CN101632382B - Pesticide composition containing flusilazole and tebuconazole and application thereof - Google Patents
Pesticide composition containing flusilazole and tebuconazole and application thereof Download PDFInfo
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Abstract
The invention discloses a pesticide composition containing flusilazole and tebuconazole, comprising common adjuvants, flusilazole and tebuconazole, wherein, the ratio of the flusilazole to the tebuconazole according to weight parts is 10:1 to 1:10, and the total weight ratio of the flusilazole and tebuconazole in the pesticide composition is 1-70%; the adjuvants include one or more of a solvent, an emulsifier, a wetting agent, a stabilizer, a dispersant, a thickener, a PH modifier, a defoaming agent, an antifreezing agent and a filling agent. The pesticide composition containing flusilazole and tebuconazole is suitable for treatment at the early stage or initial stage of the plant disease. Compared with any single preparation, the pesticide composition has obvious improved control effect, reducing use quantity of pesticide and cost.
Description
Technical field
The composition pesticide that the present invention relates to is to be active ingredient with Flusilazole and Tebuconazole, is used to prevent and treat the plant disease on the agricultural, is particularly useful for preventing and treating apple tree spot defoliation etc.
Background technology
Flusilazole (flusilazole) belongs to triazole bactericidal agent, and this medicine mainly is the biosynthesis that destroys and stop the cell membrane important composition composition ergosterol of germ, causes cell membrane not form, and makes germ dead.In the antithetical phrase due to the germ of Gammaproteobacteria, Basidiomycetes and Fungi Imperfecti disease effective.
Tebuconazole (tebuconazole) is the wide spectrum triazole bactericidal agent, has superior bioactive, and consumption is low; Interior absorption is stronger; Applied widely, Tebuconazole by plant absorbing after, in plant tissue, shift to the top; Can prevent and treat the multiple germ in the various crops, all can prevent and treat effectively Erysiphe, Puccinia, Rhynchosporium spp, nuclear cavity Pseudomonas and the microbial disease of Septoria.Because Flusilazole and Tebuconazole are widely used for many years in China, continuously independent all the year round use has made the germ pesticide resistance constantly strengthen, even continue to increase dispenser dosage, also is difficult to effective controlling plant diseases.
One Chinese patent application CN101322494 discloses a kind of composition pesticide, and this composition pesticide contains azole active substance and N, N-dialkyl group chain alkyl acid amides.The N that in composition, adds q.s, N-dialkyl group chain alkyl acid amides are used for stoping or the crystallization of azole active substance when suppressing to use said composition.Preferred N in the composition, N-dialkyl group chain alkyl acid amides is that general formula is worker's a compound, wherein: (a) represent alkyl for R1 and R2. contain 2 carbon atoms, R represents alkyl; Contain 10 to 30 carbon atoms, or (b) R1 and R2 respectively represent alkyl, contain 3 carbon atoms; R represents alkyl, contains 9 to 30 carbon atoms, or (c) R1 and R2 respectively represent alkyl; Contain 4 to 12 carbon atoms, R represents alkyl, contains 6 to 30 carbon atoms; When the active substance in the said composition was bactericide, said preparation can be more effective.Particularly bactericide is selected from Tebuconazole, cyproconazole, triticonazole, own azoles alcohol, Flutriafol, nitrile bacterium azoles, Difenoconazole, alkene azoles alcohol, propiconazole, tricyclazole, triticonazole, fluorine bacterium azoles, Flusilazole, metconazole one or more.But said composition does not disclose the proportioning of effective constituent, is suitable for inconvenient.Being mixed of different pesticide species is the common methods of the agriculture resistance disease of control.Through the formulation of pesticide screening, filter out rational prescription, can effectively improve actual control efficiency, reduce dosage, reduce cost, delay the generation of disease drug resistance, be the important means of the disease comprehensive regulation.
Summary of the invention
The technical problem that the present invention need solve provides a kind of efficient, low toxicity, quick-acting is good and the lasting period is long, helps the fluorine silicon azoles of the disease comprehensive regulation and the composition pesticide of Tebuconazole.
For addressing the above problem; The technical scheme that the present invention adopted is: the composition pesticide of a kind of fluorine silicon azoles and Tebuconazole; Comprise usual auxiliaries and Flusilazole and Tebuconazole; The ratio of weight and number of Flusilazole and Tebuconazole is 10: 1-1: 10, and Flusilazole and the percentage by weight of Tebuconazole weight summation in composition pesticide are 1-70%.Flusilazole and the preferred weight percent of Tebuconazole weight summation in composition pesticide are 15-55%.
Further: the above-mentioned fluorine silicon azoles and the composition pesticide of Tebuconazole can be configured to missible oil, microemulsion, aqueous emulsion, suspending agent, wetting powder or water dispersible granules according to well known to a person skilled in the art method.
Preparation during missible oil used auxiliary agent following: the solvent of 1-30% and cosolvent by weight; Solvent and cosolvent are arene, alcohols, ester class, ketone, amide-type etc.; Like toluene, xylol, trimethylbenzene, dimethyl formamide, methyl alcohol, ethylene glycol, acetone, cyclohexanone, dimethyl sulfoxide (DMSO) etc., solvent and cosolvent can be wherein one or more mixing.The emulsifier of 1-15% by weight; Emulsifier can be alkylbenzenesulfonate series, AEO, polyoxyethylene nonyl phenyl propyl group APEO, phenethyl phenol polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, phenethyl polyoxy ethyl polyoxyethyl propyl ether, first contract NPE, phenethyl phenol APEO, APES phosphate etc., and emulsifier can be wherein one or more mixing.The antifreezing agent of 1%-10% by weight, antifreezing agent can be one or more the mixing in glycerine, ethylene glycol, propane diols, sodium chloride, urea, the sorbierite etc.The stabilizing agent of 0.5%-8% by weight, stabilizing agent can be one or more the mixing in xanthan gum, Magnesiumaluminumsilicate, urea, methyl alcohol, benzinum, wettable starch, the cresyl glycidyl ether etc.The antifoaming agent of 0.5%-8% by weight, antifoaming agent can be one or more the mixing in organic silicone oil, methyl alcohol, ethanol, the epoxy soybean wet goods.The pH value conditioning agent of 0%-1% by weight, pH value conditioning agent are one or more the mixing in sodium hydroxide, oxyammonia, acetic acid, the hydrochloric acid etc.
Preparation during microemulsion used auxiliary agent following: the solvent of 1-20% and cosolvent by weight; Solvent and cosolvent are arene, alcohols, ester class, ketone, amide-type etc.; Like toluene, xylol, trimethylbenzene, dimethyl formamide, methyl alcohol, ethylene glycol, acetone, cyclohexanone, dimethyl sulfoxide (DMSO) etc., can be one or more mixing wherein.The emulsifier of 1-20% by weight; Emulsifier can be alkylbenzenesulfonate series, AEO, polyoxyethylene nonyl phenyl propyl group APEO, phenethyl phenol polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, phenethyl polyoxy ethyl polyoxyethyl propyl ether, first contract NPE, phenethyl phenol APEO, APES phosphate etc., and emulsifier can be wherein one or more mixing.The antifreezing agent of 1%-10% by weight, antifreezing agent can be one or more the mixing in glycerine, ethylene glycol, propane diols, sodium chloride, urea, the sorbierite etc.The stabilizing agent of 0.5%-8% by weight, stabilizing agent can be one or more the mixing in xanthan gum, Magnesiumaluminumsilicate, urea, methyl alcohol, benzinum, wettable starch, the cresyl glycidyl ether etc.The antifoaming agent of 0.5%-8% by weight, antifoaming agent can be one or more the mixing in organic silicone oil, methyl alcohol, ethanol, the epoxy soybean wet goods.The pH value conditioning agent of 0%-1% by weight, pH value conditioning agent are one or more the mixing in sodium hydroxide, oxyammonia, acetic acid, the hydrochloric acid etc.
Preparation during suspending agent used auxiliary agent following: the solvent of 1%-10% and cosolvent by weight, solvent and cosolvent can be one or more the mixing in castor oil, transformer oil, xylol, soya-bean oil, machine oil, diesel oil, dimethyl formamide, methyl alcohol, ethylene glycol, the acetonitrile.The wetting agent of 1%-15% by weight; Wetting agent can be alkylbenzenesulfonate series, APES, styryl phenol polyethenoxy ether, castor oil polyoxyethylene ether, fatty acid polyglycol oxy alkylene ester, benzylphenol polyoxyethylene groups polyoxypropylene base ether, phosphoric acid ester etc.Wetting agent can be wherein one or more mixing.The dispersant of 1%-10% by weight, dispersant are one or more the mixing in naphthalene or Fluhyzon formaldehyde condensation products and salt, fatty alcohol ethylene oxide adduct sulfonate, alkylphenol-polyethenoxy base ether sulfonate, lignin and derivative sulfonate thereof, polyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol, carboxymethyl cellulose etc.The antifreezing agent of 0.5%-8% by weight, antifreezing agent can be one or more the mixing in glycerine, ethylene glycol, propane diols, sodium chloride, urea, the sorbierite etc.The stabilizing agent of 0.5%-8% by weight, stabilizing agent can be one or more the mixing in xanthan gum, Magnesiumaluminumsilicate, urea, methyl alcohol, benzinum, wettable starch, the cresyl glycidyl ether etc.The antifoaming agent of 0.2%-5% by weight, antifoaming agent can be one or more the mixing in organic silicone oil, methyl alcohol, ethanol, the epoxy soybean wet goods.The pH value conditioning agent of 0%-1% by weight, pH value conditioning agent are one or more the mixing in sodium hydroxide, oxyammonia, acetic acid, the hydrochloric acid etc.The thickener of 0%-5% by weight, thickener are one or more the mixing in methylcellulose, polyvinyl alcohol, gum Arabic, the polyvinylpyrrolidone etc.
Preparation during aqueous emulsion used auxiliary agent following: the solvent of 3%-30% and cosolvent by weight, solvent and cosolvent can be one or more the mixing in castor oil, transformer oil, xylol, soya-bean oil, machine oil, diesel oil, dimethyl formamide, methyl alcohol, ethylene glycol, the acetonitrile etc.The emulsifier of 1%-15% by weight; Emulsifier can be alkylbenzenesulfonate series, APES, styryl phenol polyethenoxy ether, castor oil polyoxyethylene ether, fatty acid polyglycol oxy alkylene ester, benzylphenol polyoxyethylene groups polyoxypropylene base ether, phosphoric acid ester etc.Emulsifier can be wherein one or more mixing.The dispersant of 0.1%-10% by weight, dispersant are one or more the mixing in naphthalene or Fluhyzon formaldehyde condensation products and salt, fatty alcohol ethylene oxide adduct sulfonate, lignin and derivative sulfonate thereof, fatty acid ethane addition product phosphate, alkylphenol-polyethenoxy based phosphates, carboxymethyl cellulose, polyvinyl alcohol, N-Methyl pyrrolidone, polyethylene glycol etc.The antifreezing agent of 0.5%-8% by weight, antifreezing agent can be one or more the mixing in glycerine, ethylene glycol, propane diols, sodium chloride, urea, the sorbierite etc.The stabilizing agent of 0.5%-8% by weight, stabilizing agent can be one or more the mixing in xanthan gum, Magnesiumaluminumsilicate, urea, methyl alcohol, benzinum, wettable starch, the cresyl glycidyl ether etc.The antifoaming agent of 0.2%-5% by weight, antifoaming agent can be one or more the mixing in organic silicone oil, C10-20 saturated fat acids, epoxidized soybean oil, iodoxy amine, the ester ethers etc.The pH value conditioning agent of 0%-1% by weight, pH value conditioning agent are one or more the mixing in sodium hydroxide, oxyammonia, acetic acid, the hydrochloric acid etc.The thickener of 0%-5% by weight, thickener are one or more the mixing in methylcellulose, polyvinyl alcohol, gum Arabic, the polyvinylpyrrolidone etc.Mend to 100% with deionized water at last
Preparation during wetting powder used auxiliary agent following: the wetting agent of 1%-30% by weight, wetting agent can be that tea is withered, spaonin powder, bay alcohol radical sodium sulphate, neopelex, draw back one or more the mixing in powder, the washing powder etc.The dispersant of 3%-30% by weight, dispersant can be one or more the mixing in lignin and derivative sulfonate, fatty acid ethane addition product phosphate, alkyl phenol polyvinylether sulfonate, polyvinylpyrrolidone, polyvinyl alcohol, polyethylene glycol, naphthalene or Fluhyzon formaldehyde condensation products and salt, the alkylphenol-polyethenoxy based phosphates etc.The filler of 10%-50% by weight, filler can be one or more the mixing in kaolin, white carbon, talcum powder, precipitated calcium carbonate, montmorillonite, diatomite, cellulose powder, urea, bark powder, the ammonium nitrate etc.
Preparation during water dispersible granules used auxiliary agent following: the wetting agent of 1%-20% by weight, wetting agent can be one or more the mixing in sodium alkyl benzene sulfonate, sodium lignin sulfonate, fatty alcohol, polyoxyethylene carboxylate sodium sulfonate and ammonium salt, alkyl sulfate, APES, spaonin powder, the withered powder of tea etc.The dispersant of 1%-20% by weight, dispersant can be that ethoxylated dodecyl alcohol, naphthalenesulfonic acid-formaldehyde condensate (NNO), dioctyl sulfosuccinic acid are received, one or more the mixing among JFC, acrylate homopolymer sodium salt etc.The carrier of 5%-50% by weight, carrier can be one or more the mixing in kaolin, white carbon, precipitated calcium carbonate, montmorillonite, the diatomite etc.The disintegrant of 1%-15% by weight, disintegrant can be one or more the mixing in bentonite, urea, ammonium sulfate, sodium chloride, the magnesium chloride etc.The binding agent of 1%-10% by weight, binding agent can be one or more the mixing in starch, gelatin, polyvinyl alcohol, polyethylene glycol, starch, cyclodextrin, soybean lecithin, the rosin etc.The stabilizing agent of 1%-10% by weight, stabilizing agent can be one or more the mixing in benzinum, wettable starch, cresyl glycidyl ether, the sorbierite etc.
Composition pesticide provided by the invention adopts the method for spraying to use usually, also can adopt agricultural to go up other operation techniques of using as required.Agricultural chemicals method for using for example commonly used: spray-on process, bait method, seed treatment method, seed pelleting method, soil treatment method, fumigating system, fumigation method, semar technique etc.
The application of early stage or disease initial stage of origination takes place in plant disease in the composition pesticide that the present invention also provides fluorine silicon azoles and Tebuconazole, especially to the control of apple tree spot defoliation.
Compared with prior art, the present invention includes usual auxiliaries and Flusilazole and Tebuconazole, the ratio of weight and number of Flusilazole and Tebuconazole is 10: 1-1: 10, and Flusilazole and the percentage by weight of Tebuconazole weight summation in composition pesticide are 1-70%.Be that the present invention passes through repetition test, draw preferred prescription, show obvious synergistic effect, the control efficiency of composition is significantly improved than single agent, has reduced the using dosage of agricultural chemicals, has reduced cost.The active ingredient mechanism of action of composition pesticide provided by the invention is different, and the application of composition can delay or overcome the drug-fast generation of germ, helps the comprehensive regulation.
Embodiment
The present invention includes usual auxiliaries and Flusilazole and Tebuconazole, the ratio of weight and number of Flusilazole and Tebuconazole is 10: 1-1: 10, and Flusilazole and the percentage by weight of Tebuconazole weight summation in composition pesticide are 1-70%.Be that the present invention passes through repetition test, draw preferred prescription, show obvious synergistic effect, the control efficiency of composition is significantly improved than single agent, has reduced the using dosage of agricultural chemicals, has reduced cost.
Below in conjunction with embodiment content of the present invention is done further to detail, mentioned content is not to qualification of the present invention among the embodiment, and Selection of technological conditions such as temperature, time can be suited measures to local conditions and the result is not had substantial effect among the preparation method.
At first; The basic scheme of summary material prescription of the present invention: the composition pesticide of a kind of fluorine silicon azoles and Tebuconazole; Comprise usual auxiliaries and Flusilazole and Tebuconazole; It is characterized in that: the ratio of weight and number of Flusilazole and Tebuconazole is 10: 1-1: 10, and Flusilazole and the percentage by weight of Tebuconazole weight summation in composition pesticide are 1-70%.
Embodiment 1
Following material all is weight percentage: Flusilazole 30%; Tebuconazole 3%; Emulsifier AEO 4%, calcium dodecyl benzene sulfonate 5%, triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 10%, antifoaming agent epoxidized soybean oil 1%, stabilizing agent xanthan gum 0.5%; Antifreezing agent glycerine 0.5%, surplus are solvent dimethyl formamide and xylol.Above-mentioned prescription is added in the mixing kettle in proportion successively, promptly make 33% Flusilazole Tebuconazole missible oil after stirring.
Embodiment 2
Following material all is weight percentage: Flusilazole 20%, and Tebuconazole 4%, wetting agent draw back powder 3%, dispersant naphthalenesulfonate formaldehyde condensation compound 10%, filler talcum powder 5%, surplus is a filler kaolin.Above-mentioned prescription got in the blender after the coarse crushing in proportion mix, behind comminution by gas stream, promptly make 24% Flusilazole Tebuconazole wetting powder again.
Embodiment 3
Following material all is weight percentage: Flusilazole 5%, Tebuconazole 10%, emulsifier neopelex 6%, calcium dodecyl benzene sulfonate 5%; Dispersant N-Methyl pyrrolidone 8%; Antifreezing agent sodium chloride 0.5%, stabilizing agent xanthan gum 0.3%, antifoaming agent organosilicon 0.4%; Thickener polyvinyl alcohol 4%, surplus are deionized water.Above-mentioned prescription Central Plains medicine, solvent, emulsifiers dissolve are become even oil phase; With the mixed water that gets of water-soluble component and deionized water in the above-mentioned prescription; Under high-speed stirred, with oil phase and the mixed 15% Flusilazole tebuconazole aqueous emulsion that gets of water.
Embodiment 4
Following material all is weight percentage: Flusilazole 5%, and Tebuconazole 25%, wetting agent lauryl sodium sulfate 6%, dispersant polycarboxylate 4%, disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stabilizing agent wettable starch 3%, surplus is a carrier kaolin.Dry pulverization process, granulation, drying, screening make 30% Flusilazole Tebuconazole water-dispersible granules in proportion with above-mentioned prescription.
Embodiment 5
Following material all is weight percentage: Flusilazole 5%, Tebuconazole 50%, emulsifier triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 12%; Wetting agent calcium dodecyl benzene sulfonate 5%, dispersant APES formaldehyde condensation products sulphate 3%, antifreeze glycol 0.2%; Stabilizing agent xanthan gum 0.1%, antifoaming agent organosilicon 0.4%, glycerine 5%; Thickener gum Arabic 2%, surplus are deionized water.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 55% Flusilazole tebuconazole suspension concentrates after high shear mixing.
For the effect of the present composition effectively is described, below that composition of the present invention and single medicament is following to the field control effectiveness test comparative analysis as a result of apple tree spot defoliation respectively;
The medicament of optional above-mentioned 1-5 embodiment:
(1) the present invention: weight percentage is a 15%-55% Flusilazole tebuconazole aqueous emulsion (1#);
The contrast medicament:
(1) contain the single medicament of Tebuconazole: weight percentage is 25% tebuconazole aqueous emulsion (2#),
(2) the single medicament of fluorine silicon azoles: weight percentage is 10% Flusilazole aqueous emulsion (3#),
Spraying time: convert the water even spraying at apple tree spot defoliation their early stage.
Result of the test: see table 1, can find out from result of the test: after the dispenser 3 days, composition pesticide of the present invention more than 88%, obviously was better than single agent to the control efficiency of apple tree spot defoliation; After the dispenser 7 days and 14 days, composition pesticide of the present invention all more than 90%, also obviously was better than single agent to the control efficiency of apple tree spot defoliation, explain that composition pesticide of the present invention all is being superior to single agent aspect quick-acting and the lasting effect, and cost reduces greatly.
The field control effectiveness test result of table 2, control apple tree spot defoliation
| Supply the reagent agent | Extension rate (active ingredient dosage) | 1 day preventive effect (%) behind the medicine | 3 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine | 14 days preventive effects (%) behind the medicine |
| 1# | 1500 times of liquid (100 mg/kg) | 58.2 | 88.5 | 91.2 | 92.0 |
| 2# | 2500 times of liquid (100 mg/kg) | 50.7 | 81.3 | 86.4 | 86.9 |
| 3# | 2000 times of liquid (50 mg/kg) | 52.6 | 82.2 | 82.6 | 88.3 |
Be mixed to the virulence of germ for further understanding Flusilazole and Tebuconazole, the inventor is mixed to Flusilazole and Tebuconazole and has carried out a large amount of formulation screening tests.
Test adopts the mycelial growth rate method to measure.To separate the alternaria leaf spot of apple bacterium that obtains from the fresh morbidity material of apple tree spot defoliation and cultivate at oat medium, subsequent use.Under aseptic technique, handle the sterilising medium that will melt in advance according to test and quantitatively add in the aseptic conical flask, from the low concentration to the high concentration, quantitatively draw soup successively, add respectively in the above-mentioned conical flask, fully shake up.To pour 4 diameters into be in the culture dish of 9cm to equivalent then, and the pastille of processing respective concentration is dull and stereotyped.From the colony edge cut-off of oat medium, cultivating 5d directly is the bacterium cake of 5mm, is inoculated in above-mentioned pastille flat board respectively, and test is established the processing that does not contain medicament and made blank, and every processing repeats for 4 times.26 ℃ of dark conditions are cultivated 5d down, measure colony diameter, calculate the inhibiting rate (%) of each concentration medicament to mycelial growth.
Growing state investigation pathogen mycelial growth situation according to bacterium in the blank culture dish.Use the kind of calliper colony diameter, unit is a millimeter (mm).Each bacterium colony with right-angled intersection method vertical survey diameter is respectively once got its mean value.
According to survey data, to press NY/T1156.2-2006 and calculate each concentration of treatment supplying the mycelial growth inhibition rate of examination target bacterium, unit is percentage (%).
Logarithm value with drug concentration (mg/L) is independent variable x, is dependent variable y with the probit value of inhibiting rate, sets up the virulence regression equation formula respectively, adopts the EC of the single agent of DPS computed in software and each proportioning mixture
50The co-toxicity coefficient (CTC) of (95% confidence limit) and mixture.
According to the NY/T1156.6-2006 bactericide synergy criteria for classifying: co-toxicity coefficient (CTC)>=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤120 shows as antagonism; 120＜co-toxicity coefficient (CTC)＜120 shows as summation action.
Table 1, Flusilazole and Tebuconazole and different proportioning are to the toxicity test result of apple tree spot defoliation
| Supply reagent agent (active ingredient ratio of quality and the number of copies) | Virulence regression equation y=a+bx | Correlation coefficient | EC 50(mg/L) (95% confidence limit) | Co-toxicity coefficient (CTC value) |
| Flusilazole | 4.9002+1.6402x | 0.9950 | 1.15(1.03～1.29) | -- |
| Tebuconazole | 4.2327+1.5903x | 0.9984 | 3.04(2.86～3.23) | -- |
| Flusilazole: Tebuconazole (10: 1) | 4.9177+1.5722x | 0.9960 | 1.13(1.03～1.24) | 147.93 |
| Flusilazole: Tebuconazole (5: 1) | 4.9108+1.6353x | 0.9978 | 1.13(1.05～1.22) | 189.98 |
| Flusilazole: Tebuconazole (1: 2) | 5.0462+1.6013x | 0.9992 | 0.94(0.89～0.98) | 209.86 |
| Flusilazole: Tebuconazole (1: 5) | 4.8156+1.6259x | 0.9959 | 1.30(1.17～1.44) | 176.14 |
| Flusilazole: Tebuconazole (1: 10) | 4.7378+1.6605x | 0.9931 | 1.44(1.25～1.66) | 165.82 |
Can find out that from result of the test table 2 composition pesticide of Flusilazole and Tebuconazole is 10 at ratio of quality and the number of copies: 1-1: between 10, co-toxicity coefficient (CTC value) promptly all shows obvious synergistic effect all greater than 120.Flusilazole and Tebuconazole are mixed and have reasonability and feasibility.
Claims (5)
1. the composition pesticide of fluorine silicon azoles and Tebuconazole; Comprise usual auxiliaries, Flusilazole and Tebuconazole; It is characterized in that: the ratio of weight and number of Flusilazole and Tebuconazole is 10: 1-1: 10, and Flusilazole and the percentage by weight of Tebuconazole weight summation in composition pesticide are 1-70%.
2. the composition pesticide of fluorine silicon azoles according to claim 1 and Tebuconazole is characterized in that: Flusilazole and the preferred weight percent of Tebuconazole weight summation in composition pesticide are 15-55%.
3. the composition pesticide of fluorine silicon azoles according to claim 2 and Tebuconazole is characterized in that: described auxiliary agent is one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, thickener, pH regulator agent, antifoaming agent, antifreezing agent, the packing agent etc.
4. the composition pesticide of fluorine silicon azoles according to claim 3 and Tebuconazole is characterized in that: its formulation is a kind of in missible oil, microemulsion, aqueous emulsion, suspending agent, wetting powder or the dosage form of water dispersible granule.
5. the application of the composition pesticide of each described fluorine silicon azoles and Tebuconazole is the control of apple tree spot defoliation is used among the claim 1-4.
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| CN102010269B (en) * | 2010-11-02 | 2013-01-16 | 湖北富邦科技股份有限公司 | Granulation modifier for high-tower compound fertilizer and application thereof |
| CN102027934A (en) * | 2010-11-26 | 2011-04-27 | 惠州市中迅化工有限公司 | Bactericidal composition containing fluopyram and difenoconazole and application thereof |
| CN103999874B (en) * | 2014-05-28 | 2018-06-19 | 甘肃省农业科学院植物保护研究所 | A kind of grease paste and its preparation method and application |
| CN107027803A (en) * | 2017-06-19 | 2017-08-11 | 福建省农业科学院植物保护研究所 | Microbicide compositions and its application containing Flusilazole and olefin conversion |
| CN115088712B (en) * | 2022-06-23 | 2024-07-23 | 广西壮族自治区农业科学院 | Medicament for preventing and treating rust disease of radix puerariae lobatae |
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| CN101322494A (en) * | 2007-05-28 | 2008-12-17 | 江苏龙灯化学有限公司 | Agricultural chemical composition and its preparation and application |
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| CN101322494A (en) * | 2007-05-28 | 2008-12-17 | 江苏龙灯化学有限公司 | Agricultural chemical composition and its preparation and application |
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| Title |
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| 王彦杰等.几种杀菌剂防治黄瓜白粉病田间药效试验分析.《农药科学与管理》.2006,第25卷(第9期),21-22,30. * |
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