CN101601384A - A kind of desinsection, miticide composition - Google Patents
A kind of desinsection, miticide composition Download PDFInfo
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- CN101601384A CN101601384A CNA200910016868XA CN200910016868A CN101601384A CN 101601384 A CN101601384 A CN 101601384A CN A200910016868X A CNA200910016868X A CN A200910016868XA CN 200910016868 A CN200910016868 A CN 200910016868A CN 101601384 A CN101601384 A CN 101601384A
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- desinsection
- miticide composition
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- relates
- acid amides
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- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000000642 acaricide Substances 0.000 title claims abstract description 23
- 150000001408 amides Chemical class 0.000 claims abstract description 60
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 59
- 235000009566 rice Nutrition 0.000 claims abstract description 59
- 238000009472 formulation Methods 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims abstract description 3
- 241000209094 Oryza Species 0.000 claims description 57
- 239000003899 bactericide agent Substances 0.000 claims description 25
- 239000000375 suspending agent Substances 0.000 claims description 23
- 239000000843 powder Substances 0.000 claims description 16
- 230000000844 anti-bacterial effect Effects 0.000 claims description 13
- 238000009736 wetting Methods 0.000 claims description 13
- 239000005760 Difenoconazole Substances 0.000 claims description 10
- 239000005800 Kresoxim-methyl Substances 0.000 claims description 10
- 230000003115 biocidal effect Effects 0.000 claims description 10
- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 10
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims description 10
- BKBSMMUEEAWFRX-NBVRZTHBSA-N (E)-flumorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(F)=CC=1)=C\C(=O)N1CCOCC1 BKBSMMUEEAWFRX-NBVRZTHBSA-N 0.000 claims description 6
- QNBTYORWCCMPQP-JXAWBTAJSA-N (Z)-dimethomorph Chemical compound C1=C(OC)C(OC)=CC=C1C(\C=1C=CC(Cl)=CC=1)=C/C(=O)N1CCOCC1 QNBTYORWCCMPQP-JXAWBTAJSA-N 0.000 claims description 6
- 239000005761 Dimethomorph Substances 0.000 claims description 6
- 239000005784 Fluoxastrobin Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 6
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 6
- 239000002718 pyrimidine nucleoside Substances 0.000 claims description 6
- 239000000417 fungicide Substances 0.000 claims description 5
- 150000003852 triazoles Chemical class 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 3
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- 150000008059 anilinopyrimidines Chemical class 0.000 claims description 2
- 239000003242 anti bacterial agent Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 239000004530 micro-emulsion Substances 0.000 claims description 2
- XGXNTJHZPBRBHJ-UHFFFAOYSA-N n-phenylpyrimidin-2-amine Chemical compound N=1C=CC=NC=1NC1=CC=CC=C1 XGXNTJHZPBRBHJ-UHFFFAOYSA-N 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 12
- 230000002195 synergetic effect Effects 0.000 abstract description 8
- 231100000053 low toxicity Toxicity 0.000 abstract description 7
- 240000008067 Cucumis sativus Species 0.000 abstract description 5
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 abstract description 5
- 201000010099 disease Diseases 0.000 abstract description 4
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 235000007688 Lycopersicon esculentum Nutrition 0.000 abstract description 3
- 241000209140 Triticum Species 0.000 abstract description 3
- 235000021307 Triticum Nutrition 0.000 abstract description 3
- 235000013305 food Nutrition 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 241000219146 Gossypium Species 0.000 abstract description 2
- 244000061456 Solanum tuberosum Species 0.000 abstract description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 abstract description 2
- 238000007796 conventional method Methods 0.000 abstract description 2
- 230000000855 fungicidal effect Effects 0.000 abstract description 2
- 235000012015 potatoes Nutrition 0.000 abstract description 2
- 238000001228 spectrum Methods 0.000 abstract description 2
- 240000007594 Oryza sativa Species 0.000 abstract 2
- 240000003768 Solanum lycopersicum Species 0.000 abstract 1
- 239000003090 pesticide formulation Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 47
- 230000001154 acute effect Effects 0.000 description 33
- 229940079593 drug Drugs 0.000 description 28
- NNPRCLUGHFXSOU-UHFFFAOYSA-N 4-chloro-n-[cyano(ethoxy)methyl]benzamide Chemical compound CCOC(C#N)NC(=O)C1=CC=C(Cl)C=C1 NNPRCLUGHFXSOU-UHFFFAOYSA-N 0.000 description 23
- 230000000694 effects Effects 0.000 description 20
- 230000000638 stimulation Effects 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- 239000002131 composite material Substances 0.000 description 16
- 241000283973 Oryctolagus cuniculus Species 0.000 description 12
- 230000003449 preventive effect Effects 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 11
- 239000012895 dilution Substances 0.000 description 11
- 238000010790 dilution Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 11
- 239000002994 raw material Substances 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 231100000820 toxicity test Toxicity 0.000 description 11
- IXQGCWUGDFDQMF-UHFFFAOYSA-N o-Hydroxyethylbenzene Natural products CCC1=CC=CC=C1O IXQGCWUGDFDQMF-UHFFFAOYSA-N 0.000 description 10
- -1 phenethyl phenolformaldehyde resin Chemical compound 0.000 description 9
- 239000003053 toxin Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 235000018927 edible plant Nutrition 0.000 description 8
- 241000221785 Erysiphales Species 0.000 description 6
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 229920001285 xanthan gum Polymers 0.000 description 5
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 229920001568 phenolic resin Polymers 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 241000233679 Peronosporaceae Species 0.000 description 3
- 241000233622 Phytophthora infestans Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 229920005551 calcium lignosulfonate Polymers 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
- 241000198596 Alternaria tomatophila Species 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- 229920001732 Lignosulfonate Polymers 0.000 description 2
- 241000227653 Lycopersicon Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- PHLBKPHSAVXXEF-UHFFFAOYSA-N trazodone Chemical compound ClC1=CC=CC(N2CCN(CCCN3C(N4C=CC=CC4=N3)=O)CC2)=C1 PHLBKPHSAVXXEF-UHFFFAOYSA-N 0.000 description 2
- 229960003991 trazodone Drugs 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical class CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- HCWYXKWQOMTBKY-UHFFFAOYSA-N calcium;dodecyl benzenesulfonate Chemical class [Ca].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 HCWYXKWQOMTBKY-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The desinsection that relates to of the present invention, miticide composition are to be main active ingredient with the rice blast acid amides, being equipped with second dissimilar components and various auxiliary material obtains efficiently, wide range, binary built preparation cheaply, characteristics such as have efficient, low toxicity, low-residual, fungicidal spectrum is wide, synergistic effect is remarkable, use cost is low.The desinsection that the present invention relates to, the formulation of miticide composition can be any possible general pesticide formulations, adopt preparation according to a conventional method, processing and easy to use.Can be widely used in the multiple diseases control on paddy rice, wheat, cotton, tomato, cucumber, the potatoes and other crops, be specially adapted to pollution-free food production.
Description
One, technical field
The present invention relates to technical field of pesticide, relate to the agriculture chemical compounding technology, particularly with the compounded technology of rice blast acid amides.
Two, background technology
Rice blast acid amides (zarilamid) is a kind of brand-new, efficient germicide.
Chemical name: N-(cyano group-1,2-dimethyl propyl)-2-(2,4 dichloro benzene oxygen base) propionamide
Molecular formula: C
15H
18CI
2N
2O
2
Relative molecular weight: 329.22
Structural formula:
Rice blast acid amides (zarilamid) belongs to novel acid amide fungicides.It is a kind of brand-new, high-efficiency broad spectrum bactericide, does not have the cross resistance problem with other existing bactericide, and the difference of various crop is fallen ill all fine preventive effect and outstanding lasting effect, and low toxicity, low-residual, safety are good.
As safe as a house to crop under different temperature conditions, to person poultry safety, low toxicity.Be suitable for the production of pollution-free green food.
The complex preparation that with the rice blast acid amides is main component has certain effect to improving drug effect and selectivity, existing lot of documents report.
Three, summary of the invention
The object of the present invention is to provide a kind of is the efficient of main body composition with the rice blast acid amides, wide range, complex preparation cheaply.
The object of the present invention is achieved like this, is first component with the rice blast acid amides,, is equipped with various auxiliary materials and obtains efficiently, wide range, binary built preparation cheaply as second component with dissimilar bactericide.
The desinsection that the present invention relates to, miticide composition comprise the rice blast acid amides and second bactericide at least, and the active ingredient weight percent content is 5～80%, and the mass ratio of the rice blast acid amides and second bactericide is between 20: 1～1: 20.
The desinsection that the present invention relates to, miticide composition, second bactericide are selected from a kind of in methoxy acrylic bactericide, acid amide fungicides, triazole bactericidal agent, anilino-pyrimidine, organochlorine series bactericidal agent or the antibiotic class.
The desinsection that the present invention relates to, miticide composition, described methoxy acrylic bactericide are selected from a kind of in kresoxim-methyl, the Fluoxastrobin.
The desinsection that the present invention relates to, miticide composition, described acid amide fungicides are selected from a kind of in dimethomorph, the flumorph.
The desinsection that the present invention relates to, miticide composition, described triazole bactericidal agent are selected from a kind of in Difenoconazole, the triazolone.
The desinsection that the present invention relates to, miticide composition, described anilino-pyrimidine series bactericidal agent are phonetic mould amine.
The desinsection that the present invention relates to, miticide composition, described organochlorine series bactericidal agent is a tpn.
The desinsection that the present invention relates to, miticide composition, described antibiotic series bactericidal agent is an antibiotic in pyrimidine nucleoside class.
The desinsection that the present invention relates to, the formulation of miticide composition are a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
The desinsection that the present invention relates to, miticide composition adopt preparation according to a conventional method, can be mixed with various formulations, and be easy to use.Characteristics, particularly its high efficiency, low toxicity, low-residual such as have efficient, low toxicity, low-residual, fungicidal spectrum is wide, synergistic effect is remarkable, use cost is low are particularly advantageous in the production of pollution-free food.Can be used for the multiple diseases control on paddy rice, wheat, cotton, tomato, cucumber, the potatoes and other crops.
Four, embodiment
Below in conjunction with embodiment the technical scheme that invention relates to is further specified, but not as the restriction to technical scheme.
Except that mentioning especially, component ratio is weight portion among the embodiment.
Embodiment one
24% rice blast acid amides Fluoxastrobin suspending agent
Raw material consists of 20 parts of former medicines of rice blast acid amides, 4 parts of former medicines of Fluoxastrobin, 1.5 part is drawn back powder, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 3 parts of sodium carboxymethyl starches, 1.5 part calcium dodecyl benzene sulfonate, 3 parts of alkylol APEOs, 1 part of white carbon, 0.05 part of xanthans, water is supplied 100 parts, in the usual way preparation.
Toxicity test, male rat acute oral LD50＞5000mg/kg, female big white mouse acute oral LD50＞5000mg/kg, acute through skin LD50＞2000mg/kg, to the skin nonirritant of rabbit, the eyes of rabbit are had no stimulation.Show that Recompounded pesticide belongs to the agricultural chemicals of low toxicity.
Using dosage: prevent and treat potato late blight, convert 1000～2000 times of water dilutions, spray medicine 3～7 days, effect is obvious, and preventive effect is more than 95%.
Rice blast acid amides (zarilamid) and Fluoxastrobin are pressed 20/1 respectively, 15/1,10/1,8/1,6/1,1/1,1/5,1/10,1/20 ratio is composite, do check experiment with 20% rice blast acid amides suspending agent and 10% Fluoxastrobin suspending agent, the Toxicity Determination result of potato late blight shows: each medicament is to the co-toxicity coefficient 243.65～319.85 of potato late blight, and synergistic effect is remarkable.Wherein 6/1 synergistic effect is the most obvious.
Embodiment two
13.5% rice blast acid amides kresoxim-methyl suspending agent
Raw material consists of 9 parts of former medicines of rice blast acid amides, 4.5 part former medicine of kresoxim-methyl, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1 part is drawn back powder, 1 part of calcium dodecyl benzene sulfonate, 3 parts of phenethyl phenolformaldehyde resin APEOs, 2 parts of white carbons, 0.25 part of xanthans, 3 parts of glycerine, water is supplied 100 parts, in the usual way preparation.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit is acute through skin LD50＞2000mg/kg, and rat acute has no stimulation to skin through skin LD50＞2000mg/kg, eye is had no stimulation, show that compound drug belongs to the agricultural chemicals of low toxicity.
Using dosage: prevent and treat careless mould powdery mildew, convert 1000～1500 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and kresoxim-methyl are pressed 20/1,15/1,10/1 respectively, 5/1,3/1,1/1,1/5,1/10,1/20 is composite, does check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 30% kresoxim-methyl wetting powder, and the Toxicity Determination result of careless mould powdery mildew shows: each medicament is 191.59～289.68 to the co-toxicity coefficient of powdery mildew, synergistic effect is remarkable, and is wherein the most outstanding with 3/1 effect.
Embodiment three
60% rice blast acid amides dimethomorph wetting powder
Raw material consists of 40 parts of former medicines of rice blast acid amides, 20 parts of former medicines of dimethomorph, and 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 2 parts of lauryl sodium sulfate, 5 parts of calcium lignosulfonates, 5 parts of ammonium sulfate are supplied 100 parts with kaolin.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞3900mg/kg, chmice acute per os LD50＞3900mg/kg, rabbit is acute through skin LD50＞2000mg/kg, and rat acute has no stimulation to skin through skin LD50＞2000mg/kg, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: convert 2000～3500 times of water dilutions, the control cucumber downy mildew, spray medicine 3～5 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and dimethomorph are pressed 20/1 respectively, 10/1,5/1,2/1,1/1,2/2,1/5,1/8,1/20 ratio is composite, do check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 30% dimethomorph wetting powder, cucumber downy mildew Toxicity Determination result shows to have significant synergistic effect, wherein 2/1 proportioning medicament co-toxicity coefficient 275.61.
Embodiment four
25% rice blast acid amides Difenoconazole missible oil
Raw material is formed: 15 parts of former medicines of rice blast acid amides, 10 parts of difenoconazole technical materials, 10 parts of cyclohexanone, 5 parts of dimethyl formamides, 4 parts of calcium dodecyl benzene sulfonates, 5 parts of triphen ethyl-phenol APEOs, 2 parts of phenethyl phenolformaldehyde resin APEOs, all the other supply 100 parts with toluene.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞1500mg/kg, chmice acute per os LD50＞1500mg/kg, rabbit is acute through skin LD502000mg/kg, and rat acute has no stimulation to skin through skin LD50＞2000mg/kg, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: convert and prevent and treat rice sheath blight disease, 2000～3000 times of water dilutions, spray medicine 3～7 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and Difenoconazole are pressed 20/1 respectively, 10/1,5/1,3/1,3/2,1/1,1/3,1/10,1/20 ratio is composite, do check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 10% Difenoconazole wetting powder, 3: 2 proportioning medicament co-toxicity coefficient 293.53 wherein, the result shows and has significant synergies.
Embodiment five
The phonetic mould amine suspending agent of 30% rice blast acid amides
Raw material is formed: 15 parts of former medicines of rice blast acid amides, 15 parts of former medicines of phonetic mould amine, 1 part of calcium dodecyl benzene sulfonate, 3 parts of triphen ethyl-phenol APEOs, 1 part of naphthalenesulfonate formaldehyde condensation compound, 0.05 part of xanthans, 1 part of white carbon, 5 parts of glycerine, water are supplied 100 parts, and the composite mode of suspending agent is prepared routinely.
Toxicity test, rat acute per os LD50＞4000mg/kg, rabbit is acute to have no stimulation to skin through skin LD50＞5000mg/kg, and eye is had no stimulation, and shows that compound drug belongs to low-toxin farm chemicals.
Using dosage: prevent and treat gray mold, convert 1000～1500 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and phonetic mould amine are pressed 20/1,10/1,5/1 respectively, 2/1,1/1,1/2,1/5,1/10,1/20 ratio is composite, does check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 30% phonetic mould amine suspending agent, and co-toxicity coefficient is 156.17～185.23, the result shows and has significant synergies that wherein 1: 1 proportioning medicament co-toxicity coefficient is the highest.
Embodiment six
45% rice blast acid amides tpn wetting powder
Raw material is formed: 15 parts of former medicines of rice blast acid amides, 30 parts of former medicines of tpn; 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 5 parts of sodium lignin sulfonates, 4 parts of calcium lignosulfonates, 2 parts of dodecyl sodium sulfates, 10 parts of ammonium sulfate, 15 parts of diatomite are supplied 100 parts with kaolin, and the composite mode of wetting powder is prepared routinely.
Toxicity test, rat acute per os LD50＞10000mg/kg, rabbit is acute through skin LD50＞10000mg/kg, and skin is had faint spread effect, and eye is had faint spread effect, shows that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control graw mold of tomato, convert 1500～2000 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and tpn are pressed 20/1 respectively, 10/1,5/1,1/1,1/2,1/5,1/10,1/20 ratio is composite, does check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 75% tpn wetting powder, and co-toxicity coefficient is 154.35～192.25, the result shows and has significant synergies, and is wherein the most obvious with 1: 2 synergistic effect.
Embodiment seven
22% rice blast acid amides antibiotic in pyrimidine nucleoside class suspending agent
Raw material is formed: 20 parts of former medicines of rice blast acid amides, 2 parts of former medicines of antibiotic in pyrimidine nucleoside class, 1 part of calcium dodecyl benzene sulfonate, 3 parts of triphen ethyl-phenol APEOs, 5 parts of glycerine, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1 part of Nekal BX, 0.15 part of xanthans, 0.2 part of benzoic acid, water is supplied 100 parts, and the composite mode of suspending agent is prepared routinely.
Toxicity test, rat acute per os LD50＞1000mg/kg, rabbit is acute to have no stimulation to skin through skin LD50＞1500mg/kg, and eye is had no stimulation, and shows that compound drug belongs to low-toxin farm chemicals.
Using dosage: prevent and treat early blight of tomato, convert 800～1500 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 92%.
Rice blast acid amides (zarilamid) and antibiotic in pyrimidine nucleoside class are pressed 20/1,10/1,5/1 respectively, 2/1,1/1,1/2,1/15,1/10 ratio is composite, do check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 4% antibiotic in pyrimidine nucleoside class aqua, early blight of tomato is carried out Toxicity Determination, co-toxicity coefficient 144.39～185.41, the result shows that having significant synergy does, wherein with 2: the 1 the most obvious usefulness of effect.
Embodiment eight
24% rice blast acid amides flumorph suspending agent
Raw material is formed: 20 parts of former medicines of rice blast acid amides, 4 parts of former medicines of flumorph, 1 part of calcium dodecyl benzene sulfonate, 2 parts of triphen ethyl-phenol APEOs, 1 part of phenethyl phenolformaldehyde resin APEO, 5 parts of glycerine, 1 part of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate, 1.2 parts of Nekal BXs, 0.12 part xanthans, 0.2 part benzoic acid, water is supplied 100 parts, and the composite mode of suspending agent is prepared routinely.
Toxicity test, rat acute per os LD50＞2500mg/kg, rabbit is acute to have no stimulation to skin through skin LD50＞2000mg/kg, and eye is had no stimulation, and shows that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control cucumber downy mildew, convert 1000～1500 times of water dilutions, spray medicine 3-5 days, effect is obvious, and preventive effect is more than 95%.
Rice blast acid amides (zarilamid) and flumorph are pressed 20/1 respectively, 10/1,5/1,1/1,1/5,1/10,1/20 ratio is composite, does check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 20% flumorph wetting powder, and co-toxicity coefficient is 132.89～178.65, the result shows and has significant synergies, and is wherein best with 5: 1 effects.
Embodiment nine
80% rice blast acid amides trazodone wettable powder
Raw material is formed: 75 parts of former medicines of rice blast acid amides, and 5 parts of triazolones, 7 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 5 parts of sodium lignin sulfonates, 2 parts of dodecyl sodium sulfates are supplied 100 parts with kaolin, and the composite mode of wetting powder is prepared routinely.
Toxicity test, rat acute per os LD50＞10000mg/kg, rabbit is acute through skin LD50＞10000mg/kg, and skin is had faint spread effect, and eye is had faint spread effect, shows that compound drug belongs to low-toxin farm chemicals.
Using dosage: the control wheat sharp eyespot, convert 5000～6000 times of water dilutions, spray medicine 2-3 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and triazolone are pressed 20/1 respectively, 15/1,10: 1,5/1,1/1,1/10 ratio is composite, do check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 10% trazodone wettable powder, co-toxicity coefficient is 154.35～192.25, and the result shows and has significant synergies, and is wherein the most obvious with 15: 1 synergistic effects.
Embodiment ten
54% rice blast acid amides kresoxim-methyl water-dispersible granules
Raw material consists of 36 parts of former medicines of rice blast acid amides, 18 parts of former medicines of kresoxim-methyl, and 10 parts of di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonates, 3 parts are drawn back powder, 10% sodium carboxymethyl starch, 5 parts of calcium lignosulfonates, 2 parts of lauryl sodium sulfate are supplied 100 parts with ammonium sulfate, in the usual way preparation.
Toxicity test, rat acute per os LD50＞5000mg/kg, chmice acute per os LD50＞5000mg/kg, rabbit is acute through skin LD50＞2000mg/kg, and rat acute has no stimulation to skin through skin LD50＞2000mg/kg, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: prevent and treat careless mould powdery mildew, convert 5000～6000 times of water dilutions, spray medicine 2～5 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and kresoxim-methyl are pressed 20/1,15/1,10/1 respectively, 5/1,3/1,1/1,1/5,1/10,1/20 ratio is composite, does check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 30% kresoxim-methyl wetting powder, and the Toxicity Determination result of careless mould powdery mildew shows that each medicament is 191.59～289.68 to the co-toxicity coefficient of powdery mildew, have significant synergies, wherein the most outstanding with 3/1 effect.
Embodiment 11
5% rice blast acid amides Difenoconazole aqueous emulsion
Raw material is formed: 3 parts of former medicines of rice blast acid amides, 2 parts of difenoconazole technical materials, 10 parts of cyclohexanone, 10 parts of dimethylbenzene, 1 part of calcium dodecyl benzene sulfonate, 3 parts of triphen ethyl-phenol APEOs, 2 parts of phenethyl phenolformaldehyde resin APEOs, 8 parts of polyoxyethylene nonylphenol ethers, 5 parts of ethylene glycol, water are supplied 100 parts.Preparation in the usual way.
Toxicity test, rat acute per os LD50＞1500mg/kg, chmice acute per os LD50＞1500mg/kg, rabbit acute through skin LD50 greater than 2000mg/kg, rat acute has no stimulation to skin through skin LD50＞2000mg/kg, eye is had no stimulation, show that compound drug belongs to low-toxin farm chemicals.
Using dosage: prevent and treat rice sheath blight disease, convert 800～1000 times of water dilutions, spray medicine 3～7 days, effect is obvious, and preventive effect is more than 90%.
Rice blast acid amides (zarilamid) and Difenoconazole are pressed 20/1 respectively, 10/1,5/1,3/1,3/2,1/1,1/3,1/10,1/20 ratio is composite, do check experiment with 20% rice blast acid amides (zarilamid) suspending agent and 10% Difenoconazole wetting powder, the result shows and has significant synergies, wherein 3: 2 proportioning medicament co-toxicity coefficient 293.53.
Claims (9)
1, a kind of desinsection, miticide composition is characterized in that: comprise the rice blast acid amides and second bactericide at least, the active ingredient weight percent content is 5～80%, and the mass ratio of the rice blast acid amides and second bactericide is between 20: 1～1: 20.
2, the desinsection that relates to as claim 1, miticide composition is characterized in that: second bactericide is selected from a kind of in methoxy acrylic bactericide, acid amide fungicides, triazole bactericidal agent, anilino-pyrimidine, organochlorine series bactericidal agent or the antibiotic class.
3, the desinsection that relates to as claim 2, miticide composition is characterized in that: described methoxy acrylic bactericide is selected from a kind of in kresoxim-methyl, the Fluoxastrobin.
4, the desinsection that relates to as claim 2, miticide composition is characterized in that: described acid amide fungicides is selected from a kind of in dimethomorph, the flumorph.
5, the desinsection that relates to as claim 2, miticide composition is characterized in that: described triazole bactericidal agent is selected from a kind of in Difenoconazole, the triazolone.
6, the desinsection that relates to as claim 2, miticide composition is characterized in that: described anilino-pyrimidine series bactericidal agent is phonetic mould amine.
7, the desinsection that relates to as claim 2, miticide composition is characterized in that: described organochlorine series bactericidal agent is a tpn.
8, the desinsection that relates to as claim 2, miticide composition is characterized in that: described antibiotic series bactericidal agent is an antibiotic in pyrimidine nucleoside class.
9, the desinsection that relates to as claim 1, miticide composition is characterized in that: its formulation is a kind of in missible oil, wetting powder, suspending agent, granule, microemulsion, aqueous emulsion, the water-dispersible granules.
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