CN101805185B - 一种制备铌镁酸铅钛酸铅弛豫铁电陶瓷的方法 - Google Patents
一种制备铌镁酸铅钛酸铅弛豫铁电陶瓷的方法 Download PDFInfo
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- CN101805185B CN101805185B CN201010128011.XA CN201010128011A CN101805185B CN 101805185 B CN101805185 B CN 101805185B CN 201010128011 A CN201010128011 A CN 201010128011A CN 101805185 B CN101805185 B CN 101805185B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 37
- NKZSPGSOXYXWQA-UHFFFAOYSA-N dioxido(oxo)titanium;lead(2+) Chemical compound [Pb+2].[O-][Ti]([O-])=O NKZSPGSOXYXWQA-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 238000005245 sintering Methods 0.000 claims abstract description 70
- 238000002360 preparation method Methods 0.000 claims abstract description 42
- 239000000203 mixture Substances 0.000 claims abstract description 12
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims abstract description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000464 lead oxide Inorganic materials 0.000 claims abstract description 3
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 3
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000011777 magnesium Substances 0.000 claims description 15
- 239000010955 niobium Substances 0.000 claims description 15
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 12
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 7
- 238000005303 weighing Methods 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 2
- 239000002019 doping agent Substances 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 16
- 239000002994 raw material Substances 0.000 abstract description 11
- 238000001354 calcination Methods 0.000 abstract description 4
- 238000001308 synthesis method Methods 0.000 abstract description 3
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 2
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical group [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 24
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 10
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 244000309464 bull Species 0.000 description 2
- 239000003985 ceramic capacitor Substances 0.000 description 2
- 229960004643 cupric oxide Drugs 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- MFUVDXOKPBAHMC-UHFFFAOYSA-N magnesium;dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MFUVDXOKPBAHMC-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910000967 As alloy Inorganic materials 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000003701 mechanical milling Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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CN201010128011.XA CN101805185B (zh) | 2010-03-19 | 2010-03-19 | 一种制备铌镁酸铅钛酸铅弛豫铁电陶瓷的方法 |
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Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102241517B (zh) * | 2011-04-07 | 2014-08-27 | 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 | 一种功能型建筑陶瓷的制备方法 |
CN102659404A (zh) * | 2012-05-02 | 2012-09-12 | 天津大学 | 低温烧结铌镍酸铅-锆钛酸铅压电陶瓷及其制备方法 |
CN102718479A (zh) * | 2012-07-12 | 2012-10-10 | 上海师范大学 | 一种具有高电致伸缩系数的钛酸铋钠基无铅陶瓷及其制备方法 |
CN105084898B (zh) * | 2015-08-07 | 2017-08-25 | 哈尔滨工业大学 | 一种低温烧结三元系弛豫铁电陶瓷材料 |
CN106946569B (zh) * | 2017-02-24 | 2020-05-26 | 北京国械堂科技发展有限责任公司 | 一种可用于生物医学研究和临床应用的陶瓷电极材料及元件 |
CN108806976B (zh) * | 2018-05-30 | 2020-05-15 | 广东风华高新科技股份有限公司 | 一种多层陶瓷电容器及其制备方法 |
CN109650888B (zh) * | 2018-12-27 | 2019-12-31 | 哈尔滨工业大学 | 一种低温织构高电学性能三元系钛酸铅基弛豫铁电取向陶瓷 |
CN113636840B (zh) * | 2021-10-15 | 2022-01-11 | 北京国械堂科技发展有限责任公司 | 用于电场治疗肿瘤的陶瓷电极的陶瓷厚膜及其制备方法 |
CN114163234A (zh) * | 2021-12-27 | 2022-03-11 | 佛山(华南)新材料研究院 | 铌酸铅镁-钛酸铅弛豫铁电陶瓷及其制备方法和应用 |
CN114349506A (zh) * | 2022-01-07 | 2022-04-15 | 森霸传感科技股份有限公司 | 一种低损耗高介电常数铌镁酸铅-钛酸铅介质陶瓷材料制备方法及其应用 |
CN114621009B (zh) * | 2022-03-16 | 2023-02-28 | 南京理工大学 | 一种铌镁酸铅-钛酸铅基压电陶瓷材料及其制备方法 |
CN117049877B (zh) * | 2023-10-12 | 2024-01-09 | 佛山仙湖实验室 | 一种电致伸缩陶瓷及其制备方法、电致伸缩装置 |
Citations (2)
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CN1382841A (zh) * | 2002-03-12 | 2002-12-04 | 中国科学院上海硅酸盐研究所 | 铌锌酸铅钛酸铅固溶体单晶的熔体法生长 |
CN1636930A (zh) * | 2004-12-07 | 2005-07-13 | 天津大学 | 一种温度超稳定型电子陶瓷材料的组成及其制造方法 |
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- 2010-03-19 CN CN201010128011.XA patent/CN101805185B/zh active Active
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1382841A (zh) * | 2002-03-12 | 2002-12-04 | 中国科学院上海硅酸盐研究所 | 铌锌酸铅钛酸铅固溶体单晶的熔体法生长 |
CN1636930A (zh) * | 2004-12-07 | 2005-07-13 | 天津大学 | 一种温度超稳定型电子陶瓷材料的组成及其制造方法 |
Non-Patent Citations (1)
Title |
---|
曹林洪等."半化学法制备工艺对PMN-PT陶瓷电性能的影响".《精细化工》.2006,第23卷(第12期),第1148~1150、1154页. |
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Address after: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee after: Jiangsu Polytechnic University Address before: 213016 Baiyun District, Changzhou, Jiangsu Patentee before: Jiangsu Polytechnic University |
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