CN101670745B - Extruded acryl composite cloudy-color plate and manufacturing method thereof - Google Patents

Extruded acryl composite cloudy-color plate and manufacturing method thereof Download PDF

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Publication number
CN101670745B
CN101670745B CN2009100325680A CN200910032568A CN101670745B CN 101670745 B CN101670745 B CN 101670745B CN 2009100325680 A CN2009100325680 A CN 2009100325680A CN 200910032568 A CN200910032568 A CN 200910032568A CN 101670745 B CN101670745 B CN 101670745B
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CN
China
Prior art keywords
extruded
color
layer
cloudy
abs
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Expired - Fee Related
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CN2009100325680A
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Chinese (zh)
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CN101670745A (en
Inventor
金惠良
贺国华
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CHANGZHOU BOSHUANG PLASTIC CO LTD
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CHANGZHOU BOSHUANG PLASTIC CO LTD
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Priority to CN2009100325680A priority Critical patent/CN101670745B/en
Publication of CN101670745A publication Critical patent/CN101670745A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • B29C48/08Flat, e.g. panels flexible, e.g. films
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92561Time, e.g. start, termination, duration or interruption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • B29C2948/9259Angular velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92609Dimensions
    • B29C2948/92647Thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92923Calibration, after-treatment or cooling zone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92952Drive section, e.g. gearbox, motor or drive fluids

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

The invention discloses an extruded acryl composite cloudy-color plate and a manufacturing method thereof. A color layer of the extruded acryl composite cloudy-color plate is formed by the coextrusion of a cloudy-color layer and a cloud background layer, the cloudy-color layer and the cloud background layer are both made of ABS, UV and titanium dioxide-color master batches, a base layer of the plate is made of ABS and titanium dioxide-color master batches, and an acryl layer is made of UV and PMMA. The raw materials are dried, simultaneously extruded into a dispatcher by four plastic extruders, extruded out by a T-shaped die head, and rolled to form the extruded acryl composite cloudy-color plate. The thickness of the extruded acryl composite cloudy-color plate can be controlled within 0.8-10 mm. The extruded acryl composite cloudy-color plate has the characteristics of wide application, low density, good surface finish, high flexibility, favorable subsequent processability, stable color and pattern and the like. Compared with production by the traditional secondary casting method, the production efficiency and the mechanization degree of products are improved.

Description

Extruded acryl composite cloudy-color plate and preparation method thereof
Technical field
The present invention relates to a kind of Extruded acryl composite cloudy-color plate and preparation method thereof, particularly relate to a kind of method that adopts the co-extrusion mode to prepare to be applicable to the Extruded acryl composite cloudy-color plate of making cleaners and polishes, ornament materials.
Background technology
The acryl composite cloudy-color plate is widely used in decoration, handicraft and makes the field such as various cleaners and polishes, and is very popular and welcome.The preparation of traditional acryl composite cloudy-color plate generally makes by the method for casting, but because its production process is numerous and diverse, the shortcoming such as yield poorly, and can not form mass and specialized production, simultaneously on performance, its impact strength is also not ideal enough, thereby has limited to a certain extent its range of application.
Summary of the invention
One of purpose of the present invention provides a kind of Extruded acryl composite cloudy-color plate.
The Extruded acryl composite cloudy-color plate, comprise acrylic layer, color layer and sheet material basic unit, color layer is co-extruded by cloud layer and cloud background layer, cloud layer and cloud background layer form by ABS-polystyrene copolymer (ABS), Benzotriazole Ultraviolet Stabilizer (UV) and titanium dioxide color masterbatch, by weight percentage, the UV consumption accounts for the 0.1-4% of cloud stratum total, and titanium dioxide color masterbatch consumption accounts for the 2-10% of cloud stratum total, and surplus is ABS; The UV consumption accounts for the 0.1-4% of cloud layer background total amount, and titanium dioxide color masterbatch consumption accounts for the 2-10% of cloud background layer total amount, and surplus is ABS.
The used titanium dioxide color masterbatch color of described cloud layer and cloud background layer is different.
Described sheet material basic unit is comprised of ABS and titanium dioxide color masterbatch, and by weight percentage, titanium dioxide color masterbatch consumption accounts for the 2-10% of sheet material basic unit total amount, and surplus is ABS.
Described acrylic layer is comprised of PMMA and UV, and by weight percentage, the UV consumption accounts for the 0.1-4% of acrylic layer total amount, and surplus is PMMA.
Another object of the present invention provides the preparation method of above-mentioned Extruded acryl composite cloudy-color plate, comprises the steps:
A, at first above-mentioned raw materials is stirred in mixed-hopper, the drying of carrying out 1-7 hour in temperature is 60-90 ℃ scope is simultaneously processed, an extruding machine body temperature is set in 200-260 ℃ of scope, to be expressed into distributor as acrylic layer behind PMMA and the UV fusion plastification, second extruding machine body temperature is set in 200-240 ℃ of scope, with ABS, be expressed in the distributor as the cloud background layer behind UV and the titanium dioxide color masterbatch fusion plastification, the 3rd extruding machine body temperature is set as 200-240 ℃, the extruder motor rotating speed is set as the 5-20 section with finding time: in each section of finding time, the extruder motor speed setting is 900-1400r/min, the time of each section of finding time is set as 10-70 second, with ABS, be expressed in the distributor as the cloud layer behind UV and the titanium dioxide color masterbatch fusion plastification; The 4th extruding machine body temperature is set in 200-240 ℃ of scope, will be expressed in the distributor as sheet material basic unit behind ABS and the titanium dioxide color masterbatch fusion plastification;
After b, above-mentioned sheet material raw material are squeezed in the same distributor by extruding machine, are extruded into through T shape die head and prolong in the pressure roller equipment, being extruded to shape forms the composite cloudy-color plate structure.
Advantage of the present invention:
(1) can be controlled in the 0.8-10mm scope on the Extruded acryl composite cloudy-color plate thickness by the present invention's preparation, applicable purposes is more extensive;
(2) the Extruded acryl composite cloudy-color plate of the present invention's preparation is on properties of product, and it is low to have density, and surface smoothness is good, and pliability is high, and following process is good, the characteristics of color stable patterns.
(3) the extrusion molding production acryl composite cloudy-color plate of the present invention's application, more traditional second casting method is produced the production efficiency that has improved product, and mechanization degree is high.
The specific embodiment
Embodiment 1
A, at first the raw material with above-mentioned every laminate material stirs in mixed-hopper separately, the drying of carrying out 5 hours in temperature is 65 ℃ scope is simultaneously processed, wherein an extruding machine body temperature is set in 200-260 ℃ of scope, with the raw materials by weight meter, 0.1% UV, surplus is the proportioning of PMMA, be expressed into distributor behind the fusion plastification as acrylic layer, second extruding machine body temperature is set in 200-240 ℃ of scope, with the raw materials by weight meter, the blue masterbatch of 0.2% UV and 5% titanium dioxide, its surplus is the proportioning of ABS, is expressed into behind the fusion plastification in the distributor as the cloud background layer; The 3rd extruding machine body temperature is set as 200-240 ℃, extruder motor rotating speed and conversion rotating speed time period are set as 1 section: 15 seconds/900 turn, 2 sections: 40 seconds/1000 turn, 3 sections: 65 seconds/1300 turn, 4 sections: 25 seconds/1020 turn, 5 sections: 35 seconds/1400 turn, with the raw materials by weight meter, 0.1% UV and 5% titanium dioxide white color masterbatch, its surplus is the proportioning of ABS, is expressed into behind the fusion plastification in the distributor as the cloud layer; The 4th extruding machine body temperature is set in 200-240 ℃ of scope, with the raw materials by weight meter, the blue masterbatch of 5% titanium dioxide, surplus is the proportioning of ABS, is expressed into behind the fusion plastification in the distributor as sheet material basic unit;
After b, above-mentioned sheet material raw material are squeezed in the same distributor by extruding machine, are extruded into through T shape die head and prolong in the pressure roller equipment, being extruded to shape forms the cloudy-color plate structure.
C, the above-mentioned sheet material of preparing again through the extremely horizontal cutting knife of traction, namely become the sheet material of required size requirement after cutting after cutting edge, covering diaphragm.

Claims (5)

1. Extruded acryl composite cloudy-color plate, comprise acrylic layer, color layer and sheet material basic unit, it is characterized in that: color layer is co-extruded by cloud layer and cloud background layer, cloud layer and cloud background layer are by ABS-polystyrene copolymer---and be that ABS, Benzotriazole Ultraviolet Stabilizer (UV) and titanium dioxide color masterbatch form, by weight percentage, the Benzotriazole Ultraviolet Stabilizer consumption accounts for the 0.1-4% of cloud stratum total, titanium dioxide color masterbatch consumption accounts for the 2-10% of cloud stratum total, and surplus is ABS; The Benzotriazole Ultraviolet Stabilizer consumption accounts for the 0.1-4% of cloud background layer total amount, and titanium dioxide color masterbatch consumption accounts for the 2-10% of cloud background layer total amount, and surplus is ABS.
2. Extruded acryl composite cloudy-color plate according to claim 1 is characterized in that: the used titanium dioxide color masterbatch color of described cloud layer and cloud background layer is different.
3. Extruded acryl composite cloudy-color plate according to claim 1, it is characterized in that: described sheet material basic unit is comprised of ABS and titanium dioxide color masterbatch, by weight percentage, titanium dioxide color masterbatch consumption accounts for the 2-10% of sheet material basic unit total amount, and surplus is ABS.
4. Extruded acryl composite cloudy-color plate according to claim 1, it is characterized in that: described acrylic layer is comprised of PMMA and Benzotriazole Ultraviolet Stabilizer, by weight percentage, the Benzotriazole Ultraviolet Stabilizer consumption accounts for the 0.1-4% of acrylic layer total amount, and surplus is PMMA.
5. the preparation method of Extruded acryl composite cloudy-color plate according to claim 1 is characterized in that: comprise the steps:
A, at first the raw material with above-mentioned every laminate material stirs in mixed-hopper separately, the drying of carrying out 1-7 hour in temperature is 60-90 ℃ scope is simultaneously processed, wherein an extruding machine body temperature is set in 200-260 ℃ of scope, to be expressed into distributor as acrylic layer behind PMMA and the Benzotriazole Ultraviolet Stabilizer fusion plastification, second extruding machine body temperature is set in 180-240 ℃ of scope, with ABS, be expressed in the distributor as the cloud background layer behind Benzotriazole Ultraviolet Stabilizer and the titanium dioxide color masterbatch fusion plastification, the 3rd extruding machine body temperature is set as 200-240 ℃, find time and be set as the 5-20 section: in each section of finding time, the extruder motor speed setting is 900-1400r/min, the time of each section of finding time is set as 10-70 second, with ABS, be expressed in the distributor as the cloud layer behind Benzotriazole Ultraviolet Stabilizer and the titanium dioxide color masterbatch fusion plastification; The 4th extruding machine body temperature is set in 200-240 ℃ of scope, will be expressed in the distributor as sheet material basic unit behind ABS and the titanium dioxide color masterbatch fusion plastification;
After b, above-mentioned sheet material raw material are squeezed in the same described distributor by extruding machine, are extruded into through T shape die head and prolong in the pressure roller equipment, being extruded to shape forms Extruded acryl composite cloudy-color plate structure.
CN2009100325680A 2009-06-19 2009-06-19 Extruded acryl composite cloudy-color plate and manufacturing method thereof Expired - Fee Related CN101670745B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101992574B (en) * 2010-09-30 2013-06-12 山东英科环保再生资源股份有限公司 Uvioresistant multi-layer polystyrene foaming section bar with co-extrusion function
KR101379544B1 (en) * 2011-06-17 2014-03-28 (주)엘지하우시스 Window profile provided with skin layer having wood fiber
CN102617975A (en) * 2012-04-06 2012-08-01 广州远华色母厂有限公司 Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin
WO2019113809A1 (en) * 2017-12-12 2019-06-20 陈斌 Method for manufacturing flame-resistant composite board with convenient processing and decoration, and structure thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1562605A (en) * 2004-03-26 2005-01-12 蒋素珍 Method for fabricating multicolor acrylboard
TWI244966B (en) * 2004-10-13 2005-12-11 Her Chyaou Co Ltd Manufacturing method for acrylic planks
CN1962286A (en) * 2005-11-10 2007-05-16 卓成有限公司 Production method of acryl plate with inner layer pattern paper
CN101317715A (en) * 2008-06-24 2008-12-10 孙广立 Acryl decoration board and processing technique

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1562605A (en) * 2004-03-26 2005-01-12 蒋素珍 Method for fabricating multicolor acrylboard
TWI244966B (en) * 2004-10-13 2005-12-11 Her Chyaou Co Ltd Manufacturing method for acrylic planks
CN1962286A (en) * 2005-11-10 2007-05-16 卓成有限公司 Production method of acryl plate with inner layer pattern paper
CN101317715A (en) * 2008-06-24 2008-12-10 孙广立 Acryl decoration board and processing technique

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