CN102763664A - Insecticide composite containing spirodiclofen and bifenazate - Google Patents
Insecticide composite containing spirodiclofen and bifenazate Download PDFInfo
- Publication number
- CN102763664A CN102763664A CN201210284522XA CN201210284522A CN102763664A CN 102763664 A CN102763664 A CN 102763664A CN 201210284522X A CN201210284522X A CN 201210284522XA CN 201210284522 A CN201210284522 A CN 201210284522A CN 102763664 A CN102763664 A CN 102763664A
- Authority
- CN
- China
- Prior art keywords
- bifenazate
- spiral shell
- acid esters
- dibasic acid
- shell mite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005653 Bifenazate Substances 0.000 title claims abstract description 175
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 239000002131 composite material Substances 0.000 title abstract description 16
- 239000005664 Spirodiclofen Substances 0.000 title abstract 2
- DTDSAWVUFPGDMX-UHFFFAOYSA-N spirodiclofen Chemical compound CCC(C)(C)C(=O)OC1=C(C=2C(=CC(Cl)=CC=2)Cl)C(=O)OC11CCCCC1 DTDSAWVUFPGDMX-UHFFFAOYSA-N 0.000 title abstract 2
- 239000002917 insecticide Substances 0.000 title description 15
- 239000000642 acaricide Substances 0.000 claims abstract description 54
- 241000488583 Panonychus ulmi Species 0.000 claims abstract description 19
- 241000488581 Panonychus citri Species 0.000 claims abstract description 10
- 230000000895 acaricidal effect Effects 0.000 claims abstract description 8
- 241001454293 Tetranychus urticae Species 0.000 claims abstract description 7
- 235000013399 edible fruits Nutrition 0.000 claims abstract description 7
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 180
- 150000002148 esters Chemical class 0.000 claims description 109
- 239000000375 suspending agent Substances 0.000 claims description 96
- 239000000203 mixture Substances 0.000 claims description 91
- 239000000843 powder Substances 0.000 claims description 44
- 238000009736 wetting Methods 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 10
- 238000009472 formulation Methods 0.000 claims description 8
- OARRHUQTFTUEOS-UHFFFAOYSA-N safranin Chemical compound [Cl-].C=12C=C(N)C(C)=CC2=NC2=CC(C)=C(N)C=C2[N+]=1C1=CC=CC=C1 OARRHUQTFTUEOS-UHFFFAOYSA-N 0.000 claims description 8
- 239000003905 agrochemical Substances 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 230000006378 damage Effects 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 5
- 239000002775 capsule Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 3
- 239000004530 micro-emulsion Substances 0.000 claims description 3
- 239000004495 emulsifiable concentrate Substances 0.000 claims description 2
- 208000015181 infectious disease Diseases 0.000 claims description 2
- 238000003860 storage Methods 0.000 claims description 2
- 244000141359 Malus pumila Species 0.000 claims 1
- 230000003449 preventive effect Effects 0.000 abstract description 93
- 239000004480 active ingredient Substances 0.000 abstract description 37
- 230000002195 synergetic effect Effects 0.000 abstract description 16
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 241000238876 Acari Species 0.000 abstract description 3
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 235000013601 eggs Nutrition 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 230000001225 therapeutic effect Effects 0.000 abstract 1
- -1 carbazic acid isopropyl ester Chemical class 0.000 description 88
- 239000003814 drug Substances 0.000 description 37
- 238000005507 spraying Methods 0.000 description 34
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 32
- 238000010790 dilution Methods 0.000 description 32
- 239000012895 dilution Substances 0.000 description 32
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 27
- 239000007859 condensation product Substances 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 230000001988 toxicity Effects 0.000 description 20
- 231100000419 toxicity Toxicity 0.000 description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 17
- 238000012360 testing method Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 15
- 239000004562 water dispersible granule Substances 0.000 description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 14
- 239000006229 carbon black Substances 0.000 description 13
- 239000000575 pesticide Substances 0.000 description 13
- 229920001285 xanthan gum Polymers 0.000 description 13
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 12
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 12
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 11
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 11
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000002360 preparation method Methods 0.000 description 9
- 239000005995 Aluminium silicate Substances 0.000 description 8
- 241000220225 Malus Species 0.000 description 8
- 235000012211 aluminium silicate Nutrition 0.000 description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 230000002147 killing effect Effects 0.000 description 8
- 235000014347 soups Nutrition 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 241000607479 Yersinia pestis Species 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 210000000481 breast Anatomy 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 238000009313 farming Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 241000675108 Citrus tangerina Species 0.000 description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- 238000012216 screening Methods 0.000 description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 description 5
- 235000011152 sodium sulphate Nutrition 0.000 description 5
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 229930014345 anabasine Natural products 0.000 description 4
- 230000008485 antagonism Effects 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- 238000004166 bioassay Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 4
- 238000005286 illumination Methods 0.000 description 4
- 238000001802 infusion Methods 0.000 description 4
- 230000002045 lasting effect Effects 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002728 pyrethroid Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 4
- 238000012422 test repetition Methods 0.000 description 4
- 239000002562 thickening agent Substances 0.000 description 4
- 230000001018 virulence Effects 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- 241001272567 Hominoidea Species 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 230000010534 mechanism of action Effects 0.000 description 3
- 230000003129 miticidal effect Effects 0.000 description 3
- 210000004681 ovum Anatomy 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 229930192474 thiophene Natural products 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- 241000239290 Araneae Species 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 244000061458 Solanum melongena Species 0.000 description 2
- 235000002597 Solanum melongena Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- CFRPSFYHXJZSBI-DHZHZOJOSA-N (E)-nitenpyram Chemical compound [O-][N+](=O)/C=C(\NC)N(CC)CC1=CC=C(Cl)N=C1 CFRPSFYHXJZSBI-DHZHZOJOSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 description 1
- RQJQQSAYDFANNM-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid;formaldehyde Chemical compound O=C.C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 RQJQQSAYDFANNM-UHFFFAOYSA-N 0.000 description 1
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 1
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241000524057 Acacia fleckii Species 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 239000005884 Beta-Cyfluthrin Substances 0.000 description 1
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241001292007 Chrysopa Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 235000009917 Crataegus X brevipes Nutrition 0.000 description 1
- 235000013204 Crataegus X haemacarpa Nutrition 0.000 description 1
- 235000009685 Crataegus X maligna Nutrition 0.000 description 1
- 235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 1
- 235000009486 Crataegus bullatus Nutrition 0.000 description 1
- 235000017181 Crataegus chrysocarpa Nutrition 0.000 description 1
- 235000009682 Crataegus limnophila Nutrition 0.000 description 1
- 235000004423 Crataegus monogyna Nutrition 0.000 description 1
- 240000000171 Crataegus monogyna Species 0.000 description 1
- 235000002313 Crataegus paludosa Nutrition 0.000 description 1
- 235000009840 Crataegus x incaedua Nutrition 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000005903 Gamma-cyhalothrin Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical class CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241001674048 Phthiraptera Species 0.000 description 1
- 241000758706 Piperaceae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000952063 Polyphagotarsonemus latus Species 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 241000283615 Taylorilygus apicalis Species 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- QQODLKZGRKWIFG-RUTXASTPSA-N [(R)-cyano-(4-fluoro-3-phenoxyphenyl)methyl] (1S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)Cl)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-RUTXASTPSA-N 0.000 description 1
- TWWCNXGLDZPFQV-XXAVUKJNSA-N [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O Chemical compound [Na].CNCCS(=O)(=O)O.C(CCCCCCC\C=C/CCCCCCCC)(=O)O TWWCNXGLDZPFQV-XXAVUKJNSA-N 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- DFFDSQBEGQFJJU-UHFFFAOYSA-M butyl carbonate Chemical compound CCCCOC([O-])=O DFFDSQBEGQFJJU-UHFFFAOYSA-M 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
- NHFDKKSSQWCEES-UHFFFAOYSA-N dihydrogen phosphate;tris(2-hydroxyethyl)azanium Chemical compound OP(O)(O)=O.OCCN(CCO)CCO NHFDKKSSQWCEES-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229960005082 etohexadiol Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- CBYZIWCZNMOEAV-UHFFFAOYSA-N formaldehyde;naphthalene Chemical compound O=C.C1=CC=CC2=CC=CC=C21 CBYZIWCZNMOEAV-UHFFFAOYSA-N 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000003197 gene knockdown Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940059904 light mineral oil Drugs 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 230000004132 lipogenesis Effects 0.000 description 1
- 239000011419 magnesium lime Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 229940079888 nitenpyram Drugs 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an acaricide composite for agricultural use, in particular to an acaricide composite containing the first active ingredient of spirodiclofen and the second active ingredient of bifenazate. Compared with siple dosage, the acaricide composite has a remarkable synergistic effect on acarina, has good preventive and therapeutic effects on panonychus citri on fruit trees, cotton and vegetables, panonychus ulmi, tetranychus urticae, tetranychus cinnabarinus or carmine spider mite, can kill eggs, larva, nymphs and adults, and is favorable for delaying production of drug resistance of acarina.
Description
[technical field]
The present invention relates to pesticide field, particularly the present invention relates to a kind of miticide composition, especially, the present invention relates to contain the miticide composition of spiral shell mite dibasic acid esters and Bifenazate.
[background technology]
Most of cultivated plants all can suffer the harm of mite class in process of growth, the mostly intensive vacuum side of blade thorn that infests plant of these mite classes is inhaled harm, make a large amount of underproduction such as fruit tree, cotton, vegetables and ornamental plants, and loss is serious.Mite class individuality is little, distribution is wide, adaptability is strong; Its breeding is rapid, and the history of life is short, and hibernacle changes greatly; Its population structure is complicated, in a colony, can have the mite of all vegetative stages, comprises ovum, if mite, young mite and become mite etc.; It is strong to poor environment adaptability, easily medicament is developed immunity to drugs etc.All these has determined that the control ratio of mite class is difficult.
CN102428950A also discloses a kind of mixed insecticide preparation that contains pyrethroid; Its active ingredient is spiral shell mite dibasic acid esters and pyrethroid insecticides; Spiral shell mite dibasic acid esters is 1-50% by weight; Pyrethroid insecticides is 1-50% by weight; Pyrethroid insecticides wherein is beta-cypermethrin, cypermethrin, betacyfluthrin, gamma cyhalothrin, Biphenthrin, fenpropathrin or decis, and has put down in writing this pesticidal preparations and can effectively kill crop pests such as aphid and diamond-back moth.
CN102396488A also discloses a kind of mixed insecticide preparation that contains anabasine; Its active ingredient is spiral shell mite dibasic acid esters and anabasine insecticide; Spiral shell mite dibasic acid esters is 1-50% by weight; Anabasine insecticide is 1-50% by weight, and anabasine insecticide wherein is Imidacloprid, Acetamiprid, Nitenpyram, thiophene worm piperazine, thiophene worm amine or thiophene worm quinoline, and has put down in writing this pesticidal preparations and can effectively kill crop pests such as aphid and green plant bug.
But; These products all have some defectives, and especially these products all do not relate to the miticide composition that comprises spiral shell mite dibasic acid esters and Bifenazate, and its practical effect can not satisfy actual needs; Therefore on agricultural crop, also need a kind of can kill ovum, young mite, if mite with become mite; It is long to have a lasting period, has prolonged agricultural chemicals service life, delays the composition pesticide of the drug-fast generation of evil mite again.For this reason, the inventor has carried out big quantity research, obtains challenging result.
For reaching goal of the invention, the technical scheme that the present invention adopts is to have chosen the agricultural miticide composition that comprises following two kinds of active components:
Spiral shell mite dibasic acid esters, its molecular formula: C
20H
22Cl
2O
5, relative molecular mass: 413.29, chemical name is: 3-(2,4 dichloro benzene base)-2-oxo-1-oxaspiro [4,5]-last of the ten Heavenly stems-3-alkene-4-base butyl carbonate.
Has following structural formula (I)
Spiral shell mite dibasic acid esters is identical with spiral shell mite ester mechanism of action, mainly is the lipogenesis that suppresses in the pest mite body, and does not have cross resistance between the existing miticide, is applicable to be used for preventing and treating the pest mite class that existing miticide is produced resistance.Acaricidal and its broad spectrum, adaptable, on spider, yellow spider, rust Pi lice, yellow tea mite, carmine spider mite and two-spotted spider mite, etc. have a good control effect, can be used for citrus, grapes and other fruit trees and eggplant, peppers, tomatoes and other solanaceous crops mites governance; ovicidal effect is particularly outstanding, while the immature nymphs have good contact action, and long duration to control citrus red mite damage up to 40-50 days .
Bifenazate (bifenazate CAS 149877-41-8), its chemical name: 3-(4-methoxyl biphenyl base-3-yl) carbazic acid isopropyl ester, molecular formula: C
17H
20N
2O
3, molecular weight: 300.35.Be that a kind of new selective foliar spray is used miticide.Its mechanism of action is the unique effect to a reanal (GABA) acceptor of the nervous centralis conducting system of mite class.Its each life stage to mite is effective, have ovicidal activity and knock down activity (48-72h) to what become mite, and the lasting period is long.About lasting period 14d, recommend in the using dosage scope crop safety.To parasitic wasp, predation mite, Chrysopa low-risk.
Bifenazate has following structural formula (II)
Formula (II)
Spiral shell mite dibasic acid esters is to becoming the mite weak effect, and quick-acting is relatively poor, and Bifenazate is composite with it, can reduce pesticide dosage, improves miticidal effect, reduces environmental pollution, has solved harmful mite single agricultural chemicals is prone to produce resistance problem.At present, the composite and application of spiral shell mite dibasic acid esters and Bifenazate is not all seen open both at home and abroad.The inventor finds, spiral shell mite dibasic acid esters and Bifenazate carried out composite, can reduce pesticide dosage, improves miticidal effect, reduces environmental pollution, solved harmful mite single agricultural chemicals is prone to the generation resistance problem.
[summary of the invention]
[technical problem that will solve]
The purpose of this invention is to provide a kind of miticide composition.
Another object of the present invention provides the miticide that contains said miticide composition.
Another object of the present invention provides the purposes of said miticide composition.
Another object of the present invention provides a kind of method of preventing and treating agricultural evil mite.
[technical scheme]
The present invention realizes through following technical proposals.
A kind of miticide composition is characterized in that, this miticide composition contains spiral shell mite dibasic acid esters and Bifenazate, and wherein the part by weight of spiral shell mite dibasic acid esters and Bifenazate is 1:50 to 50:1
A preferred embodiment of the invention, the part by weight that it is characterized in that said spiral shell mite dibasic acid esters and Bifenazate is 1:20 to 20:1.
According to another kind of preferred implementation of the present invention, the part by weight that it is characterized in that said spiral shell mite dibasic acid esters and Bifenazate is 1:5 to 5:1.
A kind of miticide is characterized in that this miticide contains the described miticide composition of each claim of claim 1-3 of 0.5-95 weight %, and surplus is acceptable carrier and an auxiliary agent on the agricultural chemicals.
A preferred embodiment of the invention is characterized in that, this miticide contains the described miticide composition of each claim of claim 1-3 of 5-85 weight %.
According to another kind of preferred implementation of the present invention, it is characterized in that this miticide contains the described miticide composition of each claim of claim 1-3 of 20-60 weight %.
According to another kind of preferred implementation of the present invention, it is characterized in that said auxiliary agent is a surfactant.
According to another kind of preferred implementation of the present invention, it is characterized in that described acaricidal formulation is liquor, emulsifiable concentrate, suspending agent, microemulsion, aqueous emulsion, pulvis, wetting powder, soluble powder, granule or capsule.
Described miticide composition is in the purposes of control panonychus citri, European red mite, apple Tetranychus urticae, Tetranychus cinnabarinus or cotton red spider.
A kind of method of preventing and treating agricultural evil mite; Before or after crops or fruit infection evil mite, use described miticide composition of each claim of claim 1-3 or the described miticide of each claim of claim 4-8 to the place of crops or fruit and growth or storage.
Except as otherwise noted, " % " in this specification all is weight percentage.
Provided by the inventionly contain miticide spiral shell mite dibasic acid esters and the Bifenazate miticide composition can make full use of two kinds of synergistic effects that active component is mixed and is produced; The expanding prevention spectrum; Improve preventive effect, reduce agricultural cost, delay the generation of pest resistance to insecticide; Solution repeats the inconvenience that repeatedly dispenser brings to the user when various insect pests endanger simultaneously, and repeats the adverse effects such as poisoning that dispenser possibly cause.
In the farm killing mite agent composition of the present invention, the amount of application of compound also depended on the ratio of a kind of compound and another kind of compound and the degree of synergistic effect when the amount that contains active component depended on independent the use.In the acaricide composition of the present invention, the ratio of spiral shell mite dibasic acid esters and Bifenazate is 1:50 to 50:1 based on the part by weight of active component, further is preferably 1:20 to 20:1, and most preferably part by weight is 1:5 to 5:1.
Agricultural miticide composition of the present invention can also further contain carrier, and carrier can be solid or liquid, and any carrier that is generally used for preparing acaricide composition all can use.
Suitable solid carrier comprises: mineral substance, plant class, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite or talcum for example.Carbonate is calcium carbonate or dolomite for example.Sulfates such as ammonium sulfate, sodium sulphate or calcium sulphate.Oxide-based like quicklime, magnesium lime or diatomite.The plant class is oranges and tangerines slag, corncob cellulose, rice husk powder, rice husk, big soya bean stem meal, tobacco powder, walnut shell or sawdust for example.Synthetic filling class such as winnofil hydrate, winnofil or white carbon.Inorganic salts is potassium chloride or sodium chloride for example.
Liquid-carrier comprises water and organic solvent.When effective composition was aqueous emulsion or suspension emulsion, organic solvent played solubilising and antifreeze effect.Appropriate organic solvent comprises aromatic hydrocarbons, for example benzene, xylol, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, for example vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol for example, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether for example, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidones for example; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; The vegetable oil and the vegetable oil that methylates.Above-mentioned organic solvent both can use separately, also can mix use, can also be mixed together use with water.
Auxiliary agent according to the invention can comprise one or more in surfactant, antifoaming agent, thickener, suspending agent and the antifreezing agent as required, can also comprise other auxiliary agents that the industry is commonly used as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ion-type or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of fatty acid or fatty amine and oxirane that contains at least 12 carbon atoms in the molecule and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, contain the sulfuric acid of 10 carbon atoms or the alkali metal or the alkali salt of sulfonic acid at least, preferable is sodium salt, like sodium salt, alkylaryl sodium sulfonate and the neopelex of lauryl sodium sulfate, Teepol, sulfonated castor oil; The copolymer of polymers of ethylene oxide, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and commercially available emulsifier.The preferred polyoxyethylene fatty acid fat of nonionic emulsifier, polyoxyethylene aliphatic alcohol ether and polyoxyethylene fatty amine, for example ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenolic group oleic acid ester, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n
20), ether phosphoric acid triethanolamine salt, hexichol ethyl phenolic group APEO (n
18) formaldehyde condensation products, diphenyl phenol polyethenoxy (n
18) polyethenoxy ether (n
20) etc.Commercially available emulsifier comprises: agricultural newborn 0201B, agricultural newborn 0203B, farming breast 100
#, farming breast 500
#, farming breast 600
#, agricultural newborn 600-2
#, farming breast 1601, farming breast 2201, agricultural newborn NP-10, agricultural newborn NP-15, farming breast 507
#, agricultural newborn OX-635, agricultural newborn OX-622, agricultural newborn OX-653, agricultural newborn OX-667, agricultural newborn CS-7, peaceful breast 36
#
Dispersant of the present invention comprises: sodium lignin sulfonate; Draw back powder; Calcium lignosulfonate; Condensation compound of methyl naphthalene sulfonic acid and formaldehyde; Naphthalene sulfonic acid-formaldehyde condensation product; The methanonaphthalene sodium sulfonate; Oleic acid methylamino ethylsulfonic acid sodium; Epoxidized polyether; To tertbutyl ether; The dibutyl naphthalene sulfonic acid-formaldehyde condensation product; Phosphate such as calgon; The alkylphenol-polyethenoxy based phosphates; Alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; N-methyl-fatty acyl group-sodium taurocholate APES formaldehyde condensation products; Aralkyl phenol polyethenoxy ether phosphate APES; The castor oil ethylene oxide adduct; Ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation products; Alkylphenol-polyethenoxy polyethenoxy ether and methylcellulose.
Wetting agent of the present invention comprises: sldium lauryl sulfate; Alkylol polyoxyethylene groups ether sodium sulfate; Octylphenol polyethylene oxyethylene group ether sulfate; Alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate; Sodium alkyl sulfonate; Neopelex; Negel; Dialkyl succinylsuccinate sulfonate; Lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium; The alkyl amide sodium taurocholate; Aliphatic alcohol polyethenoxy base ether; Alkylphenol-polyethenoxy base ether; The polyoxyethylene polyoxypropylene block polymer; Sorbitan fatty acid ester polyoxyethylene groups ether etc.
Thickener of the present invention both can be a synthetic, for example carboxymethyl alcohol, polyvinyl alcohol or polyvinyl acetate; Also can be natural water-soluble polymer, for example xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, Magnesiumaluminumsilicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.
Antifoaming agent of the present invention is preferably: bubble enemy, silicone, C
8-10Fatty alcohol, C
10-20Saturated fat acids and acid amides etc.
The auxiliary agent of above-mentioned use such as surfactant, antifoaming agent, thickener, suspending agent and antifreezing agent, emulsifier, dispersant, stabilizing agent or wetting agent etc. all can use commercially available usual auxiliaries.
The present invention also provides a kind of farm killing mite agent that contains above-mentioned farm killing mite composition, wherein contains the 0.5-95 weight % that miticide composition accounts for gross weight, preferably accounts for 5-85 weight %, most preferably accounts for 20-60 weight %.
Farm killing mite composition of the present invention can be mixed with liquor, missible oil, suspending agent, microemulsion, aqueous emulsion, pulvis, wetting powder, soluble powder, granule or capsule etc., and these preparations can be prepared by method in common.
Agricultural miticide composition of the present invention can directly be processed the finished product preparation form, and promptly each material mixes in the composition, directly is used for desinsection; The composition of composition also can directly mix in bucket (jar) before using to be provided by independent preparation.Concentrate of the present invention mixes the concentration that obtains required active substance usually with water.
Farm killing mite agent composition of the present invention is specially adapted to prevent and treat panonychus citri, European red mite, apple Tetranychus urticae, cotton red spider; Be applicable to oranges and tangerines, apple, hawthorn, cotton, eggplant etc.
Field do farmland, orchard or warehouse etc. are used in farm killing mite agent of the present invention.
Farm killing mite agent composition of the present invention can be used by common method, like cast, injection, spraying.Amount of application is with weather conditions or crop state variation, and time of application can be before or after pest damage.The duration of protective effect is usually relevant with the content of single compound in the composition, also relevant with extraneous factor, weather for example, but through using suitable formulation can slow down climatic influences.
Farm killing mite agent composition of the present invention also can use with other compound with desinsection, weeding, bactericidal property, also can mix use with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
[beneficial effect]
Compared with prior art, beneficial effect of the present invention is:
(1) two kinds of miticides are composite in the present composition shows extremely strong synergistic effect, and mixed composition miticidal effect is significantly improved than its single agent, can kill ovum, young mite, if mite with become mite;
(2) miticide composition according to the invention or miticide have long characteristics of lasting period;
(3) reduce using dosage, reduced peasant's drug cost, utilized 2 kinds of agricultural chemicals that the different mode of action of evil mite, the different mechanism of action reasonably are mixed, both prolonged agricultural chemicals service life, delayed the drug-fast generation of evil mite again.
[embodiment]
Come the present invention is further specified below in conjunction with specific embodiment, but do not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained in claims scope all alternatives, improvement project and the equivalents that possibly comprise.
In the invention in the proportioning of all solids preparation percentage all be weight percentage, percentage is percent by volume in the proportioning of liquid preparation; The treatment dosage of biologically-active moiety is effective content; As not having specified otherwise, " proportioning ", " active ingredient ratio " all refer to the weight ratio of spiral shell mite dibasic acid esters and Bifenazate.
One, indoor biological activity determination
Instance 1 spiral shell mite dibasic acid esters and the composite Toxicity Determination of Bifenazate to panonychus citri
In order further to understand the virulence of the complex composition of spiral shell mite dibasic acid esters and Bifenazate, a large amount of formulation screening tests have been carried out to insect.Test is estimated SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopts infusion process.Oranges and tangerines leaflet tablet band handle is cut, inserted in the ampere bottle that adds water.If connect some mite.Treat if the mite activity after a period of stabilisation, is dipped in 5s in the soup with blade, inhale with blotting paper rapidly and remove unnecessary soup, blade is placed the ampere bottle again, dry naturally.Place observation ward (to cultivate in 25 ± 1 ℃, humidity 70%-80%, 16h illumination/d).Test repetition 4 times, and establish blank, check result behind the 2d.Touch polypide with writing brush during investigation, can not normally creep is regarded as dead worm.
Theory is used the content (%) of toxicity index * B in using with of content (the %)+B of toxicity index * A in using with of toxicity index (TTI)=A with
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If, be indicated as summation action greater than 80 less than 120.
The result shows: result of the test: spiral shell mite dibasic acid esters Bifenazate is mixed to supplying the examination target that very high activity is all arranged; After being mixed, spiral shell mite dibasic acid esters and Bifenazate show significant synergistic effect; Spiral shell mite dibasic acid esters: during Bifenazate=5:1, co-toxicity coefficient is maximum, and synergistic effect is the most remarkable.The result is following.
The composite Toxicity Determination result of spiral shell mite dibasic acid esters and Bifenazate to panonychus citri
Instance 2 spiral shell mite dibasic acid esters and the composite Toxicity Determination of Bifenazate to European red mite
In order further to understand the virulence of the complex composition of spiral shell mite dibasic acid esters and Bifenazate, a large amount of formulation screening tests have been carried out to insect.Test is estimated SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopts infusion process.Apple leaflet tablet band handle is cut, inserted in the ampere bottle that adds water.If connect some mite.Treat if the mite activity after a period of stabilisation, is dipped in 5s in the soup with blade, inhale with blotting paper rapidly and remove unnecessary soup, blade is placed the ampere bottle again, dry naturally.Place observation ward (to cultivate in 25 ± 1 ℃, humidity 70%-80%, 16h illumination/d).Test repetition 4 times, and establish blank, check result behind the 2d.Touch polypide with writing brush during investigation, can not normally creep is regarded as dead worm.
Theory is used the content (%) of toxicity index * B in using with of content (the %)+B of toxicity index * A in using with of toxicity index (TTI)=A with
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If, be indicated as summation action greater than 80 less than 120.
The result shows: result of the test: spiral shell mite dibasic acid esters Bifenazate is mixed to supplying the examination target that very high activity is all arranged; After being mixed, spiral shell mite dibasic acid esters and Bifenazate show significant synergistic effect; Spiral shell mite dibasic acid esters: during Bifenazate=5:1, co-toxicity coefficient is maximum, and synergistic effect is the most remarkable.The result is following.
The composite Toxicity Determination result of spiral shell mite dibasic acid esters and Bifenazate to European red mite
Instance 3 spiral shell mite dibasic acid esters and the composite Toxicity Determination of Bifenazate to the apple Tetranychus urticae
In order further to understand the virulence of the complex composition of spiral shell mite dibasic acid esters and Bifenazate, a large amount of formulation screening tests have been carried out to insect.Test is estimated SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopts infusion process.Apple leaflet tablet band handle is cut, inserted in the ampere bottle that adds water.If connect some mite.Treat if the mite activity after a period of stabilisation, is dipped in 5s in the soup with blade, inhale with blotting paper rapidly and remove unnecessary soup, blade is placed the ampere bottle again, dry naturally.Place observation ward (to cultivate in 25 ± 1 ℃, humidity 70%-80%, 16h illumination/d).Test repetition 4 times, and establish blank, check result behind the 2d.Touch polypide with writing brush during investigation, can not normally creep is regarded as dead worm.
Theory is used the content (%) of toxicity index * B in using with of content (the %)+B of toxicity index * A in using with of toxicity index (TTI)=A with
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If, be indicated as summation action greater than 80 less than 120.
The result shows: result of the test: spiral shell mite dibasic acid esters Bifenazate is mixed to supplying the examination target that very high activity is all arranged; After being mixed, spiral shell mite dibasic acid esters and Bifenazate show significant synergistic effect; Spiral shell mite dibasic acid esters: during Bifenazate=5:1, co-toxicity coefficient is maximum, and synergistic effect is the most remarkable.The result sees instance 3 for details.
Instance 3 spiral shell mite dibasic acid esters and the composite Toxicity Determination result of Bifenazate to the apple Tetranychus urticae
Instance 4 spiral shell mite dibasic acid esters and the composite Toxicity Determination of Bifenazate to cotton red spider
In order further to understand the virulence of the complex composition of spiral shell mite dibasic acid esters and Bifenazate, a large amount of formulation screening tests have been carried out to insect.Test is estimated SOP (insecticide volume) with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity, adopts infusion process.Cotton leaflet tablet band handle is cut, inserted in the ampere bottle that adds water.If connect some mite.Treat if the mite activity after a period of stabilisation, is dipped in 5s in the soup with blade, inhale with blotting paper rapidly and remove unnecessary soup, blade is placed the ampere bottle again, dry naturally.Place observation ward (to cultivate in 25 ± 1 ℃, humidity 70%-80%, 16h illumination/d).Test repetition 4 times, and establish blank, check result behind the 2d.Touch polypide with writing brush during investigation, can not normally creep is regarded as dead worm.
Theory is used the content (%) of toxicity index * B in using with of content (the %)+B of toxicity index * A in using with of toxicity index (TTI)=A with
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If, be indicated as summation action greater than 80 less than 120.
Instance 4 spiral shell mite dibasic acid esters and the composite Toxicity Determination result of Bifenazate to cotton red spider
The result shows: result of the test: spiral shell mite dibasic acid esters Bifenazate is mixed to supplying the examination target that very high activity is all arranged; After being mixed, spiral shell mite dibasic acid esters and Bifenazate show significant synergistic effect; Spiral shell mite dibasic acid esters: during Bifenazate=5:1, co-toxicity coefficient is maximum, and synergistic effect is the most remarkable.The result sees instance 4 for details.
Two, control panonychus citri field control effectiveness test
Experimental field be positioned at Dai Jia village, township, sound hole, Kaihua County, Zhejiang Province, be the outdoor cropping oranges and tangerines, 20 centimetres of spacing in the rows, 30 centimetres of line-spacings.Formulation rate is 750kg/hm
2Check experiment 48% Bifenazate suspending agent (4000 times); 20% spiral shell mite dibasic acid esters suspending agent (4000 times).Use " closing U.S.A " HM-16A type back-pack electric sprayer, plant blade face even spraying.Repeat for 4 times, district's group is arranged at random.7 days investigation results behind the medicine.Regulation according to " pesticide field efficacy medicine test criterion ()---insecticide control panonychus citri " is carried out; Every experimental plot oranges and tangerines blade adopts 5 fixed points by east, south, west, 5 azimuth marks in north; 2 strains are investigated in every sub-district, investigate all borer populations of living in every strain.
Embodiment 124% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 5:1)
Spiral shell mite dibasic acid esters 20%, Bifenazate 4% draws back powder 1.5%; Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%; 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%; Above-mentioned substance mixed add the sand mill medium sand again and be milled to certain grain size, filtering the back, to add the thickener shear agitation even, prepare 24% spiral shell mite dibasic acid esters Bifenazate suspending agent.4000 times of dilution sprayings of this mixture, 7 days preventive effects are 96.23% behind the medicine, are significantly higher than the preventive effect of 48% Bifenazate suspending agent (4000 times), 85.67% and 20% spiral shell mite dibasic acid esters suspending agent (4000 times) 84.33%.
Embodiment 222% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 10:1)
Spiral shell mite dibasic acid esters 20%, Bifenazate 2%, phenethyl phenol polyethenoxy polyethenoxy ether 3%; Magnesiumaluminumsilicate 1.0%, xanthans 0.1%, propane diols polyoxyethylene poly-oxygen propylene aether 1.0%; Water complements to 100%, the mixed 22% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.55%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 89.45%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.54% behind the medicine.
Embodiment 320% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:1)
Spiral shell mite dibasic acid esters 10%, Bifenazate 10% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 24% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are that 95.55%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 84.67%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 80.33% behind the medicine.
Embodiment 444% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:10)
Spiral shell mite dibasic acid esters 4%, Bifenazate 40% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 44% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 90.09%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.07%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 82.35% behind the medicine.
Embodiment 548% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 5:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 8%, N-methyl-oleoyl-sodium taurocholate 8%, naphtholsulfonic acid formaldehyde condensation products 10%, soluble starch 8%, sodium sulphate 10%, kaolin complements to 100%.With above-mentioned substance mixing pulverizing, after adding water again and mediating, add in the comminutor that the certain specification screen cloth is housed and carry out granulation.And then warp is dry, screening (pressing the screen cloth scope) promptly gets 48% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.7000 times of dilution sprayings of this mixture, 7 days is that 97.85%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 85.99%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.63% to the panonychus citri preventive effect behind the medicine.
Embodiment 648% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 1:5)
Spiral shell mite dibasic acid esters 8%, Bifenazate 40%, neopelex 2.0%, white carbon black 5%, sodium lignin sulfonate 10%, precipitated calcium carbonate complements to 100%.Above-mentioned substance is fully mixed, after ultrafine crusher is pulverized, make 48% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 97.73%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 88.27%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 85.47% behind the medicine.
Embodiment 742% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 20:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 2%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 93.55%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.96%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 82.60% behind the medicine.
Embodiment 851% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 50:1)
Spiral shell mite dibasic acid esters 50%, Bifenazate 1%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 51% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 96.32%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.17%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 82.45% behind the medicine.
Embodiment 942% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 1:20)
Spiral shell mite dibasic acid esters 2%, Bifenazate 40%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.20%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 80.24%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 81.93% behind the medicine.
Embodiment 1051% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:50)
Spiral shell mite dibasic acid esters 1%, Bifenazate 50% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 51% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.27%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 83.46%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 82.81% behind the medicine.
Three, control European red mite field control effectiveness test
Embodiment 1124% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 5:1)
Spiral shell mite dibasic acid esters 20%, Bifenazate 4% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 24% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are 98.05% behind the medicine, are significantly higher than the preventive effect of 48% Bifenazate suspending agent (4000 times), 90.09% and 20% spiral shell mite dibasic acid esters suspending agent (4000 times) 85.05%.
Embodiment 1224% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:5)
Spiral shell mite dibasic acid esters 4%, Bifenazate 20% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 24% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are 98.05% behind the medicine, are significantly higher than the preventive effect of 48% Bifenazate suspending agent (4000 times), 90.09% and 20% spiral shell mite dibasic acid esters suspending agent (4000 times) 85.05%.
Embodiment 1344% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 10:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 4%, sodium lignin sulfonate 15%, methyl naphthalene sulfonate formaldehyde condensate 5%, bentonite 10%, kaolin complements to 100%.Make 44% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.7000 times of dilution sprayings of this mixture, 7 days is that 92.74%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.01%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 85.66% to the European red mite preventive effect behind the medicine.
Embodiment 1433% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 1:10)
Spiral shell mite dibasic acid esters 3%, Bifenazate 30%, sodium lignin sulfonate 15%, methyl naphthalene sulfonate formaldehyde condensate 5%, bentonite 10%, kaolin complements to 100%.Make 33% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.7000 times of dilution sprayings of this mixture, 7 days is that 96.77%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.14%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.25% to the European red mite preventive effect behind the medicine.
Embodiment 1542% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 20:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 2%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 95.43%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.07%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.36% behind the medicine.
Embodiment 1651% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 50:1)
Spiral shell mite dibasic acid esters 50%, Bifenazate 1%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 51% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 97.28%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 84.24%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 85.90% behind the medicine.
Embodiment 1742% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 1:20)
Spiral shell mite dibasic acid esters 2%, Bifenazate 40%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.15%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 80.53%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 82.67% behind the medicine.
Embodiment 1851% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:50)
Spiral shell mite dibasic acid esters 1%, Bifenazate 50% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 51% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.08%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.47%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 83.06% behind the medicine.
Four, control cotton red spider field control effectiveness test
Embodiment 1960% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 5:1)
Spiral shell mite dibasic acid esters 50%, Bifenazate 10%, N-methyl-oleoyl-sodium taurocholate 8%, naphtholsulfonic acid formaldehyde condensation products 10%, soluble starch 8%, sodium sulphate 10%, kaolin complements to 100%.Make 60% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.8000 times of dilution sprayings of this mixture, 7 days is that 96.73%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 83.52%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 80.53% to the cotton red spider preventive effect behind the medicine.
Embodiment 2060% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 1:5)
Spiral shell mite dibasic acid esters 10%, Bifenazate 50%, N-methyl-oleoyl-sodium taurocholate 8%, naphtholsulfonic acid formaldehyde condensation products 10%, soluble starch 8%, sodium sulphate 10%, kaolin complements to 100%.Make 60% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.8000 times of dilution sprayings of this mixture, 7 days is that 96.73%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 83.52%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 80.53% to the cotton red spider preventive effect behind the medicine.
Embodiment 2142% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 20:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 2%, polycarboxylate 5%, white carbon black 0.3%, attapulgite 1.0%, potassium dihydrogen phosphate 0.2%, ethylene glycol 4%, tributyl phosphate 0.2%, water complements to 100%, the mixed 42% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 93.62%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 85.27%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 86.29% behind the medicine.
Embodiment 2251% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 50:1)
Spiral shell mite dibasic acid esters 50%, Bifenazate 1%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 51% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 97.42%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 83.21%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 85.06% behind the medicine.
Embodiment 2342% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 1:20)
Spiral shell mite dibasic acid esters 2%, Bifenazate 40%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 95.63%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.05%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 83.24% behind the medicine.
Embodiment 2451% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:50)
Spiral shell mite dibasic acid esters 1%, Bifenazate 50% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 51% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.98%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 81.82%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.22% behind the medicine.
Five, control
The apple Tetranychus urticaeField control effectiveness test
Embodiment 2524% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 5:1)
Spiral shell mite dibasic acid esters 20%, Bifenazate 4% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 24% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are 97.02% behind the medicine, are significantly higher than the preventive effect of 48% Bifenazate suspending agent (4000 times), 87.27% and 20% spiral shell mite dibasic acid esters suspending agent (4000 times) 86.11%.
Embodiment 2624% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:5)
Spiral shell mite dibasic acid esters 4%, Bifenazate 20% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 24% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.4000 times of dilution sprayings of this mixture, 7 days preventive effects are 97.05% behind the medicine, are significantly higher than the preventive effect of 48% Bifenazate suspending agent (4000 times), 88.37% and 20% spiral shell mite dibasic acid esters suspending agent (4000 times) 87.05%.
Embodiment 2744% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 10:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 4%, sodium lignin sulfonate 15%, methyl naphthalene sulfonate formaldehyde condensate 5%, bentonite 10%, kaolin complements to 100%.Make 44% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.7000 times of dilution sprayings of this mixture, 7 days is that 93.96%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.32%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.59% to the European red mite preventive effect behind the medicine.
Embodiment 2833% spiral shell mite dibasic acid esters Bifenazate water dispersible granules (active ingredient is than 1:10)
Spiral shell mite dibasic acid esters 3%, Bifenazate 30%, sodium lignin sulfonate 15%, methyl naphthalene sulfonate formaldehyde condensate 5%, bentonite 10%, kaolin complements to 100%.Make 33% spiral shell mite dibasic acid esters Bifenazate water dispersible granules.7000 times of dilution sprayings of this mixture, 7 days is that 96.23%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.76%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.51% to the European red mite preventive effect behind the medicine.
Embodiment 2942% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 20:1)
Spiral shell mite dibasic acid esters 40%, Bifenazate 2%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 94.98%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.34%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 83.65% behind the medicine.
Embodiment 3051% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 50:1)
Spiral shell mite dibasic acid esters 50%, Bifenazate 1%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 51% spiral shell mite dibasic acid esters Bifenazate wetting powder.7000 times of dilution sprayings of this mixture, 7 days preventive effects are that 97.10%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 83.55%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.97% behind the medicine.
Embodiment 3142% spiral shell mite dibasic acid esters Bifenazate wetting powder (active ingredient is than 1:20)
Spiral shell mite dibasic acid esters 2%, Bifenazate 40%, lauryl sodium sulfate 1.5%, naphthalene sulfonic acid-formaldehyde condensation product 5%, sodium lignin sulfonate 3%, white carbon black 8%, precipitated calcium carbonate complements to 100%.Make 42% spiral shell mite dibasic acid esters Bifenazate wetting powder.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 95.07%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.35%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 83.55% behind the medicine.
Embodiment 3251% spiral shell mite dibasic acid esters Bifenazate suspending agent (active ingredient is than 1:50)
Spiral shell mite dibasic acid esters 1%, Bifenazate 50% draws back powder 1.5%, Soproplot SC 3%, xanthans 0.15%, aluminium-magnesium silicate 1.5%, 418G 0.3%, and BIT 0.05%, and water is supplemented to 100%, the mixed 51% spiral shell mite dibasic acid esters Bifenazate suspending agent that gets.5000 times of dilution sprayings of this mixture, 7 days preventive effects are that 95.32%, 48% Bifenazate suspending agent (4000 times) preventive effect is that 82.47%, 20% spiral shell mite dibasic acid esters suspending agent (4000 times) preventive effect is 84.29% behind the medicine.
Claims (10)
1. a miticide composition is characterized in that said miticide composition contains spiral shell mite dibasic acid esters and Bifenazate, and wherein the part by weight of spiral shell mite dibasic acid esters and Bifenazate is 1:50 to 50:1.
2. miticide composition according to claim 1, the part by weight that it is characterized in that said spiral shell mite dibasic acid esters and Bifenazate is 1:20 to 20:1.
3. miticide composition according to claim 1, the part by weight that it is characterized in that said spiral shell mite dibasic acid esters and Bifenazate is 1:5 to 5:1.
4. a miticide is characterized in that this miticide contains the described miticide composition of each claim of claim 1-3 of 0.5-95 weight %, and surplus is acceptable carrier and an auxiliary agent on the agricultural chemicals.
5. miticide according to claim 4 is characterized in that said miticide contains the described miticide composition of each claim of claim 1-3 of 5-85 weight %.
6. miticide according to claim 4 is characterized in that said miticide contains the described miticide composition of each claim of claim 1-3 of 20-60 weight %.
7. miticide according to claim 4 is characterized in that said auxiliary agent is a surfactant.
8. according to any described miticide of claim in the claim 4 to 7, it is characterized in that said acaricidal formulation is liquor, emulsifiable concentrate, suspending agent, microemulsion, aqueous emulsion, pulvis, wetting powder, soluble powder, granule or capsule.
9. the described miticide composition of claim 1 is in the purposes of control panonychus citri, European red mite, apple Tetranychus urticae, Tetranychus cinnabarinus or cotton red spider.
10. prevent and treat the method that agricultural does harm to mite for one kind; Before or after crops or fruit infection evil mite, use described miticide composition of each claim of claim 1-3 or the described miticide of each claim of claim 4-8 to the place of crops or fruit and growth or storage.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210284522.XA CN102763664B (en) | 2012-08-06 | 2012-08-06 | Insecticide composite containing spirodiclofen and bifenazate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210284522.XA CN102763664B (en) | 2012-08-06 | 2012-08-06 | Insecticide composite containing spirodiclofen and bifenazate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102763664A true CN102763664A (en) | 2012-11-07 |
| CN102763664B CN102763664B (en) | 2014-03-12 |
Family
ID=47091429
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210284522.XA Active CN102763664B (en) | 2012-08-06 | 2012-08-06 | Insecticide composite containing spirodiclofen and bifenazate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102763664B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2532419A (en) * | 2014-11-17 | 2016-05-25 | Rotam Agrochem Int Co Ltd | A pesticidal composition |
| WO2018171817A1 (en) * | 2017-03-23 | 2018-09-27 | 浙江省化工研究院有限公司 | Miticide composition containing spiro ether derivatives |
| CN108617685A (en) * | 2017-03-23 | 2018-10-09 | 浙江省化工研究院有限公司 | One kind ether compound containing loop coil and the acaricidal composition of organic tin |
| CN108684694A (en) * | 2017-04-11 | 2018-10-23 | 浙江省化工研究院有限公司 | A kind of composition of ether compound containing loop coil and Bifenazate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101730470A (en) * | 2007-06-29 | 2010-06-09 | 拜尔农作物科学股份公司 | Acaricidal active substance combinations |
| CN101978829A (en) * | 2010-11-16 | 2011-02-23 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing bifenazate and spirodiclofen |
| CN102379300A (en) * | 2010-08-27 | 2012-03-21 | 青岛奥迪斯生物科技有限公司 | Acaricidal combination containing bifenazate and spirodiclofen |
-
2012
- 2012-08-06 CN CN201210284522.XA patent/CN102763664B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101730470A (en) * | 2007-06-29 | 2010-06-09 | 拜尔农作物科学股份公司 | Acaricidal active substance combinations |
| CN102379300A (en) * | 2010-08-27 | 2012-03-21 | 青岛奥迪斯生物科技有限公司 | Acaricidal combination containing bifenazate and spirodiclofen |
| CN101978829A (en) * | 2010-11-16 | 2011-02-23 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing bifenazate and spirodiclofen |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2532419A (en) * | 2014-11-17 | 2016-05-25 | Rotam Agrochem Int Co Ltd | A pesticidal composition |
| GB2532419B (en) * | 2014-11-17 | 2019-05-29 | Rotam Agrochem Int Co Ltd | A pesticidal composition comprising spirobudiclofen and diafenthiuron |
| WO2018171817A1 (en) * | 2017-03-23 | 2018-09-27 | 浙江省化工研究院有限公司 | Miticide composition containing spiro ether derivatives |
| CN108617685A (en) * | 2017-03-23 | 2018-10-09 | 浙江省化工研究院有限公司 | One kind ether compound containing loop coil and the acaricidal composition of organic tin |
| CN108684694A (en) * | 2017-04-11 | 2018-10-23 | 浙江省化工研究院有限公司 | A kind of composition of ether compound containing loop coil and Bifenazate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102763664B (en) | 2014-03-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102027991A (en) | Herbicide composition and application thereof | |
| CN103300019B (en) | Pesticidal composition | |
| CN102763664B (en) | Insecticide composite containing spirodiclofen and bifenazate | |
| CN101589723B (en) | Compound pesticide of indoxacarb and pyridaphenthion | |
| CN102907444A (en) | Pest killing composition containing abamectin or methylamino abamectin | |
| CN101485329B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN102805102B (en) | Disinsection combination containing fosthiazate and ryanodine receptor inhibitor insecticide | |
| CN102919260B (en) | Insecticidal composition containing ZJ3757 and neonicotinoid insecticides | |
| CN102696642B (en) | Acaricidal composition containing spirodiclofen and cyflumetofen | |
| CN105613511B (en) | A kind of agricultural pesticide composition and application thereof | |
| CN101669479B (en) | Mite-killing combination | |
| CN101558757A (en) | Insecticidal and acaricidal composition containing spirodiclofen and nitenpyram | |
| CN102204561B (en) | Agricultural pesticide composition | |
| CN101305724A (en) | Insecticidal composition containing thiocyclam | |
| CN106577709A (en) | Pesticide compound containing cyhalodiamide and hexaflumuron | |
| CN104920393A (en) | Acaricidal composition containing cyenopyrafen and abamectin | |
| CN103355328B (en) | Mite-killing composition containing C20H22Cl2O5 and etoxazole | |
| CN111011391A (en) | Composite insecticidal composition and application thereof | |
| CN102907438A (en) | Insecticidal composite containing ZJ3757 and pymetrozine | |
| CN102246811A (en) | Insecticidal composition containing ZJ3265 and profenofos | |
| CN108617675A (en) | A kind of composition of ether compound containing loop coil and plant insecticide | |
| CN106973922A (en) | A kind of composition pesticide containing destruxins and pleocidin | |
| CN106818806A (en) | A kind of farm killing mite composition containing doractin and Bifenazate | |
| CN107114392A (en) | Bio-insecticidal composition comprising destruxins | |
| CN105685067B (en) | A kind of agricultural pesticide composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 311106 No. 172, Zhangjiadun Road, Tangqi Town, Linping District, Hangzhou, Zhejiang Patentee after: Zhejiang Yulong Pharmaceutical Co.,Ltd. Address before: No. 172, zhangjiadun Road, Tangqi Town, Yuhang District, Hangzhou City, Zhejiang Province, 311106 Patentee before: Hangzhou Udragon Chemical Co.,Ltd. |