CN101717131B - 一种双甘膦废水的处理方法 - Google Patents
一种双甘膦废水的处理方法 Download PDFInfo
- Publication number
- CN101717131B CN101717131B CN200910230008A CN200910230008A CN101717131B CN 101717131 B CN101717131 B CN 101717131B CN 200910230008 A CN200910230008 A CN 200910230008A CN 200910230008 A CN200910230008 A CN 200910230008A CN 101717131 B CN101717131 B CN 101717131B
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- CN
- China
- Prior art keywords
- phosphonomethyl
- iminodiacetic acid
- acid wastewater
- sodium nitrite
- youxiaolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002351 wastewater Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 32
- FDQQNNZKEJIHMS-UHFFFAOYSA-N 3,4,5-trimethylphenol Chemical compound CC1=CC(O)=CC(C)=C1C FDQQNNZKEJIHMS-UHFFFAOYSA-N 0.000 title claims abstract description 22
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 38
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 24
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 19
- 238000001704 evaporation Methods 0.000 claims abstract description 15
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011780 sodium chloride Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 7
- 239000012141 concentrate Substances 0.000 claims abstract description 3
- 238000002425 crystallisation Methods 0.000 claims description 11
- 230000008025 crystallization Effects 0.000 claims description 11
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 2
- 239000011555 saturated liquid Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 13
- 230000008020 evaporation Effects 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 10
- 238000007254 oxidation reaction Methods 0.000 abstract description 9
- 230000003197 catalytic effect Effects 0.000 abstract description 8
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000001914 filtration Methods 0.000 abstract description 7
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- 230000008878 coupling Effects 0.000 abstract 1
- 238000010168 coupling process Methods 0.000 abstract 1
- 238000005859 coupling reaction Methods 0.000 abstract 1
- 238000004065 wastewater treatment Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 10
- 230000000694 effects Effects 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- 230000001590 oxidative effect Effects 0.000 description 6
- 239000006200 vaporizer Substances 0.000 description 6
- 239000005562 Glyphosate Substances 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 4
- 229940097068 glyphosate Drugs 0.000 description 4
- 239000002917 insecticide Substances 0.000 description 4
- 239000010413 mother solution Substances 0.000 description 4
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 235000019600 saltiness Nutrition 0.000 description 3
- 238000004821 distillation Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- -1 after stirring Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000003851 biochemical process Effects 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
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- Treatment Of Water By Oxidation Or Reduction (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
Abstract
Description
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN200910230008A CN101717131B (zh) | 2009-11-04 | 2009-11-04 | 一种双甘膦废水的处理方法 |
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CN200910230008A CN101717131B (zh) | 2009-11-04 | 2009-11-04 | 一种双甘膦废水的处理方法 |
Publications (2)
Publication Number | Publication Date |
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CN101717131A CN101717131A (zh) | 2010-06-02 |
CN101717131B true CN101717131B (zh) | 2012-10-10 |
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CN200910230008A Active CN101717131B (zh) | 2009-11-04 | 2009-11-04 | 一种双甘膦废水的处理方法 |
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102153224A (zh) * | 2011-03-15 | 2011-08-17 | 常州市国宇环保科技有限公司 | 羧甲基纤维素钠工业污水处理工艺 |
CN102153225B (zh) * | 2011-03-15 | 2013-08-14 | 常州市国宇环保科技有限公司 | 羧甲基纤维素钠工业污水处理装置 |
CN102180559A (zh) * | 2011-03-15 | 2011-09-14 | 常州市国宇环保科技有限公司 | 羧甲基纤维素钠工业污水处理工艺中蒸发器的控制方法 |
CN103601331B (zh) * | 2013-11-27 | 2014-08-20 | 京博农化科技股份有限公司 | 一种农化高浓含盐废水处理工艺 |
CN104724872B (zh) * | 2013-12-24 | 2017-09-15 | 上海泰禾国际贸易有限公司 | 从生产苯氧乙酸类农药的废水中回收氯化钠的方法 |
CN104478151B (zh) * | 2014-12-18 | 2016-08-24 | 重庆海洲化学品有限公司 | 含烧碱次氯酸钠废液的环保处理方法 |
CN105819469B (zh) * | 2016-03-14 | 2018-01-12 | 安徽华星化工有限公司 | 一种利用高温催化氧化处理双甘膦废盐的方法 |
-
2009
- 2009-11-04 CN CN200910230008A patent/CN101717131B/zh active Active
Non-Patent Citations (1)
Title |
---|
董文庚等.次氯酸钠氧化预处理草甘膦生产废水.《化工环保》.1996,第16卷(第5期),第280-283页. * |
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CN101717131A (zh) | 2010-06-02 |
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Owner name: SHANDONG CHAMBROAD HOLDING CO., LTD. Free format text: FORMER OWNER: SHANDONG JINGBO HOLDING DEVELOPMENT CO., LTD. Effective date: 20110822 Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD AGROCHEMICAL CO., LTD. |
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Effective date of registration: 20110822 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Applicant after: SHANDONG CHAMBROAD HOLDING Co.,Ltd. Co-applicant after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Applicant before: SHANDONG JINGBO HOLDING DEVELOPMENT Co.,Ltd. Co-applicant before: Shandong Jingbo Agrochemicals Co.,Ltd. |
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Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD HOLDING CO., LTD. Effective date: 20130426 Free format text: FORMER OWNER: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Effective date: 20130426 |
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Effective date of registration: 20130426 Address after: 256500 Boxing Economic Development Zone, Binzhou, Shandong Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee before: SHANDONG CHAMBROAD HOLDING Co.,Ltd. Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
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Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. Address before: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |
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Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Address before: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee before: JINGBO AGROCHEMICALS TECHNOLOGY Co.,Ltd. |