CN101679031A - 生产合成气的方法 - Google Patents

生产合成气的方法 Download PDF

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Publication number
CN101679031A
CN101679031A CN200880019756A CN200880019756A CN101679031A CN 101679031 A CN101679031 A CN 101679031A CN 200880019756 A CN200880019756 A CN 200880019756A CN 200880019756 A CN200880019756 A CN 200880019756A CN 101679031 A CN101679031 A CN 101679031A
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synthetic gas
dry weight
reaction
partial oxidation
whole
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Chinese (zh)
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S·顺克
A·朗格德奥利韦拉
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BASF SE
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BASF SE
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/46Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using discontinuously preheated non-moving solid materials, e.g. blast and run
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/061Methanol production
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86Carbon dioxide sequestration
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN200880019756A 2007-05-11 2008-05-09 生产合成气的方法 Pending CN101679031A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102007022723.1 2007-05-11
DE102007022723A DE102007022723A1 (de) 2007-05-11 2007-05-11 Verfahren zur Herstellung von Synthesegas
PCT/EP2008/055770 WO2008138899A1 (de) 2007-05-11 2008-05-09 Verfahren zur herstellung von synthesegas

Publications (1)

Publication Number Publication Date
CN101679031A true CN101679031A (zh) 2010-03-24

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CN200880019756A Pending CN101679031A (zh) 2007-05-11 2008-05-09 生产合成气的方法

Country Status (7)

Country Link
US (1) US8691181B2 (enExample)
EP (1) EP2146926B1 (enExample)
JP (1) JP5595265B2 (enExample)
KR (1) KR101594188B1 (enExample)
CN (1) CN101679031A (enExample)
DE (1) DE102007022723A1 (enExample)
WO (1) WO2008138899A1 (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103641068A (zh) * 2013-12-06 2014-03-19 中国科学院工程热物理研究所 中低温太阳能热化学互补发电的变辐照调控系统及方法
CN104919023A (zh) * 2013-01-04 2015-09-16 沙特阿拉伯石油公司 利用太阳辐射通过合成气制备单元将二氧化碳转化为烃类燃料
CN109790018A (zh) * 2016-09-16 2019-05-21 沙特基础工业全球技术公司 将烃进料转化为用于多种应用的c2不饱和烃和合成气组合物的工艺
CN110357039A (zh) * 2019-08-12 2019-10-22 中国科学院工程热物理研究所 一种沼气和太阳能互补的合成气制备系统及方法
CN110589765A (zh) * 2019-10-09 2019-12-20 中石化南京工程有限公司 一种利用天然气制备不同比例合成气的方法及系统

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9605522B2 (en) * 2006-03-29 2017-03-28 Pioneer Energy, Inc. Apparatus and method for extracting petroleum from underground sites using reformed gases
AT505927B1 (de) * 2007-12-21 2009-05-15 Holcim Technology Ltd Verfahren zum verbessern der produkteigenschaften von klinker beim brennen von rohmehl
DE102009014728A1 (de) * 2009-03-25 2010-09-30 Siemens Aktiengesellschaft Verfahren zum Betreiben eines Fossilbrennstoff-Kraftwerks und Fossilbrennstoff-Kraftwerk mit vermindertem Kohlendioxidausstoß
KR20120005447A (ko) * 2009-04-10 2012-01-16 유니버시티 오브 써던 캘리포니아 석유를 연료용의 환경적으로 이산화탄소 중립 공급 물질, 유도 생성물, 및 재생 탄소 공급원으로 만드는 방법
EP2534362A2 (en) * 2010-02-13 2012-12-19 McAlister Technologies, LLC Coupled thermochemical reactors and engines, and associated systems and methods
DE102010053902B4 (de) * 2010-12-09 2014-06-18 Deutsches Zentrum für Luft- und Raumfahrt e.V. Verfahren zur kontinuierlichen Durchführung solar beheizter chemischer Reaktionen sowie solarchemischer Reaktor mit Solarstrahlungsempfänger
JP5489004B2 (ja) * 2011-03-11 2014-05-14 株式会社日本製鋼所 合成ガスとナノカーボンの製造方法および製造システム
DE102011089656A1 (de) * 2011-12-22 2013-06-27 Friedrich-Alexander-Universität Erlangen-Nürnberg Verfahren zur Einspeicherung von Energie die in Form von elektrischem Strom oder Wärme vorliegt in ein Eduktgasgemisch sowie eine Vorrichtung zur Durchführung dieses Verfahrens
US20130197288A1 (en) * 2012-01-31 2013-08-01 Linde Ag Process for the conversion of synthesis gas to olefins
CN104169210A (zh) 2012-03-13 2014-11-26 拜耳知识产权有限责任公司 在两种操作模式之间交替操作制备co和/或h2的方法
WO2013135667A1 (de) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren für die synthesegasherstellung
WO2013135657A1 (de) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren für die synthesegasherstellung im wechselbetrieb zwischen zwei betriebsarten
EP2695946A1 (de) 2012-08-09 2014-02-12 Methapower Biogas GmbH Verfahren und Anlage zur Herstellung von Dimethylether
US9682899B2 (en) 2013-12-06 2017-06-20 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
WO2015084576A2 (en) 2013-12-06 2015-06-11 Exxonmobil Chemical Patents Inc. Hydrocarbon conversion
DE102013020905A1 (de) * 2013-12-16 2015-06-18 Ralf Spitzl Verfahren und Vorrichtungen zur Herstellung von Synthesegas
US20160101977A1 (en) * 2014-10-09 2016-04-14 Be Energy Group, Inc. Method and apparatus for capturing and sequestering carbon
WO2019212072A1 (ko) * 2018-05-02 2019-11-07 한국과학기술원 이산화탄소를 이용하는 건식 개질 반응을 이용한 아세트산의 생성 방법 및 그 시스템
EP3816101A4 (en) 2018-06-05 2022-03-16 IHI Corporation DEVICE AND METHOD FOR PRODUCTION OF HYDROGEN
EP3816144A4 (en) * 2018-06-05 2022-04-20 IHI Corporation DEVICE FOR THE MANUFACTURE OF UNSATURATED CARBONS
KR20210103677A (ko) * 2020-02-14 2021-08-24 현대자동차주식회사 수소 개질 시스템
CN112958143A (zh) * 2021-03-18 2021-06-15 宁夏大学 一种用于一氧化碳加氢制备低碳烯烃的催化剂
US12269741B2 (en) 2021-09-06 2025-04-08 Bong Ju Lee Reforming system and method
CN114506817B (zh) * 2022-03-03 2023-01-31 西南石油大学 一种利用地热能辅助加热的气藏原位转化制氢方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2110650A1 (de) * 1971-03-05 1972-09-14 Siegener Ag Geisweid Verfahren zur Durchfuehrung chemischer Reaktionen
DE2438949A1 (de) * 1974-08-14 1976-02-26 Juergen Dipl Ing Rheinlaender Methanumsetzung mit hilfe konzentrierter sonnenenergie
US4229184A (en) 1979-04-13 1980-10-21 The United States Of America As Represented By The United States Department Of Energy Apparatus and method for solar coal gasification
JPS58122987A (ja) * 1982-01-14 1983-07-21 Mitsui & Co Ltd 核熱を利用する合成方法
DE3337078A1 (de) 1983-10-12 1985-05-02 M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8000 München Verfahren und vorrichtung zum herstellen von synthesegas
DE3445486A1 (de) * 1984-12-13 1986-06-26 Hochtemperatur-Reaktorbau GmbH, 4600 Dortmund Zylindrischer roehrenspaltofen zur erzeugung von synthesegas mittels nuklear gewonnener waermeenergie
US4668494A (en) 1984-12-24 1987-05-26 Foster Wheeler Energy Corporation Method of using solar energy in a chemical synthesis process
US4756806A (en) * 1987-06-18 1988-07-12 Gas Research Institute Hybrid thermoelectrochemical synthesis of gaseous fuels from water and carbon dioxide
DE3933285A1 (de) 1989-10-05 1991-04-18 Steinmueller Gmbh L & C Verfahren zur kontinuierlichen erzeugung von synthesegas durch solare reformierung von methan und vorrichtung zur durchfuehrung des verfahrens
IL100520A (en) * 1991-12-26 1995-12-31 Yeda Res & Dev Solar energy gasification of solid carbonaceous material in liquid dispersion
GB9817526D0 (en) * 1998-08-13 1998-10-07 Ici Plc Steam reforming
JP4132295B2 (ja) * 1998-09-30 2008-08-13 千代田化工建設株式会社 炭酸ガスを含む低級炭化水素ガスから液体炭化水素油を製造する方法
US6461539B1 (en) * 1999-10-18 2002-10-08 Conoco Inc. Metal carbide catalysts and process for producing synthesis gas
US6670058B2 (en) 2000-04-05 2003-12-30 University Of Central Florida Thermocatalytic process for CO2-free production of hydrogen and carbon from hydrocarbons
US7033570B2 (en) * 2000-05-08 2006-04-25 Regents Of The University Of Colorado Solar-thermal fluid-wall reaction processing
US6872378B2 (en) * 2000-05-08 2005-03-29 Midwest Research Institute Solar thermal aerosol flow reaction process
US6774148B2 (en) * 2002-06-25 2004-08-10 Chevron U.S.A. Inc. Process for conversion of LPG and CH4 to syngas and higher valued products
EP1419814A1 (en) * 2002-11-15 2004-05-19 L'AIR LIQUIDE, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Perovskite catalyst for the partial oxidation of natural gas
JP4304025B2 (ja) * 2002-12-25 2009-07-29 大阪瓦斯株式会社 改質ガス製造装置の運転方法
US7125913B2 (en) * 2003-03-14 2006-10-24 Conocophillips Company Partial oxidation reactors and syngas coolers using nickel-containing components
US20040265158A1 (en) * 2003-06-30 2004-12-30 Boyapati Krishna Rao Co-producing hydrogen and power by biomass gasification
JP2005206404A (ja) * 2004-01-21 2005-08-04 Katsusato Hanamura メタンを水素ガスに改質する方法およびメタンの改質反応炉
JP2005214013A (ja) * 2004-01-27 2005-08-11 Mitsubishi Heavy Ind Ltd メタン含有ガスを供給ガスとした発電システム
US7420004B2 (en) * 2004-04-15 2008-09-02 The United States Of America As Represented By The Secretary Of The Navy Process and System for producing synthetic liquid hydrocarbon fuels
US7435760B2 (en) * 2004-05-14 2008-10-14 Battelle Memorial Institute Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels
US20060016722A1 (en) * 2004-07-08 2006-01-26 Conocophillips Company Synthetic hydrocarbon products
JP4738024B2 (ja) * 2005-03-08 2011-08-03 関西電力株式会社 二酸化炭素及び水蒸気によるメタンの改質方法及びシステム、この改質用の触媒、並びにこの触媒の製造方法
KR100732784B1 (ko) * 2005-06-17 2007-06-27 한국가스공사 탄화수소로부터 디메틸에테르를 제조하는 방법

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104919023A (zh) * 2013-01-04 2015-09-16 沙特阿拉伯石油公司 利用太阳辐射通过合成气制备单元将二氧化碳转化为烃类燃料
CN104919023B (zh) * 2013-01-04 2016-08-24 沙特阿拉伯石油公司 利用太阳辐射通过合成气制备单元将二氧化碳转化为烃类燃料
CN103641068A (zh) * 2013-12-06 2014-03-19 中国科学院工程热物理研究所 中低温太阳能热化学互补发电的变辐照调控系统及方法
CN103641068B (zh) * 2013-12-06 2015-10-28 中国科学院工程热物理研究所 中低温太阳能热化学互补发电的变辐照调控系统及方法
CN109790018A (zh) * 2016-09-16 2019-05-21 沙特基础工业全球技术公司 将烃进料转化为用于多种应用的c2不饱和烃和合成气组合物的工艺
CN110357039A (zh) * 2019-08-12 2019-10-22 中国科学院工程热物理研究所 一种沼气和太阳能互补的合成气制备系统及方法
CN110589765A (zh) * 2019-10-09 2019-12-20 中石化南京工程有限公司 一种利用天然气制备不同比例合成气的方法及系统

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Publication number Publication date
JP2010526759A (ja) 2010-08-05
EP2146926A1 (de) 2010-01-27
JP5595265B2 (ja) 2014-09-24
WO2008138899A1 (de) 2008-11-20
US8691181B2 (en) 2014-04-08
US20100305221A1 (en) 2010-12-02
KR101594188B1 (ko) 2016-02-15
KR20100017757A (ko) 2010-02-16
DE102007022723A1 (de) 2008-11-13
EP2146926B1 (de) 2013-01-02

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Application publication date: 20100324