CN101597452A - A kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof - Google Patents
A kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof Download PDFInfo
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- CN101597452A CN101597452A CNA2009100673354A CN200910067335A CN101597452A CN 101597452 A CN101597452 A CN 101597452A CN A2009100673354 A CNA2009100673354 A CN A2009100673354A CN 200910067335 A CN200910067335 A CN 200910067335A CN 101597452 A CN101597452 A CN 101597452A
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Abstract
The present invention relates to a kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof, belong to paint field.It is that raw material stirring by following ratio of weight and number forms: base-material: 20 parts～40 parts of aqueous acrylic emulsions; Elastomerics: 10 parts～50 parts of thermoplastic styrene butadiene rubber SBS water-based latex; Mineral filler: 20 parts～50 parts; Auxiliary agent: 1 part～10 parts; Water: 5 parts～15 parts.The present invention can give original water-borne coatings does not possess snappiness and excellent waterproofness, and nontoxic, do not fire not quick-fried, wear-resisting free of contamination novel aqueous environment-friendly type thick elastic waterproof paint.This product is the superior prod of place widespread uses such as indoor and outdoor basketball court, tennis court, volleyball court, court, table tennis court swimming pool and parking lot, can also be used in the gymnasium, the color elastic terrace is made in health body space for activities.
Description
Technical field
The invention belongs to paint field, is a kind of novel aqueous environment-friendly type thick elastic waterproof paint.
Background technology
At present, the inwall of some swimming pools and pond base paint are owing to lack rebound resilience, easily scratch after the skin contact, and basketball court, tennis court, volleyball court, court, table tennis court, ground such as parking lot are most, and what use is polyurethane bicomponent coating, elasticity is little, and contain organic solvent, the volatilization of solvent causes environmental pollution, influences HUMAN HEALTH.
The applicant has applied for that on July 18th, 2008 " a kind of thermoplastic butadiene styrene rubber aqueous rubber latex asphalt modifying agent and preparation method thereof " number of patent application is 200810050972.6 Chinese invention patent, this patent is open on January 21st, 2009, and publication number is CN101348598.
Rubber in the thermoplastic styrene butadiene rubber SBS water-based latex in this invention is one or more in the segmented copolymer of styrene-butadiene-styrene, and thermoplastic styrene butadiene rubber SBS promptly gets thermoplastic styrene butadiene rubber SBS water-based latex through dissolving, emulsification, distillation; Its preparation method sees this patent for details.
Summary of the invention
The invention provides a kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof, is polyurethane bicomponent coating with what solve present use, and elasticity is little, and contains organic solvent, and the volatilization of solvent causes environmental pollution, influences the problem of HUMAN HEALTH.The technical scheme that the present invention takes is:
It is that raw material stirring by following ratio of weight and number forms:
Base-material: 20 parts～40 parts of aqueous acrylic emulsions;
Elastomerics: 10 parts～50 parts of thermoplastic styrene butadiene rubber SBS water-based latex;
Mineral filler: 20 parts～50 parts;
Auxiliary agent: 1 part～10 parts;
Water: 5 parts～15 parts.
One embodiment of the present invention is: aqueous acrylic emulsion is the snappiness acrylate copolymer emulsion, a kind of in modified acrylic acid emulsion or the elasticity building ACRYLIC EMULSION.
One embodiment of the present invention is: mineral filler is several in cement, silica powder, fine particle calcium carbonate, titanium dioxide, wollastonite, wilkinite or the talcum powder.
One embodiment of the present invention is: auxiliary agent comprises presses the row raw materials by weight percent:
Water-borne coatings dispersion agent 40%-80%;
Water-borne coatings thickening material 20%-60%; Wherein:
The water-borne coatings dispersion agent is a kind of in polycarboxylate sodium, the polyacrylic acid sodium salt.
The water-borne coatings thickening material is modified carboxylic acid class alkali swelling type thickening material or acrylate and methacrylic ester copolymer emulsion.
One embodiment of the present invention is: water is deionized water or distilled water.
The present invention mainly is to be base-material with the ACRYLIC EMULSION, is water-proof elastomer with the thermoplastic styrene butadiene rubber SBS water-based latex with snappiness and excellent water-repellancy, adds mineral filler, and auxiliary agent, water etc. mixes together.
Rubber water-based latex among the present invention is that the rubber in the thermoplastic styrene butadiene rubber SBS water-based latex is one or more in the segmented copolymer of styrene-butadiene-styrene, and thermoplastic styrene butadiene rubber is promptly got thermoplastic styrene butadiene rubber SBS water-based latex through dissolving, emulsification, distillation.Concrete preparation method sees that patent " a kind of thermoplastic butadiene styrene rubber aqueous rubber latex asphalt modifying agent and preparation method thereof ", number of patent application are 200810050972.6, publication number is CN101348598.
The invention has the advantages that the thermoplastic styrene butadiene rubber SBS water-based latex to have snappiness and excellent water-repellancy is an elastomerics, a kind of as base-material with in snappiness acrylate copolymer emulsion, modified acrylic acid emulsion or the elasticity building ACRYLIC EMULSION adds mineral filler, auxiliary agent, water etc.The thermoplastic styrene butadiene rubber SBS water-based latex that the present invention will have snappiness and excellent water-repellancy first is applied in the water-borne coatings, gives water-borne coatings special advantage--snappiness, damping property, water-repellancy, wear resistance, anti-skid.The invention reside in provide a kind of novel water resistance excellence, rebound resilience good, nontoxic, do not fire not quick-fried, wear-resisting free of contamination aqueous environment protection snappiness thick coating, its performance characteristics is as follows:
1, professional performance: have good damping and rebound resilience, both can make the fast starting of sportsmen, can alleviate the surging force in the motion again, safety and comfort for the sportsmen provides safe athletic ground, are the preferred material in professional court.
2, environmental-protecting performance: this coating is that water base organic solvent that do not contain does not add any organic solvent diluting in construction process, and not residual any poisonous or heavy metal ingredients substance is real environmentfriendly products, meets national requirements for environmental protection fully.
3, Practical Performance: this coating can be made into distinct colors, color and luster is attractive in appearance, wear-resisting, anti-skidding, ageing-resistant, have good rebound resilience and water-repellancy, it is round-the-clock court material, it also is the preferred material of swimming pool, and can on bituminous concrete basis or cement concrete fundamental plane, construct, it is simple and easy, easy to maintenance to construct.
This product is the superior prod of place widespread uses such as indoor and outdoor basketball court, tennis court, volleyball court, court, table tennis court swimming pool and parking lot, can also be used in the gymnasium, the color elastic terrace is made in health body space for activities.
Properties of sample technical indicator such as following table
Embodiment
Embodiment 1
In the beaker that fills 30g snappiness acrylate copolymer emulsion, add 30g thermoplastic styrene butadiene rubber SBS water-based latex, stir evenly the back and add 5g silica powder, 8g external application titanium dioxide, 7g white cement, the 10g deionized water stirs evenly, add the 8g polyacrylic acid sodium salt again, 2g acrylate and methacrylic ester copolymer emulsion, mixing and stirring get final product the present invention.
Embodiment 2:
In the beaker that fills 20g snappiness acrylate copolymer emulsion, add 50g thermoplastic elastomer SIS water-based latex, stir evenly the back and add 11g silica powder, 7g external application titanium dioxide, 10g white cement, 2g iron oxide red, the 5g deionized water, stir evenly the back and add 3g polyacrylic acid sodium salt, 2g acrylate and methacrylic ester copolymer emulsion, mixing and stirring get final product the present invention.
Embodiment 3
In the beaker that fills 20g snappiness acrylate copolymer emulsion, add 50g thermoplastic styrene butadiene rubber SBS water-based latex, stir evenly the back and add 4g silica powder, 6g external application titanium dioxide, the blackish green cement of 10g, 9g deionized water, stir evenly the back and add 0.4g polyacrylic acid sodium salt, 0.6g acrylate and methacrylic ester copolymer emulsion, mixing and stirring get final product the present invention.
Embodiment 4
In the beaker that fills the 20g modified acrylic acid emulsion, add 20g thermoplastic styrene butadiene rubber SBS water-based latex, stir evenly the back and add 18g silica powder, 10g external application titanium dioxide, 12g scarlet cement, 15g deionized water, stir evenly the back and add 3g polycarboxylate sodium, 2g modified carboxylic acid class alkali swelling thickening material, mixing and stirring get final product the present invention.
Embodiment 5
In the beaker that fills the 30g modified acrylic acid emulsion, add 10g thermoplastic styrene-butadiene rubber(SBR) SBS water-based latex, stir evenly the back and add 20g silica powder, 7g external application titanium dioxide, 10g white cement, 8g fine particle calcium carbonate, the 5g talcum powder, the 7g deionized water, stir evenly the back and add 2.4g polyacrylic acid sodium salt, 0.6 part of modified carboxylic acid class alkali swelling thickening material, mixing and stirring get final product the present invention.
Embodiment 6
In the beaker that fills 40g snappiness ACRYLIC EMULSION for building, add 50g thermoplastic styrene-butadiene rubber(SBR) SBS water-based latex, stir evenly the back and add 13g silica powder, 7g external application titanium dioxide, 10g safran cement, 5g deionized water, stir evenly the back and add 3g polyacrylic acid sodium salt, 2g part acrylate and methacrylic ester copolymer emulsion, mixing and stirring get final product the present invention.
Preparation method's reference of thermoplastic styrene butadiene rubber SBS water-based latex in the various embodiments described above: patent " a kind of thermoplastic butadiene styrene rubber aqueous rubber latex asphalt modifying agent and preparation method thereof " number of patent application is 200810050972.6 Chinese invention patent, this patent is open on January 21st, 2009, and publication number is CN101348598.
Each embodiment performance test table look-up is as follows:
Claims (7)
1, a kind of SBS aqueous thick environment protection waterproof paint with high elasticity is characterized in that, it is that raw material stirring by following ratio of weight and number forms:
Base-material: 20 parts～40 parts of aqueous acrylic emulsions;
Elastomerics: 10 parts～50 parts of thermoplastic styrene butadiene rubber SBS water-based latex;
Mineral filler: 20 parts～50 parts;
Auxiliary agent: 1 part～10 parts;
Water: 5 parts～15 parts.
2, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 1 is characterized in that: aqueous acrylic emulsion is snappiness acrylate copolymer emulsion, modified acrylic acid emulsion or elasticity building ACRYLIC EMULSION.
3, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 1 is characterized in that: mineral filler is several in cement, silica powder, fine particle calcium carbonate, titanium dioxide, wollastonite, wilkinite or the talcum powder.
4, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 1 is characterized in that: auxiliary agent comprises presses the row raw materials by weight percent:
Water-borne coatings dispersion agent 40%-80%;
Water-borne coatings thickening material 20%-60%.
5, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 4 is characterized in that: the water-borne coatings dispersion agent is polycarboxylate sodium or polyacrylic acid sodium salt.
6, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 4 is characterized in that: the water-borne coatings thickening material is modified carboxylic acid class alkali swelling type thickening material or acrylate and methacrylic ester copolymer emulsion.
7, SBS aqueous thick environment protection waterproof paint with high elasticity according to claim 1 is characterized in that: water is deionized water or distilled water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100673354A CN101597452A (en) | 2009-07-24 | 2009-07-24 | A kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100673354A CN101597452A (en) | 2009-07-24 | 2009-07-24 | A kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof |
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| CN101597452A true CN101597452A (en) | 2009-12-09 |
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| CNA2009100673354A Pending CN101597452A (en) | 2009-07-24 | 2009-07-24 | A kind of SBS aqueous thick environment protection waterproof paint with high elasticity and preparation method thereof |
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Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103387779A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Special paint for wear-resistant skid-resistant sport field |
| CN103602148A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Waterproof paint difficult to scratch |
| CN103614025A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市高华电子有限公司 | Environmentally-friendly highly-elastic waterproof coating |
| CN103740226A (en) * | 2013-12-20 | 2014-04-23 | 南车长江车辆有限公司 | Strippable protective coating |
| CN103756464A (en) * | 2013-12-13 | 2014-04-30 | 张家港市双林制墨涂装有限公司 | Waterproof paint, and preparation method thereof |
| CN103756419A (en) * | 2013-12-27 | 2014-04-30 | 安徽省美域节能环保技术应用有限公司 | Aqueous outer wall coating and preparation method thereof |
| CN103755264A (en) * | 2014-01-17 | 2014-04-30 | 东海建设集团有限公司 | Polymer-based waterproof coating |
| CN104119759A (en) * | 2014-07-10 | 2014-10-29 | 广东柏胜新材料科技有限公司 | Wear-resistant weather-proof antiskid sports ground silicone-acrylic coating |
| CN104387974A (en) * | 2014-12-04 | 2015-03-04 | 王凯 | Anti-slip waterproof paint |
| CN104449173A (en) * | 2014-12-02 | 2015-03-25 | 广西大学 | Thermoplastic-elastomer-modified polymethyl methacrylate color antiskid paint |
| CN104497751A (en) * | 2014-12-10 | 2015-04-08 | 李永志 | Preparation method of waterproof paint |
| WO2015051526A1 (en) * | 2013-10-11 | 2015-04-16 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
| CN104910743A (en) * | 2015-07-14 | 2015-09-16 | 桂林市和鑫防水装饰材料有限公司 | Single-component acrylate waterproof coating |
| CN107118634A (en) * | 2017-05-18 | 2017-09-01 | 广州双虹建材有限公司 | A kind of high resiliency anticracking waterproof coating and preparation method thereof |
| CN107459934A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | One kind improvement quick-drying waterproof architectural coating and preparation method thereof |
| CN107474669A (en) * | 2017-09-29 | 2017-12-15 | 山东天汇防水股份有限公司 | Acrylate waterproof paint and preparation method thereof |
| CN108587354A (en) * | 2018-05-16 | 2018-09-28 | 苏州金螳螂建筑装饰股份有限公司 | Multifunctional containment hardens primary coat and its preparation method and application |
| CN108795198A (en) * | 2018-05-25 | 2018-11-13 | 南通市晗泰化工有限公司 | A kind of construction waterproof coating and preparation method thereof |
| CN109439074A (en) * | 2018-09-25 | 2019-03-08 | 宁波港集隆包装材料有限公司 | A kind of non-skid coating |
| CN109988468A (en) * | 2019-02-27 | 2019-07-09 | 湖北国创高新材料股份有限公司 | A kind of bituminous pavement protective agent and preparation method thereof |
| CN110698799A (en) * | 2019-08-07 | 2020-01-17 | 大茂环保新材料股份有限公司 | Prefabricated elastic sheet and preparation method thereof |
| CN112876720A (en) * | 2021-01-15 | 2021-06-01 | 安徽昊森新材料科技有限公司 | Fireproof and antiskid wood-plastic composite material and preparation method thereof |
| CN113956742A (en) * | 2021-11-26 | 2022-01-21 | 合众（佛山）化工有限公司 | Water-based paint for modified acrylic resin steel structure |
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2009
- 2009-07-24 CN CNA2009100673354A patent/CN101597452A/en active Pending
Cited By (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103387779A (en) * | 2013-07-08 | 2013-11-13 | 吴江市物华五金制品有限公司 | Special paint for wear-resistant skid-resistant sport field |
| WO2015051526A1 (en) * | 2013-10-11 | 2015-04-16 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
| US10793709B2 (en) | 2013-10-11 | 2020-10-06 | Dow Global Technologies Llc | Polymer mixture, multilayer article containing the same, and process of preparing the multilayer article |
| CN103614025A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市高华电子有限公司 | Environmentally-friendly highly-elastic waterproof coating |
| CN103602148A (en) * | 2013-11-19 | 2014-02-26 | 青岛广联达精密机械有限公司 | Waterproof paint difficult to scratch |
| CN103602148B (en) * | 2013-11-19 | 2016-05-11 | 青岛祥嘉知识产权服务有限公司 | A kind of water-repellent paint of difficult scuffing |
| CN103756464A (en) * | 2013-12-13 | 2014-04-30 | 张家港市双林制墨涂装有限公司 | Waterproof paint, and preparation method thereof |
| CN103740226A (en) * | 2013-12-20 | 2014-04-23 | 南车长江车辆有限公司 | Strippable protective coating |
| CN103740226B (en) * | 2013-12-20 | 2016-01-13 | 南车长江车辆有限公司 | A kind of strippable protective coating |
| CN103756419A (en) * | 2013-12-27 | 2014-04-30 | 安徽省美域节能环保技术应用有限公司 | Aqueous outer wall coating and preparation method thereof |
| CN103755264A (en) * | 2014-01-17 | 2014-04-30 | 东海建设集团有限公司 | Polymer-based waterproof coating |
| CN104119759A (en) * | 2014-07-10 | 2014-10-29 | 广东柏胜新材料科技有限公司 | Wear-resistant weather-proof antiskid sports ground silicone-acrylic coating |
| CN104119759B (en) * | 2014-07-10 | 2017-05-03 | 广东柏胜新材料科技有限公司 | Wear-resistant weather-proof antiskid sports ground silicone-acrylic coating |
| CN104449173A (en) * | 2014-12-02 | 2015-03-25 | 广西大学 | Thermoplastic-elastomer-modified polymethyl methacrylate color antiskid paint |
| CN104449173B (en) * | 2014-12-02 | 2017-02-22 | 广东立得新材料科技有限公司 | Thermoplastic-elastomer-modified polymethyl methacrylate color antiskid paint |
| CN104387974A (en) * | 2014-12-04 | 2015-03-04 | 王凯 | Anti-slip waterproof paint |
| CN104497751A (en) * | 2014-12-10 | 2015-04-08 | 李永志 | Preparation method of waterproof paint |
| CN104910743A (en) * | 2015-07-14 | 2015-09-16 | 桂林市和鑫防水装饰材料有限公司 | Single-component acrylate waterproof coating |
| CN107118634A (en) * | 2017-05-18 | 2017-09-01 | 广州双虹建材有限公司 | A kind of high resiliency anticracking waterproof coating and preparation method thereof |
| CN107459934A (en) * | 2017-08-31 | 2017-12-12 | 苏州仲勉装饰有限公司 | One kind improvement quick-drying waterproof architectural coating and preparation method thereof |
| CN107474669A (en) * | 2017-09-29 | 2017-12-15 | 山东天汇防水股份有限公司 | Acrylate waterproof paint and preparation method thereof |
| CN108587354A (en) * | 2018-05-16 | 2018-09-28 | 苏州金螳螂建筑装饰股份有限公司 | Multifunctional containment hardens primary coat and its preparation method and application |
| CN108587354B (en) * | 2018-05-16 | 2020-12-22 | 苏州金螳螂建筑装饰股份有限公司 | Multifunctional seal hardening base coat and preparation method and application thereof |
| CN108795198A (en) * | 2018-05-25 | 2018-11-13 | 南通市晗泰化工有限公司 | A kind of construction waterproof coating and preparation method thereof |
| CN109439074A (en) * | 2018-09-25 | 2019-03-08 | 宁波港集隆包装材料有限公司 | A kind of non-skid coating |
| CN109988468A (en) * | 2019-02-27 | 2019-07-09 | 湖北国创高新材料股份有限公司 | A kind of bituminous pavement protective agent and preparation method thereof |
| CN110698799A (en) * | 2019-08-07 | 2020-01-17 | 大茂环保新材料股份有限公司 | Prefabricated elastic sheet and preparation method thereof |
| CN112876720A (en) * | 2021-01-15 | 2021-06-01 | 安徽昊森新材料科技有限公司 | Fireproof and antiskid wood-plastic composite material and preparation method thereof |
| CN113956742A (en) * | 2021-11-26 | 2022-01-21 | 合众（佛山）化工有限公司 | Water-based paint for modified acrylic resin steel structure |
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Open date: 20091209 |