CN101768499B - Lipid type antirust oil with gaseous phase antirust function - Google Patents
Lipid type antirust oil with gaseous phase antirust function Download PDFInfo
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- CN101768499B CN101768499B CN 201010100937 CN201010100937A CN101768499B CN 101768499 B CN101768499 B CN 101768499B CN 201010100937 CN201010100937 CN 201010100937 CN 201010100937 A CN201010100937 A CN 201010100937A CN 101768499 B CN101768499 B CN 101768499B
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- oil
- antirust
- gaseous phase
- grease
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- 239000007792 gaseous phase Substances 0.000 title claims abstract description 12
- 150000002632 lipids Chemical class 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004519 grease Substances 0.000 claims description 30
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 30
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- 241000158728 Meliaceae Species 0.000 claims description 9
- 239000012528 membrane Substances 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 239000011575 calcium Substances 0.000 claims description 7
- LYFOJMFAKWDWCW-FJHGATQLSA-N C(CCCCCCCCCCCCCCCCC)N.C(CCCCCCC\C=C/CCCCCCCC)(=O)N([C@@H](CCO)C(=O)O)CCC Chemical compound C(CCCCCCCCCCCCCCCCC)N.C(CCCCCCC\C=C/CCCCCCCC)(=O)N([C@@H](CCO)C(=O)O)CCC LYFOJMFAKWDWCW-FJHGATQLSA-N 0.000 claims description 6
- WERKSKAQRVDLDW-ANOHMWSOSA-N [(2s,3r,4r,5r)-2,3,4,5,6-pentahydroxyhexyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO WERKSKAQRVDLDW-ANOHMWSOSA-N 0.000 claims description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 6
- 239000012964 benzotriazole Substances 0.000 claims description 6
- 239000003112 inhibitor Substances 0.000 claims description 6
- 229940099259 vaseline Drugs 0.000 claims description 6
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 229920003987 resole Polymers 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 150000003852 triazoles Chemical class 0.000 claims description 5
- 239000012808 vapor phase Substances 0.000 claims description 5
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 239000013556 antirust agent Substances 0.000 abstract 2
- 238000005336 cracking Methods 0.000 abstract 1
- 125000003473 lipid group Chemical group 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 29
- 230000005764 inhibitory process Effects 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- -1 ferrous metals Chemical class 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 241000122205 Chamaeleonidae Species 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Abstract
The invention discloses a lipid type antirust oil with gaseous phase antirust function; the composition of the lipid type antirust oil in weight percent is as follows: 70-90% of base lipid, 4-15% of antirust agent, 1-5% of gaseous phase antirust agent and 5-10% of oil film modifying agent; the inventive antirust oil has long protection period, sun and rain exposure resistance, non-leakage at high temperature, non-cracking at low temperature, transparent and soft oil film, good paintability, and easy removal, and is mainly applied for antirusting for various metalwares, precise instruments, mechanical equipments, metal rotation sequence of workshops in machining industry, etc.
Description
Technical field
The invention belongs to chemical field, especially a kind of grease type rust preventing oil with gaseous phase antirust function.
Background technology
Along with China's mechanical processing industry develop, import and export the increasing of equipment rapidly, antirust grease plays very important effect in machinofacture, transportation, storage and normal operation.Metallic substance and the mechanical means overwhelming majority be take iron as main, and the cast iron in the ferrous metal, carbon steel and low alloy steel etc. gets rusty easily especially, and the non-ferrous metals such as copper, magnesium also are easy to corrosive chameleon.Surface oxidisation can make the performance of metal products and mechanical means and commodity value be subject to very big infringement, even can cause significant trouble and make equipment scrapping.
China's mechanical processing industry often uses butter for a long time, machinery oil, and Vaseline, the grease that this class such as paraffin does not possess special-purpose antirust technology performance is used as metal rust preventing, and this series products the oil film drying shrinkage can occur after use, and sclerosis is difficult for the problems such as removal.In the situation that more abominable being difficult to of environment for use has rust-proof effect.Chinese patent CN1385507A discloses a kind of rust-resistant cream, the product produced in conventional processes mixes calcium grease, lithium saponify, sodium-base grease, butter and gasoline or diesel oil, although this type of rust-resistant cream is easily produced, but do not add rust-preventive agent, rustless property is not good.Chinese patent CN101381650A discloses a kind of long-acting rust-proof grease, although product has good rustless property, the adipose membrane performance is general, and has used the barium mahogany sulfonate composition, makes product have certain toxicity.Chinese patent CN1102855A discloses a kind of metal rust-proof grease, although product has improved the adipose membrane performance, uses formaldehyde as sanitas, and contaminate environment is toxic.
Summary of the invention
The object of the invention is to, provide a kind of and added adipose membrane properties-correcting agent and with the grease type rust preventing oil of gaseous phase antirust function.
The present invention is achieved through the following technical solutions.
A kind of grease type rust preventing oil with gaseous phase antirust function, its component and weight percent thereof are:
Basic grease 70～90%
Rust-preventive agent 4～15%
Vapor phase inhibitor 1～5%
Adipose membrane properties-correcting agent 5～10%.
Described basic grease is selected from Vaseline or machinery oil, perhaps the mixture between them.Vaseline is medical grade Vaseline.Machinery oil is the 22# machinery oil.
Described rust-preventive agent is selected from the mixture of a kind of in the rust-preventive agent such as petroleum sodium sulfonate, calcium mahogany sulfonate, barium mahogany sulfonate, sorbitol monooleate, lanolin magnesium soap, naphthenic soap, N-oleoyl propylhomoserin stearylamine salt, benzotriazole, methyl benzotriazazole or four kinds.Be preferably calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole.
Described calcium mahogany sulfonate be rust-preventive agent be again detergent-dispersant additive, rust-proof effect is similar to barium mahogany sulfonate, and nontoxic, has in the good acid and performance and certain characteristic of solubilizing.
Described sorbitol monooleate has good moisture-resistant pattern of fever.
Described N-oleoyl propylhomoserin stearylamine salt has the tensio-active agent of multiple group, not only has a good moisture-resistant hot, and good resistance to salt(spray)fog and sour neutrality are arranged.
The benzotriazole that the present invention selects has good inhibition antirust function to non-ferrous metals such as copper.
Described vapor phase inhibitor is stearylamine or 124 Triazole Tributylamine, the perhaps mixture between them.
Described stearylamine has with the 124 Triazole Tributylamine and contacts antirust and gaseous phase antirust function, can play antirust and gaseous phase antirust function to various metals.
Described adipose membrane properties-correcting agent is stearic acid or resol, perhaps the mixture between them.Stearic acid makes oil film have good application property.
Described resol had both made oil film have good hydrophobicity, and made oil film have good compactness.
Preparation method of the present invention: proportionally basic grease is joined in the reactor, be warmed up to 70 ℃, add adipose membrane properties-correcting agent, stirred 15 minutes, keep 70 ℃ and add successively rust-preventive agent, stirred 30 minutes; To be cooled to 60 ℃, add vapor phase inhibitor, restir got final product in 1 hour.
The present invention has advantages of: anti-Japanese solarization drenches with rain, and high temperature does not run off, and low temperature does not ftracture, and oil film is transparent, soft, and coating is good, easily removes; Added vapor phase inhibitor; make grease type rust preventing oil have certain volatile inhibition concurrently; unique VCI technology; can volatilize at normal temperatures the inhibition particle with rust inhibition; because the vapour-phase inhibitor particle volatility of this technology is higher, as long as its steam-energy gets at and reaches the metallic surface metal is protected.
Embodiment
The preparation of the grease type rust preventing oil of embodiment 1～4 band gaseous phase antirust function of the present invention joins Vaseline and 22# machinery oil in the reactor according to the ratio of table 1, be warmed up to 70 ℃, add stearic acid, resol, stirred 15 minutes, keep 70 ℃, add successively calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole, stirred 30 minutes; To be cooled to 60 ℃, add 124 Triazole fourth triamine and stearylamine, restir got final product in 1 hour.
The composition of table 1 grease type rust preventing oil of the present invention and schedule of proportion thereof.
| The 22# machinery oil | 15 | 11 | 8 | 10 |
| Calcium mahogany sulfonate | 2 | 2 | 1 | 1 |
| Sorbitol monooleate | 2 | 3 | 3 | 2 |
| N-oleoyl propylhomoserin stearylamine salt | 2 | 2.5 | 3 | 1.5 |
| Benzotriazole | 0.4 | 0.6 | 0.8 | 1 |
| 124 Triazole fourth triamine | 1.0 | 0.8 | 0.6 | 0.4 |
| Stearylamine | 0.7 | 1.0 | 1.3 | 1.5 |
| Stearic acid | 2 | 3 | 4 | 5 |
| Resol | 4.9 | 2.1 | 2.3 | 2.6 |
Embodiment 5 grease type rust preventing oil performance index of the present invention detect
According to the test method shown in the table 2, embodiment 3 prepared grease type rust preventing oils are detected, detected result sees Table 2
The performance test results table of table 2 grease type rust preventing oil of the present invention
| Project | Quality index | Test method | Test-results |
| Melt drop temperature ℃ is not less than | 55 | GB/T 8026 | 57 |
| Flash-point ℃ is not less than | 175 | GB/T 3536 | 181 |
| Sludge number, ml is not more than | 0.05 | SH/T 0215 | 0.04 |
| Abradability | Without scar | SH/T 0215 | Without scar |
| Flow down a little, ℃ be not less than | 40 | SH/T 0082 | 43 |
By table 2 data as seen, grease type rust preventing oil of the present invention not only satisfies the technical indicator of L-RK grease type rust preventing oil, and has excellent volatile inhibition, makes the metal that can't apply slushing oil also can obtain corrosion protection.
Embodiment 6 grease type rust preventing oil rustless property simultaneous tests of the present invention
In order to verify that grease type rust preventing oil of the present invention has excellent gaseous phase antirust function, according to SH/T 0660 test method, selected commercially available blue star board LX-85 rust preventing grease, shell Bang Lite board 903 rust preventing greases,, shell Bang Lite board 663 rust preventing greases carry out volatile rust prevention performance simultaneous test.Contrast and experiment sees Table 3
Table 3 volatile rust prevention performance comparative test result table
| The simultaneous test product | Grease type rust preventing oil of the present invention | Blue star board LX-85 rust preventing grease | Shell Bang Lite board 903 rust preventing greases | Shell Bang Lite board 663 rust preventing greases |
| Volatile inhibition SH/T 0660 | Non-corroding | Corrosion is arranged | Corrosion is arranged | Corrosion is arranged |
Can find out grease type rust preventing oil of the present invention from table 2, table 3 data, adipose membrane is transparent, and softness has good workability, sun-resistant drenching with rain, and have excellent volatile inhibition, make the metal that can't apply slushing oil also can obtain corrosion protection.Be particluarly suitable for height damp and hot, long-term antirust use under the severe environment such as high salt fog.
Claims (2)
1. grease type rust preventing oil with gaseous phase antirust function is characterized in that its component and weight percent thereof are:
Described rust-preventive agent is the mixture of calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole;
Described vapor phase inhibitor is the mixture of stearylamine and 124 Triazole Tributylamine;
Described adipose membrane properties-correcting agent is the mixture of stearic acid and resol.
2. grease type rust preventing oil according to claim 1 is characterized in that described basic grease is Vaseline or machinery oil, or the mixture between them.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010100937 CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010100937 CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101768499A CN101768499A (en) | 2010-07-07 |
| CN101768499B true CN101768499B (en) | 2013-01-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010100937 Expired - Fee Related CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101768499B (en) |
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| CN105297059B (en) * | 2015-11-09 | 2018-01-02 | 广东新球清洗科技股份有限公司 | A kind of anti-metal surface oxidation and the agent for carbon hydrogen detergent of discoloration |
| CN105950006A (en) * | 2016-05-27 | 2016-09-21 | 唐世群 | Anti-rusting paint for chemical pipe flanges |
| CN106281597A (en) * | 2016-07-18 | 2017-01-04 | 启东市清汉农副产品专业合作社 | A kind of grease type rust preventing oil |
| CN106635457A (en) * | 2016-11-11 | 2017-05-10 | 成都陵川特种工业有限责任公司 | Cleaning agent for dirt of mechanical device and preparation method of cleaning agent |
| CN110616094A (en) * | 2019-10-12 | 2019-12-27 | 滨州市坤厚工贸有限责任公司 | High-efficiency gas-phase anti-rust oil complexing agent and preparation method thereof |
| CN111117739A (en) * | 2019-12-12 | 2020-05-08 | 沈阳防锈包装材料有限责任公司 | Gas-phase anti-rust oil and preparation method thereof |
| CN112266817A (en) * | 2020-11-14 | 2021-01-26 | 马鞍山中集瑞江润滑油有限公司 | Special anti-rust oil for ultra-low sound bearing |
| CN116179253A (en) * | 2022-12-30 | 2023-05-30 | 富兰克润滑科技（太仓）有限公司 | Rust-proof compound agent of barium-free rust-proof oil, preparation method and barium-free rust-proof oil |
-
2010
- 2010-01-25 CN CN 201010100937 patent/CN101768499B/en not_active Expired - Fee Related
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