CN101638333A - Water-soluble fertilizer containing chitin and humic acid and production method thereof - Google Patents
Water-soluble fertilizer containing chitin and humic acid and production method thereof Download PDFInfo
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- CN101638333A CN101638333A CN200910017671A CN200910017671A CN101638333A CN 101638333 A CN101638333 A CN 101638333A CN 200910017671 A CN200910017671 A CN 200910017671A CN 200910017671 A CN200910017671 A CN 200910017671A CN 101638333 A CN101638333 A CN 101638333A
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Abstract
The invention discloses a water-soluble fertilizer containing chitin and humic acid and a production method thereof. The method is characterized by degrading chitin, a natural high polymer, and then mixing chitin with humic acid solution and nitrogen fertilizer to produce the water-soluble fertilizer containing chitin and humic acid. The produced water-soluble fertilizer contains 20-40g/l of chitin, 20-40g/l of nitrogen, 170-190g/l of humic acid and 1-5g/l of plant growth regulators. The method is simple, easy to operate and high in feasibility of implementation. The produced water-soluble fertilizer integrates the functions of nutrition supplement, bacteria immunity and virus immunity, improves soil conditions, prevents hardening, raises ground temperature, promotes prematurity, resists diseases and tolerates stress, resists continuous cropping and balances nutrition, and features stable status and lasting fertilizer efficiency.
Description
Technical field
The invention belongs to the technical field of organic fertilizer, be specifically related to a kind of chitin humic acid water-soluble fertilizer and production method thereof.
Background technology
Chemical fertilizer (abbreviation chemical fertilizer) comprises mineral manure and organic fertilizer two classes; On form, then can be divided into solid fertilizer and liquid fertilizer two classes.Chemical fertilizer plays significant effect to improving crop yield, is the indispensable production factors of modern agriculture.People's life-time service inorganic fertilizer easily causes soil fertility to reduce, and has both destroyed the acid base equilibrium of soil, has caused the appearance of problems such as soil compaction, salinization; Make that nitrate content exceeds standard in the agricultural-food, quality variation.Replace inorganic fertilizer to produce non-polluted farm product with fertilizer (mainly being traditional farm manure), though improved soil fertility, improved advantages such as crop quality, but the shortcoming of fertilizer is that fertilizer efficiency is slow, the output of farm crop improves not quite, if want to improve the amount of application that output just must roll up fertilizer.And because organic manure resource is limited, demand, especially the gourd, fruit and vegetable class crop that can not satisfy modern agricultural development far away.Humic acid fertilizer has remedied the deficiency of inorganic fertilizer and fertilizer preferably with its advantage, because humic acids is a kind of natural organic high molecular compound, it contains elements such as carbon, hydrogen, oxygen, nitrogen, aromatic proton, hydroxyl, carboxyl, carbonyl, quinonyl, methoxyl group isoreactivity gene.These active groups have determined humic acids to have slightly acidic, wetting ability, ion exchangeable, complexing, oxidation-reduction quality and physiologically active etc., have concurrently to improve the soil and stimulate the crop growth dual function.And humic acid liquid fertilizer is compared with solid fertilizer, is rich in various nutrient elements such as the essential nitrogen of plant, phosphorus, potassium and copper, iron, manganese, zinc, boron, have more fertilizer efficiency fast, balanced in nutrition, use advantages such as easy.And chitin can improve plant to various nutrient absorbing utilizations, well developed root system, plant strain growth is vigorous, fruit expands rapidly, balanced, ripe early, color and luster is good, anti-early ageing, volume increase reaches more than the 20%-50%.Effectively improve commercial grade and interior quality.Getting soluble chitin (chitosan) behind the chitin deacetylase base, is the most important derivative of chitin, and degraded is the high-quality fertilizer material later, can be made for thing and absorb.Not only can suppress the pathogenic bacteria growth and breeding in the soil, have antibiotic, antiviral efficacy, can effectively improve the crumb structure of soil simultaneously.Chitin then is to be that raw material makes by Crustacean, extensively is present in the crust of shrimp, crab and insect, contains chitin 20%~30% in shrimp, crab shell, and high reaches 58%~85%; In the puparium of locust, butterfly, mosquito, fly, silkworm, contain chitin 20%~60%, very abundant of content.Therefore along with the Sustainable development of modern agriculture, the industrial scale of humic acid liquid fertilizer constantly enlarges, and its application is also increasingly extensive.And with chitin as fertilizer application in agriculture production improving soil quality, improve crop yield and also become a kind of formula that becomes.
Summary of the invention
Technical problem to be solved by this invention has provided a kind of simple, easy to operate, the product method of the chitin humic acid water-soluble fertilizer that exploitativeness is high, and the chitin humic acid water-soluble fertilizer of producing integrates nutritional supplementation, antibiotic, antiviral three large effects, have improve the soil, prevent to harden, promote ground temperature, promotion precocity, disease-resistant degeneration-resistant, anti-continuous cropping, balanced in nutrition, in stable condition, fertilizer efficiency is lasting.
Chitin humic acid water-soluble fertilizer of the present invention contains chitin and humic acids, and wherein chitin is 20-40g/l, nitrogen 20-40g/l, humic acids is 170-190g/l, also contains plant-growth regulator, and plant-growth regulator content is 1-5g/l in the water-soluble fertilizer.Nitrogen can add with the form of liquid ammonia or urea soln.
The product method of chitin humic acid water-soluble fertilizer, contain chitin, humic acids and nitrogenous fertilizer, be earlier with soluble chitin with make the chitin humic acid water-soluble fertilizer after humic acid solution and nitrogenous fertilizer mix, chitin 20-40g/l in the chitin humic acid water-soluble fertilizer that makes, nitrogen 20-40g/l, humic acids 170-190g/l.
Soluble chitin adds plant-growth regulator again with after humic acid solution mixes, and plant-growth regulator content is 1-5g/l in the chitin humic acid water-soluble fertilizer that makes.Can certainly add other materials according to the needs of producing, as other compositions such as phosphorus, potassium and disease-resistant antiseptic-germicides.
Wherein, used humic acids is to be that raw material forms through microbial fermentation with molasses.Characteristics are pure quality, no residue, active high, instant effect, and both fusions are the gold partner in the fertilizer, the elaboration in the current especially water-soluble fertilizer.
Mix with humic acid solution after the natural polymers degradation of chitin.Prepare chitosan oligomer by DeR, method can adopt conventional acid degradation method, enzyme liberating method, oxidation degradation method and mechanical degradation method etc.
Described natural polymers chitin be adopt raw material marine organisms housing through washing, drying, crushing and screening, demineralization, protein separation, deacetylation, wash, dehydrate, make soluble chitin behind the crushing and screening.
Production method of the present invention is simple, and is easy to operate, the exploitativeness height.And the chitin humic acid water-soluble fertilizer of producing includes high-purity crust, can cultivate a large amount of actinomycetes rapidly, uses back about 12 days in science, and soil microbial activities can improve nearly 20 times, fundamentally suppresses root knot nematode.Chitin can improve plant to various nutrient absorbing utilizations simultaneously, well developed root system, plant strain growth is vigorous, fruit expands rapidly, balanced, ripe early, color and luster is good, anti-early ageing, volume increase reaches more than the 20%-50%, especially concerning gourd, fruit and vegetable class crop, effectively improves commercial grade and interior quality.And the humic acids in this product is to be that raw material forms through microbial fermentation with molasses, pure quality, no residue, active high, rapid-action.Biochemical class xanthohumic acid and plant growth promote the factor (UGF) to have high physiologically active, after being manured into soil, quicken the interior protoplasma of plant materials and flow, promote root system development, delay the root system aging, strengthen the root system receptivity, use the back to absorb onset in 24-36 hour in 4-8 hour.Therefore this chitin humic acid water-soluble fertilizer has: 1. and disease-resistant degeneration-resistant, anti-continuous cropping, balanced in nutrition, fertilizer efficiency is lasting.Use this product and can breed a large amount of probioticss, suppress the breeding of various harmful germs in the soil, thereby reduce the generation of disease, effectively resist the generation of root-rot, mashed root, improve crop disease-resistant, cold-resistant, drought-resistant ability; The acting in conjunction of various active material has effects such as anti-continuous cropping, anti-dead.2. good soil prevents to harden, and promotes ground temperature, promotes precocious.Include decomposed organic matter, biochemical class xanthohumic acid, amino acid, the soil organism is increased, promote ground temperature, looseness of soil is improved soil aggregate, improves the soil cation exchange capacity (CEC), regulates P in soil H value, improves soil water-retaining getting fat ability greatly.Use the thin dish fruit of this chitin humic acid water-soluble fertilizer can improve ground temperature 2~4 degree, went on the market in advance 7~10 days, prolong and plucked 10~20 days.3. improve the fruit commercial grade, improve quality.Can obviously improve outward appearance and the interior quality of crop after using, improve VC, soluble solid, sugar part content, the fruit type is straight, painted good, the reguarity height, and keeping quality is strong, improves commodity performance and the nutritive value of crop comprehensively.But this chitin humic acid water-soluble fertilizer application process for this product dilution back with water dash execute, also drip irrigation, spread manuer in holes, ditch spread, filling root, base execute, use in nutrition critical period and maximum phase of efficient, uses about 10 kilograms of this product for general each every mu.Also can increase and decrease consumption according to crop growing state.
Embodiment
Embodiment one
Adopt raw material marine organisms shrimp shell through washing, drying, crushing and screening, demineralization, protein separation, deacetylation, wash, dehydrate, make soluble chitin behind the crushing and screening; with soluble chitin degraded back with after humic acid solution mixes; add plant-growth regulator again; stir afterwards; after metering, packing, get chitin humic acid water-soluble fertilizer finished product again; chitin 20g/l in the chitin humic acid water-soluble fertilizer that makes; nitrogen 20g/l; humic acids 170g/l, plant-growth regulator content are 1g/l.
Embodiment two
Adopt raw material marine organisms crab shell through washing; dry; crushing and screening; demineralization; protein separation; deacetylation; washing; dehydrate; make soluble chitin behind the crushing and screening; with molasses is that raw material is made humic acid solution through microbial fermentation; with soluble chitin degraded back with after humic acid solution mixes; add plant-growth regulator again; stir afterwards; again through metering; get chitin humic acid water-soluble fertilizer finished product after the packing; chitin 25g/l in the chitin humic acid water-soluble fertilizer that makes; nitrogen 30g/l; humic acids 190g/l, plant-growth regulator content are 5g/l.
Embodiment three
Adopt raw material marine organisms crab shell and crab shell through washing, drying, crushing and screening, demineralization, protein separation, deacetylation, wash, dehydrate, make soluble chitin behind the crushing and screening; with soluble chitin degraded back with after humic acid solution mixes; add plant-growth regulator again; stir afterwards; after metering, packing, get chitin humic acid water-soluble fertilizer finished product again; chitin 40g/l in the chitin humic acid water-soluble fertilizer that makes; nitrogen 40g/l; humic acids 180g/l, plant-growth regulator content are 3g/l.
More than be the application's a embodiment, should be understood that these embodiment only are used to the present invention is described and are not used in to limit the scope of the invention.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims institute restricted portion equally.
Claims (7)
1, a kind of chitin humic acid water-soluble fertilizer, it is characterized in that: described water-soluble fertilizer contains chitin, humic acids and nitrogenous fertilizer, and wherein chitin is 20-40g/l, and nitrogen 20-40g/l, humic acids are 170-190g/l.
2, chitin humic acid water-soluble fertilizer as claimed in claim 1 is characterized in that: also contain plant-growth regulator in the described water-soluble fertilizer, and plant-growth regulator content is 1-5g/l in the water-soluble fertilizer.
3, the production method of chitin humic acid water-soluble fertilizer, it is characterized in that: present method be with soluble chitin with make the chitin humic acid water-soluble fertilizer after humic acid solution and nitrogenous fertilizer mix, chitin 20-40g/l in the chitin humic acid water-soluble fertilizer that makes, nitrogen 20-40g/l, humic acids 170-190g/l.
4, the production method of the plain humic acid water-soluble fertilizer of shell as claimed in claim 3, it is characterized in that: soluble chitin is with after humic acid solution mixes, add plant-growth regulator again, plant-growth regulator content is 1-5g/l in the chitin humic acid water-soluble fertilizer that makes.
5, the production method of chitin humic acid water-soluble fertilizer as claimed in claim 3 is characterized in that: used humic acids is to be that raw material forms through microbial fermentation with molasses.
6, the production method of chitin humic acid water-soluble fertilizer as claimed in claim 3 is characterized in that: mix with humic acid solution soluble chitin degraded back.
7, as the production method of claim 3,4,5 or 6 described chitin humic acid water-soluble fertilizers, it is characterized in that: described soluble chitin be adopt raw material marine organisms housing through washing, drying, crushing and screening, demineralization, protein separation, deacetylation, wash, dehydrate, make soluble chitin behind the crushing and screening.
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Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102173956A (en) * | 2011-01-04 | 2011-09-07 | 潍坊德孚尔生物科技有限公司 | Multi-effect organic water-soluble fertilizer and preparation method thereof |
CN102249823A (en) * | 2011-05-03 | 2011-11-23 | 湖北富邦科技股份有限公司 | Method for controlling fertilizer appearance by using molasses |
CN102249812A (en) * | 2011-04-27 | 2011-11-23 | 北京雷力农用化学有限公司 | Organic granular fertilizer and preparation method thereof |
CN102550355A (en) * | 2012-02-27 | 2012-07-11 | 行唐县甲壳素红枣有限公司 | Method for producing jujube with chitin |
CN102674979A (en) * | 2012-06-06 | 2012-09-19 | 郑州农达生化制品有限公司 | Long-acting novel water soluble water flush fertilizer formula capable of resisting continuous cropping activity |
CN103708944A (en) * | 2013-12-18 | 2014-04-09 | 青岛崂乡茶制品有限公司 | Biomass fertilizer for tea trees |
CN105646084A (en) * | 2016-02-29 | 2016-06-08 | 张学杰 | Instant microelement water-soluble fertilizer capable of increasing soil organic matter content |
CN105646083A (en) * | 2016-02-29 | 2016-06-08 | 王越 | Instant macroelement water-soluble fertilizer capable of increasing soil organic matter content |
CN105685039A (en) * | 2016-03-21 | 2016-06-22 | 海南正业中农高科股份有限公司 | Organic-matter containing agricultural composition and use thereof |
CN105732207A (en) * | 2016-03-10 | 2016-07-06 | 董万里 | Soil ecological restoration conditioner and preparation method thereof and soil ecological restoration method |
CN106854110A (en) * | 2016-12-21 | 2017-06-16 | 王兴杰 | One kind prepares feature Water soluble fertilizer and its preparation technology using chitin production recovered liquid |
CN107840712A (en) * | 2017-11-14 | 2018-03-27 | 潍坊友容实业有限公司 | Efficient humic acid fertilizer for salt-soda soil |
CN110483208A (en) * | 2019-08-08 | 2019-11-22 | 陕西海德尔生物科技有限责任公司 | A kind of organic water-soluble chitosan multi-Functional Fertilizers |
CN110698281A (en) * | 2019-10-14 | 2020-01-17 | 赵时珊 | Water flush fertilizer containing chitosan |
CN111170787A (en) * | 2020-01-15 | 2020-05-19 | 好牧人干细胞生物科技有限公司 | Multifunctional plant stem cell growth substance |
CN112279740A (en) * | 2020-11-25 | 2021-01-29 | 广东海洋大学 | Special liquid fertilizer for sugarcane and preparation method thereof |
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2009
- 2009-08-18 CN CN200910017671A patent/CN101638333A/en active Pending
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102173956A (en) * | 2011-01-04 | 2011-09-07 | 潍坊德孚尔生物科技有限公司 | Multi-effect organic water-soluble fertilizer and preparation method thereof |
CN102249812A (en) * | 2011-04-27 | 2011-11-23 | 北京雷力农用化学有限公司 | Organic granular fertilizer and preparation method thereof |
CN102249812B (en) * | 2011-04-27 | 2013-12-18 | 北京雷力农用化学有限公司 | Organic granular fertilizer and preparation method thereof |
CN102249823A (en) * | 2011-05-03 | 2011-11-23 | 湖北富邦科技股份有限公司 | Method for controlling fertilizer appearance by using molasses |
CN102550355A (en) * | 2012-02-27 | 2012-07-11 | 行唐县甲壳素红枣有限公司 | Method for producing jujube with chitin |
CN102550355B (en) * | 2012-02-27 | 2013-05-29 | 行唐县甲壳素红枣有限公司 | Method for producing jujube with chitin |
CN102674979A (en) * | 2012-06-06 | 2012-09-19 | 郑州农达生化制品有限公司 | Long-acting novel water soluble water flush fertilizer formula capable of resisting continuous cropping activity |
CN103708944A (en) * | 2013-12-18 | 2014-04-09 | 青岛崂乡茶制品有限公司 | Biomass fertilizer for tea trees |
CN105646084A (en) * | 2016-02-29 | 2016-06-08 | 张学杰 | Instant microelement water-soluble fertilizer capable of increasing soil organic matter content |
CN105646083A (en) * | 2016-02-29 | 2016-06-08 | 王越 | Instant macroelement water-soluble fertilizer capable of increasing soil organic matter content |
CN105732207A (en) * | 2016-03-10 | 2016-07-06 | 董万里 | Soil ecological restoration conditioner and preparation method thereof and soil ecological restoration method |
CN105685039A (en) * | 2016-03-21 | 2016-06-22 | 海南正业中农高科股份有限公司 | Organic-matter containing agricultural composition and use thereof |
CN106854110A (en) * | 2016-12-21 | 2017-06-16 | 王兴杰 | One kind prepares feature Water soluble fertilizer and its preparation technology using chitin production recovered liquid |
CN107840712A (en) * | 2017-11-14 | 2018-03-27 | 潍坊友容实业有限公司 | Efficient humic acid fertilizer for salt-soda soil |
CN110483208A (en) * | 2019-08-08 | 2019-11-22 | 陕西海德尔生物科技有限责任公司 | A kind of organic water-soluble chitosan multi-Functional Fertilizers |
CN110698281A (en) * | 2019-10-14 | 2020-01-17 | 赵时珊 | Water flush fertilizer containing chitosan |
CN111170787A (en) * | 2020-01-15 | 2020-05-19 | 好牧人干细胞生物科技有限公司 | Multifunctional plant stem cell growth substance |
CN112279740A (en) * | 2020-11-25 | 2021-01-29 | 广东海洋大学 | Special liquid fertilizer for sugarcane and preparation method thereof |
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Open date: 20100203 |