CN101701129A - High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating - Google Patents

High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating Download PDF

Info

Publication number
CN101701129A
CN101701129A CN200910272845A CN200910272845A CN101701129A CN 101701129 A CN101701129 A CN 101701129A CN 200910272845 A CN200910272845 A CN 200910272845A CN 200910272845 A CN200910272845 A CN 200910272845A CN 101701129 A CN101701129 A CN 101701129A
Authority
CN
China
Prior art keywords
coating
acrylate
functionality
percent
nano
Prior art date
Application number
CN200910272845A
Other languages
Chinese (zh)
Inventor
廖春花
张淑娴
汤兴国
Original Assignee
武汉嘉特利佰联创科技有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 武汉嘉特利佰联创科技有限公司 filed Critical 武汉嘉特利佰联创科技有限公司
Priority to CN200910272845A priority Critical patent/CN101701129A/en
Publication of CN101701129A publication Critical patent/CN101701129A/en

Links

Abstract

The invention relates to a light solidifying high-abrasion resistant fingerprint resistant coating which is used for the surfaces of plastic shells of portable electronic products, such as mobile phones, MP3, digital cameras, handheld computers, and the like and comprises the following components: 10-35 percent of high-functionality urethane acrylate, 5-25 percent of bifunctional urethane acrylate, 0.01-20 percent of acrylic ester monomer, 5-20 percent of high-functionality acrylic ester, 5-40 percent of fluorin-contained acrylic ester, 0.01-10 percent of nano inorganic powder filler, 1-5 percent of light initiating agent, 0.01-5 percent of auxiliary agent and 5-30 percent of solvent. The invention improves the fingerprint resistant capability of a coating film by the enrichment and microphase separation of a fluorin-contained group added into the coating on the surface of a coating surface, provides excellent abrasion resistance and hardness by using the polyurethane structure in the coating and the added nano abrasion resistant filler and meets the requirements of abrasion resistance, scratch resistance and fingerprint resistance of the portable electronic products.

Description

High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating

Technical field

The present invention relates to a kind of anti-fingerprint coating of photocuring high abrasion that is used for portable type electronic product plastic casing surfaces such as mobile phone, MP3, digital camera, laptop computer.

Technical background

Ultraviolet-curing paint be a kind of be subjected to UV-irradiation after, the coating of physics and chemical transformation can take place in the short period of time.Compare with traditional seasoning or heat curing coating; ultraviolet-curing paint except have curing speed fast, save the energy, film performance good, to base material applied widely, the volatile solvent consumption is few; also have an outstanding feature: solidification process does not need heating; this for some can not heat-stable plastics, very useful the optics, electronic component, therefore be suitable for very much the protection and the decoration on electronic product plastic casing surfaces such as mobile phone, computer.

Along with social development, the use of portable type electronic products such as mobile phone, MP3, digital camera, laptop computer is more and more frequent, and the human consumer is also more and more higher to the requirement of its outward appearance.Except requiring the attractive in appearance and hand feel and drape of its color, also require its surface abrasion resistance, scratch resistance to hinder to adapt to the needs of carrying.Simultaneously wish that in use product surface has the performance of anti-fingerprintization, just in use product surface is difficult for being stayed after the hand contact vestiges such as water stain, grease, dust, even or also be easy to be removed by wiping after staying spot.

CN1557882A, CN101250340 provide the performance of a kind of ultraviolet-curing paint in order to the anti-fingerprintization of raising plastic casing, but its film performance is difficult to satisfy the high wear-resistant requirement of portable type electronic product.CN1553944A has applied for being used for the anti-fingerprint coating of photocuring and the coating process thereof of coating metal base material, and this coating is not suitable for the ABS or the PC plastic casing of most portable type electronic products.

Summary of the invention

The purpose of this invention is to provide a kind of anti-fingerprint voltinism of rub resistance energy that improves portable type electronic product frostings such as mobile phone, MP3, digital camera, laptop computer, had the photo-cured coating of high-wear resistance simultaneously.

Technical scheme of the present invention is: high-abrasion resistant ultraviolet light solidifying fingerprint resistant coating, comprise: 10~35% high-functionality polyurethane acrylic, 5~25% difunctionality urethane acrylate, 0.01~20% acrylate monomer, 5~20% high functionality acrylate, 5~40% fluorinated acrylate, 0.01~10% nano inorganic powder filler, 1~5% light trigger, 0.01~5% auxiliary agent and 5~30% solvent, above-mentioned per-cent is weight percentage.

High-functionality polyurethane acrylic of the present invention is meant that functionality is 3~9, especially three, six or nine polyurethane acrylate prepolymer, the SM-6318 of Sanmu Group Co., Ltd., Jiangsu (three-functionality-degree) for example, M-80 (six functionality), the M-81 (nine functionality) etc. of Competing company limited.

Two functionality urethane acrylates of the present invention are meant that functionality is two polyurethane acrylate prepolymer, for example get M-60, the M-70 of Competing company limited, the SM-6201 of Sanmu Group Co., Ltd., Jiangsu, SM-6202 etc.

Acrylate monomer of the present invention is: methyl acrylate, ethyl propenoate, vinylformic acid-2-hydroxyl ethyl ester, one or more in butyl acrylate, iso-bornyl acrylate, mono acrylic ester, methyl methacrylate, Jia Jibingxisuanyizhi, butyl methacrylate, the 2-hydroxyethyl methacrylate.

High functionality acrylate of the present invention is meant the acrylate monomer with 2~6 functionality: 1, the 4-butylene glycol diacrylate, 1,6 hexanediol diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, tripropylene glycol diacrylate, PDDA, Viscoat 295, trimethylolpropane trimethacrylate, the third oxidation Viscoat 295, the ethoxyquin Viscoat 295, tetramethylol methane tetraacrylate, in the double pentaerythritol methacrylate one or more.

Fluorinated acrylate of the present invention is: one or more in trifluoromethyl acrylate, methacrylic acid hexafluoro butyl ester, trifluoroethyl methacrylate, methacrylic acid ten difluoro heptyl esters, vinylformic acid hexafluoro butyl ester, dodecafluorhe-ptylacrylate, methacrylic acid ten trifluoro monooctyl esters, vinylformic acid ten trifluoro monooctyl esters, methacrylic acid 17 fluorine monooctyl esters, the vinylformic acid 17 fluorine monooctyl esters.

Nano inorganic powder filler of the present invention is: nano silicon, nano titanium oxide, nano-calcium carbonate, nano zirconium dioxide, nanometer silicon carbide, nano aluminium oxide.

Light trigger of the present invention is: Diisopropyl azodicarboxylate, methyl vinyl ketone, st-yrax, benzophenone, fluorescein, eosin, Benzoin ethyl ether, DEAP, camphorquinone, Alpha-hydroxy isopropyl benzene ketone, Alpha-hydroxy phenylcyclohexane ketone, 2-methyl-4 '-methylthio group-2-morpholinyl Propiophenone, 2,4-diethyl thiazolone etc.

Auxiliary agent of the present invention comprises one or more of following composition: flow agent, defoamer, wetting agent, pigment.

Solvent of the present invention comprises one or more of following composition: vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, dimethylbenzene, toluene, acetone, 4-methyl 2 pentanone, Virahol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, glycol ether, ethylene glycol ether acetate, propylene-glycol ethyl ether acetic ester.

The preparation method of coating of the present invention only need proportionally stir each component of coating and get final product, and can mix with random order.

High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating provided by the invention can be used as the ultraviolet-curing paint of portable type electronic product plastic casing, utilize the fluoro-containing group that adds in this coating to improve the anti-fingerprint ability of filming in the enrichment and the microphase-separated of film coated surface, utilize the polyurethane structural in the coating and the nano wearproof filler of interpolation that excellent abrasive energy and hardness are provided simultaneously, satisfy that portable type electronic product is wear-resisting, scratch resistance is hindered and the requirement of anti-fingerprintization.

The photo-cured coating of the anti-fingerprint of high abrasion provided by the invention has the following advantages:

1. employed high-functionality polyurethane acrylic double bond content is big, bridge formation density height, can form filming of high rigidity, high abrasion; Excellent water tolerance and levelling property are arranged; Adherence to plastics such as ABS and PC is good.

2. add two functionality urethane acrylates and improve the toughness of high-functionality polyurethane, reducing films explosion occurs when " high low-temperature test "; And two the functionality urethane acrylate because double bond content is few, and bridge formation density is low, can effectively reduce " reaction shrink "; The content of " polyurethane structural " of resin is big, can strengthen wear resistance.

3. adding nanometer inorganic filler, nanometer inorganic filler to the enhancing of filming, significantly improves the abrasion property energy under the prerequisite that does not influence the film coated surface glossiness.

4. the high chemical stability that utilizes the low surface energy of fluorinated acrylate, high bond energy and show can improve the ageing-resistant performance of coating.Because the polar difference, fluoro-containing group tends to surface enrichment in film process, even thereby under the less fluorinated acrylate consumption, coatingsurface fluorine content is still higher, greatly reduces the surface energy of filming.The enrichment meeting of fluoro-containing group simultaneously makes the surface form trickle coarse outstanding structure, reduces the contact area of external dirt and film coated surface, and external dirt is difficult for adhering to and easily wiping, has improved its anti-fingerprint performance.

In sum, above-mentioned coating is used for portable type electronic product plastic outer layers such as mobile phone, MP3, digital camera, laptop computer, has improved wear resistance and has given anti-fingerprint voltinism energy.And preparation is simple, only need each component is mixed in proportion, but automatic production, the production efficiency height is easy to scale operation.

Embodiment

Embodiment 1:

With following component: the high-functionality polyurethane acrylic M-80 of six functionality of Competing company limited () 20%; Difunctionality urethane acrylate (getting the M-60 of Competing company limited) 15%; Acrylate monomer (methyl acrylate) 10%; High functionality acrylate (Viscoat 295) 15%; Fluorinated acrylate (vinylformic acid 17 fluorine monooctyl esters) 15%; Nano inorganic powder filler 5% (silicon-dioxide of particle diameter 10~50nm); Light trigger (benzophenone) 2%; Auxiliary agent (flow agent BYK-3060.5%, defoamer BYK-0660.2%, wetting agent BYK-1640.3%) 1%; Solvent (5% vinyl acetic monomer, 5% N-BUTYL ACETATE, 7% 4-methyl 2 pentanone) 17%.Join in the stirring tank, mix, form coating.Above per-cent is weight ratio.

Above paint spay-coating to the ABS base material, is tested film performance behind the ultraviolet light polymerization.Described UV curing method and film performance testing method are known technology in the coating property field tests, do not repeat them here.

Film performance:

1. outward appearance is not had foaming, peels off, and does not have obvious variable color;

2. contact angle is 120 °, has excellent anti-fingerprint;

3. pencil hardness 3H (GB/T6739-96);

4. sticking power 100/100 (GB/T9286-88);

5. wear resistance: RCA abrasion are 1300 times;

6. acid resistance: 5% sulfuric acid soaks 48h does not have considerable change; Alkali resistance: 5%NaOH soaks 48h does not have considerable change: 5%NaCl soaks 48h does not have considerable change.

Embodiment 2:

With following component: the high-functionality polyurethane acrylic M-81 of nine functionality of Competing company limited () 15%; Difunctionality urethane acrylate (getting the M-70 of Competing company limited) 25%; Acrylate monomer (butyl acrylate) 8%; High functionality acrylate (trimethylolpropane trimethacrylate) 5%; Fluorinated acrylate (vinylformic acid 17 fluorine monooctyl esters) 25%; Nano inorganic powder filler (titanium dioxide of particle diameter 20~60nm) 5%; Light trigger (DEAP) 2%; Auxiliary agent (flow agent BYK UV35000.5%, defoamer BYK-0660.2%, wetting agent BYK-1610.3%) 1%; Solvent (3% ethylene glycol monomethyl ether, 5% acetone, 6% 4-methyl 2 pentanone) 14%.Join in the stirring tank, mix, form coating.Above per-cent is weight ratio.

Above paint spay-coating to the ABS base material, is tested film performance behind the ultraviolet light polymerization.

Film performance:

1. outward appearance is not had foaming, peels off, and does not have obvious variable color;

2. contact angle is 140 °, has excellent anti-fingerprint;

3. pencil hardness 2H (GB/T6739-96);

4. sticking power 100/100 (GB/T9286-88);

5. wear resistance: RCA wears away 1400 times (the wear-resisting tester of Norman RCA, load 175g);

6. acid resistance: 5% sulfuric acid soaks 48h does not have considerable change; Alkali resistance: 5%NaOH soaks 48h does not have considerable change: 5%NaCl soaks 48h does not have considerable change.

Embodiment 3:

With following component: high-functionality polyurethane acrylic (SM-6318 of Sanmu Group Co., Ltd., Jiangsu) 25%; Difunctionality urethane acrylate (SM-6201 of Sanmu Group Co., Ltd., Jiangsu) 15%; Acrylate monomer (iso-bornyl acrylate) 5%; High functionality acrylate (tetramethylol methane tetraacrylate) 8%; Fluorinated acrylate (methacrylic acid ten trifluoro monooctyl esters) 20%; Nano inorganic powder filler (particle diameter is 20~30 nano-calcium carbonate) 8%; Light trigger (Alpha-hydroxy phenylcyclohexane ketone) 5%; Auxiliary agent (flow agent BYK 3580.8%, defoamer BYK-0660.2%, wetting agent EFKA-48000.3%, Holliday ultramarine HG 0.5%) 1.8%; Solvent (4% propylene-glycol ethyl ether acetic ester, 5% dimethylbenzene, 3.2% butanols) 12.2%.Join in the stirring tank, mix, form coating.Above per-cent is weight ratio.

Above paint spay-coating to the ABS base material, is tested film performance behind the ultraviolet light polymerization.

Film performance:

1. outward appearance is not had foaming, peels off, and does not have obvious variable color;

2. contact angle is 140 °, has excellent anti-fingerprint;

3. pencil hardness 2H (GB/T6739-96);

4. sticking power 100/100 (GB/T9286-88);

5. wear resistance: RCA wears away 1500 times (the wear-resisting tester of Norman RCA, load 175g);

6. acid resistance: 5% sulfuric acid soaks 48h does not have considerable change; Alkali resistance: 5%NaOH soaks 48h does not have considerable change; Perspiration resistance: 5%NaCl soaks 48h does not have considerable change.

Embodiment 4:

With following component: the high-functionality polyurethane acrylic M-81 of nine functionality of Competing company limited () 20%; Difunctionality urethane acrylate (SM-6202 of Sanmu Group Co., Ltd., Jiangsu) 10%; Acrylate monomer (10% methyl acrylate, 5% butyl acrylate) 15%; High functionality acrylate (ethoxyquin Viscoat 295) 15%; Fluorinated acrylate (methacrylic acid ten difluoro heptyl esters) 20%; Nano inorganic powder filler 5% (particle diameter is the zirconium dioxide of 40~50nm); Light trigger (Alpha-hydroxy isopropyl benzene ketone) 2%; Auxiliary agent (flow agent BYK 3580.8%, defoamer BYK-066 0.2%, wetting agent EFKA-48000.3%, Holliday ultramarine HG 0.5%) 1.8%; Solvent (3% vinyl acetic monomer, 5% N-BUTYL ACETATE, 3.2% ethylene glycol ether acetate) 11.2%.Join in the stirring tank, mix, form coating.Above per-cent is weight ratio.

Above paint spay-coating to the ABS base material, is tested film performance behind the ultraviolet light polymerization.

Film performance:

1. outward appearance is not had foaming, peels off, and does not have obvious variable color;

2. contact angle is 130 °, has excellent anti-fingerprint;

3. pencil hardness 3H (GB/T6739-96);

4. sticking power 100/100 (GB/T9286-88);

5. wear resistance: RCA wears away 1200 times (the wear-resisting tester of Norman RCA, load 175g);

6. acid resistance: 5% sulfuric acid soaks 48h does not have considerable change; Alkali resistance: 5%NaOH soaks 48h does not have considerable change: 5%NaCl soaks 48h does not have considerable change.

Embodiment 5:

With following component: the high-functionality polyurethane acrylic M-80 of six functionality of Competing company limited () 10%; Difunctionality urethane acrylate (SM-6202 of Sanmu Group Co., Ltd., Jiangsu) 18%; Acrylate monomer (butyl methacrylate) 1%; High functionality acrylate (double pentaerythritol methacrylate) 8%; Fluorinated acrylate (10% methacrylic acid hexafluoro butyl ester, 20% vinylformic acid 17 fluorine monooctyl esters) 35%; Nano inorganic powder filler (particle diameter is the aluminum oxide of 10~30nm) 9%; Light trigger (2-methyl-4 '-methylthio group-2-morpholinyl Propiophenone) 3%; Auxiliary agent (flow agent BYK 37770.8%, defoamer BYK 0550.2%) 1%; Solvent (8% ethylene glycol ether acetate, 5% dimethylbenzene, 2% 4-methyl 2 pentanone) 15%.Join in the stirring tank, mix, form coating.Above per-cent is weight ratio.

Above paint spay-coating to the PC base material, is tested film performance behind the ultraviolet light polymerization.

Film performance:

1. outward appearance is not had foaming, peels off, and does not have obvious variable color;

2. contact angle is 140 °, has excellent anti-fingerprint;

3. pencil hardness 2H (GB/T6739-96);

4. sticking power 100/100 (GB/T9286-88);

5. wear resistance: RCA wears away 1300 times (the wear-resisting tester of Norman RCA, load 175g);

6. acid resistance: 5% sulfuric acid soaks 48h does not have considerable change; Alkali resistance: 5%NaOH soaks 48h does not have considerable change: 5%NaCl soaks 48h does not have considerable change.

Claims (10)

1. high-abrasion resistant ultraviolet light solidifying fingerprint resistant coating, comprise: 10~35% high-functionality polyurethane acrylic, 5~25% difunctionality urethane acrylate, 0.01~20% acrylate monomer, 5~20% high functionality acrylate, 5~40% fluorinated acrylate, 0.01~10% nano inorganic powder filler, 1~5% light trigger, 0.01~5% auxiliary agent and 5~30% solvent, above-mentioned per-cent is weight percentage.
2. coating according to claim 1 is characterized in that: the functionality of described high-functionality polyurethane acrylic is 3~9.
3. coating according to claim 1 and 2, it is characterized in that: described acrylate monomer is methyl acrylate, ethyl propenoate, vinylformic acid-2-hydroxyl ethyl ester, one or more in butyl acrylate, iso-bornyl acrylate, mono acrylic ester, methyl methacrylate, Jia Jibingxisuanyizhi, butyl methacrylate or the 2-hydroxyethyl methacrylate.
4. coating according to claim 1 and 2 is characterized in that: described high functionality acrylate is meant the acrylate monomer with 2~6 functionality.
5. coating according to claim 4, it is characterized in that: described high functionality acrylate is 1, the 4-butylene glycol diacrylate, 1,6 hexanediol diacrylate, neopentylglycol diacrylate, the third oxidation neopentylglycol diacrylate, tripropylene glycol diacrylate, PDDA, Viscoat 295, trimethylolpropane trimethacrylate, the third oxidation Viscoat 295, the ethoxyquin Viscoat 295, in tetramethylol methane tetraacrylate or the double pentaerythritol methacrylate one or more.
6. coating according to claim 1 and 2 is characterized in that: described fluorinated acrylate is one or more in trifluoromethyl acrylate, methacrylic acid hexafluoro butyl ester, trifluoroethyl methacrylate, methacrylic acid ten difluoro heptyl esters, vinylformic acid hexafluoro butyl ester, dodecafluorhe-ptylacrylate, methacrylic acid ten trifluoro monooctyl esters, vinylformic acid ten trifluoro monooctyl esters, methacrylic acid 17 fluorine monooctyl esters or the vinylformic acid 17 fluorine monooctyl esters.
7. coating according to claim 1 and 2 is characterized in that: described nano inorganic powder filler is nano silicon, nano titanium oxide, nano-calcium carbonate, nano zirconium dioxide, nanometer silicon carbide or nano aluminium oxide.
8. coating according to claim 1 and 2, it is characterized in that: described light trigger is Diisopropyl azodicarboxylate, methyl vinyl ketone, st-yrax, benzophenone, fluorescein, eosin, Benzoin ethyl ether, DEAP, camphorquinone, Alpha-hydroxy isopropyl benzene ketone, Alpha-hydroxy phenylcyclohexane ketone, 2-methyl-4 '-methylthio group-2-morpholinyl Propiophenone or 2,4-diethyl thiazolone.
9. coating according to claim 1 and 2 is characterized in that: described auxiliary agent comprises one or more in flow agent, defoamer, wetting agent, the pigment.
10. coating according to claim 1 and 2 is characterized in that: described solvent comprises in vinyl acetic monomer, N-BUTYL ACETATE, propyl carbinol, dimethylbenzene, toluene, acetone, 4-methyl 2 pentanone, Virahol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, glycol ether, ethylene glycol ether acetate, the propylene-glycol ethyl ether acetic ester one or more.
CN200910272845A 2009-11-24 2009-11-24 High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating CN101701129A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910272845A CN101701129A (en) 2009-11-24 2009-11-24 High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910272845A CN101701129A (en) 2009-11-24 2009-11-24 High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating

Publications (1)

Publication Number Publication Date
CN101701129A true CN101701129A (en) 2010-05-05

Family

ID=42156057

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200910272845A CN101701129A (en) 2009-11-24 2009-11-24 High-abrasion resistant ultraviolet light solidifying fingerprint resistant coating

Country Status (1)

Country Link
CN (1) CN101701129A (en)

Cited By (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102146226A (en) * 2010-12-28 2011-08-10 西安航天三沃化学有限公司 Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film
CN102329558A (en) * 2011-08-15 2012-01-25 江苏海田技术有限公司 Low-odor high-wear-resistance UV (ultraviolet) metal printing oil polish
CN102618163A (en) * 2012-03-31 2012-08-01 金甲化工企业(中山)有限公司 Ultraviolet wear resistant primer and preparation method thereof
CN102618020A (en) * 2011-01-28 2012-08-01 比亚迪股份有限公司 Polyurethane emulsion, preparation method of the polyurethane emulsion, nanometer color paste, preparation method of the nanometer color paste, ultraviolet light-cured coating composition and preparation method of the ultraviolet light-cured coating composition
CN102854075A (en) * 2011-06-28 2013-01-02 东莞劲胜精密组件股份有限公司 A testing method for artificial claw abrasion-resisting performance of coating
CN103129062A (en) * 2011-12-05 2013-06-05 三星电子株式会社 Coating structure, method for forming the same and apparatus provided with the coating structure
CN103242691A (en) * 2013-05-29 2013-08-14 江西师范大学 Anti-fingerprint coating and preparation method thereof
CN103265831A (en) * 2013-05-30 2013-08-28 苏州艾特斯环保材料有限公司 High temperature resistant and wear resistant paint containing 2-methyl methacrylate
CN103540256A (en) * 2013-09-27 2014-01-29 上海维凯化学品有限公司 Ultraviolet-curing high-hardness fingerprint-resistant coating for PMMA (Polymethyl Methacrylate) and composite base material of PMMA
CN103666239A (en) * 2013-12-12 2014-03-26 段晶晶 Nano-modified high-hardness ultraviolet curing paint with scratching resistance
CN103865376A (en) * 2014-03-11 2014-06-18 上海长润发涂料有限公司 UV spraying frosted paint
CN103897578A (en) * 2012-12-27 2014-07-02 乐金显示有限公司 Anti-finger printed hard coating resin composition and method of fabricating anti-finger printed hard coating film using the same
CN104178018A (en) * 2014-09-09 2014-12-03 苏州圣谱拉新材料科技有限公司 Acrylic coating for ceramic
CN104520387A (en) * 2012-05-31 2015-04-15 株式会社Lg化学 Hard coating composition
CN104673044A (en) * 2015-02-04 2015-06-03 苏州康华净化系统工程有限公司 Ageing resistant steel surface coating material and preparation method thereof
CN104804637A (en) * 2015-05-20 2015-07-29 湖南松井新材料有限公司 Super stain resistance ultraviolet curing coating
CN104845521A (en) * 2015-06-15 2015-08-19 张家港康得新光电材料有限公司 UV curing coating, wear-resistant and antifouling coating layer and mobile phone protection film containing wear-resistant and antifouling coating layer
CN104893542A (en) * 2015-05-26 2015-09-09 深圳市中联讯科技有限公司 Anti-fingerprint coating and spraying method thereof
CN104910793A (en) * 2015-06-05 2015-09-16 江苏理工学院 Water-based fossil anti-aging paint and preparation method thereof
CN105038553A (en) * 2015-07-31 2015-11-11 安徽和润特种玻璃有限公司 Anti-fouling and abrasion-resistant film used for anti-dazzle glass
CN105349025A (en) * 2015-12-16 2016-02-24 常熟理工学院 Light-cured waterproof coating for polymer substrate and preparation method of light-cured waterproof coating
CN105412968A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Air purificant
WO2016043263A1 (en) * 2014-09-19 2016-03-24 横浜ゴム株式会社 Ultraviolet light curable resin composition and laminate using same
CN105623477A (en) * 2016-03-17 2016-06-01 柳州市凯佰化工有限公司 Anti-fingerprint ultraviolet curing high-gloss varnish
CN105670492A (en) * 2016-03-18 2016-06-15 湖州国信物资有限公司 Sweat-resistant water-based polyurethane composite paint and method for preparing same
CN106336699A (en) * 2016-07-28 2017-01-18 江苏昌悦重工科技有限公司 Sewage treatment container
CN106749873A (en) * 2016-12-27 2017-05-31 广东衡光化工有限公司 A kind of fluorine carbon elastic emulsion and preparation method thereof
CN106905801A (en) * 2015-12-22 2017-06-30 北京奥托米特电子有限公司 Metal electrode protection liquid, metal electrode protective layer and preparation method thereof
CN107118684A (en) * 2017-06-13 2017-09-01 深圳市美丽华油墨涂料有限公司 A kind of coating material solidified and preparation method thereof the applications of anti-soil type UV
US9778398B2 (en) 2012-05-31 2017-10-03 Lg Chem, Ltd. Hard coating film and preparation method thereof
CN107501587A (en) * 2017-08-25 2017-12-22 南通通州湾新材料科技有限公司 The preparation method and applications of organic inorganic duricrust composite shell of tough core
CN107641455A (en) * 2017-09-27 2018-01-30 芜湖春风新材料有限公司 A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications
US9926461B2 (en) 2012-05-31 2018-03-27 Lg Chem, Ltd. Hard coating film
US10000655B2 (en) 2012-08-23 2018-06-19 Lg Chem, Ltd. Hard coating composition
CN108250816A (en) * 2017-12-21 2018-07-06 定远县保尔工贸有限公司 A kind of high abrasion mobile phone tempered glass film
CN109504298A (en) * 2018-11-26 2019-03-22 浙江欧仁新材料有限公司 The preparation method of anti-scratching wearproof silica gel screen protecting film
CN109575825A (en) * 2018-11-26 2019-04-05 浙江欧仁新材料有限公司 The wear-resisting silicone protective film of Curved screen
WO2019131701A1 (en) * 2017-12-26 2019-07-04 東洋インキScホールディングス株式会社 Active-energy-ray-curable hard coating agent, and layered body
CN110684460A (en) * 2019-11-13 2020-01-14 宁波富纳新材料科技有限公司 Low-cost high-wear-resistance UV (ultraviolet) curing coating and preparation method and application thereof
CN110760256A (en) * 2019-11-13 2020-02-07 宁波富纳新材料科技有限公司 High-hardness wear-resistant anti-fingerprint nano coating for PC material and preparation method thereof
CN112094588A (en) * 2020-11-02 2020-12-18 宁波富纳新材料科技有限公司 Fingerprint-preventing and anti-glare coating, protective film comprising same and preparation method of protective film

Cited By (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102146226A (en) * 2010-12-28 2011-08-10 西安航天三沃化学有限公司 Ultraviolet-cured high-adhesion scraping-resistant agent for heat insulating film
CN102618020B (en) * 2011-01-28 2015-03-04 比亚迪精密制造有限公司 Polyurethane emulsion, preparation method of the polyurethane emulsion, nanometer color paste, preparation method of the nanometer color paste, ultraviolet light-cured coating composition and preparation method of the ultraviolet light-cured coating composition
CN102618020A (en) * 2011-01-28 2012-08-01 比亚迪股份有限公司 Polyurethane emulsion, preparation method of the polyurethane emulsion, nanometer color paste, preparation method of the nanometer color paste, ultraviolet light-cured coating composition and preparation method of the ultraviolet light-cured coating composition
CN102854075A (en) * 2011-06-28 2013-01-02 东莞劲胜精密组件股份有限公司 A testing method for artificial claw abrasion-resisting performance of coating
CN102854075B (en) * 2011-06-28 2016-03-09 东莞劲胜精密组件股份有限公司 The method of testing of the resistance to artificial pawl wear hardness of a kind of coating
CN102329558A (en) * 2011-08-15 2012-01-25 江苏海田技术有限公司 Low-odor high-wear-resistance UV (ultraviolet) metal printing oil polish
CN103129062A (en) * 2011-12-05 2013-06-05 三星电子株式会社 Coating structure, method for forming the same and apparatus provided with the coating structure
CN102618163A (en) * 2012-03-31 2012-08-01 金甲化工企业(中山)有限公司 Ultraviolet wear resistant primer and preparation method thereof
US9926461B2 (en) 2012-05-31 2018-03-27 Lg Chem, Ltd. Hard coating film
US9896597B2 (en) 2012-05-31 2018-02-20 Lg Chem, Ltd. Method of preparing hard coating film
CN104520387B (en) * 2012-05-31 2017-05-24 株式会社Lg化学 Hard coating composition
US10294387B2 (en) 2012-05-31 2019-05-21 Lg Chem, Ltd. Hard coating film
US9403991B2 (en) 2012-05-31 2016-08-02 Lg Chem, Ltd. Hard coating composition
US9701862B2 (en) 2012-05-31 2017-07-11 Lg Chem, Ltd. Method of preparing hard coating film
US9778398B2 (en) 2012-05-31 2017-10-03 Lg Chem, Ltd. Hard coating film and preparation method thereof
CN104520387A (en) * 2012-05-31 2015-04-15 株式会社Lg化学 Hard coating composition
US9884977B2 (en) 2012-05-31 2018-02-06 Lg Chem, Ltd. Hard coating composition
US10000655B2 (en) 2012-08-23 2018-06-19 Lg Chem, Ltd. Hard coating composition
KR102067416B1 (en) * 2012-12-27 2020-01-17 엘지디스플레이 주식회사 Anti finger printed-hard coating resin composition and method of fabricating anti finger printed-hard coating layer using the same
CN103897578B (en) * 2012-12-27 2017-03-01 乐金显示有限公司 The hard coating resin composition of anti-fingerprint print and the method manufacturing the hard coating film of anti-fingerprint print using it
CN103897578A (en) * 2012-12-27 2014-07-02 乐金显示有限公司 Anti-finger printed hard coating resin composition and method of fabricating anti-finger printed hard coating film using the same
KR20140085073A (en) * 2012-12-27 2014-07-07 엘지디스플레이 주식회사 Anti finger printed-hard coating resin composition and method of fabricating anti finger printed-hard coating layer using the same
US9296914B2 (en) 2012-12-27 2016-03-29 Lg Display Co., Ltd. Anti-finger printed hard coating resin composition and method of fabricating anti-finger printed hard coating film using the same
CN103242691A (en) * 2013-05-29 2013-08-14 江西师范大学 Anti-fingerprint coating and preparation method thereof
CN103265831A (en) * 2013-05-30 2013-08-28 苏州艾特斯环保材料有限公司 High temperature resistant and wear resistant paint containing 2-methyl methacrylate
CN103265831B (en) * 2013-05-30 2015-08-05 苏州艾特斯环保材料有限公司 A kind of heat-resisting antiwear paint containing 2-methyl methacrylate
CN103540256A (en) * 2013-09-27 2014-01-29 上海维凯化学品有限公司 Ultraviolet-curing high-hardness fingerprint-resistant coating for PMMA (Polymethyl Methacrylate) and composite base material of PMMA
CN103540256B (en) * 2013-09-27 2016-04-13 上海维凯光电新材料有限公司 The anti-fingerprint coating of ultraviolet light polymerization high rigidity of acrylic and composite material base thereof
CN103666239B (en) * 2013-12-12 2016-07-06 义乌市鼎盛印刷有限公司 A kind of anti-scratch ultraviolet-cured paint of nano modification high rigidity
CN103666239A (en) * 2013-12-12 2014-03-26 段晶晶 Nano-modified high-hardness ultraviolet curing paint with scratching resistance
CN103865376A (en) * 2014-03-11 2014-06-18 上海长润发涂料有限公司 UV spraying frosted paint
CN104178018A (en) * 2014-09-09 2014-12-03 苏州圣谱拉新材料科技有限公司 Acrylic coating for ceramic
WO2016043263A1 (en) * 2014-09-19 2016-03-24 横浜ゴム株式会社 Ultraviolet light curable resin composition and laminate using same
CN104673044A (en) * 2015-02-04 2015-06-03 苏州康华净化系统工程有限公司 Ageing resistant steel surface coating material and preparation method thereof
CN104804637A (en) * 2015-05-20 2015-07-29 湖南松井新材料有限公司 Super stain resistance ultraviolet curing coating
CN104893542A (en) * 2015-05-26 2015-09-09 深圳市中联讯科技有限公司 Anti-fingerprint coating and spraying method thereof
CN104910793A (en) * 2015-06-05 2015-09-16 江苏理工学院 Water-based fossil anti-aging paint and preparation method thereof
CN104910793B (en) * 2015-06-05 2018-05-25 江苏理工学院 A kind of aqueous fossil antiaging coating and preparation method thereof
CN104845521A (en) * 2015-06-15 2015-08-19 张家港康得新光电材料有限公司 UV curing coating, wear-resistant and antifouling coating layer and mobile phone protection film containing wear-resistant and antifouling coating layer
CN105038553A (en) * 2015-07-31 2015-11-11 安徽和润特种玻璃有限公司 Anti-fouling and abrasion-resistant film used for anti-dazzle glass
CN105349025A (en) * 2015-12-16 2016-02-24 常熟理工学院 Light-cured waterproof coating for polymer substrate and preparation method of light-cured waterproof coating
CN105412968A (en) * 2015-12-16 2016-03-23 无锡吉进环保科技有限公司 Air purificant
CN105349025B (en) * 2015-12-16 2018-05-04 常熟理工学院 A kind of photocuring waterproof coating of polymer-based timber-used and preparation method thereof
CN106905801A (en) * 2015-12-22 2017-06-30 北京奥托米特电子有限公司 Metal electrode protection liquid, metal electrode protective layer and preparation method thereof
CN105623477A (en) * 2016-03-17 2016-06-01 柳州市凯佰化工有限公司 Anti-fingerprint ultraviolet curing high-gloss varnish
CN105670492A (en) * 2016-03-18 2016-06-15 湖州国信物资有限公司 Sweat-resistant water-based polyurethane composite paint and method for preparing same
CN106336699A (en) * 2016-07-28 2017-01-18 江苏昌悦重工科技有限公司 Sewage treatment container
CN106749873A (en) * 2016-12-27 2017-05-31 广东衡光化工有限公司 A kind of fluorine carbon elastic emulsion and preparation method thereof
CN107118684A (en) * 2017-06-13 2017-09-01 深圳市美丽华油墨涂料有限公司 A kind of coating material solidified and preparation method thereof the applications of anti-soil type UV
CN107501587A (en) * 2017-08-25 2017-12-22 南通通州湾新材料科技有限公司 The preparation method and applications of organic inorganic duricrust composite shell of tough core
CN107641455B (en) * 2017-09-27 2019-12-24 芜湖春风新材料有限公司 Anti-fingerprint UV coating for automotive interior parts, and preparation method and application thereof
CN107641455A (en) * 2017-09-27 2018-01-30 芜湖春风新材料有限公司 A kind of automotive upholstery anti-fingerprint UV coating, preparation method and applications
CN108250816A (en) * 2017-12-21 2018-07-06 定远县保尔工贸有限公司 A kind of high abrasion mobile phone tempered glass film
WO2019131701A1 (en) * 2017-12-26 2019-07-04 東洋インキScホールディングス株式会社 Active-energy-ray-curable hard coating agent, and layered body
CN109575825A (en) * 2018-11-26 2019-04-05 浙江欧仁新材料有限公司 The wear-resisting silicone protective film of Curved screen
CN109504298A (en) * 2018-11-26 2019-03-22 浙江欧仁新材料有限公司 The preparation method of anti-scratching wearproof silica gel screen protecting film
CN110684460A (en) * 2019-11-13 2020-01-14 宁波富纳新材料科技有限公司 Low-cost high-wear-resistance UV (ultraviolet) curing coating and preparation method and application thereof
CN110760256A (en) * 2019-11-13 2020-02-07 宁波富纳新材料科技有限公司 High-hardness wear-resistant anti-fingerprint nano coating for PC material and preparation method thereof
CN112094588A (en) * 2020-11-02 2020-12-18 宁波富纳新材料科技有限公司 Fingerprint-preventing and anti-glare coating, protective film comprising same and preparation method of protective film

Similar Documents

Publication Publication Date Title
CN103013241B (en) Fluorocarbon nanometer solar heat-insulation reflective paint, preparation method and using method thereof
TWI472587B (en) Colored aqueous uv curable coating composition
CN104673069B (en) A kind of highly corrosion resistant wear-resistant coating and preparation method thereof
CN101215438B (en) Anti-soiling aging-resisting stainless steel paint and preparation method thereof
CN104530321B (en) Preparation method of nanoparticle-modified polyurethane acrylate copolymer resin microemulsion
CN101235672B (en) Ultraviolet light curing overlay film decorative board for wall and method for making same
CN1935917B (en) Bottom coating composition, and its preparing method and multilayer coat
CN101139499B (en) Aqueous automobile framework and automobile motorcycle wheel surface protection coating
CN102643600B (en) Ultraviolet light curing coating composition
CN101979449B (en) Ultraviolet curing coating for white board
CN102786875B (en) Anti-static hardened film
CN102311688B (en) Aqueous transparent heat insulation paint
CN102129090B (en) Optical hardening film
CN105058929B (en) A kind of Multifunction screen protective film
CN101463222B (en) UV curing color coating
CN101837667B (en) Ultraviolet cured coating and application thereof
CN101654571B (en) UV-curable colored paint composition
CN1255487C (en) Ultraviolet cured paint
CN103436079A (en) Environmental-friendly water-based nylon printing ink used for screen printing and preparation method thereof
CN1626587A (en) Water born paint of imitating metal in use for plastic painting dressing
CN104974631B (en) With the matrix resin and the self polishing copolymer antifouling paint of preparation from polishing performance
CN102898939B (en) Two-coating type ultraviolet light curing paint
CN103045050A (en) Antirust coating for metal pipeline
CN101608088A (en) A kind of powder coating and preparation method thereof
CN101935425B (en) Modified polyurethane (PU) acrylic resin and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
C06 Publication
SE01 Entry into force of request for substantive examination
C10 Entry into substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20100505

C12 Rejection of a patent application after its publication