CN101804331B - 树枝形多氨基吸附树脂及其制备方法 - Google Patents
树枝形多氨基吸附树脂及其制备方法 Download PDFInfo
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- CN101804331B CN101804331B CN 201010116293 CN201010116293A CN101804331B CN 101804331 B CN101804331 B CN 101804331B CN 201010116293 CN201010116293 CN 201010116293 CN 201010116293 A CN201010116293 A CN 201010116293A CN 101804331 B CN101804331 B CN 101804331B
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- resin
- polyamine
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- dendritic
- adsorptive
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- 239000011347 resin Substances 0.000 title claims abstract description 70
- 229920005989 resin Polymers 0.000 title claims abstract description 70
- 229920000768 polyamine Polymers 0.000 title claims abstract description 17
- 230000000274 adsorptive effect Effects 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims description 8
- 229920003053 polystyrene-divinylbenzene Polymers 0.000 claims abstract description 14
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 35
- 238000003756 stirring Methods 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- WGQKYBSKWIADBV-UHFFFAOYSA-N benzylamine Chemical compound NCC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-N 0.000 claims description 12
- 235000019441 ethanol Nutrition 0.000 claims description 11
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- 239000012508 resin bead Substances 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 230000007935 neutral effect Effects 0.000 claims description 5
- 238000010992 reflux Methods 0.000 claims description 5
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 5
- 239000012279 sodium borohydride Substances 0.000 claims description 5
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 238000003786 synthesis reaction Methods 0.000 abstract description 5
- 125000001302 tertiary amino group Chemical group 0.000 abstract description 5
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 abstract description 4
- 125000000524 functional group Chemical group 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- 239000011734 sodium Substances 0.000 abstract description 2
- 125000003277 amino group Chemical group 0.000 abstract 4
- 239000003607 modifier Substances 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 125000002560 nitrile group Chemical group 0.000 abstract 1
- 239000003463 adsorbent Substances 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000012043 crude product Substances 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 150000003141 primary amines Chemical group 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000000967 suction filtration Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 230000010148 water-pollination Effects 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- MYRTYDVEIRVNKP-UHFFFAOYSA-N divinylbenzene Substances C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Description
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 201010116293 CN101804331B (zh) | 2010-03-02 | 2010-03-02 | 树枝形多氨基吸附树脂及其制备方法 |
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CN 201010116293 CN101804331B (zh) | 2010-03-02 | 2010-03-02 | 树枝形多氨基吸附树脂及其制备方法 |
Publications (2)
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CN101804331A CN101804331A (zh) | 2010-08-18 |
CN101804331B true CN101804331B (zh) | 2013-05-08 |
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CN 201010116293 Active CN101804331B (zh) | 2010-03-02 | 2010-03-02 | 树枝形多氨基吸附树脂及其制备方法 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105461156B (zh) * | 2014-09-03 | 2018-01-23 | 中国石油化工股份有限公司 | 一种丁腈橡胶生产废水的处理方法 |
CN112300207B (zh) * | 2020-11-19 | 2024-01-30 | 南京曙光新材料有限公司 | 一种去除副产盐水中多硫化物硅烷偶联剂的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85104153A (zh) * | 1985-06-03 | 1986-12-03 | 核工业部北京第五研究所 | 丙烯酸型弱碱性阴离子交换树脂的合成方法 |
US20010002656A1 (en) * | 1999-12-03 | 2001-06-07 | Ulrich Schnegg | Process for preparing monodisperse adsorber resins and their use |
CN1370789A (zh) * | 2001-02-27 | 2002-09-25 | 巴陵石化岳阳石油化工总厂 | 一种多氨基多酰胺树脂的制备方法 |
CN1865302A (zh) * | 2006-04-25 | 2006-11-22 | 南京大学 | 一种含季胺基复合功能超高交联吸附树脂及其制备方法 |
-
2010
- 2010-03-02 CN CN 201010116293 patent/CN101804331B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85104153A (zh) * | 1985-06-03 | 1986-12-03 | 核工业部北京第五研究所 | 丙烯酸型弱碱性阴离子交换树脂的合成方法 |
US20010002656A1 (en) * | 1999-12-03 | 2001-06-07 | Ulrich Schnegg | Process for preparing monodisperse adsorber resins and their use |
CN1370789A (zh) * | 2001-02-27 | 2002-09-25 | 巴陵石化岳阳石油化工总厂 | 一种多氨基多酰胺树脂的制备方法 |
CN1865302A (zh) * | 2006-04-25 | 2006-11-22 | 南京大学 | 一种含季胺基复合功能超高交联吸附树脂及其制备方法 |
Non-Patent Citations (1)
Title |
---|
王学江等.氨基修饰聚苯乙烯树脂对酚酸物质的吸附性能.《高分子学报》.2005,(第1期),93-97. * |
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CN101804331A (zh) | 2010-08-18 |
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Address after: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee after: Jiangsu Polytechnic University Address before: 213016 Baiyun District, Changzhou, Jiangsu Patentee before: Jiangsu Polytechnic University |
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Effective date of registration: 20151021 Address after: Daitou town of Liyang City Ferry Street 213311 Jiangsu city of Changzhou province 8-2 No. 7 Patentee after: Liyang Chang Technology Transfer Center Co., Ltd. Address before: Gehu Lake Road Wujin District 213164 Jiangsu city of Changzhou province No. 1 Patentee before: Jiangsu Polytechnic University |