CN102617975A - Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin - Google Patents
Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin Download PDFInfo
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Abstract
The invention discloses a marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin. The composition can only consist of a face color composition, and can consist of a ground color composition and a face color composition. The face color composition consists of the following components in percentage by mass: 20-95 percent of thermoplastic polyester resin, 1-40 percent of a coloring agent, 0-50 percent of a filling material, 0-10 percent of a dispersing agent and 0-10 percent of a lubricating agent. The ground color composition consists of the following components in percentage by mass: 1-40 percent of a coloring agent, 40-99 percent of titanium pigment, 0-50 percent of a filling material, 0-10 percent of a dispersing agent and 0-10 percent of a lubricating agent. The color master batch composition is easy to use, and an ABS material with a 2D (two-dimensional) or 3D (three-dimensional) marble vision effect can be obtained by adding the marble vision effect color master batch composition into the ABS resin.
Description
Technical field
The present invention relates to fine chemistry industry colour batch compound composition and preparation method thereof field, particularly, the present invention relates to a kind of marble visual effect look female compsn that is used for ABS resin, be particularly useful for ABS resin injection moulding and extruded material molding process.
Background technology
In recent years, the look mother who has a special visual effect is enlarging such as the application in toy, gift and makeup and the daily necessities packing day by day.This palette mother comprises grouan look, flash of light look and pearly-lustre, fluorescence, marble grain, rainbow and edge lighting look etc.; Wherein, Grouan look, Dali stone, spot look nearest 2 years be fashion rather; Can cover the article surface portion and scrape scar, be used for the painted of garden furniture, market facility, office's apparatus and makeup packing more.
Grouan (Granite), the mineral grain that marble often can form and physically well develop, naked eyes can be distinguished, thereby gain the name, their colors are many, and range of choice is big, can select one or more distinct colors collocation to use, and good decorating effect has luxurious sense.But stone material grouan (no matter be natural or synthetic) exist density big, contain problems such as heavy metal and radioactive substance, and the appearance with plastic material of grouan effect has perfectly solved this problem.
ABS resin is an acrylonitrile-butadiene-styrene copolymer; Have surface of good gloss and chemical proofing; Have mechanical property tough and tensile, that matter is hard and good processibility; Be the macromolecular material that a demand is big, development is fast between engineering plastics and general-purpose plastics, be widely used in fields such as household electrical appliance, automotive trim, household apparatus, office's apparatus.But, at present rarely have report about being specifically designed to the look female compsn that ABS has a marble visual effect.
CN1557870A discloses a kind of imitative natural and multi-functional Masterbatch and uses thereof; Be characterized in: by masterbatch main body vector resin A, process with A paired vector resin X, compatilizer, pigment, mineral dye, static inhibitor, photostabilizer, oxidation inhibitor and pigment lubrication dispersion agent; Have notable difference as goods with consistency and the melting behavior of base resin B with parent vector resin A paired vector resin X, with the matrix resin A of A resin paired vector resin X and masterbatch can alloying, constitute the alloy vector resin.The present invention can independent assortment, a plurality of or single can the use.But the present invention needs two kinds of vector resins, because in the polymer blended formation high polymer alloy process, polymer is difficult for the system that blend forms homogeneous, has influenced the dispersiveness of final Masterbatch, reduces its use properties.
The female compsn of marble look of the present invention can be the painted starting material and the method for use of providing of common polymer wrapping material.Marble colour batch compsn of the present invention has the so-called marble visual effect of visual effects such as grouan visual effect, mountains and rivers, cloud and mist for injection moulding production ABS plastic material provides technological foundation stone to go out.
Summary of the invention
The object of the present invention is to provide a kind of marble visual effect look female compsn that is used for the acrylonitrile-butadiene-styrene copolymer resin, it can be used for the ABS material that injection moulding production has 2D plane effect and 3D stereoeffect.
In order to achieve the above object, the present invention has adopted following technical scheme:
The marble visual effect look female compsn that is used for the acrylonitrile-butadiene-styrene copolymer resin according to the invention, it comprises the complexion compsn, said complexion compsn comprises thermoplastic polyester.
It is a kind of thermoplastic polyester Masterbatch in itself for said complexion compsn; Add it to can produce irregular, inhomogeneous dispersion and diffusion in the ABS resin visual effect, and then reach the purpose of the female compsn of the look with marble visual effect that obtains being used for ABS.As vector resin, those skilled in the art can obtain above-mentioned said complexion compsn according to disclosed thermoplastic polyester Masterbatch formulation selection is suitable in the prior art tinting material and auxiliary agent commonly used with thermoplastic polyester in the present invention.The present invention utilizes mainly that the melting range of ABS resin and thermoplastic polyester is different, crystallinity is different and the velocity of diffusion of tinting material in vector resin and the ABS resin ultimate principle different with degree; Through test in a large number repeatedly; Finally confirm as carrier with thermoplastic polyester; Cooperate different types of tinting material; Add an amount of dispersion agent, lubricant again to control the speed and the degree of the diffusion of look female compsn in ABS resin, can make the female compsn of the look that is applicable to ABS with marble visual effect.
As optimal technical scheme; Said thermoplastic polyester accounts for 20～95% of complexion compsn total mass; For example 25%, 30%, 35%, 40%, 45%, 50%, 55%, 60%, 65%, 70%, 75%, 80%, 85%, 92%; Preferred 25～90%, further preferred 30～90%.
As optimal technical scheme; Said thermoplastic polyester is selected from polyethylene terephthalate (PET), mutual-phenenyl two acid bromide two alcohol ester (PBT), amorphized polyethylene terephthalate (APET), polyethylene terephthalate-1; 4-cyclohexanedimethanoester ester (PETG), PEN (PEN), poly terephthalic acid 1; The mixture of a kind of in 4-hexanaphthene dimethyl ester (PCT) and the PTT (PTT) or at least two kinds; Preferred polyethylene terephthalate (PET), mutual-phenenyl two acid bromide two alcohol ester (PBT), amorphized polyethylene terephthalate (APET&PETG) and polyethylene terephthalate-1; The mixture of a kind of in the 4-cyclohexanedimethanoester ester (PETG) or at least two kinds, further preferred polyethylene terephthalate and/or mutual-phenenyl two acid bromide two alcohol ester and multipolymer thereof.
The intrinsic viscosity IV of said thermoplastic polyester is 0.60～1.20dl/g, and the fusing point of said thermoplastic polyester is 220～270 ℃.
As optimal technical scheme, complexion compsn according to the invention also comprises tinting material, and further preferably, said complexion compsn also comprises additive, and said additive is selected from the combination of a kind of in stopping composition, dispersion agent and the lubricant or at least two kinds.Those skilled in the art can select suitable tinting material and auxiliary agent commonly used according to disclosed complexion composite formula in the prior art, obtain above-mentioned said complexion compsn.
The ABS of being used for of the present invention has a female compsn of marble visual effect look; Can only be made up of the complexion compsn, simultaneously, it can also comprise the background color compsn; Promptly be made up of jointly background color compsn and complexion both compositions, said background color compsn comprises tinting material and white titanium pigment.
Said white titanium pigment also can be used as tinting material and uses, and in the present invention, white titanium pigment is the essential component of said background color compsn.Said tinting material those skilled in the art can select any one or the multiple tinting material except that white titanium pigment voluntarily.
As optimal technical scheme, said background color compsn also comprises additive, and said additive is selected from the combination of a kind of in dispersion agent, stopping composition and the lubricant or at least two kinds.
The marble visual effect must some belong to background colour from visually looking like effects such as cloud and mist, mountains and rivers, grouan, and the purpose of background color compsn promptly is used to produce background colour.Its essential purpose is that to the ABS resin substrate coloring said background color compsn comprises tinting material and white titanium pigment.In order to reduce cost and to improve dispersing property, also can add additive usually, said additive is selected from the combination of a kind of in dispersion agent, stopping composition and the lubricant or at least two kinds.
Tinting material according to the invention comprises pigment and/dyestuff.
As preferred version; Said dyestuff is selected from the mixture of a kind of in anthraquinone dyes, Oil Soluble Azo Dyes, phthalocyanine pigment, indoles mattress base methine dyes and the quinophthalone dyestuff or at least two kinds; Said mixture is the combination of anthraquinone dyes and Oil Soluble Azo Dyes for example; The combination of phthalocyanine pigment and quinophthalone dyestuff; The combination of Oil Soluble Azo Dyes, phthalocyanine pigment, quinophthalone dyestuff; Preferred solvent is red 55, the mixture of a kind of in solvent of red 135, solvent red 196, DISPERSE YELLOW 201, DISPERSE YELLOW 24, solvent yellow 114, DISPERSE ORANGE 30 200 47, solvent orange 63,63 ,DIS,PER,SE ,Vio,let, 63 26,63 ,DIS,PER,SE ,Vio,let, 63 31, solvent blue 19 04, solvent blue 97, solvent green 3 and the solvent green 28 or at least two kinds, further the mixture of a kind of in preferred solvent red 135, solvent red 196,63 ,DIS,PER,SE ,Vio,let, 63 26,63 ,DIS,PER,SE ,Vio,let, 63 31, solvent blue 19 04, solvent blue 97, solvent green 3 and the solvent green 28 or at least two kinds.
As preferred version, pigment according to the invention comprises pigment dyestuff and/or mineral dye.
Said pigment dyestuff is selected from the mixture of a kind of in diketone-pyrroles-pyrrole pigment, azo lake pigment, benzimidazolone azo pigment, quinacridone pigments, azo condensation pigment 、 perylene pigments, En Kun piceneketone pigment 、 triazine dioxin pigment, phthalocyanine pigment and the carbon black or at least two kinds; The mixture of a kind of in preferred diketone-pyrroles-pyrrole pigment, azo lake pigment 、 triazine dioxin pigment, phthalocyanine pigment, benzimidazolone pigment and the carbon black or at least two kinds, the mixture of a kind of in further excellent diketone-pyrroles-pyrrole pigment, benzimidazolone pigment, phthalocyanine pigment and the carbon black or at least two kinds.
Preferably; Said mineral dye is selected from the mixture of a kind of in Pigment Yellow 73, Pigment red, Pigment blue, ultramarine violet and the pigment brown or at least two kinds; Preferred pigments is yellow 24, the mixture of a kind of in pigment yellow 34, Pigment Yellow 73 35, Pigment Yellow 73 53, Pigment Yellow 73 164, Pigment Yellow 73 184, Pigment red 101, Pigment red 104, Pigment red 108, Pigment blue 28, Pigment blue 29, ultramarine violet 15, ultramarine violet 16, pigment brown 24, pigment brown 29 and the pigment brown 43 or at least two kinds; The further mixture of a kind of in yellow 24, the Pigment Yellow 73 35 of preferred pigments, Pigment Yellow 73 53, Pigment Yellow 73 164, Pigment Yellow 73 184, Pigment red 101, Pigment red 108, Pigment blue 29, pigment violet 15, pigment violet 16 and the pigment brown 24 or at least two kinds, the more preferably mixture of a kind of in Pigment Yellow 73 53, Pigment red 101, Pigment blue 29, pigment violet 15, pigment violet 16 and the pigment brown 24 or at least two kinds.
Those skilled in the art can select suitable tinting material as required for use, and for example said complexion compsn can be selected pigment Blue 15 for use: 3 with the mixture of white titanium pigment as tinting material.
Dispersion agent described in the present invention is selected from the mixture of a kind of in metallic soap, new LDPE (film grade) and copolymer waxes thereof, low-molecular-weight ethylenic-vinyl acetate copolymer wax, ethylene-acrylic acid copolymer ion salt, metallocene PE wax, metallocene polypropylene wax, aliphatic amide and verivate thereof, micro mist wax and the illiteracy dawn acid esters wax or at least two kinds.Said mixture is the mixture of new LDPE (film grade) wax and low-molecular-weight ethylenic-vinyl acetate copolymer wax for example; The mixture of aclyn 295 and metallocene PE wax; Calcium stearate and the mixture that covers dawn acid esters wax; Metallocene polypropylene wax, cover the mixture of dawn acid esters wax, the mixture of a kind of in preferable alloy soap, metallocene PE wax, metallocene polypropylene wax, micro mist wax and the illiteracy dawn acid esters wax or at least two kinds.The effect of dispersion agent is to improve look female compsn processing fluidity, helps look female compsn and in ABS resin, disperses more uniformly.Those skilled in the art can select according to the performance characteristic of stopping composition and vector resin.
Add the dispersing property that lubricant can further improve Masterbatch; Lubricant according to the invention is selected from the mixture of a kind of in saturated hydrocarbons, metallic soap class, aliphatic amide type, aliphatics acids, aliphatic ester and the aliphatics alcohols or at least two kinds; Said mixture is saturated hydrocarbons/metallic soap class, aliphatic amide type/aliphatics acids, aliphatic ester/aliphatics alcohols for example; The saturated hydrocarbons arbitrarily that those skilled in the art can be known, metallic soap class, aliphatic amide type, aliphatics acids, aliphatic ester, fatty alcohol series lubricant agent all can be realized the present invention; The mixture of a kind of in preferable alloy soap class, aliphatic amide type and the aliphatic ester or at least two kinds, the mixture of a kind of in further preferred Triple Pressed Stearic Acid, calcium stearate, Zinic stearas, Magnesium Stearate, erucicamide and EBS and the verivate thereof or at least two kinds.
Preferably; Said stopping composition is selected from the mixture of a kind of in permanent white, zinc sulfide white, WHITE CARBON BLACK, talcum powder, lime carbonate, wollastonite, mica powder, kaolin, brucite, wilkinite, zeyssatite and the pumice sand or at least two kinds; Said mixture is the mixture of permanent white, zinc sulfide white for example, WHITE CARBON BLACK, talcous mixture, the mixture of lime carbonate, wollastonite; Mica powder, kaolinic mixture; Brucite, bentonitic mixture, the mixture of zeyssatite, pumice sand, the mixture of zinc sulfide white, talcum powder, wollastonite; The mixture of a kind of in preferably barium sulfate, lime carbonate, zinc sulfide white and the WHITE CARBON BLACK or at least two kinds, the further mixture of a kind of in preferably barium sulfate, water-ground limestone, light calcium carbonate, nano-calcium carbonate, zinc sulfide white and the WHITE CARBON BLACK or at least two kinds.
As optimal technical scheme, complexion compsn according to the invention comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Or said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Or said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Each component sum of said complexion compsn is 100%.
Said dispersion agent mass percent is 0～10%, and is preferred 0～8%, and " 0 " means in the said complexion compsn and do not contain dispersion agent.
Said stopping composition mass percent is 0～50%, and is preferred 0～40%, and " 0 " means in the said complexion compsn and do not contain stopping composition.
Said lubricant mass percent is 0～10%, and is preferred 0～8%, and " 0 " means in the said complexion compsn and do not contain lubricant.
As optimal technical scheme, background color compsn according to the invention comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Or said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Or said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Each component sum of said background color compsn is 100%.
Said dispersion agent mass percent is 0～10%, and is preferred 0～8%, and " 0 " means in the said background color compsn and do not contain dispersion agent.
Said stopping composition mass percent is 0～50%, and is preferred 0～40%, and " 0 " means in the said background color compsn and do not contain stopping composition.
Said lubricant mass percent is 0～10%, and is preferred 0～8%, and " 0 " means in the said background color compsn and do not contain lubricant.
As optimal technical scheme, compsn according to the invention is made up of the complexion compsn, and said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Each component sum of said complexion compsn is 100%.
Said dispersion agent mass percent is 0～10%, and " 0 " means in the said complexion compsn and do not contain dispersion agent.
Said stopping composition mass percent is 0～50%, and " 0 " means in the said complexion compsn and do not contain stopping composition.
Said lubricant mass percent is 0～10%, and " 0 " means in the said complexion compsn and do not contain lubricant.
As optimal technical scheme, said compsn is made up of complexion compsn and background color both compositions jointly, and the ratio of said complexion compsn and background color compsn can be selected according to the color of selected needs voluntarily, and the present invention does not limit this.Wherein, said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Each component sum of said complexion compsn is 100%,
Said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Each component sum of said background color compsn is 100%.
In the complexion compsn, said dispersion agent mass percent is 0～10%, and " 0 " means in the said complexion compsn and do not contain dispersion agent.
Said stopping composition mass percent is 0～50%, and " 0 " means in the said complexion compsn and do not contain stopping composition.
Said lubricant mass percent is 0～10%, and " 0 " means in the said complexion compsn and do not contain lubricant.
In the background color compsn, said dispersion agent mass percent is 0～10%, and " 0 " means in the said background color compsn and do not contain dispersion agent.
Said stopping composition mass percent is 0～50%, and " 0 " means in the said background color compsn and do not contain stopping composition.
Said lubricant mass percent is 0～10%, and " 0 " means in the said background color compsn and do not contain lubricant.
" comprising " of the present invention, mean it except that said component, can also comprise other components, make said look female compsn have other functions.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
The form of background color compsn according to the invention can also can generally adopt Powdered for granular for Powdered; The form of complexion compsn can also can generally adopt granular for granular for Powdered.The complexion compsn is used in separately in the ABS resin, and prepared material has marble 2D plane visual effect; Be used in simultaneously in the ABS resin with the background color compsn, prepared material has marble 3D stereoscopic visual effect.
ABS belongs to amorphous polymer, no sharp melting point, and heat-drawn wire is 90～120 ℃, generally in 220 ℃～280 ℃ fusion ranges, processes; And thermoplastic polyester is a crystalline polymer, and the specific melting point scope is arranged, and for example PBT is 224～227 ℃, and PET is between 240～252 ℃, but its fusing point is generally within ABS processing temperature scope.
Compared with prior art, the present invention has following beneficial effect:
(1) sees from visual effect; The female compsn of look provided by the present invention can be used for the ABS resin injection moulding and produce the ABS an injectable plastic material with 2D plane effect and 3D stereoeffect; The visual effect of the ABS material of being produced can be background color with the base material of ABS both; Make the ABS material of being produced have 3D spatial visual effect thereby also can introduce various background colors such as light gray, Dark grey, sky blue, acid blue, pink, white, yellow, the marble that for example can provide the ABS Shooting Technique to produce is light blue, marble is green, marble is black, marble light is purple, marble of green, the red end of marble light is blue, marble of the red end marble of green, the yellow end is blue, marble of the yellow end is coffee-like, marble of the blue end is black, marble is coffee-like at the bottom of green, the light gray of marble light of green, the pink end of marble light green, the pink end of marble at the bottom of green, the colour of skin of marble at the bottom of purple, the colour of skin of marble light at the bottom of purple, the colour of skin of marble at the bottom of the colour of skin, marble light of the light grey end is purple, marble of the light green end is black, white background marble coffee, the white background marble is blue, the white background marble is deceived, marble of light grey end indigo plant, marble of the light grey end marble indigo plant of the white and light grey end etc.;
(2) the prepared Masterbatch preparation method of the present invention is simple, and the background color compsn can be through color matching, weighing, abrasive dust, sieving makes the material of powder state, also can mix the back and become pellet through single screw extrusion machine or prepared in twin-screw extruder; The complexion compsn is generally granular, and the preparation method is identical with conventional Masterbatch;
(3) compsn method of use according to the invention is simple, directly adds in ABS injection moulding or the forcing machine basestocks mixing injection moulding after complexion compsn or background color compsn and complexion compsn mix by colour vision effect proportioning, the weighing of design in advance to or extrude to get final product;
(4) addition of the female compsn of the look of the present invention with marble visual effect is low; Generally speaking, the total addition level sum of background color compsn and complexion compsn is merely 1%～5% of ABS quality and can makes finished product have special marble visual effects such as grouan true to nature, marble, mountains and rivers, cloud and mist.
Description of drawings
Further specify technical scheme of the present invention below in conjunction with accompanying drawing and through embodiment.
Fig. 1: the ABS plate-shaped products that uses the look female preparation of compositions of forming jointly by complexion compsn and background color compsn of the present invention to obtain with marble visual effect.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical case of the present invention but non-restrictive example is following:
Embodiment 1
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PETG:70% (intrinsic viscosity IV is 0.78dl/g)
White titanium pigment: 22%
Pigment Blue 15: 3:4%
Aclyn?295：4％
Embodiment 1 said look female compsn is added in the ABS resin, and addition is the 1.5wt% of ABS resin quality, can obtain having the ABS material of the light blue visual effect of marble.
Embodiment 2
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PETG:80% (intrinsic viscosity IV is 0.86dl/g)
Pigment red 101:17%
Erucicamide: 3%
Embodiment 2 said looks female compsn is added in the ABS resin, and addition is the 1wt% of ABS resin quality, can obtain having the ABS material of the coffee-like visual effect of marble.
Embodiment 3
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PET:85% (intrinsic viscosity IV is 0.68dl/g)
Pigment black 6:10%
Micro mist wax: 4%
Calcium stearate: 1%
Embodiment 3 said looks female compsn is added in the ABS resin, and addition is the 1wt% of ABS resin quality, can obtain having the ABS material of imitative black granite line visual effect.
Embodiment 4
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---powder morphology
Solvent of red 135: 0.4%
Pigment red 104:2.0%
White titanium pigment: 97.6%
Complexion compsn---particulate state
PET:86% (intrinsic viscosity IV is 0.92dl/g)
Solvent red 196:0.2%
63 DISPERSE Violet 63: 0.35%
White titanium pigment: 10%
EBS：3.45％
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～4: 1; It is added in the ABS resin; Total addition level is the 2.5wt% of ABS resin quality, can obtain the ABS material of the purple visual effect of marble light at the bottom of the three-dimensional colour of skin of different 3D.
Embodiment 5
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---powder morphology
White titanium pigment: 97.8%
Solvent red 55:1.2%
Erucicamide: 1%
Complexion compsn---particulate state
PBT:80% (intrinsic viscosity IV is 0.62dl/g)
Pigment green: 15%
Metallocene PE wax: 5%
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～3: 1, and it is added in the ABS resin, can obtain the ABS material of the green visual effect of different 3D three-dimensional pink end marble.
Embodiment 6
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---Masterbatch form
Carbon black: 2%
White titanium pigment: 90%
TAF (aliphatic amide verivate): 8%
Complexion compsn-particulate state
PBT:40% (intrinsic viscosity IV is 0.62dl/g)
PETG:45% (intrinsic viscosity IV is 0.72dl/g)
Carbon black: 10%
Metallocene PE wax: 5%
Complexion compsn and background color compsn mix with weight part 1: 1～3: 1 and obtain look female compsn, and it is added in the ABS resin, can obtain marble blackout at the bottom of the three-dimensional grey of different 3D and feel the ABS material of effect.
Embodiment 7
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---Masterbatch form
Pigment blue 29:0.25%
Pigment violet 1 5:0.25%
White titanium pigment: 90%
Low-molecular polyethylene wax: 6.5%
Calcium stearate: 3%
Complexion compsn---Masterbatch form
PET:80% (intrinsic viscosity IV is 1.02dl/g)
PEN:5% (intrinsic viscosity IV is 0.75dl/g)
Pigment Blue 15: 3:6.5%
Solvent blue 19 04:4.5%
Cover dawn acid esters wax: 4%
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～3: 1, and it is added in the ABS resin, can obtain the ABS material of the three-dimensional white background marble of different 3D Cyanopia feel effect.
Embodiment 8
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PETG:95% (intrinsic viscosity IV is 0.78dl/g)
Pigment Blue 15: 3:3%
Acyln 295A (ethylene-acrylic acid copolymer ion salt): 2%
Embodiment 8 said looks female compsn is added in the ABS resin, and addition is the 1wt% of ABS resin quality, can obtain having the ABS material of the blue visual effect of marble.
Embodiment 9
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PETG:45% (intrinsic viscosity IV is 0.90dl/g)
63 DISPERSE Violet 63 26:1%
Nano-calcium carbonate: 50%
mPE：4％
Embodiment 9 said looks female compsn is added in the ABS resin, and addition is 2～3wt% of ABS resin quality, can obtain having the ABS material of marble purple visual effect.
Embodiment 10
Said look female compsn is made up of the complexion compsn, and said complexion compsn is formed as follows:
PETG:20% (intrinsic viscosity IV is 0.80dl/g)
Pigment brown 24:40%
Erucicamide: 10%
Zinc sulfide white: 20%
m-PE：10％
Embodiment 10 said looks female compsn is added in the ABS resin, and addition is 3～4wt% of ABS resin quality, can obtain having the ABS material of the coffee-like visual effect of marble.
Embodiment 11
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---powder shaped
Solvent of red 135: 20%
Pigment red 104:20%
White titanium pigment: 60%
Complexion compsn---particulate state
PET:85% (intrinsic viscosity IV is 0.92dl/g)
Solvent red 196:0.2%
Solvent violet 13:0.35%
White titanium pigment: 11%
EBS：3.45％
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 2: 1～4: 1; Addition is 1～2wt% of ABS resin quality; It is added in the ABS resin, can obtain the ABS material of the purple visual effect of marble light at the bottom of the three-dimensional colour of skin of different 3D.
Embodiment 12
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---Masterbatch form
Carbon black: 1%
White titanium pigment: 80%
Low-molecular polyethylene wax: 9%
Permanent white: 10%
Complexion compsn---Masterbatch form
PBT:40% (intrinsic viscosity IV is 0.72dl/g)
PETG:45% (intrinsic viscosity IV is 0.86dl/g)
Carbon black: 10%
Metallocene PE wax: 5%
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～3: 1; Addition is 2～3wt% of ABS resin quality; It is added in the ABS resin, can obtain marble blackout at the bottom of the three-dimensional grey of different 3D and feel the ABS material of effect.
Embodiment 13
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---Masterbatch form
Ultramarine blue: 0.5%
Ultramarine violet: 0.5%
White titanium pigment: 60%
WHITE CARBON BLACK: 39%
Complexion compsn---Masterbatch form
PET:75% (intrinsic viscosity IV is 1.02dl/g)
PEN:10% (intrinsic viscosity IV is 0.75dl/g)
Pigment Blue 15: 3:6.5%
Solvent blue 19 04:4.5%
Cover dawn acid esters wax: 4%
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～3: 1, and addition is 3～4wt% of ABS resin quality, and it is added in the ABS resin, can obtain the ABS material of the three-dimensional white background marble of different 3D Cyanopia feel effect.
Embodiment 14
Said look female compsn is made up of complexion compsn and background color compsn, and said complexion compsn and background color compsn are formed as follows:
Background color compsn---Masterbatch form
Pigment Yellow 73 184:21%
White titanium pigment: 40%
Low-molecular polyethylene wax: 9%
Permanent white: 30%
Complexion compsn---Masterbatch form
PBT:40% (intrinsic viscosity IV is 0.72dl/g)
PETG:35% (intrinsic viscosity IV is 0.86dl/g)
Carbon black: 10%
Metallocene PE wax: 5%
EBS：10％
Complexion compsn and background color compsn obtain look female compsn with weight part mixing in 1: 1～3: 1; Addition is 2～3wt% of ABS resin quality; It is added in the ABS resin, can obtain the ABS material of marble blackout feel of the three-dimensional yellow end of different 3D effect.
Applicant's statement, the present invention explains detailed composition of the present invention through the foregoing description, but the present invention is not limited to above-mentioned detailed prescription, does not mean that promptly the present invention must rely on above-mentioned detailed prescription and could implement.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of each raw material of product of the present invention and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. a marble visual effect look female compsn that is used for the acrylonitrile-butadiene-styrene copolymer resin is characterized in that said compsn comprises the complexion compsn, and said complexion compsn comprises thermoplastic polyester.
2. compsn as claimed in claim 1 is characterized in that, said thermoplastic polyester accounts for 20～95% of complexion compsn total mass, preferred 25～90%, further preferred 30～90%;
Preferably; Said thermoplastic polyester is selected from polyethylene terephthalate, mutual-phenenyl two acid bromide two alcohol ester, amorphized polyethylene terephthalate, polyethylene terephthalate-1; 4-cyclohexanedimethanoester ester, PEN, poly terephthalic acid 1; The mixture of a kind of in 4-hexanaphthene dimethyl ester and the PTT or at least two kinds; Preferred polyethylene terephthalate, mutual-phenenyl two acid bromide two alcohol ester, amorphized polyethylene terephthalate and polyethylene terephthalate-1; The mixture of a kind of in the 4-cyclohexanedimethanoester ester or at least two kinds, further preferred polyethylene terephthalate and/or mutual-phenenyl two acid bromide two alcohol ester and multipolymer thereof.
3. like the described compsn of one of claim 1-2, it is characterized in that said complexion compsn also comprises tinting material;
Preferably, said complexion compsn also comprises additive, and said additive is selected from the combination of a kind of in stopping composition, dispersion agent and the lubricant or at least two kinds.
4. like the described compsn of one of claim 1-3, it is characterized in that said compsn also comprises the background color compsn, said background color compsn comprises tinting material and white titanium pigment;
Preferably, said background color compsn also comprises additive, and said additive is selected from the combination of a kind of in dispersion agent, stopping composition and the lubricant or at least two kinds.
5. like the described compsn of one of claim 1-4, it is characterized in that said tinting material comprises pigment and/dyestuff;
Preferably; Said dyestuff is selected from the mixture of a kind of in anthraquinone dyes, Oil Soluble Azo Dyes, phthalocyanine pigment, indoles mattress base methine dyes and the quinophthalone dyestuff or at least two kinds; The mixture of a kind of in preferred solvent red 135, solvent red 196, DISPERSE YELLOW 201, solvent yellow 114, DISPERSE ORANGE 30 200 47, solvent orange 63,63 ,DIS,PER,SE ,Vio,let, 63 26,63 ,DIS,PER,SE ,Vio,let, 63 31, solvent blue 19 04, solvent blue 97, solvent green 3 and the solvent green 28 or at least two kinds, the mixture of further preferred a kind of in solvent red 135, solvent red 196,63 ,DIS,PER,SE ,Vio,let, 63 26,63 ,DIS,PER,SE ,Vio,let, 63 31, solvent blue 19 04, solvent blue 97, solvent green 3 and solvent green 28 or at least two kinds;
Preferably, said pigment comprises pigment dyestuff and/or mineral dye;
Preferably; Said pigment dyestuff is selected from the mixture of a kind of in diketone-pyrroles-pyrrole pigment, azo lake pigment, benzimidazolone azo pigment, quinacridone pigments, azo condensation pigment 、 perylene pigments, En Kun piceneketone pigment 、 triazine dioxin pigment, phthalocyanine pigment and the carbon black or at least two kinds; The mixture of a kind of in preferred diketone-pyrroles-pyrrole pigment, azo lake pigment 、 triazine dioxin pigment, phthalocyanine pigment, benzimidazolone pigment and the carbon black or at least two kinds, the mixture of a kind of in further preferred diketone-pyrroles-pyrrole pigment, benzimidazolone pigment, phthalocyanine pigment and the carbon black or at least two kinds;
Preferably; Said mineral dye is selected from the mixture of a kind of in Pigment Yellow 73, Pigment red, Pigment blue, ultramarine violet and the pigment brown or at least two kinds; Preferred pigments is yellow 24, the mixture of a kind of in pigment yellow 34, Pigment Yellow 73 35, Pigment Yellow 73 53, Pigment Yellow 73 164, Pigment Yellow 73 184, Pigment red 101, Pigment red 104, Pigment red 108, Pigment blue 28, Pigment blue 29, ultramarine violet 15, ultramarine violet 16, pigment brown 24, pigment brown 29 and the pigment brown 43 or at least two kinds; The further mixture of a kind of in yellow 24, the Pigment Yellow 73 35 of preferred pigments, Pigment Yellow 73 53, Pigment Yellow 73 164, Pigment Yellow 73 184, Pigment red 101, Pigment red 108, Pigment blue 29, pigment violet 15, pigment violet 16 and the pigment brown 24 or at least two kinds, the more preferably mixture of a kind of in Pigment Yellow 73 53, Pigment red 101, Pigment blue 29, pigment violet 15, pigment violet 16 and the pigment brown 24 or at least two kinds.
6. like the described compsn of one of claim 1-5; It is characterized in that; Said dispersion agent is selected from the mixture of a kind of in metallic soap, new LDPE (film grade) and copolymer waxes thereof, low-molecular-weight ethylenic-vinyl acetate copolymer wax, ethylene-acrylic acid copolymer ion salt, metallocene PE wax, metallocene polypropylene wax, aliphatic amide and verivate thereof, micro mist wax and the illiteracy dawn acid esters wax or at least two kinds, the mixture of a kind of in preferable alloy soap, metallocene PE wax, metallocene polypropylene wax, micro mist wax and the illiteracy dawn acid esters wax or at least two kinds;
Preferably; Said lubricant is selected from the mixture of a kind of in saturated hydrocarbons, metallic soap class, aliphatic amide type, aliphatics acids, aliphatic ester and the aliphatics alcohols or at least two kinds; The mixture of a kind of in preferable alloy soap class, aliphatic amide type and the aliphatic ester or at least two kinds, the mixture of a kind of in further preferred Triple Pressed Stearic Acid, calcium stearate, Zinic stearas, Magnesium Stearate, erucicamide and EBS and the verivate thereof or at least two kinds;
Preferably; Said stopping composition is selected from the mixture of a kind of in permanent white, zinc sulfide white, WHITE CARBON BLACK, talcum powder, lime carbonate, wollastonite, mica powder, kaolin, brucite, wilkinite, zeyssatite and the pumice sand or at least two kinds; The mixture of a kind of in preferably barium sulfate, lime carbonate, zinc sulfide white and the WHITE CARBON BLACK or at least two kinds, the further mixture of a kind of in preferably barium sulfate, water-ground limestone, light calcium carbonate, nano-calcium carbonate, zinc sulfide white and the WHITE CARBON BLACK or at least two kinds.
7. like the described compsn of one of claim 1-6, it is characterized in that said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Or said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Or said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Said each component of complexion compsn and be 100%.
8. like the described compsn of one of claim 1-7, it is characterized in that said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Or said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Or said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Each component sum of said background color compsn is 100%.
9. like the described compsn of one of claim 1-8, it is characterized in that said compsn is made up of the complexion compsn, said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Each component sum of said complexion compsn is 100%.
10. like the described compsn of one of claim 1-9, it is characterized in that said compsn is made up of complexion compsn and background color compsn, said complexion compsn comprises by the mass percent of its each ingredients constitute complexion compsn total mass:
Each component sum of said complexion compsn is 100%;
Said background color compsn comprises by the mass percent of its each ingredients constitute background color compsn total mass:
Each component sum of said background color compsn is 100%.
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| CN2012100984783A CN102617975A (en) | 2012-04-06 | 2012-04-06 | Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin |
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| CN2012100984783A CN102617975A (en) | 2012-04-06 | 2012-04-06 | Marble vision effect color master batch composition for acrylonitrile-butadiene-styrene (ABS) copolymer resin |
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| CN108976693A (en) * | 2018-08-07 | 2018-12-11 | 东莞市荣晟颜料有限公司 | A kind of marbling Masterbatch and its application method suitable for ABS |
| CN108976693B (en) * | 2018-08-07 | 2021-01-15 | 东莞市荣晟颜料有限公司 | Marble-like grain color master batch suitable for ABS and use method thereof |
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| CN110564177A (en) * | 2019-10-09 | 2019-12-13 | 江苏亚邦染料股份有限公司 | purple disperse dye composition for printing |
| CN110564177B (en) * | 2019-10-09 | 2021-04-20 | 江苏亚邦染料股份有限公司 | Purple disperse dye composition for printing |
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| CN116199913A (en) * | 2023-03-15 | 2023-06-02 | 大韩高性能材料(广东)有限公司 | ABS (Acrylonitrile butadiene styrene) high-light-color master batch and preparation method thereof |
| CN116199913B (en) * | 2023-03-15 | 2023-10-20 | 大韩高性能材料(广东)有限公司 | ABS (Acrylonitrile butadiene styrene) high-light-color master batch and preparation method thereof |
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