CN101703050A - Insecticidal composite containing chlorantraniliprole and organic phosphorus - Google Patents
Insecticidal composite containing chlorantraniliprole and organic phosphorus Download PDFInfo
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- CN101703050A CN101703050A CN200910223712A CN200910223712A CN101703050A CN 101703050 A CN101703050 A CN 101703050A CN 200910223712 A CN200910223712 A CN 200910223712A CN 200910223712 A CN200910223712 A CN 200910223712A CN 101703050 A CN101703050 A CN 101703050A
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Abstract
The invention relates to an insecticidal composite which includes chlorantraniliprole belonging to anthranilic diamides insecticides and at least one compound selected from organic phosphorus insecticide: chlorpyrifos, quinalphos, profenofos and triazophos. The composite can be processed into water emulsions water dispersible granules micro-capsules and suspending agents. Field experiments on different control objects are conducted, the results show that the insecticidal composite has high insecticidal efficiency and wide control range, and can effectively control main pests such as rice stem borers, rice planthoppers, beet armyworms, diamondback moths and the like harmful to multiple crops.
Description
Technical field
The present invention relates to a kind of Pesticidal combination and application thereof in the pesticide field, especially a kind of Pesticidal combination and application thereof that contains Rynaxypyr and organophosphorus insecticide.
Background technology
Rynaxypyr:
Rynaxypyr is a kind of new drug of du pont company exploitation, and is environmentally safe, to the little poison of aquatile, honeybee and people.Its insecticidal mechanism is by activating the ryania acceptor in the insect muscle, cause the internal calcium ion unrestrictedly to discharge, stop contraction of muscle, thereby make insect stop to get food rapidly, muscular paralysis, vigor disappearance, paralysis occurring, until thorough death.Insect eats paralysis from getting, and stops harm, only needs about 7 minutes time.Rynaxypyr can be prevented and treated multiple lepidoptera pest, and especially the insect to conventional pesticide generation resistance has special efficacy.In China, because Rynaxypyr import price height, therefore peasant's drug cost height can not use in the crop pests control widely.
Organophosphorous pesticide of the present invention, comprise chlopyrifos, quinalphos, Profenofos, Hostathion etc., main insecticidal mechanism is: suppressing in the insect bodies is that " acetylcholinesterase (AChE) " or " cholinesterase " activity (ChE) in the nerve destroyed normal nerve impulse conduction, causes a series of poisoning symptoms of insect and arrive death.
Active ingredient Rynaxypyr and organophosphorous pesticide are composite, and the two mechanism of action difference can be complementary.
Chlopyrifos: O, O-diethyl-O-3,5,6-trichloro-2-pyridyl phosphorothionate is a kind of broad-spectrum organic insecticide, and its mechanism of action is an acetylcholine esterase inhibition, have tag, stomach toxicity and stifling three kinds of modes of action, insecticidal spectrum is wide, toxicity is lower, is one of main insecticide of control grain, fruit tree, vegetables and other economic crops insect pest, to user's safety.
Quinalphos: O, O-diethyl-O-(2-diethquinalphione) thiophosphate has desinsection, acaricidal action, have stomach toxicity and action of contace poison, do not inhale and stifling performance in not having, good penetration is arranged on plant, certain ovicidal action is arranged, and degradation speed is fast on plant, and the longevity of residure is short.Be applicable to the control of various pests on paddy rice, cotton, fruit tree, the vegetables.
Profenofos: Profenofos is a broad-spectrum organophosphorous pesticide, is a kind of anticholinesterase, have tag, stomach poison function and interior absorption, be mainly used in the lepidoptera pest of control paddy rice, cotton and vegetable field, degraded easily in environment.
Hostathion: Hostathion is a kind of broad-spectrum organophosphorous pesticide, miticide, has strong tagging and stomach poison function, good disinsection effect, and ovicidal action is obvious, and permeability is stronger, no systemic action.Be used for various crop such as paddy rice and prevent and treat various pests.Be mainly used in the lepidoptera pest on control paddy rice, fruit tree, cotton and the grain class crop.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, have the complex preparation of notable synergistic effect, and can produce high insecticidal effect, drug cost is low, and can delay the resistance of insecticide.Technical scheme of the present invention is as follows:
A kind of Pesticidal combination is characterized in that, comprises two active components.First active ingredient is to activate calcium release channel in blue Buddhist nun's alkali recipient cell, causes storing the O-formammidotiazol-benzamide insecticide Rynaxypyr of the property out of control release of calcium ion; The second active component B is a kind of organophosphorus insecticides, and wherein organophosphorus insecticide is a kind of of chlopyrifos, quinalphos, Profenofos and Hostathion.
Must the measuring than being 3～70 of the first active component Rynaxypyr and the second active component B in the Pesticidal combination: 5～80, be preferably 8～30: 5～40.The formulation that insecticides of the present invention can be prepared according to the known method of those skilled in the art of the present technique is missible oil, aqueous emulsion, water-dispersible granules, microcapsule formulations and suspending agent.
One of technical scheme of the present invention, described Pesticidal combination are cream preparation, and the percentage by weight of component is:
Rynaxypyr 3～70%
Active ingredient B 5～80%
Conventional emulsifier 10～30%
Conventional solvent 20～50%
Conventional synergist 1～5%
The concrete production stage of this cream preparation adds emulsifier, the synergist back that stirs after the dissolving fully again and becomes the oily liquids of transparent and homogeneous for earlier Rynaxypyr, active ingredient B being added in the solvent, can promptly makes the cream preparation that contains the Rynaxypyr Pesticidal combination of the present invention.
Two of technical scheme of the present invention, described Pesticidal combination are aqueous emulsion, and the percentage by weight of component is:
Rynaxypyr 3～70%
Active ingredient B 5～80%
Emulsifier 3～30%
Solvent 5～15%
Antimicrobial 0.1～1%
Stabilizing agent 2～15%
Antifreezing agent 2～5%
Defoamer 0.1～8%
Thickener 0.2～2%
Water surplus
The concrete production stage of this aqueous emulsion is: at first former medicine Rynaxypyr is added with active ingredient B, solvent and emulsifier, cosolvent and be in the same place, make and be dissolved into uniform oil phase; With part water, antifreeze, other insecticides adjuvant such as antimicrobial mixes into uniform water; When the reactor high speed stirs, oil phase is added water, slowly add water, open clipper and carry out high speed shear, and add remaining water, shear half an hour approximately, form the aqueous emulsion of oil-in-water type until reaching the phase inversion point.Promptly make the aqueous emulsion that contains the Rynaxypyr Pesticidal combination.
Three of technical scheme of the present invention, described Pesticidal combination are water dispersible granules, and the percentage by weight of component is:
Rynaxypyr 3～70%,
Active ingredient B 5～80%
Dispersant 3～10%
Wetting agent 1～10%
Disintegrant 1～5%
The filler surplus.
The concrete production stage of this water dispersible granules is: by above-mentioned prescription Rynaxypyr, active ingredient B and dispersant, wetting agent, disintegrant and filler are mixed, pulverize with micro jet, through mediating, add then and carry out granulation, drying, screening in the fluidized bed prilling dryer after sample analysis makes the water dispersible granules that contains the Rynaxypyr Pesticidal combination of the present invention.
Four of technical scheme of the present invention, described Pesticidal combination are microcapsule formulations, and the percentage by weight of component is:
Rynaxypyr 3～70%
Active ingredient B 5～80%
Urea 5～20%
Formaldehyde 10～30%
Emulsifying dispersant 5～20%
Antifreezing agent 1～5%
Thickener 0.1～2%
Antimicrobial 0.1～1%
Stabilizing agent 2～15%
Defoamer 0.1～0.8%
Water surplus
In the there-necked flask of agitating device is housed, add urea and formaldehyde (amount of substance ratio be about 1: 1.5～2.0), about pH value to 8～9, be warming up to 70～80 ℃ then, react and obtain stable urea resin prepolymer with the sodium hydroxide solution regulator solution.The former medicine of getting a certain amount of Rynaxypyr and active ingredient B is dissolved in the cyclohexane, and adds emulsifying dispersant in solution, follows vigorous stirring, and being made into the aqueous solution that contains emulsifying dispersant is the O/W type stable emulsion of water.Above-mentioned urea resin prepolymer is added in the emulsion, regulate the pH value, polymerization reaction take place under the acid catalysis condition is wrapped oil phase substance, forms microcapsule granule.Slowly heat up, solidify, temperature is controlled at 40～50 ℃, hardening time 1h.Select to add an amount of auxiliary agent, the microcapsule suspending agent that gets final product stablely.
Five of technical scheme of the present invention, described Pesticidal combination are suspending agent, and the percentage by weight of component is:
Rynaxypyr 3～70%
Active ingredient B 5～80%
Dispersant 5～20%
Antifreezing agent 1～5%
Stabilizing agent 2～15%
Thickener 0.1～2%
Defoamer 0.1～0.8%
Water surplus
The concrete production stage of this suspending agent is earlier other auxiliary agents to be mixed, mix through high speed shear, add Rynaxypyr and active ingredient B, abrading-ball is 2～3 hours in ball crusher, make a diameter all below 5mm, make the suspending agent preparation that contains the Rynaxypyr Pesticidal combination of the present invention.
The described active ingredient B of this Pesticidal combination is meant organophosphorus insecticide, and wherein organophosphorus insecticide is meant a kind of in chlopyrifos, quinalphos, Profenofos, the Hostathion.
Described conventional emulsifier is selected from any one or more mixtures formed with arbitrary proportion in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styryl phenol APEO, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, the polyoxyethylene aliphatic alcohol ether.
Described conventional solvent is any one or more mixed solvents formed with arbitrary proportion in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), the water equal solvent.
Described conventional synergist is meant to have the medicament of enhancing penetration, wetting extended capability, knock down insect speed, improve the resistance of rainwater washing against power of agricultural chemicals, thereby improve a class safety, environmental protection of agricultural insecticide, desinsection, bactericidal effect, the New-type adjuvant of nontoxic, noresidue, optional in organic silicon pesticide synergist ZC-650 or organic silicon pesticide bleeding agent spreading agent Agrowet810c, agricultural organic silicon pesticide synergist Silwet408, azone any.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, the fatty acid glyceride APEO.
The choosing of described wetting agent is white: lauryl sodium sulfate, DBSA, Nekal BX., among the wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder one or more.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, the sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, the polyvinyl alcohol.
Described antifreeze is selected from: one or more in ethylene glycol, propane diols, the glycerine.
Described stabilizing agent is selected from: pentaerythrite, xylitol, mannitol a kind of.
Described antimicrobial is selected from: one or both in Sodium Benzoate, sodium salicylate, the sodium sorbate.
Described defoamer is selected from: silicone oil, silicone compound, C
10-20Saturated fat acid compounds, C
8-10In the aliphatic alcohols compound one or more.
Described emulsifying dispersant comprises: dispersant, wetting agent, antimicrobial, stabilizing agent, thickener, defoamer and antifreezing agent etc.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, the precipitated calcium carbonate.
It is remarkable that described Pesticidal combination is used to prevent and treat apple spot fallen leaves, rice sheath blight disease, citrus anthracnose effect, compares with single agent, has obvious synergistic effect.
The present invention has following characteristics:
1. double action mechanism, insect are difficult for producing resistance;
2. synergistic effect is obvious, component of the present invention is reasonable, drug effect is high, use cost is low, synergistic effect is obvious, and the present invention is to drug effect height such as rice grub such as striped rice borer, rice fulgorid and rice leaf roller, and can effectively prevent and treat primary pests such as diamond-back moth, beet armyworm on fruit tree, the vegetables;
3. active ingredient novel phthalic amide insecticides Rynaxypyr and conventional organic phosphorous built are efficient equally to the insect of conventional pesticide generation resistance;
4. genus environment friendly agricultural, Rynaxypyr and chlopyrifos, quinalphos, Profenofos, Hostathion all belong to the agricultural chemicals to the person poultry safety in the scope of application, its complex preparation, high-efficiency low-toxicity to crop and Environmental security, helps the sustainable development of agricultural production.
Specific embodiment
Further explain content of the present invention with following embodiment, but do not limit the scope of the invention.
Example of formulations 1: fluorine worm benzamide 5g, chlopyrifos 50g, emulsifier 15g, stabilizing agent 5g, the solvent polishing is to 100g.Make 55% fluorine worm benzamide chlorpyrifos ec preparation through above-mentioned missible oil procedure of processing.
Example of formulations 2: fluorine worm benzamide 10g, quinalphos 40g, emulsifier 15g, stabilizing agent 5g, the solvent polishing is to 100g.Through above-mentioned missible oil procedure of processing make 50% fluorine worm benzamide chlorpyrifos ec preparation.
Example of formulations 3: fluorine worm benzamide 20g, Profenofos 30g, emulsifier 15g, stabilizing agent 5g, the solvent polishing is to 100g.Through above-mentioned missible oil procedure of processing make 50% fluorine worm benzamide Profenofos cream preparation.
Example of formulations 4: fluorine worm benzamide 40g, chlopyrifos 10g, solvent 20g, emulsifier 10g, cosolvent 5g, dispersant 5g, antifreezing agent 2g, defoamer 2g adds the water polishing to 100g.Make homodisperse 50% fluorine worm benzamide chlorpyrifos aqueous emulsion through above-mentioned aqueous emulsion procedure of processing.
Example of formulations 5: fluorine worm benzamide 20g, quinalphos 20g, solvent 20g, emulsifier 10g, cosolvent 5g, dispersant 5g, antifreezing agent 2g, defoamer 2g adds the water polishing to 100g.Make homodisperse 40% fluorine worm benzamide quinalphos aqueous emulsion through above-mentioned aqueous emulsion procedure of processing.
Example of formulations 6: fluorine worm benzamide 15g, Hostathion 20g, solvent 20g, emulsifier 10g, cosolvent 5g, dispersant 5g, antifreezing agent 2g, defoamer 2g adds the water polishing to 100g.Make homodisperse 35% fluorine worm benzamide aqueous emulsion of triazophos through above-mentioned aqueous emulsion procedure of processing.
Example of formulations 7: fluorine worm benzamide 50g, Hostathion 10g, sodium lignin sulfonate 15g, naphthalenesulfonate formaldehyde condensation compound 15g, disintegrant 2g, kaolin or bentonite surplus.Through above-mentioned water dispersible granules procedure of processing, make 60% fluorine worm benzamide Hostathion water dispersible granules.
Example of formulations 8: fluorine worm benzamide 30g, quinalphos 10g, sodium lignin sulfonate 15g, naphthalenesulfonate formaldehyde condensation compound 15g, disintegrant 2g, kaolin or bentonite surplus.Through above-mentioned water dispersible granules procedure of processing, make 40% fluorine worm benzamide quinalphos water dispersible granules.
Example of formulations 9: fluorine worm benzamide 20g, Profenofos 10g, sodium lignin sulfonate 15g, naphthalenesulfonate formaldehyde condensation compound 15g, disintegrant 2g, kaolin or bentonite surplus.Through above-mentioned water dispersible granules procedure of processing, make 30% fluorine worm benzamide Profenofos water dispersible granules.
Example of formulations 10: fluorine worm benzamide 40g, chlopyrifos 10g, alkylol 20g, sodium lignin sulfonate 15g, ethylene glycol 8g, xanthans 1.7g, organosilicon 0.3g, deionized water 20g through above-mentioned suspending agent procedure of processing, makes 50% fluorine worm benzamide chlopyrifos suspending agent.
Example of formulations 11: fluorine worm benzamide 20g, chlopyrifos 10g, alkylol 20g, sodium lignin sulfonate 15g, ethylene glycol 8g, xanthans 1.7g, organosilicon 0.3g, deionized water 20g through above-mentioned suspending agent procedure of processing, makes 30% fluorine worm benzamide chlopyrifos suspending agent.
Example of formulations 12: fluorine worm benzamide 20g, Hostathion 20g, alkylol 20g, sodium lignin sulfonate 15g, ethylene glycol 8g, xanthans 1.7g, organosilicon 0.3g, deionized water 20g through above-mentioned suspending agent procedure of processing, makes 40% fluorine worm benzamide Hostathion suspending agent.
Biological Examples 1:
The cream preparation of above-mentioned example of formulations 1-3 is converted 3000 times of water dilutions, clear water compares, at paddy rice rice leaf roller initial stage spray medicine, example of formulations 2 and example of formulations 3 behind medicine 1 day preventive effect up to 80%, 3 days insects are gone down rate up to 95% behind the medicine, preventive effect is 91%, and 7 days preventive effects are 98% behind the medicine.
Biological Examples 2:
The aqueous emulsion preparation of above-mentioned example of formulations 4-6 is converted 3000 times of water dilutions, and clear water compares, at paddy rice rice leaf roller initial stage spray medicine, three kinds of medicaments behind medicine 1 day preventive effect all up to 82%, 3 days insects are gone down rate up to 93% behind the medicine, and preventive effect is 92%, 7 days preventive effect average out to 98% behind the medicine.
Biological Examples 3:
The water-dispersible grain agent formulation of above-mentioned example of formulations 7-9 is converted 3000 times of water dilutions, clear water compares, at paddy rice rice leaf roller high-incidence season spray medicine, three kinds of medicaments behind medicine 1 day preventive effect all up to 85%, 3 days insects are gone down rate up to 97% behind the medicine, preventive effect is 90%, 7 days preventive effect average out to 95% behind the medicine.
Biological Examples 4:
The suspending agent preparation of above-mentioned example of formulations 10-12 is converted 3000 times of water dilutions, and clear water compares, at paddy rice rice leaf roller high-incidence season spray medicine, three kinds of medicaments behind medicine 1 day preventive effect all up to 86%, 3 days insects are gone down rate up to 92% behind the medicine, and preventive effect is 90%, 7 days preventive effect average out to 96% behind the medicine.
Claims (6)
1. Pesticidal combination, it is characterized in that: this Pesticidal combination contains Rynaxypyr and active component B, and the weight ratio between two kinds of active components is 1～70: 5～80;
2. according to the described Pesticidal combination of claim 1, it is characterized in that: active component B is selected from a kind of of organophosphorus insecticide chlopyrifos, quinalphos, Profenofos, Hostathion;
3. according to the described Pesticidal combination of claim 1, it is characterized in that: the weight ratio between two kinds of active components of the described organophosphorus insecticide of component Rynaxypyr and B component is 3～50: 10～60;
4. according to the described Pesticidal combination of claim 2, it is characterized in that: the mass percent that two kinds of active components of the described organophosphorus insecticide Pesticidal combination of component Rynaxypyr and B component are accumulated shared total preparation is 5%～70%;
5. according to the described Pesticidal combination of claim 1, it is characterized in that: composition can be processed into aqueous emulsion, water-dispersible granules, microcapsule formulations, suspending agent;
6. according to claim 1,2 or 3 described Pesticidal combinations, it is characterized in that: the primary pest that can be used to prevent and treat various crop such as the snout moth's larva of rice, rice fulgorid, beet armyworm, diamond-back moth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN200910223712A CN101703050A (en) | 2009-11-18 | 2009-11-18 | Insecticidal composite containing chlorantraniliprole and organic phosphorus |
Applications Claiming Priority (1)
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| CN200910223712A CN101703050A (en) | 2009-11-18 | 2009-11-18 | Insecticidal composite containing chlorantraniliprole and organic phosphorus |
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Cited By (11)
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| CN102047908A (en) * | 2011-01-21 | 2011-05-11 | 中国水稻研究所 | Chlorantraniliprole and quintiofos compound pesticide |
| CN102047906A (en) * | 2011-01-21 | 2011-05-11 | 中国水稻研究所 | Chlorantraniliprole and profenofos compound pesticide |
| CN102067877A (en) * | 2011-01-21 | 2011-05-25 | 中国水稻研究所 | Chlorantraniliprole and fenitrothion complex pesticide |
| CN102113515A (en) * | 2011-01-14 | 2011-07-06 | 潍坊市信得生物科技有限公司 | Chlorpyrifos-chlorantraniliprole water emulsion and preparation method thereof |
| CN102907456A (en) * | 2012-11-06 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide combination containing ZJ3757 and profenofos |
| CN103039501A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 |
| CN103120184A (en) * | 2012-06-01 | 2013-05-29 | 北京明德立达农业科技有限公司 | Fosthiazate pesticide composition and application thereof |
| CN104957172A (en) * | 2015-06-24 | 2015-10-07 | 浙江省化工研究院有限公司 | Insecticide composition containing quinalphos and cyhalodiamide |
| CN105707119A (en) * | 2016-04-15 | 2016-06-29 | 杭州宇龙化工有限公司 | Agricultural insecticidal combination containing HY366 and chlorpyrifos and application thereof |
| CN111406760A (en) * | 2019-12-30 | 2020-07-14 | 金华市农业科学研究院 | Synergistic pesticide composition, preparation method and application thereof |
| CN114901074A (en) * | 2019-12-31 | 2022-08-12 | 阿达玛马克西姆有限公司 | Insecticide mixtures |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102113515A (en) * | 2011-01-14 | 2011-07-06 | 潍坊市信得生物科技有限公司 | Chlorpyrifos-chlorantraniliprole water emulsion and preparation method thereof |
| CN102067877B (en) * | 2011-01-21 | 2013-04-24 | 中国水稻研究所 | Chlorantraniliprole and fenitrothion complex pesticide |
| CN102067877A (en) * | 2011-01-21 | 2011-05-25 | 中国水稻研究所 | Chlorantraniliprole and fenitrothion complex pesticide |
| CN102047906A (en) * | 2011-01-21 | 2011-05-11 | 中国水稻研究所 | Chlorantraniliprole and profenofos compound pesticide |
| CN102047908A (en) * | 2011-01-21 | 2011-05-11 | 中国水稻研究所 | Chlorantraniliprole and quintiofos compound pesticide |
| CN103120184A (en) * | 2012-06-01 | 2013-05-29 | 北京明德立达农业科技有限公司 | Fosthiazate pesticide composition and application thereof |
| CN102907456A (en) * | 2012-11-06 | 2013-02-06 | 中化蓝天集团有限公司 | Pesticide combination containing ZJ3757 and profenofos |
| CN103039501A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 |
| CN103039501B (en) * | 2013-01-06 | 2014-06-04 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 |
| CN104957172A (en) * | 2015-06-24 | 2015-10-07 | 浙江省化工研究院有限公司 | Insecticide composition containing quinalphos and cyhalodiamide |
| CN105707119A (en) * | 2016-04-15 | 2016-06-29 | 杭州宇龙化工有限公司 | Agricultural insecticidal combination containing HY366 and chlorpyrifos and application thereof |
| CN105707119B (en) * | 2016-04-15 | 2018-04-20 | 杭州宇龙化工有限公司 | A kind of agricultural pesticide composition containing sulphur insect amide and chlopyrifos and application thereof |
| CN111406760A (en) * | 2019-12-30 | 2020-07-14 | 金华市农业科学研究院 | Synergistic pesticide composition, preparation method and application thereof |
| CN114901074A (en) * | 2019-12-31 | 2022-08-12 | 阿达玛马克西姆有限公司 | Insecticide mixtures |
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Application publication date: 20100512 |