CN101805500B - Decoration material and production method thereof - Google Patents

Decoration material and production method thereof Download PDF

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Publication number
CN101805500B
CN101805500B CN2010100193608A CN201010019360A CN101805500B CN 101805500 B CN101805500 B CN 101805500B CN 2010100193608 A CN2010100193608 A CN 2010100193608A CN 201010019360 A CN201010019360 A CN 201010019360A CN 101805500 B CN101805500 B CN 101805500B
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China
Prior art keywords
preparation
glass
mould
cullet
unsaturated polyester
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Expired - Fee Related
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CN2010100193608A
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Chinese (zh)
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CN101805500A (en
Inventor
宋发炫
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KIND LIGHT MANUFACTORY Ltd
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KIND LIGHT MANUFACTORY Ltd
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Priority to CN2010100193608A priority Critical patent/CN101805500B/en
Publication of CN101805500A publication Critical patent/CN101805500A/en
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Abstract

The invention relates to the technical field of a transparent unsaturated polyester resin processing technic, in particular to a decoration material produced by adopting colorful cullet and transparent unsaturated polyester resin products and a production method thereof. The decoration material contains the following components in parts by weight: 15-24.4% of transparent unsaturated polyester resin, 0.6-1.8% of cyclohexanone peroxide, 0.3-1% of dibutyl phthalate and 72.8-84.1% of colorful cullet. The production method of the material is mainly as follows: firstly preparing an A material composed of the transparent unsaturated polyester resin and a hardener, after the A material is slicked and vacuumized in a die, preparing a B material by the A material and the cullet to cover the A material so as to form the required decoration material. The invention has the advantages of simple processing technic, low cost and environmental protection.

Description

A kind of category of glass finishing material and preparation method thereof
Technical field
The present invention relates to transparent the bag and vibrin technology field, be specifically related to adopt the preparation of colored glass cullet and transparent unsaturated polyester rosin products the category of glass finishing material and method of manufacture.
Background technology
Along with the development of society, the improving constantly of people's living standard, human consumer's aesthetic taste is also improving constantly.And existing finishing material also has only constantly to weed out the old and bring forth the new the approval that obtains people is just arranged.Ambetti is common a kind of finishing material, the glass decoration that various buildings place can both be seen and vary in color, moulding is exquisite.
A large amount of discarded leftover bits that various glass material production processes can produce, can effectively utilizing this type glass edge horn scraps, to produce high-grade decorative sheet also be constantly one of direction of research of industry.
Summary of the invention
Technical problem to be solved by this invention provides that a kind of complete processing is simple, cost is low and the novel glass class finishing material of environmental protection and preparation method thereof.
For solving the problems of the technologies described above, the composition proposal of category of glass finishing material of the present invention is:
A kind of category of glass finishing material calculates with parts by weight, contains 15~24.4% transparent insatiable hunger vibrin, 0.6~1.8% peroxo-hexamethylene copper, 0.3~1% O-phthalic dibutylester and 72.8~84.1% colored glass cullet.
The preparation method of above-mentioned category of glass finishing material is following:
1), determines the color and the size of glass cullet according to set finishing material plan; From the good stained glass leftover bits of prior collection; Pick out required versicolor leftover bits; Drop in the glass kibbler and be ground into needed size, the colored glass cullet that will crush then clean up;
2), preparation A material: the A material comprises that transparent unsaturated polyester resin, peroxo-hexamethylene copper and its part by weight of O-phthalic dibutylester are 89: 7: 4~96: 3: 1; The A material is stirred with stirrer; The A material that stirs poured into utilize perching knife to scrape the A material of mould the inside evenly smooth in the previously prepd mould; Put into the vacuum machine again and vacuumize the steam bubble of resin material the inside is removed fully, take out and put back on the mold work platform for use then;
3), preparation B material: the B material comprises A material and colored glass cullet; The materials weight ratio of A material and colored glass cullet is 0.9: 4.1~1: 4; After the B material stirred with stirrer; Pour in the A material mould that exhausts vacuum and cover the A material fully, once again the surface is scraped smoothly with perching knife, then entire die is put into the vacuum machine and vacuumize;
4), mould and the material that will take out vacuum take out and place workplatform, lets its naturally cooling and setting;
5), the product of preparation is carried out surperficial shaping, utilize mill end machine and polishing machine with the product external surfaces sanding and polishing for preparing;
6), the product of accomplishing shaping puts into buck and soaks and carry out decontamination and oil stain approximately, washes with jetting machine again, product is cleaned up.
The present invention compared with prior art has the following advantages:
1, the finishing material of the present invention preparation is to the making full use of of waste, and reduces the rubbish environmental pollution.The scrap stock of stained glass are the rejected materials that in all Buddhist nun's lamp decorations of Supreme Being production process, is produced; This is inevasible; All bring it when refuse treatment and can't utilize again in the production process in the past; So just cause a large amount of garbage problems, can in rosin products, add the stained glass offcut of suitable proportion now, as long as through the simple course of processing; Can recycle these originally by stained glass offcut, so just can reach and reduce the target that rubbish produces as refuse treatment.
2, preparation method of the present invention can reduce the usage quantity of transparent resin and reduce cost: the transparent polyester resin belongs to petroleum chemicals; Environment there is certain pollution hazard; A large amount of use transparent polyester resins increases the pollution burden of environment virtually in various daily necessitiess; If utilize the stained glass offcut to replace transparent resin in a large number, can directly reduce the transparent resin consumption relatively, so not only environment is reduced source of pollution; More can recycle rubbish, reduce the material cost of unsaturated polyester resin.
3, utilize the transparent unsaturated polyester resin to variegate the synthetic materials that stirs into behind the glass cullet; Special processing mode through manual air dry celluloid paint; Produce special visual effect, and can promote the texture of this series products greatly, produce the special aesthstic artistic effect of various different jewelry.
4, the present invention prepares finishing material, makes product can not re-use tinted paint the preparation layers of material and carries out the special aesthstic artistic effect that baking vanish just can show various different jewelry, can practice thrift manual work and material cost, and reduce the environmental pollution that paint brings.
Description of drawings
Fig. 1 is the material structure synoptic diagram that the present invention prepares.
Specific embodiments
The present invention will be described through concrete preparation example below
Embodiment 1
1), determines the color and the size of glass cullet according to set finishing material plan; From the good stained glass leftover bits of prior collection; Pick out required versicolor leftover bits; Drop in the glass kibbler and be ground into needed size, the colored glass cullet that will crush then clean up;
2), preparation A material: the A material comprises that transparent unsaturated polyester resin, peroxo-hexamethylene copper and its part by weight of O-phthalic dibutylester are 96: 3: 1.Peroxo-hexamethylene copper is as stiffening agent, and the O-phthalic dibutylester is as promotor, and two kinds of material effects are accelerate hardening, prevents distortion.The A material is stirred with stirrer; The A material that stirs is poured in the previously prepd mould; A material consumption is as the criterion to cover mould 3mm; It is evenly smooth to utilize perching knife that the A material of mould the inside is scraped, and puts into the vacuum machine again and vacuumizes the steam bubble of resin material the inside is removed fully, takes out then and returns on the mold work platform for use;
3), preparation B material: the B material comprises A material and colored glass cullet, and the materials weight ratio of A material and colored glass cullet is 1: 4, and can keep good flowability after the ratio between A material and colored glass cullet is mixed with both is standard.After the B material stirred with stirrer, pour in the A material mould that exhausts vacuum and cover the A material fully, once again the surface is scraped smoothly with perching knife, then entire die will be put into the vacuum machine and vacuumize 2 minutes; Be bonded together by stiffening agent and after vacuumizing between A material and the B material.
4), mould and the material that will take out vacuum take out and place workplatform, lets its naturally cooling and setting, fixing time is 20 fens kinds;
5), the product of preparation is carried out surperficial shaping, utilize mill end machine and polishing machine with the product external surfaces sanding and polishing for preparing;
6), the product of accomplishing shaping puts into buck and soaks and carried out decontamination and oil stain in about 8 minutes, washes with jetting machine again, product is cleaned up.
Use air-drying varnish at last; Modify the finishing material that processing promptly obtains containing glass cullet at product surface by hand, the component of prepared finishing material is respectively 19.2% transparent insatiable hunger vibrin, 0.6% peroxo-hexamethylene copper, 0.2% O-phthalic dibutylester and 80% colored glass cullet.
Embodiment 2
Change the proportioning in the preparation process 2,3, transparent unsaturated polyester resin and peroxo-hexamethylene copper and its part by weight of O-phthalic dibutylester are 89: 7: 4 during preparation A material; The materials weight ratio of A material and colored glass cullet is 0.9: 4.1 during preparation B material, is respectively 16.02% transparent insatiable hunger vibrin, 1.26%% peroxo-hexamethylene copper, 0.72% O-phthalic dibutylester and 82% colored glass cullet according to the component of the prepared finishing material of the similar preparation method of embodiment.

Claims (3)

1. the preparation method of a category of glass finishing material may further comprise the steps:
1), determines the color and the size of glass cullet according to set finishing material plan; From the good stained glass leftover bits of prior collection; Pick out required versicolor leftover bits; Drop in the glass kibbler and be ground into needed size, the colored glass cullet that will crush then clean up;
2), preparation A material: the A material comprises that transparent unsaturated polyester resin, cyclohexanone peroxide and its part by weight of O-phthalic dibutylester are 89: 7: 4~96: 3: 1; The A material is stirred with stirrer; The A material that stirs poured into utilize perching knife to scrape the A material of mould the inside evenly smooth in the previously prepd mould; Put into the vacuum machine again and vacuumize the steam bubble of resin material the inside is removed fully, take out then and return on the mold work platform for use;
3), preparation B material: the B material comprises A material and colored glass cullet; The materials weight ratio of A material and colored glass cullet is 0.9: 4.1~1: 4; After the B material stirred with stirrer; Pour in the A material mould that exhausts vacuum and cover the A material fully, once again the surface is scraped smoothly with perching knife, then entire die is put into the vacuum machine and vacuumize;
4), mould and the material that will take out vacuum take out and place workplatform, lets its naturally cooling and setting;
5), the product of preparation is carried out surperficial shaping, utilize mill end machine and polishing machine with the product external surfaces sanding and polishing for preparing;
6), the product of accomplishing shaping puts into buck and soaks and carry out decontamination and oil stain, washes with jetting machine again, product is cleaned up,
Prepared category of glass finishing material calculates with parts by weight, contains 15~24.4% transparent unsaturated polyester resins, 0.6~1.8% cyclohexanone peroxide, 0.3~1% O-phthalic dibutylester and 72.8~84.1% colored glass cullet.
2. the preparation method of category of glass finishing material according to claim 1 is characterized in that: step 2) thickness of described A material on mould is 2.5~3.5mm.
3. the preparation method of category of glass finishing material according to claim 2 is characterized in that: soak time is 7~10 minutes in the described buck of described step 6.
CN2010100193608A 2010-01-12 2010-01-12 Decoration material and production method thereof Expired - Fee Related CN101805500B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010100193608A CN101805500B (en) 2010-01-12 2010-01-12 Decoration material and production method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010100193608A CN101805500B (en) 2010-01-12 2010-01-12 Decoration material and production method thereof

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CN101805500A CN101805500A (en) 2010-08-18
CN101805500B true CN101805500B (en) 2012-02-29

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87206551U (en) * 1987-04-16 1988-07-06 刘巨申 Colour composite polyester glass
CN1204486A (en) * 1997-07-07 1999-01-13 徐敏 Inlay technology for imitation jade and wooden product
CN1403306A (en) * 2001-09-08 2003-03-19 江门市新力塑料厂有限公司 Stereo decorating material UP process and product
CN1539657A (en) * 2003-04-25 2004-10-27 陈金兰 Glass artware of ice flower and fabricating method
CN1919927A (en) * 2005-08-26 2007-02-28 天津市世纪东方建筑景观雕塑技术开发中心 Manufacture method of plexiglass crystal video display wall brick

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN87206551U (en) * 1987-04-16 1988-07-06 刘巨申 Colour composite polyester glass
CN1204486A (en) * 1997-07-07 1999-01-13 徐敏 Inlay technology for imitation jade and wooden product
CN1403306A (en) * 2001-09-08 2003-03-19 江门市新力塑料厂有限公司 Stereo decorating material UP process and product
CN1539657A (en) * 2003-04-25 2004-10-27 陈金兰 Glass artware of ice flower and fabricating method
CN1919927A (en) * 2005-08-26 2007-02-28 天津市世纪东方建筑景观雕塑技术开发中心 Manufacture method of plexiglass crystal video display wall brick

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JP平2-199049A 1990.08.07
JP平3-287667A 1991.12.18

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