[0017] 表1GB 18596-2001《畜禽养殖业污染物排放标准》（mg/L)
<table>table see original document page 4</column></row>
<table>
[0019] 所述的SBBR反应器包括序批式生物膜反应器、进水口、布气管、气体流量计、空压 机、进水玻璃转子流量计、进水阀门、隔膜泵、储水池、PLC自动控制系统、排泥管，其特征是 序批式生物膜反应器的侧壁上端开有进水口，序批式生物膜反应器的底端设有布气管，布 气管连接气体流量计，气体流量计连接空压机，布气管下端连有进水玻璃转子流量计，进水玻璃转子流量计连接进水阀门，进水阀门连接隔膜泵，隔膜泵连接储水池，序批式生物膜反应器顶端连有液位计，液位计、空压机和进水阀门分别连接PLC自动控制系统，序批式生物 膜反应器底端连有排泥管。
[0020] 本发明的优点是：①由于厌氧器去除了废水中大量的有机物和悬浮物，后续的 SBBR好氧工艺的生物量相对会减少很多，其容积也会减少，在实践中，厌氧-好氧工艺的总 容积不到单独好氧工艺容积的一半，减少占地面积；②厌氧器可以省掉污泥稳定所需的操 作单元，进一步减少占地面积和处理费用；③剩余污泥量比单独好氧工艺少，因为厌氧环境 下污泥产率远小于好氧。此外厌氧器的污泥浓度高，处理废水效果更好；④SBBR反应器采 用专门针对猪场废水的设计模式与运行方式，提高了装置的抗冲击负荷能力和处理能力， 脱氮效率高，并且处理效果稳定；⑤最后充分利用组合型人工湿地的处理效能，进行脱氮除 磷的深度处理，同时起到降低SBBR系统的能耗作用。
附图说明
[0021] 图1为本发明SBBR反应器的结构示意图。
[0022] 在图中，1、序批式生物膜反应器2、进水口 3、布气管4、气体流量计5、空压 机6、进水玻璃转子流量计7、进水阀门8、隔膜泵9、储水池10液位计11、PLC自 动控制系统12、排泥管
具体实施方式
[0023] 实施例1 ：原水为某规模化猪场废水，日处理量为150m3/d，原水水质：C0D5000〜 10000mg/L,NH4+-N 400〜1500mg/L TP30〜100mg/L。原水进入水解酸化池，再进入厌氧反 应器，利用异养菌的代谢功能将难生物降解有机物分解成易生物降解的小分子有机物，并 且同时矿化有机氮，降解去除大部分易生物降解有机物。但厌氧部分并没有去除NH4+-N，厌 氧环境反而使TP增加，厌氧反应器出水COD 500〜1000mg/L，NH4+-N 400〜1500mg/L TP 50〜150mg/L ；厌氧反应器出水出水经过SBBR反应器后，确定SBBR运行工况：进水lh、厌 氧 3h、好氧 7h、沉淀 0. 5h、排水 0. 5h, SBBR 出水 COD 300 〜400mg/L，NH4+_N40 〜80mg/L TP 5〜8mg/L。再经过人工湿地深度处理后，综合出水水质C0D100〜200mg/L，NH4+-N 30〜 60mg/L TP 4 〜8mg/L。
[0024] 实施例2 ：原水为某规模化猪场废水，日处理量为150m3/d，原水水质：C0D4000〜 8000mg/L,NH4+-N 320〜1200mg/L TP24〜80mg/L。原水进入水解酸化池，再进入厌氧反应 器，利用异养菌的代谢功能将难生物降解有机物分解成易生物降解的小分子有机物，并且 同时矿化有机氮，降解去除大部分易生物降解有机物。但厌氧部分并没有去除NH4+-N，厌氧 环境反而使TP增加，厌氧反应器出水C0D 400〜800mg/L，NH4+-N320〜1200mg/L TP 40〜 120mg/L ；厌氧反应器出水出水经过SBBR反应器后，确定SBBR运行工况：进水lh、厌氧3h、 好氧 7h、沉淀 0. 5h、排水 0. 5h, SBBR 出水 COD 240 〜320mg/L，NH4+_N 32 〜64mg/L TP 4 〜 6. 4mg/L。再经过人工湿地深度处理后，综合出水水质COD 80〜160mg/L，NH4+_N 24〜48mg/ L TP 3. 2 〜6. 4mg/L。
[0025] 实施例3 ：原水为某规模化猪场废水，日处理量为150m3/d，原水水质：C0D6000〜 12000mg/L,NH4+-N 480〜1800mg/L TP36〜120mg/L。原水进入水解酸化池，再进入厌氧反应器，利用异养菌的代谢功能将难生物降解有机物分解成易生物降解的小分子有机物，并 且同时矿化有机氮，降解去除大部分易生物降解有机物。但厌氧部分并没有去除NH4+-N，厌 氧环境反而使TP增加，厌氧反应器出水COD 600〜1200mg/L，NH4+-N 480〜1800mg/L TP 60〜180mg/L ；厌氧反应器出水出水经过SBBR反应器后，确定SBBR运行工况：进水lh、厌 氧 3h、好氧 7h、沉淀 0. 5h、排水 0. 5h, SBBR 出水 COD 360 〜480mg/L，NH4+-N 50 〜96mg/L TP 6〜9. 6mg/L。再经过人工湿地深度处理后，综合出水水质COD 120〜240mg/L，NH4+_N 36 〜72mg/L TP 5 〜9. 6mg/L。
[0026] 所述的SBBR反应器包括序批式生物膜反应器1、进水口 2、布气管3、气体流量计 4、空压机5、进水玻璃转子流量计6、进水阀门7、隔膜泵8、储水池9、液位计10、PLC自动控 制系统11、排泥管12，序批式生物膜反应器1的侧壁上端开有进水口 2，序批式生物膜反应 器1的底端设有布气管3，布气管3连接气体流量计4，气体流量计4连接空压机5，布气管 3下端连有进水玻璃转子流量计6，进水玻璃转子流量计6连接进水阀门7，进水阀门7连接 隔膜泵8，隔膜泵8连接储水池9，序批式生物膜反应器1顶端连有液位计10，液位计10、空 压机5和进水阀门7分别连接PLC自动控制系统11，序批式生物膜反应器1底端连有排泥 管12。
[0027] 通过中试研究，得到组合工艺处理养殖场废水的最佳工况条件与最优的经济运行 参数。为厌氧-SBBR-人工湿地组合工艺产业化推广建立标准化生产工艺流程。
[0028] 本发明中，最为关键的是SBBR反应器设计与运行方式，为增强SBBR反应器的脱氮 除磷效果，并克服了 SBR工艺脱氮效率不高与连续流分段反应时间固定池容限制等缺点， SBBR反应器采取如下设计与运行方式：
[0029] 1、SBBR反应器采取上端进水与滗水，微孔曝气头装设于反应容器底部，位于球型 组合填料下方，通过管路与装于反应容器内的曝气头相连，反应器设有电磁阀和液位计，整 个反应器运行可以实现自动控制；
[0030] 2、SBBR反应容器设有填料固定支架，采用球型组合填料装于填料固定支架上，曝 气头为由固定式球型组合填料底部垂直向上曝气的微孔曝气盘，球形填料的材质为聚乙 烯、聚氯乙烯、聚苯乙烯、聚丙烯或聚氨酷；
[0031] 3、SBBR反应器采用分段式进水模式分散进水负荷，分为进水一反应一沉淀一排水 的序批间歇操作、反应阶段非曝气一曝气交替操作和分步进水三个基本特征，提高了装置 的抗冲击负荷能力和处理能力，脱氮效率高，并且处理效果稳定。
Claims (2)
- 一种厌氧-序批式膜生物反应器-人工湿地处理猪场废水的方法，其特征是方法步骤为：(1)废水经污水收集管网收集后，经过机械格栅的截留，去除污水中的大颗粒污染物质和漂浮物，保护水泵及其他处理设施能正常运行，废水进入水解酸化池；(2)水解酸化池池内的厌氧环境使有机废物发生生物降解，同时起到对养殖废水水质水量均质调节的作用，水解酸化池设置在为地下式；(3)废水水平流入厌氧器、沼气池或IOC反应器中，经过高效厌氧消解，在去除大部分COD后溢流进入SBBR调节池，由于SBBR反应器为间断式进水，SBBR调节池能起到调节水质水量的作用；(4)SBBR反应器的进水从SBBR调节池泵入，经过好氧/兼氧硝化反硝化反应后，进一步的去除废水水的COD、氨氮和磷等污染物，使废水达到GB 185962001《畜禽养殖业污染物排放标准》要求；(5)SBBR反应器的出水再经过人工湿地的深度处理，利用人工湿地系统中基质-水生植物-微生物的物理、化学、生物三重协同作用，通过基质过滤、吸附、沉淀、离子交换、植物吸收和微生物分解来实现对污水的高效净化，同时也可以根据人工湿地的处理能力，调整SBBR反应器的曝气量，使SBBR反应器运行效果与能耗量达到最优组合。
- 2.根据权利要求1所述的厌氧_序批式膜生物反应器_人工湿地处理猪场废水的方 法，其特征是所述的SBBR反应器包括序批式生物膜反应器、进水口、布气管、气体流量计、 空压机、进水玻璃转子流量计、进水阀门、隔膜泵、储水池、PLC自动控制系统、排泥管，序批 式生物膜反应器的侧壁上端开有进水口，序批式生物膜反应器的底端设有布气管，布气管 连接气体流量计，气体流量计连接空压机，布气管下端连有进水玻璃转子流量计，进水玻璃 转子流量计连接进水阀门，进水阀门连接隔膜泵，隔膜泵连接储水池，序批式生物膜反应器 顶端连有液位计，液位计、空压机和进水阀门分别连接PLC自动控制系统，序批式生物膜反 应器底端连有排泥管。
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