CN101563409B - 可发泡含氟聚合物组合物 - Google Patents
可发泡含氟聚合物组合物 Download PDFInfo
- Publication number
- CN101563409B CN101563409B CN2007800472477A CN200780047247A CN101563409B CN 101563409 B CN101563409 B CN 101563409B CN 2007800472477 A CN2007800472477 A CN 2007800472477A CN 200780047247 A CN200780047247 A CN 200780047247A CN 101563409 B CN101563409 B CN 101563409B
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- China
- Prior art keywords
- composition
- fluoropolymer
- foam
- per
- combination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 229920002313 fluoropolymer Polymers 0.000 title claims description 59
- 239000004811 fluoropolymer Substances 0.000 title claims description 58
- 239000006260 foam Substances 0.000 claims abstract description 62
- 206010000269 abscess Diseases 0.000 claims description 30
- 239000002131 composite material Substances 0.000 claims description 30
- 230000006911 nucleation Effects 0.000 claims description 29
- 238000010899 nucleation Methods 0.000 claims description 29
- 239000000126 substance Substances 0.000 claims description 23
- -1 alkyl vinyl ether Chemical compound 0.000 claims description 19
- 239000011148 porous material Substances 0.000 claims description 15
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 8
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 229910052582 BN Inorganic materials 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052801 chlorine Inorganic materials 0.000 claims description 6
- FJKIXWOMBXYWOQ-UHFFFAOYSA-N ethenoxyethane Chemical compound CCOC=C FJKIXWOMBXYWOQ-UHFFFAOYSA-N 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 150000001457 metallic cations Chemical class 0.000 claims description 5
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 claims description 5
- OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- 125000002091 cationic group Chemical group 0.000 claims description 4
- KKKYJLNWARAYSD-UHFFFAOYSA-N hexacalcium;tetraborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-] KKKYJLNWARAYSD-UHFFFAOYSA-N 0.000 claims description 4
- 150000003009 phosphonic acids Chemical class 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 3
- 229910052794 bromium Inorganic materials 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229910052698 phosphorus Chemical group 0.000 claims description 3
- 239000011574 phosphorus Chemical group 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 238000012360 testing method Methods 0.000 claims description 2
- 159000000009 barium salts Chemical class 0.000 claims 3
- 210000000497 foam cell Anatomy 0.000 abstract 2
- 229920005548 perfluoropolymer Polymers 0.000 abstract 2
- 210000004027 cell Anatomy 0.000 abstract 1
- 239000004020 conductor Substances 0.000 description 61
- 238000009413 insulation Methods 0.000 description 31
- 230000001413 cellular effect Effects 0.000 description 13
- 239000012212 insulator Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 239000007787 solid Substances 0.000 description 9
- 229920001169 thermoplastic Polymers 0.000 description 9
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 230000006835 compression Effects 0.000 description 7
- 238000007906 compression Methods 0.000 description 7
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 239000004416 thermosoftening plastic Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000011810 insulating material Substances 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910001414 potassium ion Inorganic materials 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000008247 solid mixture Substances 0.000 description 3
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- 239000004160 Ammonium persulphate Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 101100005280 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) cat-3 gene Proteins 0.000 description 2
- 239000004159 Potassium persulphate Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 235000019395 ammonium persulphate Nutrition 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000006855 networking Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
- 235000019394 potassium persulphate Nutrition 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000004876 x-ray fluorescence Methods 0.000 description 2
- 244000287680 Garcinia dulcis Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000012491 analyte Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000003709 fluoroalkyl group Chemical group 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010128 melt processing Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000190 proton-induced X-ray emission spectroscopy Methods 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000011885 synergistic combination Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US87621906P | 2006-12-21 | 2006-12-21 | |
| US60/876,219 | 2006-12-21 | ||
| PCT/US2007/026000 WO2008079264A2 (en) | 2006-12-21 | 2007-12-20 | Foamable fluoropolymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101563409A CN101563409A (zh) | 2009-10-21 |
| CN101563409B true CN101563409B (zh) | 2013-07-24 |
Family
ID=39345419
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800472477A Active CN101563409B (zh) | 2006-12-21 | 2007-12-20 | 可发泡含氟聚合物组合物 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US20080149899A1 (enExample) |
| EP (1) | EP2102275B1 (enExample) |
| JP (1) | JP5478257B2 (enExample) |
| CN (1) | CN101563409B (enExample) |
| WO (1) | WO2008079264A2 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080153936A1 (en) * | 2006-12-21 | 2008-06-26 | E. I. Du Pont De Nemours And Company | Foamed Fluoropolymer Article |
| US9293241B2 (en) * | 2009-10-08 | 2016-03-22 | General Cable Technologies Corporation | Communication cable |
| JP5766415B2 (ja) * | 2010-07-23 | 2015-08-19 | 矢崎総業株式会社 | ワイヤハーネス |
| US10246572B2 (en) * | 2010-12-16 | 2019-04-02 | Solvay Specialty Polymers Italy S.P.A. | Foamable fluoropolymer compositions |
| CN103748175A (zh) * | 2011-06-30 | 2014-04-23 | 美国圣戈班性能塑料公司 | 能熔融加工的组合物及制造方法 |
| KR20140120350A (ko) * | 2012-01-27 | 2014-10-13 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 폼 절연 전도체 |
| WO2014115623A1 (ja) | 2013-01-24 | 2014-07-31 | ダイキン工業株式会社 | 組成物、並びに、発泡成形体及び電線の製造方法 |
| CN104955892B (zh) * | 2013-01-24 | 2019-03-12 | 大金工业株式会社 | 组合物以及发泡成型体和电线的制造方法 |
| EP3256501B1 (en) | 2015-02-12 | 2018-12-12 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups and methods of making and using the same |
| WO2016130914A1 (en) | 2015-02-12 | 2016-08-18 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers including perfluoroalkoxyalkyl pendant groups |
| WO2016130900A1 (en) | 2015-02-12 | 2016-08-18 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers having pendant sulfonyl groups |
| WO2025099650A1 (en) * | 2023-11-08 | 2025-05-15 | Daikin America, Inc. | System and method for forming wire and cable |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1066858A (zh) * | 1991-05-20 | 1992-12-09 | 纳幕尔杜邦公司 | 发泡剂组合物及生产发泡材料的方法 |
| US5610203A (en) * | 1996-04-10 | 1997-03-11 | E. I. Du Pont De Nemours And Company | Foamable fluoropolymer composition |
| CN1639254A (zh) * | 2001-06-26 | 2005-07-13 | 大金工业株式会社 | 树脂组合物、其制备方法和泡沫绝缘电线 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743658A (en) * | 1985-10-21 | 1988-05-10 | E. I. Du Pont De Nemours And Company | Stable tetrafluoroethylene copolymers |
| US4761256A (en) * | 1987-01-27 | 1988-08-02 | Eastman Kodak Company | Method for producing microcellular foamed plastic material with smooth integral skin |
| US4764538A (en) * | 1987-12-16 | 1988-08-16 | E. I. Du Pont De Nemours And Company | Foam nucleation system for fluoropolymers |
| US5182343A (en) * | 1988-04-15 | 1993-01-26 | Japan Synthetic Rubber Co., Ltd. | Homopolymers of sulfonated isoprene and 1,3-butadiene and agents containing the same |
| ATE170895T1 (de) * | 1989-02-17 | 1998-09-15 | Du Pont | Keimbildungsmittel für thermoplastische kunstharze |
| US4877815A (en) * | 1989-02-17 | 1989-10-31 | E. I. Du Pont De Nemours And Company | Nucleating agents for thermoplastic resins |
| WO1992021129A1 (fr) * | 1991-05-17 | 1992-11-26 | The Furukawa Electric Co., Ltd. | Procede de fabrication d'une mousse servant a isoler un fil electrique |
| US5182342A (en) | 1992-02-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon solvents for fluoromonomer polymerization |
| JP3109523B2 (ja) * | 1992-08-28 | 2000-11-20 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | テトラフルオロエチレンのコポリマーを含むゲル |
| US5677404A (en) * | 1996-02-23 | 1997-10-14 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene terpolymer |
| US5821273A (en) * | 1996-05-22 | 1998-10-13 | E. I. Du Pont De Nemours And Company | Extrusion foaming of fluoropolymers |
| US5885494A (en) * | 1996-05-22 | 1999-03-23 | E. I. Du Pont De Nemours And Company | Method of forming foamed fluoropolymer composites |
| DE69717465T2 (de) * | 1996-08-27 | 2003-07-10 | Trexel, Inc. | Verfahren und vorrichtung zum extrudieren von polymerschaum, insbesondere mikrozellenschaum |
| US5726214A (en) * | 1996-12-26 | 1998-03-10 | E. I. Du Pont De Nemours And Company | Self-foaming fluoropolymer composition |
| SE9802087D0 (sv) * | 1998-06-12 | 1998-06-12 | Borealis Polymers Oy | An insulating composition for communication cables |
| DE19903657A1 (de) * | 1999-01-29 | 2000-08-03 | Dyneon Gmbh | Tetrafluorethylen/Hexafluorpropylen-Copolymere mit besserer Aufziehbarkeit |
| TR200102130T2 (tr) | 1999-01-29 | 2001-12-21 | Dyneon Gmbh & Co. Kg | Tetrafluor etilen / hesafluor profilen kopolimerleri |
| US6541588B1 (en) * | 1999-01-29 | 2003-04-01 | 3M Innovative Properties Company | Tetrafluoroethylene/hexafluoropropylene copolymers with higher drawability |
| US6395795B1 (en) * | 2000-09-29 | 2002-05-28 | Ausimont Usa, Inc. | Titanium dioxide nucleating agent systems for foamable polymer compositions |
| US6838545B2 (en) * | 2002-11-08 | 2005-01-04 | E. I. Du Pont De Nemours And Company | Reaction of fluoropolymer melts |
| US20040242819A1 (en) * | 2003-05-14 | 2004-12-02 | Earnest Thomas Robert | High melt flow fluoropolymer |
| US20080161435A1 (en) * | 2006-12-21 | 2008-07-03 | E. I. Du Pont De Nemours And Company | Extrusion of a Foamable Fluoropolymer |
-
2007
- 2007-12-19 US US11/959,617 patent/US20080149899A1/en not_active Abandoned
- 2007-12-20 CN CN2007800472477A patent/CN101563409B/zh active Active
- 2007-12-20 JP JP2009542911A patent/JP5478257B2/ja active Active
- 2007-12-20 EP EP07867852.1A patent/EP2102275B1/en active Active
- 2007-12-20 WO PCT/US2007/026000 patent/WO2008079264A2/en not_active Ceased
-
2009
- 2009-03-24 US US12/409,834 patent/US8354461B2/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1066858A (zh) * | 1991-05-20 | 1992-12-09 | 纳幕尔杜邦公司 | 发泡剂组合物及生产发泡材料的方法 |
| US5610203A (en) * | 1996-04-10 | 1997-03-11 | E. I. Du Pont De Nemours And Company | Foamable fluoropolymer composition |
| CN1639254A (zh) * | 2001-06-26 | 2005-07-13 | 大金工业株式会社 | 树脂组合物、其制备方法和泡沫绝缘电线 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101563409A (zh) | 2009-10-21 |
| US20080149899A1 (en) | 2008-06-26 |
| US20090186956A1 (en) | 2009-07-23 |
| EP2102275A2 (en) | 2009-09-23 |
| JP2010513677A (ja) | 2010-04-30 |
| US8354461B2 (en) | 2013-01-15 |
| WO2008079264A2 (en) | 2008-07-03 |
| JP5478257B2 (ja) | 2014-04-23 |
| WO2008079264A3 (en) | 2009-01-15 |
| EP2102275B1 (en) | 2016-09-28 |
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