CN101575245B - Organic titanium-potassium fertilizer and preparation method thereof - Google Patents
Organic titanium-potassium fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN101575245B CN101575245B CN2009100229359A CN200910022935A CN101575245B CN 101575245 B CN101575245 B CN 101575245B CN 2009100229359 A CN2009100229359 A CN 2009100229359A CN 200910022935 A CN200910022935 A CN 200910022935A CN 101575245 B CN101575245 B CN 101575245B
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- potassium
- organic
- titanium
- borax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses organic titanium-potassium fertilizer and a preparation method thereof. The fertilizer is characterized in that the fertilizer takes water as solvent; and the compositions of the fertilizer in every liter of water are: 5 to 100g of organic chelated titanium, 75 to 200g of glucose, 600 to 800g of potassium citrate, 0 to 130g of borax or boric acid, 0 to 90g of humic acid or potassium humate, 0 to 60g of EDDHA chelating agent and 7 to 12g of auxiliary agent. The organic titanium-potassium fertilizer not only makes effective use of the prior fertilizer resources to change the status quo of constant high potassium fertilizer price in China, relieve contradictions between supply and demand and save resource, but also overcomes the differences between southern China and northern China in climate, soil, and the like, thereby playing a remarkable role in solving soil hardening, salinization and acidification. The fertilizer can also improve adverse circumstance resistance of crops, and is suitable for soil of various climates and various crops; moreover, the fertilizer better ensures yield increase of various crops and solves the problems of farmers such as low economic benefits, income increase, labor intensity reduction and the like; meanwhile, the fertilizer is propitious to advocate rational application of the fertilizer and improve the quality of farm products.
Description
Technical field
The invention belongs to the agricultural fertilizer production field, relate to a kind of macroelement potash fertilizer class chemical fertilizer, especially a kind of organic titanium-potassium fertilizer and preparation method thereof.
Background technology
Along with agrotechnical continuous development, modern agriculture has proposed requirement higher, that upgrade to using of fertilizer.The main effect of fertilizer is to improve crop yield in the traditional agriculture, and along with modern agricultural development, very big variation has taken place for the technology of fertilising and purpose; Fertilising is not only wanted and can be increased production, and also wants to improve crop quality, saves resource, helps culture fertility, regulates Soil structure, reduces labor intensity; More important is to want to improve utilization rate of fertilizer; Reduce environmental pollution, increase economic efficiency, help green agriculture and Sustainable development.
Growth and development of plant mainly depends on macroelement nitrogen, phosphorus, potassium, and as important a kind of in the macroelement, potassium element often is called as " article prime element ".It mainly contains the effect of crop quality product: 1. can impel crop to utilize nitrogen preferably, increase Protein content, and can promote the generation of sugar and starch; Kernel, seed, fruit and stem tuber, piece root are increased, and shape and color and luster are attractive in appearance; 3. improve the oleaginousness of oil crops, increase ascorbic content in the fruit; 4. quicken the maturation of fruit, vegetables and other crops, the ripening stage is reached unanimity; 5. strengthen that product is anti-damages and the ability of rotting naturally, prolong to store and transport the time limit; 6. increase intensity, length and the fineness of cotton, crudefiber crop fiber, color and luster purity.
The potash fertilizer that uses in the traditional agriculture has following weak point:
1) most of potash fertilizer of the prior art (no matter being organic potassic fertilizer or inorganic potash fertilizer) all can not use at the florescence of farm crop, otherwise can cause fallen flowers or burn leaf;
2) potash fertilizer of the prior art can not mix use with acid or alkaline agricultural chemicals, topdresses and need carry out separately, and labor capacity is big;
3) inorganic potash fertilizer is (like KCl, K
2SO
4Deng) Cl, SO in the parent
4Deng existence make inorganic potash fertilizer that limitation arranged in the use, long-term a large amount of the use produces harm to crop and soil, while crop absorption of K is more; Also can cause Cl to remain in the soil, or lose, the meeting increasing soil acidity with current; Soil structure is degenerated, cause hardening.On the saltings, use and then increase the weight of salt damage, K
2SO
4Also belong to physiological acidic fertilizer, on the stronger soil of reductibility, also be prone to produce H for crop
2The murder by poisoning of S, cause mashed root (as, capsicum, paddy rice, etc. crop) in present agricultural production practice, the acidifying phenomenon of soil is day by day serious, and since the crop pest that soil acidification causes be prone to draw attention.
In sum, it is thus clear that the problem that the new fertilizer variety of searching solves in the production is extremely urgent.
State Economic and Trade Commission divided in " economical operation in 2002 regulation and control are just wanted " of announcing in February, 2002, and propose to list high-concentration fertilizer in technological transformation and help emphasis, be target to promote industrial competitiveness.U.S.'s liquid fertilizer accounts for about 30% of chemical fertilizer total amount.Country such as Britain, Russia also all a large amount of use various in liquid fertilizer, bring into play many advantages of liquid fertilizer.The production of domestic liquid fertilizer starts to walk already, and the bright prospects of exploitation liquid fertilizer have been described.And liquid fertilizer mainly is meant liquid nitrogen fertilizer etc.Therefore, exploitation high energy, high-content, the high phosphorus of highly enriched full nutrition, the liquid fertilizer of high potassium content have become a direction of scientific rersearch.Because crop is in the middle and later periods of growth, neck, leaf riotous growth, nutrient consumption is very big, and the ability that absorbs nutriment is quite big, and it is irrational leaning on the root absorption solid fertilizer to satisfy the plant-growth needs fully.Utilize axis, the potassium element that leaf is easy to absorb conversion sprays, so that increase operation rate, not only mends potassium, can also replenish the element that other not have utilization simultaneously, can remedy the defective of the potassium deficiency that fertilization mode causes of the low-phosphorous low potassium of the high nitrogen of China.
Chelate fertilizer has appearred in modern agriculture, and it is to carry out chelating with sequestrant and metals ion, and the compound behind the chelating is difficult for being fixed in soil, and is soluble in water, does not dissociate again, can be well by the plant absorbing utilization.Also can be with other solid-state or liquid fertilizer mixed applying and chemical reaction does not take place, do not reduce the fertilizer efficiency of any fertilizer.Chelate fertilizer is compared with the present fertilizer that uses, and following advantage is arranged: strong to metal ion-chelant power; Applied widely, in pH 3～10 scopes, all can use; BA is high, and usage quantity is few; Environmental pollution is little.Chelate fertilizer only is used for the required trace element of plant at present, combines for high-content potassium and organic chelated titanium, and also not seeing has relevant report.
Titanium elements is the new highlight that the field of plant science fertilising in recent years occurs, and is described as " fertilizer catalyzer ".Its effect is to promote plant to N, P, K and other trace elements absorbed and running forcefully, promotes activity, strengthens photosynthesis, improves the content of plant chlorophyll and fruit nutrient.But, be prone to generate water-fast titanium oxide under field conditions (factors), not by the plant absorbing utilization because inorganic titanium salt character is unstable.Therefore, it is fertile to have occurred organic chelated titanium in recent years, and organic chelated titanium is the white solid powder; Soluble in water; PH value of water solution is 6, is research and development of middle nineteen nineties in last century and the high-tech plant nutrition additive of having accomplished field experiment, and its staple is that titanium is (according to TiO
2Meter,>=15%), organic chelated machine matter (>=33%) and ammonium nitrogen nutritive substances such as (>=12%).Though organic chelated titanium fertilizer has above plurality of advantages, if it is fertile to use organic chelated titanium merely, because it costs an arm and a leg, cost is very big, is unfavorable for the big area popularization.
Summary of the invention
The objective of the invention is to overcome defective of the prior art, a kind of organic titanium-potassium fertilizer and working method are provided, this organic titanium-potassium fertilizer mixes organic chelated titanium with potash fertilizer; And the form of employing liquid fertilizer; Can also directly change into organic substance with mineral manure with by the absorption of the fertilizer of soil fixing, economize on resources, improve Soil structure; Make crop alimentary more comprehensive, it is more reasonable to apply fertilizer.
The objective of the invention is to solve through following technical scheme:
This organic titanium-potassium fertilizer is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium 5～100g, glucose 75～200g, Tripotassium Citrate 600～800g, borax or boric acid 0～130g, humic acid or potassium humate 0～90g, EDDHA sequestrant 0～60g and auxiliary agent 7～12g;
The mass concentration of above-mentioned glucose is 99%; Said Tripotassium Citrate is the technical grade Tripotassium Citrate; Said borax is the technical grade borax; Said auxiliary agent is one or more mixtures of bioactive peptide, plug ketone, Frosst).The quality of organic matter content of said humic acid is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order.
Further, with one or more mixture replacing glucose of sucrose, sugar alcohol and Polysaccharides, peptide complexes.
Further, substitute Tripotassium Citrate with saltpetre or Potassium ethanoate, said saltpetre and Potassium ethanoate are technical grade.
Further, with the mixture replacing Tripotassium Citrate of Hydrocerol A and Pottasium Hydroxide, said Hydrocerol A and Pottasium Hydroxide mol ratio are 1: 3.
This organic titanium-potassium fertilizer is got by following method preparation:
(1) according to the formula ratio of each component among each embodiment, each component except that EDDHA sequestrant, borax or boric acid and auxiliary agent is mixed, drop in the reaction kettle, and add the uniform solution of entry stirring formation;
(2) add borax or boric acid and EDDHA sequestrant according to formula ratio, the temperature chelating 1-2h with 40-60 ℃ processes chelating liquid;
(3) in chelating liquid, add auxiliary agent, stir 0.5～1h;
(4) at room temperature with 80-100 purpose strainer filtering, the filtrating that obtains is described organic titanium-potassium fertilizer.
The present invention has the following advantages;
1, the breakthrough raising of the present invention the content of potassium be 280--420 gram/L; The auxiliary agent thiophene ketone that adds is that pharmaceutical grade, its specific activity levulinic acid potassium are more outstanding; Acetic acid wherein; Sugar alcohol, Hydrocerol A have not only replaced the organic matter and the carrier function of levulinic acid, and the trophic function of increase plant more is superior to levulinic acid.
2, the present invention adopts sugar alcohol and Hydrocerol A to mix in organic nutrition, and major cause is the bast position that Hydrocerol A can not directly get into plant, is that organic matter can not change the lower defective of utilization ratio fully by crop utilization and absorption,
3, using organic huge legendary turtle to close titanium can dissolved metal ions, even if use also and can well the inorganic substance dissolving be changed into organic substance by plant absorbing at plant root,
4, change the hormones auxiliary agents such as multiple nitre atmosphere sodium of life-time service on auxiliary agent uses, in the agriculture prodn of more than ten years, multiple nitre atmosphere sodium is very big by the vast farmers cognitive side effects; Harm is to dark; Can only play hormesis at that time, and can not keep the normal growth of plant, destroy the quality of crop and fruit; Tree vigo(u)r is aging year by year, and is weak how sick.And the present invention adopts the thiophene ketone of pharmaceutical grade not only to strengthen tree vigo(u)r but also increase the function of plant absorbing nutrition, and is absorbed by crop within an hour, not only is safe from harm but also improves the resistance against diseases of crop; Secondly thiophene ketone and peptide add jointly, increase the resistance against diseases of crop, improve crop quality; And peptide is the protein to the human body beneficial; Plant growth has suitable help to fruit, and environmental protection meets the requirement of the national green ecological Agricultural Development demand and the ecological agriculture.The Frosst) formal name used at school Xaxa that wherein adds is met water and can be dissolved generation Whitfield's ointment and acetic acid, and solution is subacidity.Whitfield's ointment has antibiotic and preservative activity, and can make the stomata guard cell around the plant stomata closed, and moisture evaporation reduces; And acetic acid can suppress the biological activity of the interior glycolate oxidase of body in the plant respiration process; Thereby make respiratory generation obstacle; The photosynthate accumulation too much; In practical application, possess the freeze proof waterlogging-resistant function of the antibiotic drought resisting of sterilization, and increase the plant color and luster and play good result, play good effect in practice.
Embodiment
Embodiment 1
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 5g; Glucose: 75g;
Tripotassium Citrate: 600g; Borax: 50g;
Potassium humate: 90g; EDDHA sequestrant 5g;
Bioactive peptide: 7g;
The quality of organic matter content of said potassium humate is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order, and the mass concentration of said glucose is 99%, and Tripotassium Citrate adopts technical grade, and borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, glucose, Tripotassium Citrate and potassium humate earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add bioactive peptide, stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 2
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 20g; Glucose: 100g;
Tripotassium Citrate: 650g; Borax: 90g;
EDDHA sequestrant 8g; Bioactive peptide: 12g;
The mass concentration of said glucose is 99%, and Tripotassium Citrate adopts technical grade, and borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, glucose and Tripotassium Citrate earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to prescription, the temperature chelating 1.5h with 50 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add bioactive peptide, stir 1h;
(4) at room temperature with 100 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 3
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 30g; Glucose: 200g;
Tripotassium Citrate: 700g; Humic acid: 20g;
EDDHA sequestrant 10g; Plug ketone: 7g
The organic matter 45～65% of said humic acid, moisture are less than 15%, and fineness is the 80-100 order.The mass concentration of said glucose is 99%.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, glucose, Tripotassium Citrate and humic acid earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add the EDDHA sequestrant according to prescription, the temperature chelating 2h with 45 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add plug ketone, stir 1h;
(4) at room temperature with 100 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 4
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 40g; Sucrose: 75g;
Tripotassium Citrate: 750g; Borax: 100g;
Humic acid: 50g; EDDHA sequestrant 20g;
Plug ketone: 12g
The quality of organic matter content of said humic acid is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; The mass concentration of glucose is 99%; Tripotassium Citrate adopts technical grade; Said borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, sucrose, Tripotassium Citrate and humic acid earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add plug ketone, stir 1h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 5
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 50g; Sucrose: 100g;
Saltpetre: 650g; Humic acid: 80g;
EDDHA sequestrant 25g; Plug ketone: 9g;
The quality of organic matter content of said humic acid is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Saltpetre adopts technical grade.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, sucrose, saltpetre and humic acid earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add the EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add plug ketone, stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 6
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 70g; Sugar alcohol: 100g;
The mixture of Hydrocerol A and Pottasium Hydroxide (mol ratio is 1: 3): 700g;
Borax: 130g; Potassium humate: 80g;
EDDHA sequestrant: 35g; Frosst): 7g;
The quality of organic matter content of said potassium humate is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Said borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add the mixture of organic chelated titanium, sugar alcohol, potassium humate and Hydrocerol A and Pottasium Hydroxide earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 50 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add Frosst), stir 0.5h;
(4) at room temperature with 100 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 7
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 60g; Sugar alcohol: 80g;
Potassium ethanoate: 700g; Borax: 110g;
Humic acid: 90g; EDDHA sequestrant: 60g;
Plug ketone: 11g;
The quality of organic matter content of said humic acid is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Potassium ethanoate adopts technical grade; Said borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, sugar alcohol, Potassium ethanoate and humic acid earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add plug ketone, stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 8
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 80g; Polysaccharides, peptide complexes: 75g;
Potassium ethanoate: 800g; Boric acid: 90g;
Potassium humate: 60g; EDDHA sequestrant: 40g;
Frosst): 10g
The quality of organic matter content of said potassium humate is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Tripotassium Citrate adopts technical grade; Said boric acid is technical grade boric acid.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, Polysaccharides, peptide complexes, Potassium ethanoate and potassium humate earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add boric acid and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add Frosst), stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 9
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 90g; Polysaccharides, peptide complexes: 200g;
Saltpetre: 800g; Boric acid: 110g;
Potassium humate: 50g; EDDHA sequestrant: 5g;
Frosst): 12g
The quality of organic matter content of said potassium humate is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Saltpetre adopts technical grade; Said boric acid is technical grade.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add organic chelated titanium, Polysaccharides, peptide complexes, saltpetre and potassium humate earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add boric acid and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add Frosst), stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 10
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 100g; Sucrose 100g+ sugar alcohol 100g;
Tripotassium Citrate: 800g; Boric acid: 130g;
Frosst): 11g;
Tripotassium Citrate adopts technical grade; Said boric acid is technical grade.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add the mixture of organic chelated titanium, Tripotassium Citrate and sucrose and sugar alcohol earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add boric acid according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add Frosst), stir 0.5h;
(4) at room temperature with 80 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
Embodiment 11
The organic titanium-potassium fertilizer of present embodiment is a solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium: 90g; Polysaccharides, peptide complexes 80g+ sucrose 80g;
Saltpetre: 800g; Borax: 100g;
Potassium humate: 60g; EDDHA sequestrant: 5g;
Bioactive peptide 3g+ Frosst) 6g;
The quality of organic matter content of said potassium humate is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order; Tripotassium Citrate adopts technical grade; Said borax is the technical grade borax.
The organic titanium-potassium fertilizer of present embodiment prepares according to following steps:
(1) at first, according to above prescription, in water, add the mixture of organic chelated titanium, saltpetre, potassium humate and Polysaccharides, peptide complexes and sucrose earlier, the mixing back is dropped into to stir in the reaction kettle and is homogeneous solution;
(2) add borax and EDDHA sequestrant according to above prescription, the temperature chelating 1h with 60 ℃ processes chelating liquid;
(3) according to prescription, in chelating liquid, add bioactive peptide and Frosst), stir 0.5h;
(4) at room temperature with 100 purpose strainer filterings, the filtrating that obtains is described organic titanium-potassium fertilizer.
More than among each embodiment used organic chelated titanium can from market, directly buy; Also can directly prepare; The preparation method of said organic chelated titanium is: using butyl(tetra)titanate and methyl ethyl diketone is mixing in 1: 2 with the mole proportioning; And form chelating liquid with 40-60 ℃ of low-grade fever chelating, and be 95% terepthaloyl moietie with mol ratio with analytically pure glacial acetic acid and massfraction again be to mix at 1: 1 to form mixture, treat then after the chelating liquid cooling but the mass ratio mixing of mixture and chelating liquid with 1: 1; Stirring obtains faint yellow limpid liquid, is dried to solid with 80 ℃ and promptly obtains organic chelated titanium.
Organic titanium-potassium fertilizer of the present invention has following characteristics:
(1) property in full force and effect on the composition: the small organic molecule matter in the organic titanium-potassium fertilizer is the beneficiating ingredient that can be utilized fully by crop.Potassium is one of required macroelement of plant growth, and it improves effects such as product quality and enhancing crop resistance by extensive understanding.Titanium is a kind of transition metal; By the metal of the unique permission implant into body of WHO (WHO); Titanium is one of teleorganic element, and the inner complex of titanium is one of most important method of whole world increases in grain production, and plant is one of important factor that influences its growth to the absorption of titanium.Organic chelated titanium with main effect be to promote crop photosynthesis effect and respiration, combine organic matter (like glucose) and humic acid in soil, soil to be played better activatory effect; Biologically active peptides has good absorptivity; Its assimilated efficiency is all higher than amino acid and protein; It also has unique physiological regulation function, and activity is very high, and often very little amount just can play very big effect; And it is to the human body beneficial, and the biologist is called the biologically active substance of good reputations such as the favorite of human health " 21st century ", " angel of happy mystery ", " soul of life ", " the most promising heath food ".
(2) environmental protection: the present invention efficiently utilizes the resource of potassium and other fertilizer, and agricultural-food, soil and environment are not produced any residue, is a kind of environmental friend fertilizer;
(3) safe in utilization: because organic chelated titanium can change into all inorganic and organic element the nutrient of plant, can be relieved use at the plant florescence, and can not cause plant fallen flowers, burn the leaf phenomenon.Evade a lot of fertilizer florescences and can not use drawback;
(4) easy to use: the pH value of organic titanium-potassium fertilizer is 6-8, can mix use with any acid-basicity agricultural chemicals, has evaded other liquid fertilizers and the mineral manure out of use problem of the inclined to one side alkali of meta-acid in use, has practiced thrift the time to the operator.And this fertilizer overcome the effect that other liquid fertilizers can only simply spray in operation, and organic titanium-potassium fertilizer can spray, irritates that root, base are executed, topdressed, drip irrigation, seed soaking and seed dressing, and operational selectivity is provided, and uses convenient;
(5) organic titanium-potassium fertilizer changes into the required nutrition of plant with inorganic deleterious element, has improved the nutrition of plant, has reduced the infringement of harmful element; Add that the content of potassium element is the premier high-content fertilizer in present domestic and international market in the product, reinforced the ability of crop resistance disease, the removal of harmful element in the soil; Thereby make loosing soil; Permeability strengthens, and the nutrient in the soil is activated, and is fabulous by crop utilization;
(6) the present invention has improved that other utilization rate of fertilizer are low to absorb slow volatile weak point, and thiophene ketone wherein is a kind of new and effective nontoxic infiltration accelerating agent, and thiophene ketone short oozed the infiltration accelerating agent azone that effect is better than present widespread use, and the short effect of oozing is 3 times of azone.Can break the outer field colloid of plant effectively fast, let organic carrier carry nutritive substance very soon and get in the plant materials, almost completely by plant absorbing, specific absorption reaches more than 90%, has improved the absorption rate more than the 5-20% than other potash fertilizer in one hour.The peptide compound that to be two or more amino acid link to each other with peptide bond is the high a kind of brand-new nutrition of tiring of between macro-molecular protein and amino acid a section tool activity, the easiest absorption, physiological function.Peptide is than other materials such as amino acid, protein, oligose, and maximum characteristics are to have extremely strong activity and variety, worldwide cause concern, have become the new focus of high section industry so far.Sugar alcohol is the polyvalent alcohol that contains plural hydroxyl; But sugar alcohol and petrochemical complex synthetic terepthaloyl moietie, Ucar 35, to defend polyvalent alcohols such as tetrol season different; Sugar alcohol is that the reproducible carbohydrate with nature 1 year all one's life is a raw material, and it is inexhaustible to originate, and with low cost.Aldehyde radical on the glycan molecule or ketone group are reduced into hydroxyl, just become sugar alcohol, sugar alcohol to be called the sugar substitute.
In sum; The present invention successively in Shaanxi, ground such as Guangxi, Sichuan have done hundreds of tests, remarkably productive significantly, can increase production and reach about 15%～60%; And each item index has all reached the high target of company's research and development; High-content meets China and world agriculture development situation, can make outstanding contribution for China's ecological agriculture and common people very soon.Therefore all have international advanced, leading domestic status on the content of this invention effective ingredient, the function, leading in world's liquid fertilizer ranks.
Claims (6)
1. an organic titanium-potassium fertilizer is characterized in that, is solvent with water, in every premium on currency, contains following component respectively:
Organic chelated titanium 5～100g, glucose 75～200g, Tripotassium Citrate 600～800g, borax or boric acid 0～130g, humic acid or potassium humate 0～90g, EDDHA sequestrant 0～60g and auxiliary agent 7～12g;
The mass concentration of said glucose is 99%; Said Tripotassium Citrate is the technical grade Tripotassium Citrate; Said borax is the technical grade borax; Said auxiliary agent is one or more mixtures of bioactive peptide, plug ketone, Frosst);
According to the formula ratio of each component, each component except that EDDHA sequestrant, borax or boric acid and auxiliary agent is mixed, drop in the reaction kettle, and add the uniform solution of entry stirring formation; Add borax or boric acid and EDDHA sequestrant according to formula ratio then, the temperature chelating 1-2h with 40-60 ℃ processes chelating liquid; In chelating liquid, add auxiliary agent, stir 0.5～1h; At room temperature with 80-100 purpose strainer filtering, the filtrating that obtains is organic titanium-potassium fertilizer at last.
2. organic titanium-potassium fertilizer according to claim 1 is characterized in that, with one or more mixture replacing glucose of sucrose, sugar alcohol and Polysaccharides, peptide complexes.
3. organic titanium-potassium fertilizer according to claim 1 is characterized in that, the quality of organic matter content of said humic acid is 45～65%, and the mass content of moisture is less than 15%, and fineness is the 80-100 order.
4. organic titanium-potassium fertilizer according to claim 1 is characterized in that, substitutes Tripotassium Citrate with saltpetre or Potassium ethanoate, and said saltpetre and Potassium ethanoate are technical grade.
5. organic titanium-potassium fertilizer according to claim 1 is characterized in that, with the mixture replacing Tripotassium Citrate of Hydrocerol A and Pottasium Hydroxide, said Hydrocerol A and Pottasium Hydroxide mol ratio are 1: 3.
6. the preparation method of the said organic titanium-potassium fertilizer of claim 1 is characterized in that, carries out according to following steps:
(1) according to the formula ratio of each component, each component except that EDDHA sequestrant, borax or boric acid and auxiliary agent is mixed, drop in the reaction kettle, and add the uniform solution of entry stirring formation;
(2) add borax or boric acid and EDDHA sequestrant according to formula ratio, the temperature chelating 1-2h with 40-60 ℃ processes chelating liquid;
(3) in chelating liquid, add auxiliary agent, stir 0.5～1h;
(4) at room temperature with 80-100 purpose strainer filtering, the filtrating that obtains is organic titanium-potassium fertilizer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100229359A CN101575245B (en) | 2009-06-12 | 2009-06-12 | Organic titanium-potassium fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100229359A CN101575245B (en) | 2009-06-12 | 2009-06-12 | Organic titanium-potassium fertilizer and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101575245A CN101575245A (en) | 2009-11-11 |
| CN101575245B true CN101575245B (en) | 2012-07-04 |
Family
ID=41270338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009100229359A Expired - Fee Related CN101575245B (en) | 2009-06-12 | 2009-06-12 | Organic titanium-potassium fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101575245B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531771B (en) * | 2011-12-13 | 2013-11-13 | 福州超大现代农业发展有限公司 | Method for preparing organic titanium-organic potassium salt organic fertilizer by salting-out process |
| CN102557822B (en) * | 2011-12-13 | 2013-11-13 | 福州超大现代农业发展有限公司 | Method for preparing urea peroxide containing organic titanium by recrystallization process |
| CN102557826B (en) * | 2011-12-13 | 2014-03-19 | 福州超大现代农业发展有限公司 | Method for preparing organic titanium-chitooligosaccharide potassium salt biological fertilizer through salting-out process |
| CN102531773B (en) * | 2011-12-13 | 2014-03-19 | 福建超大现代种业有限公司 | Manufacturing method of oxygenation type seed treatment agent containing titanium superoxide |
| CN102557818B (en) * | 2011-12-13 | 2013-11-13 | 福州超大现代农业发展有限公司 | Method for preparing fulvic acid ammonium phosphate fertilizer containing organic titanium through recrystallization process |
| CN102531769B (en) * | 2011-12-13 | 2013-11-13 | 福州超大现代农业发展有限公司 | Method for preparing potassium fulvate phosphate fertilizer containing organic titanium by recrystallization process |
| CN102557825B (en) * | 2011-12-13 | 2013-11-13 | 福建超大集团有限公司 | Method for preparing trace element fertilizer containing organic titanium through microwave chelating process |
| CN102531770B (en) * | 2011-12-13 | 2013-11-13 | 福建超大集团有限公司 | Method for preparing organic titanium-containing potassium borate fertilizer by recrystallization process |
| CN102887779A (en) * | 2012-11-08 | 2013-01-23 | 广西新方向化学工业有限公司 | Liquid fertilizer containing many kinds of phytols and medium-trace elements and preparation method thereof |
| CN105439707A (en) * | 2015-12-10 | 2016-03-30 | 马鞍山科邦生态肥有限公司 | Highly efficient fertilizer for reducing cost of illumination for greenhouse vegetable cultivation and preparation method thereof |
| CN106007974A (en) * | 2016-05-25 | 2016-10-12 | 广德县新农民水稻种植专业合作社 | Special culture substrate for rapes |
| CN106190134A (en) * | 2016-06-30 | 2016-12-07 | 山东胜伟园林科技有限公司 | A kind of anti-salt alkali composition containing Rhizoma Dioscoreae extract and preparation method thereof |
| CN106431685A (en) * | 2016-10-13 | 2017-02-22 | 郝杰 | Novel chemical fertilizercontainingpotassium, enzyme and titanium |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| CN1534003A (en) * | 2003-04-01 | 2004-10-06 | 雁 栾 | Animal and plant high effect ecological nutritive liquid and its preparation method |
-
2009
- 2009-06-12 CN CN2009100229359A patent/CN101575245B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1176954A (en) * | 1996-09-17 | 1998-03-25 | 裴圣镐 | Multi-element and composite tiltanium trace element fertilizer |
| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| CN1534003A (en) * | 2003-04-01 | 2004-10-06 | 雁 栾 | Animal and plant high effect ecological nutritive liquid and its preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101575245A (en) | 2009-11-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101575245B (en) | Organic titanium-potassium fertilizer and preparation method thereof | |
| CN101575230B (en) | Organic titanium-boron fertilizer and preparation method thereof | |
| CN102167634B (en) | Oligosaccharide-containing foliar fertilizer composite and application thereof | |
| CN102229511B (en) | Rapid long-acting humic acid multivariate fertilizer and production method thereof | |
| CN105254452A (en) | Fertilizer for fruit trees and production method of fertilizer | |
| CN101857472A (en) | Foliar compound fertilizer and preparation method thereof | |
| CN110498717A (en) | A kind of mineral resources potassium fulvate water-soluble fertilizer and preparation method thereof | |
| CN101805226A (en) | Plant foliar fertilizer | |
| CN101935243B (en) | High-water-solubility organic fertilizer | |
| CN111995465B (en) | Heavy metal blocking agent, application and use method thereof | |
| CN108440138A (en) | Compound colloidal solid leaf surface trace fertilizer of sugar alcohol zinc boron molybdenum manganese and preparation method thereof | |
| CN103641640A (en) | Activity-enhanced algae microorganism fertilizer and preparation method thereof | |
| CN105036926A (en) | Foliar nutrient special for tea-oil trees and application thereof | |
| CN110240518A (en) | A kind of high-efficiency multi-function plant leaf surface sprays hyperconcetration fertilizer and preparation method thereof | |
| CN109704876A (en) | A kind of water-soluble fertilizer synergistic composition and its preparation method and application | |
| CN104230514A (en) | Earthworm hydrolysate and rare earth compound active foliar liquid fertilizer as well as preparation method and using method thereof | |
| CN102219616A (en) | Natural conditioner functioning in soil conditioning and fertilizing | |
| CN102887794A (en) | Nitrogen-phosphorus-potassium high-concentration liquid fertilizer containing synergist and preparation method thereof | |
| CN102260120A (en) | Chelated multi-element foliage fertilizer and preparation method thereof | |
| CN101152989A (en) | Drought resisting accretion modifying agent for yellow humic acid plants | |
| CN101597194A (en) | A kind of raising stress resistance of plant high-nutrition foliage fertilizer | |
| CN105646084A (en) | Instant microelement water-soluble fertilizer capable of increasing soil organic matter content | |
| CN103193526A (en) | Preparation method of potassium yellowish-brown humate from lignite humic acid | |
| CN106396802A (en) | Composite amino acid chelated trace element water-soluble fertilizer and preparation method thereof | |
| CN105453883A (en) | Maca cultivation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: YULIN YUYANG HAOPOYI AGRICULTURAL TECHNOLOGY CO., Free format text: FORMER OWNER: SHANXI HUIRUIDE AGRICULTURE TECHNOLOGY CO., LTD. Effective date: 20130717 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Han Hui Inventor before: Han Hui Inventor before: Sun Qiang Inventor before: Yang Zhen |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: HAN HUI SUN QIANG YANG ZHEN TO: HAN HUI Free format text: CORRECT: ADDRESS; FROM: 710048 XI AN, SHAANXI PROVINCE TO: 719000 YULIN, SHAANXI PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20130717 Address after: 719000 Yao village, Guta Township, Yuyang District, Shaanxi, Yulin Patentee after: Yulin city Yuyang District Poyi good agricultural science and Technology Co Ltd Address before: 710048, 68, dragon road, persimmon Road, Xi'an, Shaanxi Patentee before: Shanxi Huiruide Agriculture Technology Co., Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120704 Termination date: 20150612 |
|
| EXPY | Termination of patent right or utility model |