CN109439074A - A kind of non-skid coating - Google Patents
A kind of non-skid coating Download PDFInfo
- Publication number
- CN109439074A CN109439074A CN201811113630.4A CN201811113630A CN109439074A CN 109439074 A CN109439074 A CN 109439074A CN 201811113630 A CN201811113630 A CN 201811113630A CN 109439074 A CN109439074 A CN 109439074A
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- skid coating
- skid
- coating
- water
- elastomer powder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D107/00—Coating compositions based on natural rubber
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/58—Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of non-skid coatings, including water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder, water, film forming agent, nano silica and adhesion promoter.Non-skid coating of the invention is suitable for spraying or being coated in a variety of substrate surfaces, such as paper, plastics, steel;After non-skid coating of the invention is sprayed or is coated on substrate, it can form a film at room temperature, considerably increase the use scope of non-skid coating;Non-skid coating of the invention is water paint, and environmental-protecting performance is excellent.
Description
Technical field
The present invention relates to technical field of coatings more particularly to a kind of non-skid coatings.
Background technique
In cargo transport, need to avoid cargo that opposite slide occurs due to inertia etc..Common method is to pass through
Attaching means constrains cargo, and cargo is avoided to slide between each other, at present there is a method in which being exactly the frictional force increased between cargo,
To avoid cargo that opposite sliding occurs.
In the patent of Patent No. CN201720972847.5, a kind of gum antiskid paper is disclosed, by paper
Coat anti-slip layer, the frictional force of Lai Zengjia antiskid paper in side.The gum antiskid paper is attached on cargo or cargo pallet, Ke Yizeng
Add the frictional force of cargo surfaces, to play the effect of anti-sliding stop.
But existing non-skid coating needs to place a period of time at a higher temperature after being coated on substrate surface
Afterwards, nonskid coating could be obtained, which limits the applications of non-skid coating.For example, in some cases, cargo has been completed to wrap
Dress, also there is no antiskid effects for the packaging bag of cargo, at this point, traditional non-skid coating can not be coated in outside packaging bag, make to wrap
Pack obtains nonskid coating.
Summary of the invention
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of non-skid coating, be suitable for spraying or
Coated in substrate surface, to quickly and easily form nonskid coating in substrate surface.
The purpose of the present invention adopts the following technical scheme that realization:
A kind of non-skid coating, comprising: water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder, water, film forming
Agent, nano silica and adhesion promoter.
Further, the granularity of the elastomer powder is 100 mesh~400 mesh.
Further, the elastomer powder is selected from one or more of: rubber powder, elastic polyurethane powder, elasticity are poly-
Ethylene powder.
Further, the non-skid coating includes water-and acrylate lotion, and the water-and acrylate lotion is non-anti-
Answer type acrylic acid ester emulsion.
Further, the non-skid coating includes aqueous polyurethane emulsion, and the aqueous polyurethane emulsion is poly- for one pack system
Urethane lotion.
Further, the mass fraction of each component in the non-skid coating is respectively as follows:
Compared with prior art, it is suitable for spraying the beneficial effects of the present invention are: non-skid coating of the invention or is coated in more
Kind substrate surface, such as paper, plastics, steel;Non-skid coating spraying of the invention or after being coated on substrate, can at room temperature at
Film considerably increases the use scope of non-skid coating;Non-skid coating of the invention is water paint, and environmental-protecting performance is excellent.
Specific embodiment
In the following, being described further in conjunction with specific embodiment to the present invention, it should be noted that is do not collided
Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
First preferred embodiment according to the present invention, non-skid coating of the invention include: water-and acrylate lotion,
Elastomer powder, water, film forming agent, nano silica and adhesion promoter.
Water-and acrylate lotion is used in coating more and more because of its feature of environmental protection, but water-and acrylate
The non-skid property of itself is poor, in the prior art mainly by carrying out graft modification to acrylate, to improve acrylate
The skid resistance of coating.And the present invention is formed anti-mainly by directly mixing elastomer powder with water-and acrylate lotion
Sliding coating, preparation method is simple, at low cost.
In some embodiments, water-and acrylate lotion of the invention is non-reactive acrylic acid ester emulsion, film forming
When rely primarily on the coalescence of interparticle physics to improve the performance of film, it is of the invention due to not needing to crosslink reaction
Non-skid coating can form a film at room temperature.The preparation method of non-reactive acrylic acid ester emulsion can refer to the prior art, the present invention
No longer it is described in detail.
Nano silica is to improve the important channel of aqueous polymer emulsion performance, and nano silica is of the invention
In formula, it can also play the role of preventing elastomer powder from depositing, the uniformity of elastomer powder distribution be improved, thus favorably
In the coefficient of friction for the nonskid coating for improving non-skid coating preparation of the present invention.
Elastomer powder main function is the frictional force of increase non-skid coating, and granularity is preferably 100 mesh~400 mesh.
Elastomer powder be selected from one or more of: rubber powder, TPU, TPE, wherein rubber powder include but is not limited to acrylonitrile-butadiene rubber powder,
Styrene butadiene rubber powder, EP rubbers, natural rubber.
Adhesion promoter can be aqueous or oiliness.In some embodiments, adhesion promoter is aqueous, adhesive force
Promotor includes but is not limited to BYK-4500, BYK-4510, and BYK-4500, BYK-4510 are the attached of German Bi Ke company exploitation
Adhesion promoter, is the prior art, and the present invention is no longer described in detail.
Preferably, the mass fraction of each component in non-skid coating is respectively as follows:
Second preferred embodiment according to the present invention, non-skid coating of the invention include: aqueous polyurethane emulsion, bullet
Property body powder, water, film forming agent, nano silica and adhesion promoter.
Aqueous polyurethane emulsion is not only environmentally friendly material, and function admirable, is widely used in paint field.
In some embodiments, aqueous polyurethane emulsion of the invention is monocomponent waterborne polyurethane lotion, using water as dispersing agent,
The crosslinking reaction may not occur in film forming procedure, and due to not needing to crosslink reaction, non-skid coating of the invention can be in room temperature
Lower film forming.The type and preparation method of monocomponent waterborne polyurethane lotion can refer to the prior art, and the present invention is no longer described in detail.
Nano silica is to improve the important channel of aqueous polymer emulsion performance, and nano silica is of the invention
In formula, it can also play the role of preventing elastomer powder from depositing, the uniformity of elastomer powder distribution be improved, thus favorably
The coefficient of friction of nonskid coating is prepared in raising non-skid coating of the present invention.
Elastomer powder main function is the frictional force of increase non-skid coating, and granularity is preferably 100 mesh~400 mesh.
Elastomer powder be selected from one or more of: rubber powder, TPU, TPE, wherein rubber powder include but is not limited to acrylonitrile-butadiene rubber powder,
Styrene butadiene rubber powder, EP rubbers, natural rubber.
Adhesion promoter can be aqueous or oiliness.In some embodiments, adhesion promoter is aqueous, attachment
Power promotor includes but is not limited to BYK-4500, BYK-4510.BYK-4500, BYK-4510 are that German Bi Ke company develops
Adhesion promoter, is the prior art, and the present invention is no longer described in detail.
Preferably, the mass fraction of each component in non-skid coating is respectively as follows:
[embodiment 1]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 2]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 3]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 4]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 5]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[embodiment 6]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, non-skid coating is obtained.
[comparative example 1]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 1.
[comparative example 2]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 2.
[comparative example 3]
Coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 3.
[comparative example 4]
Non-skid coating includes the component of following mass percent:
At 25 DEG C~45 DEG C, the above components are uniformly mixed, obtain the coating of comparative example 4.
The coating of each embodiment and comparative example is sprayed on to brown paper, PP plastic knitting band, surface of steel plate respectively, then
The confficient of static friction and dynamic friction coefficient of each sample are tested, experimental result is shown in Table 1.
Table 1
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed range.
Claims (6)
1. a kind of non-skid coating characterized by comprising water-and acrylate lotion or aqueous polyurethane emulsion, elastomer powder
End, water, film forming agent, nano silica and adhesion promoter.
2. non-skid coating according to claim 1, which is characterized in that the granularity of the elastomer powder is 100 mesh~400
Mesh.
3. non-skid coating according to claim 1, which is characterized in that the elastomer powder is selected from following a kind of or more
Kind: rubber powder, TPU, TPE.
4. non-skid coating according to claim 1, which is characterized in that the non-skid coating includes water-and acrylate cream
Liquid, the water-and acrylate lotion are non-reactive acrylic acid ester emulsion.
5. non-skid coating according to claim 1, which is characterized in that the non-skid coating includes aqueous polyurethane emulsion,
The aqueous polyurethane emulsion is mono-component polyurethane lotion.
6. -5 any non-skid coating according to claim 1, which is characterized in that the quality of each component in the non-skid coating
Number is respectively as follows:
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CN201811113630.4A CN109439074A (en) | 2018-09-25 | 2018-09-25 | A kind of non-skid coating |
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CN201811113630.4A CN109439074A (en) | 2018-09-25 | 2018-09-25 | A kind of non-skid coating |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073088A (en) * | 2019-09-29 | 2020-04-28 | 大茂环保新材料股份有限公司 | Water-based elastic floor block and production process thereof |
CN112708322A (en) * | 2020-12-11 | 2021-04-27 | 广东西敦千江粉漆科学研究有限公司 | Anti-skid powder coating and preparation method and spraying process thereof |
CN113174777A (en) * | 2021-03-31 | 2021-07-27 | 美盈森集团股份有限公司 | Bi-component coating type anti-slip coating and preparation method thereof |
CN116179068A (en) * | 2023-03-17 | 2023-05-30 | 天津科技大学 | Anti-friction polyurethane super-hydrophobic coating prepared based on organic/inorganic particle composite, coating, method and application |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111073088A (en) * | 2019-09-29 | 2020-04-28 | 大茂环保新材料股份有限公司 | Water-based elastic floor block and production process thereof |
CN111073088B (en) * | 2019-09-29 | 2022-03-25 | 大茂环保新材料股份有限公司 | Water-based elastic floor block and production process thereof |
CN112708322A (en) * | 2020-12-11 | 2021-04-27 | 广东西敦千江粉漆科学研究有限公司 | Anti-skid powder coating and preparation method and spraying process thereof |
CN113174777A (en) * | 2021-03-31 | 2021-07-27 | 美盈森集团股份有限公司 | Bi-component coating type anti-slip coating and preparation method thereof |
CN116179068A (en) * | 2023-03-17 | 2023-05-30 | 天津科技大学 | Anti-friction polyurethane super-hydrophobic coating prepared based on organic/inorganic particle composite, coating, method and application |
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