CN101642093A - Botanical pesticide solvent - Google Patents
Botanical pesticide solvent Download PDFInfo
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- CN101642093A CN101642093A CN200910152314A CN200910152314A CN101642093A CN 101642093 A CN101642093 A CN 101642093A CN 200910152314 A CN200910152314 A CN 200910152314A CN 200910152314 A CN200910152314 A CN 200910152314A CN 101642093 A CN101642093 A CN 101642093A
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Abstract
The invention relates to a botanical pesticide solvent, in particular to a pesticide solvent taking vegetable oil and co-solvent as raw materials. The invention is characterized in that the botanicalpesticide solvent contains 85% to 100% of vegetable oil and 0% to 15% of co-solvent in percentage by weight; the vegetable oil is at least one of jatropha curcas oil methyl ester and jatropha curcas oil. The co-solvent is at least one of isopropanol, glycol, N-methylpyrrolidone, N-ethyl pyrrolidone, N-octyl pyrrolidone and azone. The botanical pesticide solvent can be applied to the preparations such as emulsifiable concentrates, oil solution, oil suspension, microemulsion, aqueous emulsion and ultra-low-volume concentrate, is suitable for preparing various kinds of pesticide ingredients suchas insecticide, acaricide, bactericide, weedicide and plant growth regulator and the like. The botanical pesticide solvent of the invention has strong dissolving power, environmentally-friendly performance, wide material source and low cost, and does not drive for food with human, has good spreading permeability and drifting-resisting performance and is an ideal choice for replacing aromatic organic solvents.
Description
Technical field
The present invention relates to a kind of plant source pesticide solvent, especially relate to a kind of plant source pesticide solvent that contains vegetable oil.
Background technology
Domestic for a long time pesticide liquid body preparation is produced, be extensive use of aromatic hydrocarbons (comprising benzene,toluene,xylene etc.) organic solvent, polar solvent (N for example, dinethylformamide (DMF), cyclohexanone etc.) etc., but its toxicity to human body, environment can not be ignored.As everyone knows, aromatic hydrocarbon solvent (comprising benzene,toluene,xylene etc.) is the strong carcinogen that the World Health Organization determines, is the maximum etiology that causes alpastic anemia (leukemia) and fetal congenital defective.And aromatic hydrocarbon solvent (comprising benzene,toluene,xylene etc.) is again a kind of inflammable and explosive Hazardous Chemical Substances, danger close all in pesticidal preparations processing and storage and transport process.N, dinethylformamide (DMF) can pass through respiratory tract, skin and digestive tract and invade body, and is difficult for being discharged by human body, and main clinical manifestation is symptom of digestive tract and hepatic disorder, the reproductive function of humans and animals all there is to a certain degree detrimental effect, and can causes neonate's defective.
1992, U.S. government put into effect and has forbidden the regulation that organic solvents such as toluene, dimethylbenzene are used for pesticidal preparations, and after this, European countries have put into effect similar regulation in succession; By the end of in February, 2006,38 kinds of organic solvents that use in the Pesticidal products such as China Taiwan agricultural commission paraxylene, aniline, benzene, carbon tetrachloride, trichloro-ethylene management of having carried out limiting the quantity of, the content of dimethylbenzene, cyclohexanone can not surpass 10% in the agricultural chemicals finished product, dimethyl formamide and methyl alcohol should be less than 30%, the content of ethylbenzene can not surpass 2%, and remaining 33 kinds of auxiliary agent all can not be greater than 1%.
Along with the structural adjustment of National Development and Reform Committee's increasing to formulations of pesticide product, the output of compression missible oil product, agricultural chemicals enterprise presses for to be sought high effective additives environmentally friendly, that toxicity is low, easy degraded, renewable resources are derived and replaces petrochemical industry series products or derivatives thereof.Meet the requirement of environment-friendly type preparation based on the formulations of pesticide of plant resource environment-protection pesticide solvent processing, can be in the use on vegetables, fruit, oil crop, tealeaves, the traditional Chinese medicine; With target stronger affinity is arranged, can give full play to the preventive and therapeutic effect of active ingredient, compare, need not to add the function that a large amount of synergist improve preparation with waterborne preparation.In addition, when plant resource environment-protection pesticide solvent is used as the carrier fluid of agricultural chemicals, can make weed killer herbicide be able to more effective application during the low capacity dispenser, its major advantage is soup not volatile and drift in the sprinkling process, it is more even that soup is labeled covering plant, and weed killer herbicide is difficult for being fallen by rain drop erosion.
In existing patent documentation, adopt vegetable oil or its derivative many as the report that pesticide solvent uses, as soybean oil, corn oil, rapeseed oil, cottonseed oil, soybean oil methyl esters etc., these auxiliary agents all exist with the people strives food, the more high shortcoming of price.
The little seeds of a tung oil tree also claim little tung oil tree, Jatropha curcas (Jatropha curcas L.), are euphorbia plants, and the whole world has 200 kinds approximately, belong to the perennial woody oil plants, originate in America and Africa, are distributed in the torrid zone or subtropical zone.Usually be born in level land, hilly upland and the hillside fields, deserted mountain, river valley of height above sea level 700-1600m; All can grow at stone stony soil, coarse soil, limestone open ground.In the torrid areas, cultivated area is wider in China cultivation or semi-wild, and resource is than horn of plenty.The little seeds of a tung oil tree of China mainly are distributed in provinces and regions such as Guizhou, Sichuan, Guangdong, Guangxi, Yunnan, Taiwan, Fujian, Hainan.
Little seeds of a tung oil tree seeds well developed root system, main root is dark, and lateral root distributes wide, and rudiment is strong, and solid abundant, seed is big.Happiness light is heat-resisting, drought-resistant barren.Can be at annual precipitation 480-2380mm, average temperature of the whole year 18-28.5 ℃ environment is existence down; The solid amount of the little seeds of a tung oil tree is big, and seed is big, and the high about 35%-50% of seed kind benevolence oil content reaches as high as 60%, and oil content surpasses common oil crop such as rape and soybean, but plantation then is then with regard to the result.According to the study, the dry fruit output of the wild little seeds of a tung oil tree is 4500-12000kg/hm2, and the about 10000kg/hm2 of average yield can extract and process about 2700kg Jatropha curcas oil.The Jatropha curcas oil methyl esters that domestic application at present obtains after only being confined to Jatropha curcas oil methylated uses as a kind of biofuel, and is subjected to the lower influence of crude oil price in the recent period, the continued downturn of biofuel market, and application is very limited.
Contain some natural activity compositions in the Jatropha curcas oil, have the biologically active of agricultural chemicals, medicine, antibiotic, resisting tobacco mosaic virus is arranged and some cancer cell had effect such as the activity of inhibition.
It is simple that the plantation of the little seeds of a tung oil tree can not account for arable land, drought-resistant, impoverishment tolerant, tillage method, and the oil production height belongs to the row of the minimum oil plants of cost.The processing cost of one ton of Jatropha curcas oil methyl esters of present every production is no more than 4500 yuan, compares with the vegetable oil of present use to have good development potentiality.And the development selection substitutes dangerous poisonous benzene kind solvent and polar solvent in the plant resource environmentally friendly solvent of recyclable regenerative, alleviates non-renewable petroleum resources shortage pressure, also is the needs of the sustainable development of socio-economy.
Summary of the invention
The purpose of this invention is to provide a kind of plant source pesticide solvent that is applicable to that pesticidal preparations processing is used, possess the machine solvent, simultaneously, overcome problems such as frequently seen plants oil is little to farm chemical ingredients solvability, use cost height to substitute acyclics such as aromatic hydrocarbons.
The vegetable oil that the present invention relates to is selected from Jatropha curcas oil or Jatropha curcas oil methyl esters, wide material sources, mature production technology, moderate cost.
The inventor finds in research screening, derives from the Jatropha curcas oil of the little seeds of a tung oil tree, has preferably dissolving power, penetration strong to most of agricultural chemicals, and intrinsic active skull cap components makes it have synergistic effect in the Jatropha curcas oil.Simultaneously, little seeds of a tung oil tree vegetable oil has wide material sources, output is big, price is low, do not strive food with the people, do not strive characteristics such as ground with agricultural production, has possessed the primary condition that is developed as the environment-protection pesticide solvent.
The plant source pesticide solvent that the present invention relates to is characterized in that containing vegetable oil 85%-100%, cosolvent 0%-15% in mass percent, and described vegetable oil is Jatropha curcas oil or its methyl esters; Described cosolvent is one or more in isopropyl alcohol, ethylene glycol, N-Methyl pyrrolidone, N-ethyl pyrrolidone, N-octylpyrrolidone, the azone.Through test, plant source pesticide solvent of the present invention can compare favourably with the aromatic hydrocarbons organic solvent to the solvability of agricultural chemicals, can substitute the aromatic hydrocarbons organic solvent fully, be applied to produce pesticidal preparations such as missible oil, finish, oil suspending agent, microemulsion, aqueous emulsion, ultra low volume spraying agent.Plant source pesticide solvent of the present invention is suitable for Multiple Pesticides components matching such as insecticide, bactericide, weed killer herbicide, plant growth regulator to be used, can and produce the different of preparation type according to pesticide species, can use the composition of vegetable oil or vegetable oil and described cosolvent separately.
Plant source pesticide solvent of the present invention can also be processed and be mixed with the mixed auxiliary agent of bucket that does not contain pesticide activity component, cooperates bucket to mix with the commercially available agricultural chemical preparation that contains active ingredient as a kind of builder and uses, and is remarkable to the pesticide synergistic effect.When being used for the mixed auxiliary agent of bucket, it is characterized in that containing by mass percentage Jatropha curcas oil methyl esters 85%-95%, surfactant 5%-15%, described surfactant is one or more in the pure APEO in C12～14, expoxy propane/epoxyethane block copolymer, anhydrous sorbitol APEO, sodium diethylhexyl sulfosuccinate, rosin polyoxyethylene sulfonate, the ethoxylated alkyl phosphate.In the practical application, should the mixed auxiliary agent of bucket convert 200 times to 2000 times of water dilutions and mix with pesticide barrel and use, can significantly improve pharmacy effect.
The plant source pesticide solvent that the present invention relates to is compared with the aromatic hydrocarbons organic solvent, has following significant technological progress: 1, plant resource solvent, and environment-friendly degradable, pollution-free; 2, good with the agricultural chemicals compatibility, solvability is big; 3, flash-point height [〉=45 ℃ (remaining silent), (dimethylbenzene is 25 ℃)], the burning-point height, aromatic-free class organic solvent, security performance is good, and the production accumulating is safe and reliable.
Compare with traditional vegetable oil with the aromatic hydrocarbons organic solvent, plant source pesticide solvent of the present invention has following advantage: the fruit that 1, derives from the little seeds of a tung oil tree, wide material sources, oil production is big, price is low, do not strive food, do not strive ground with agricultural production with the people, is renewable resources; 2, this solvent is suitable with the aromatic hydrocarbons organic solvent to the solvability of farm chemical ingredients, and has good permeability and the anti-drift of opening up; Intrinsic active skull cap components makes it have excellent synergistic effect in the vegetable oil, and safety and integrated control effect all are better than using the preparation of aromatic hydrocarbon solvent; 3, applied widely, can be applicable to pesticidal preparations such as missible oil, finish, oil suspending agent, microemulsion, aqueous emulsion, ultra low volume spraying agent.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.
Embodiment 1 adds 950 kilograms of Jatropha curcas oil methyl esters in reactor, 50 kilograms of isopropyl alcohols stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 2 adds 980 kilograms of Jatropha curcas oil methyl esters in reactor, 20 kilograms of ethylene glycol stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 3 adds 850 kilograms of Jatropha curcas oil methyl esters in reactor, 150 kilograms of N-Methyl pyrrolidone stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 4 adds 850 kilograms of Jatropha curcas oil methyl esters in reactor, 30 kilograms of isopropyl alcohols, and 120 kilograms of N-Methyl pyrrolidone stir, and promptly get 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 5 adds 900 kilograms of Jatropha curcas oil methyl esters in reactor, N-ethyl pyrrolidone double centner stirs, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 6 adds 950 kilograms of Jatropha curcas oil methyl esters in reactor, 50 kilograms of N-octylpyrrolidone stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 7 adds 920 kilograms of Jatropha curcas oil methyl esters in reactor, 30 kilograms of isopropyl alcohols, and 50 kilograms of N-octylpyrrolidone stir, and promptly get 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 8 adds 980 kilograms of Jatropha curcas oil methyl esters in reactor, 20 kilograms of azones stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 9 adds 920 kilograms of Jatropha curcas oil methyl esters in reactor, 30 kilograms of isopropyl alcohols, and 50 kilograms of N-octylpyrrolidone stir, and promptly get 1000 kilograms of plant source pesticide solvents of the present invention.
1000 kilograms of embodiment 10 Jatropha curcas oils promptly get 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 11 adds 950 kilograms of Jatropha curcas oils in reactor, 50 kilograms of N-octylpyrrolidone stir, and promptly gets 1000 kilograms of plant source pesticide solvents of the present invention.
Embodiment 12 adds 400 kilograms of Jatropha curcas oils in reactor, 550 kilograms of Jatropha curcas oil methyl esters, and 50 kilograms of N-octylpyrrolidone stir, and promptly get 1000 kilograms of plant source pesticide solvents of the present invention.
The mixed auxiliary agent compound method of bucket that the present invention relates to describes with following specific embodiment, but the present invention is limited to these examples absolutely not.
Embodiment 13 adds 850 kilograms of Jatropha curcas oil methyl esters in reactor, 60 kilograms of the pure APEOs in C12～14,40 kilograms of expoxy propane/epoxyethane block copolymers, 50 kilograms of ethoxylated alkyl phosphate, stir, promptly get 1000 kilograms of pesticide barrels and mix auxiliary agent.
Embodiment 14 adds 900 kilograms of Jatropha curcas oil methyl esters in reactor, 40 kilograms of sodium diethylhexyl sulfosuccinates, 30 kilograms of anhydrous sorbitol APEOs, 30 kilograms in rosin polyoxyethylene sulfonate, stir, promptly get 1000 kilograms of pesticide barrels and mix auxiliary agent.
Embodiment 15 adds 900 kilograms of Jatropha curcas oil methyl esters in reactor, 30 kilograms of N-octylpyrrolidone, 20 kilograms of the pure APEOs in C12～14,20 kilograms of anhydrous sorbitol APEOs, 30 kilograms of ethoxylated alkyl phosphate stir, and promptly get 1000 kilograms of pesticide barrels and mix auxiliary agent.
Following examples are quoted the plant source pesticide solvent that the present invention relates to its application in the agricultural chemicals different dosage form are described, but the present invention is limited to these examples absolutely not.
Embodiment 16 adds 490 kilograms of embodiment 1 plant source pesticide solvents in reactor, stir, add 400 kilograms of phoxims successively, 50 kilograms of triphen ethyl phenol APEOs, 20 kilograms of the pure APEOs in C12～14,40 kilograms of calcium dodecyl benzene sulfonates, stirring and dissolving promptly gets 1000 kilogram of 40% phoxim emulsifiable concentrate
Embodiment 17 adds 420 kilograms of embodiment 3 plant source pesticide solvents in reactor, stir, add 480 kilograms of chlopyrifos successively, 40 kilograms of alkylphenol polyoxyethylene, 10 kilograms of the pure APEOs in C12～14,50 kilograms of calcium dodecyl benzene sulfonates, stirring and dissolving promptly gets 1000 kilogram of 48% chlorpyrifos ec.
Embodiment 18 adds 740 kilograms of embodiment 4 plant source pesticide solvents in reactor, stir, add 50 kilograms of Avermectin successively, the ethanol double centner, 40 kilograms of alkylphenol polyoxyethylene, 20 kilograms of the pure APEOs in C12～14,20 kilograms of castor oil polyoxyethylene ethers, 30 kilograms of calcium dodecyl benzene sulfonates, stirring and dissolving promptly gets 1000 kilogram of 5% abamectin emulsifiable concentrate.
Embodiment 19 adds 742 kilograms of embodiment 6 plant source pesticide solvents in reactor, stir, add 88 kilograms of Quizalotop-ethyls successively, 20 kilograms of isopropyl alcohols, 50 kilograms of alkylphenol polyoxyethylene, 40 kilograms of the pure APEOs in C12～14,60 kilograms of calcium dodecyl benzene sulfonates, stirring and dissolving promptly gets 1000 kilogram of 8.8% Quizalotop-ethyl missible oil.
Embodiment 20 adds 640 kilograms of embodiment 9 plant source pesticide solvents in reactor, stir, add 250 kilograms of propiconazoles successively, 30 kilograms of the pure APEOs in C12～14,40 kilograms of alkyl phenol formaldehyde resin polyoxyethylene ethers, 40 kilograms of calcium dodecyl benzene sulfonates, stirring and dissolving promptly gets 1000 kilogram of 25% propiconazole emulsifiable concentrate.
Embodiment 21 adds 200 kilograms of atrazines in grinding still, 60 kilograms of gaseous state silica, 660 kilograms of embodiment 10 plant resource environment-protection pesticide solvents, 30 kilograms of the pure APEOs in C12～14,20 kilograms of anhydrous sorbitol APEOs, 30 kilograms of lignosulfonates through sand milling, promptly get 1000 kilogram of 20% atrazine oil suspending agent.
Embodiment 22 adds 200 kilograms of four mite piperazines in grinding still, 00 kilogram of gaseous state silica 1,630 kilograms of embodiment 8 plant resource environment-protection pesticide solvents, 30 kilograms of expoxy propane/epoxyethane block copolymers, 20 kilograms of castor oil polyoxyethylene ethers, 20 kilograms of alkyl naphthalene sulfonates through sand milling, promptly get 1000 kilogram of 20% 4 mite piperazine oil suspending agent.
Embodiment 23 adds 45 kilograms of beta-cypermethrins in reactor, 120 kilograms of embodiment 2 plant source pesticide solvents, 60 kilograms of ethanol, 70 kilograms of alkylphenol polyoxyethylene phosphates, 30 kilograms of the pure APEOs in C12～14,40 kilograms of ethoxylated alkyl phosphate, stirring and dissolving, add 635 kilograms of entry again, stir, promptly get 1000 kilogram of 4.5% beta-cypermethrin microemulsion.
Embodiment 24 adds 45 kilograms of beta-cypermethrins in reactor, 20 kilograms of glycerine, embodiment 2 plant source pesticide solvent double centners stir, 40 kilograms of alkylphenol polyoxyethylene phosphates, 20 kilograms of the pure APEOs in C12～14, polyvinyl alcohol 20, stirring and dissolving, add 755 kilograms of entry again, stir, high speed shear emulsification under 5000 rev/mins of conditions of rotating speed promptly gets 1000 kilogram of 4.5% high performance aqueous emulsion of cypermethrin.
Embodiment 25 adds 250 kilograms of phoxims in reactor, 40 kilograms of ethylene glycol, 650 kilograms of embodiment 10 plant source pesticide solvents, 50 kilograms of alkylphenol polyoxyethylene, 10 kilograms of alkylphenol polyoxyethylene phosphates, stirring and dissolving, promptly getting can be for 1000 kilogram of 25% phoxim finish of ultra low volume spraying.
The plant source pesticide solvent that the present invention relates to has the effect of good synergy to pesticidal preparations, and to compare drug effect better for main pesticidal preparations with using aromatic hydrocarbon solvent.Below be the prescription drug effect comparative test result that pesticidal preparations uses different solvents:
Indoor, adopt the dip method method to measure the control efficiency of 5% abamectin emulsifiable concentrate to diamond-back moth 3 instar larvaes, result of the test sees Table 1.
Table 1 adopts dip method to measure the indoor pharmacodynamic test result of 5% abamectin emulsifiable concentrate different formulations to diamond-back moth 3 instar larvaes
Indoor, employing is soaked slide method and is measured the control efficiency of 5% abamectin emulsifiable concentrate to two spotted spider mite (the female one-tenth mite in 3-5 days ages), and result of the test sees Table 2.
Table 2 employing is soaked slide method and is measured the indoor pharmacodynamic test result of 5% abamectin emulsifiable concentrate different formulations to two spotted spider mite (the female one-tenth mite in 3-5 days ages)
Can find that from table 1 and table 2 result the plant source pesticide solvent that the present invention relates to is remarkable to 5% abamectin emulsifiable concentrate synergistic effect.
Indoor, employing is soaked the worm immersion method and is measured the control efficiency of 4.5% beta-cypermethrin microemulsion to beet armyworm 3 instar larvaes, and result of the test sees Table 3.
Table 3 employing is soaked slide method and is measured the indoor pharmacodynamic test result of 4.5% beta-cypermethrin microemulsion different formulations to beet armyworm 3 instar larvaes
Can find that from table 3 result the plant source pesticide solvent that the present invention relates to is remarkable to 4.5% beta-cypermethrin microemulsion synergistic effect.
Adopt soil spraying facture to measure the control efficiency of 20% atrazine oil-suspending agent to lady's-grass, eleusine indica, lamb's-quarters, kitchen garden, 4 kinds of common weeds of corn field are adopted in test, 2 kinds of grassy weeds: lady's-grass (Digitaria sanguinalis (L.) Scop), eleusine indica (Eleusine indica); 2 kinds of broad leaved weeds: kitchen garden (Portulaca oleracea L.), lamb's-quarters (Chenopodium album) are the seed of the susceptible weeds collection of growth in the experimental field.Result of the test sees Table 4.
Table 4 adopts soil spraying facture to the result of the test of 20% atrazine oil-suspending agent to lady's-grass, eleusine indica, lamb's-quarters, kitchen garden
As can be seen from Table 4, control efficiency can reach 97.56% during 20% atrazine oil suspending agent 500ppm, is much higher than the control efficiency of 20% atrazine oil-suspending agent 79.89% of corn oil base under the Isodose.The actual preventive effect of 20% atrazine oil suspending agent 200ppm control efficiency during near 20% atrazine oil-suspending agent 400ppm of corn oil base.Show that the plant source pesticide solvent that the present invention relates to is remarkable to 20% atrazine oil suspending agent synergistic effect.
Indoor, adopt pot-culture method to measure barrel indoor exercising result that mixed auxiliary agent (embodiment 13) is prevented and treated wheat powdery mildew to 25% propiconazole emulsifiable concentrate and see Table 5.
Table 5 adopt pot-culture method measure the mixed auxiliary agent of bucket to 25% propiconazole emulsifiable concentrate control wheat powdery mildew indoor treatment results
Can find that from table 5 result the mixed auxiliary agent of bucket that the present invention relates to is remarkable to 25% propiconazole emulsifiable concentrate synergistic effect.
Claims (5)
1, a kind of plant source pesticide solvent is characterized by in mass percent and contains vegetable oil 85%-100%, cosolvent 0%～15%, and described vegetable oil is at least a in Jatropha curcas oil methyl esters, the Jatropha curcas oil.
2,, it is characterized in that described cosolvent is one or more in isopropyl alcohol, ethylene glycol, N-Methyl pyrrolidone, N-ethyl pyrrolidone, N-octylpyrrolidone, the azone according to claim 1.
3, plant source pesticide solvent according to claim 1 is characterized in that this plant source pesticide solvent can be applicable to prepare emulsifiable concentrates for agricultural chemicals, finish, oil suspending agent, microemulsion, aqueous emulsion, ultra low volume spraying agent with pesticide activity component.
4, plant source pesticide solvent according to claim 1 is characterized in that being used to prepare the mixed auxiliary agent of agricultural bucket that does not contain pesticide activity component, mixes with other pesticidal preparations bucket and uses its synergistic effect of agricultural chemicals.
5, according to claim 5, it is characterized by: in the mixed auxiliary agent of this agricultural bucket, contain Jatropha curcas oil methyl esters 85%～95%, surfactant 5%～15% in mass percent; Described surfactant is one or more in the pure APEO in C12～14, expoxy propane/epoxyethane block copolymer, anhydrous sorbitol APEO, sodium diethylhexyl sulfosuccinate, rosin polyoxyethylene sulfonate, the ethoxylated alkyl phosphate.In ester sodium sulfonate, rosin polyoxyethylene sulfonate, the ethoxylated alkyl phosphate one or more.
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| CN200910152314A CN101642093A (en) | 2009-06-24 | 2009-06-24 | Botanical pesticide solvent |
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| CN200910152314A CN101642093A (en) | 2009-06-24 | 2009-06-24 | Botanical pesticide solvent |
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| CN102132708A (en) * | 2011-01-28 | 2011-07-27 | 深圳市东域投资发展有限公司 | Bacteriostat from Jatropha curcas and bacteriostasis application thereof in planting edible mushrooms |
| CN102283195A (en) * | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | Pesticide adjuvant and preparation method thereof |
| CN102511476A (en) * | 2011-09-29 | 2012-06-27 | 海南利蒙特生物农药有限公司 | Spray assistant and preparation method thereof |
| CN103444702A (en) * | 2013-08-01 | 2013-12-18 | 广东中迅农科股份有限公司 | Environment-friendly solvent for processing of pesticide preparation |
| CN103651365A (en) * | 2013-12-30 | 2014-03-26 | 青岛崂乡茶制品有限公司 | Novel pesticide containing cypress camphor |
| WO2014063321A1 (en) * | 2012-10-24 | 2014-05-01 | 深圳诺普信农化股份有限公司 | Jatropha curcas-derived pesticide solvent, and preparation method and application thereof |
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| CN102132708B (en) * | 2011-01-28 | 2013-03-27 | 深圳市东域投资发展有限公司 | Bacteriostat from Jatropha curcas and bacteriostasis application thereof in planting edible mushrooms |
| CN102132708A (en) * | 2011-01-28 | 2011-07-27 | 深圳市东域投资发展有限公司 | Bacteriostat from Jatropha curcas and bacteriostasis application thereof in planting edible mushrooms |
| CN102283195A (en) * | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | Pesticide adjuvant and preparation method thereof |
| CN102511476A (en) * | 2011-09-29 | 2012-06-27 | 海南利蒙特生物农药有限公司 | Spray assistant and preparation method thereof |
| CN102511476B (en) * | 2011-09-29 | 2013-11-20 | 海南利蒙特生物农药有限公司 | Spray assistant and preparation method thereof |
| WO2014063321A1 (en) * | 2012-10-24 | 2014-05-01 | 深圳诺普信农化股份有限公司 | Jatropha curcas-derived pesticide solvent, and preparation method and application thereof |
| AU2012392861B2 (en) * | 2012-10-24 | 2015-09-03 | Shenzhen Noposion Crop Science Co., Ltd. | Jatropha curcas-derived pesticide solvent, and preparation method and application thereof |
| CN103444702A (en) * | 2013-08-01 | 2013-12-18 | 广东中迅农科股份有限公司 | Environment-friendly solvent for processing of pesticide preparation |
| CN103651365A (en) * | 2013-12-30 | 2014-03-26 | 青岛崂乡茶制品有限公司 | Novel pesticide containing cypress camphor |
| CN104872114A (en) * | 2014-06-13 | 2015-09-02 | 中国日用化学工业研究院 | Environmentally friendly insecticidal microemulsion and preparation technology thereof |
| CN104082283A (en) * | 2014-06-27 | 2014-10-08 | 罗云华 | Pesticide solvent |
| CN104082283B (en) * | 2014-06-27 | 2015-11-18 | 罗云华 | A kind of pesticide solvent |
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| CN104738080A (en) * | 2015-03-26 | 2015-07-01 | 湖北犇星农化有限责任公司 | Chlorpyrifos missible oil and preparation method thereof |
| CN106518395A (en) * | 2016-11-10 | 2017-03-22 | 云南农业大学 | Liquid water-soluble fertilizer high in spreading permeability and high in nutrient content and preparation method thereof |
| CN107743960A (en) * | 2017-09-25 | 2018-03-02 | 深圳诺普信农化股份有限公司 | Plant oil sources auxiliary agent and its preparation and application |
| CN110692653A (en) * | 2019-10-30 | 2020-01-17 | 凉山德农生物能源股份有限公司 | Jatropha curcas source environment disinfectant and preparation method thereof |
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Application publication date: 20100210 |